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At least 37 records · Page 2

Hydrogen Sensor via Plasma Techniques Development

Currently, NASA Kennedy Space Center’s Exploration Ground Systems (EGS) uses liquid hydrogen (LH2) as fuel for launches and ensures hydrogen is no longer in the fill lines by sampling gas into a controlled environment. Then they use a catalytic sensor that detects when hydrogen interacts with oxygen. However, this procedure requires repeatedly backfilling and flushing with helium, which can be wasteful during a global helium shortage and expensive for each sampling port. Therefore, the team at KSC set out to establish proof-of-concept of a plasma-based hydrogen sensor that is anaerobic – and can in fact detect in most environments and below atmospheric pressures – and with a small footprint and more sensitive than other hydrogen sensors currently on the market. The technology development was done by testing known concentrations of hydrogen in argon gas fed through a vacuum cube containing an electrode feedthrough at varying pressures. The resultant emission spectra were recorded with a fiber optic spectrometer and analyzed to determine the instrument's accuracy. Throughout testing, efforts were made to prove the off-the-shelf capabilities of the setup. The traditional high voltage AC-power source was switched to an affordable, handheld plasma lighter. Additionally, the spectrometer was supplemented with a double photodiode circuit to take targeted measurements of the Balmer-α and - β lines in the hydrogen spectrum. From this, we established a proof of concept sensor. SLS required it to detect as low as 100 ppm whereas we detected hydrogen in concentrations as low as 50 ppm and in an anaerobic environment.

plasma↗

NREL Hydrogen Sensor Testing Laboratory

Relevance: Detection is recognized as a critical element for hydrogen facility safety design and supports risk mitigation. Detection methodologies will support validation of H2 behavior research. Hydrogen point sensors play a critical role for safety and process monitoring, but other methodologies can be developed. Approach: NREL Sensor Laboratory tests and verifies sensor performance for manufacturers, developers, end-users, regulatory agencies and SDOs/CDOs NREL deployment activity supports regulatory requirement verification, hydrogen behavior models, and method development for use by stakeholders. Accomplishments and Progress: NREL's R&D accomplishments have supported developers, industry, and SDOs by providing sensor performance and deployment expertise not otherwise available. Development of alternative detection strategies for hydrogen applications have been initiated. HyWAM and advanced detection methodologies deployments at H2@Scale Facilities are being implemented. Collaborations: Collaboration with government laboratories, universities, private organizations and regulatory agencies has leveraged the NREL Sensor Laboratory's success in advancing hydrogen safety sensors and process control. Proposed Future Work: NREL will support hydrogen deployment by the proper implementation of hydrogen sensors and advanced detection strategies. NREL will continue to support science-based codes and standards. This effort will be guided by the needs of the hydrogen community.

codes and standards↗

Thin Film Hydrogen Sensor Development, Testing and Integration Into Low Cost Wireless Sensing Systems (SBIR Phase 1 Final Report)

Element One, Inc. is reporting on the results of its DOE SBIR Phase I project for the development and testing of low-cost thin film hydrogen sensors and their subsequent integration into wireless sensing systems and networks. This work is based on Element One’s chemo-chromic sensing technology which indicates hydrogen presence (leaks) colorimetrically and electronically with no power required. The lack of required power makes them particularly suitable for passive Radio Frequency Identification Device (RFID) technology which can be deployed affordably and abundantly to detect leaks in hazardous environments. Element One built upon its experience with chemochromic materials that change color in the presence of hydrogen. Both thin films and pigments have been used, but thin films have the ability to change conductivity by more than three orders of magnitude making them ideal for resistive sensors. Prototype sensors were fabricated, tested and characterized. For the wireless component, Element One partnered with Esensor, Inc. to construct and test a wireless sensing network. The network was tested and validated at the National Renewable Energy Laboratory (NREL) in February and March. The tests involved exposing the wireless system to hydrogen gas concentrations of 1% and 5%. There were no significant problems encountered, and the system is ready for commercial development. The system demonstrated the viability of wireless hydrogen sensing networks for hydrogen leak detection and other applications.

08 HYDROGEN↗

Chemochromic Hydrogen Sensors

As fossil fuel supplies decline, hydrogen is quickly becoming an increasingly important fuel source. Currently hydrogen is the prime fuel of today's space vehicles (e.g., Space Shuttle) and featured as a fuel for some prototype vehicles such as the BMW seven series model. Hydrogen is a colorless, odorless gas with a 4% lower explosive limit which makes leak detection a priority. In an effort to support the use of hydrogen, a chemochromic (color changing) sensor was developed that is robust, simple to use, and does not require active operation. It can be made into a thin tape which can be conveniently used for leak detection at flanges, valves, or outlets. Chemochromic sensors can be either reversible or irreversible; however, irreversible chemochromic sensors will be analyzed in this report. The irreversible sensor is useful during hazardous operations when personnel cannot be present. To actively monitor leaks, testing of the irreversible sensor against environmental effects was completed and results indicated this material is suitable for outdoor use in the harsh beachside environment of Kennedy Space Center. The experiments in this report will give additional results to the environmental testing by adding solid rocket booster residue as a variable. The primary motivation for these experiments is to prepare the sensors for the launch pad environment at the Kennedy Space Center. In an effort to simulate the atmosphere at the pads before and after launch, the chemochromic sensors are exposed to solid rocket residue under various conditions.

Wiggins, Bryan C.↗

Hydrogen Research for Spaceport and Space-Based Applications: Hydrogen Sensors and Systems

The activities presented are a broad based approach to advancing key hydrogen related technologies in areas such as fuel cells, hydrogen production, and distributed sensors for hydrogen-leak detection, laser instrumentation for hydrogen-leak detection, and cryogenic transport and storage. Presented are the results from research projects, education and outreach activities, system and trade studies. The work will aid in advancing the state-of-the-art for several critical technologies related to the implementation of a hydrogen infrastructure. Activities conducted are relevant to a number of propulsion and power systems for terrestrial, aeronautics and aerospace applications. Sensor systems research was focused on hydrogen leak detection and smart sensors with adaptive feedback control for fuel cells. The goal was to integrate multifunction smart sensors, low-power high-efficiency wireless circuits, energy harvesting devices, and power management circuits in one module. Activities were focused on testing and demonstrating sensors in a realistic environment while also bringing them closer to production and commercial viability for eventual use in the actual operating environment.

Anderson, Tim↗

Fabrication method for a room temperature hydrogen sensor

A sensor for selectively determining the presence and measuring the amount of hydrogen in the vicinity of the sensor. The sensor comprises a MEMS device coated with a nanostructured thin film of indium oxide doped tin oxide with an over layer of nanostructured barium cerate with platinum catalyst nanoparticles. Initial exposure to a UV light source, at room temperature, causes burning of organic residues present on the sensor surface and provides a clean surface for sensing hydrogen at room temperature. A giant room temperature hydrogen sensitivity is observed after making the UV source off. The hydrogen sensor of the invention can be usefully employed for the detection of hydrogen in an environment susceptible to the incursion or generation of hydrogen and may be conveniently used at room temperature.

Seal, Sudipta↗

A High-Temperature Multipoint Hydrogen Sensor Using an Intrinsic Fabry–Perot Interferometer in Optical Fiber

This paper presents a multiplexable fiber optic chemical sensor with the capability of monitoring hydrogen gas concentration at high temperatures up to 750 °C. The Pd-nanoparticle infused TiO 2 films coated on intrinsic Fabry–Perot interferometer (IFPI) array were used as sensory films. Strains induced upon exposure to hydrogen with varied concentrations can be monitored by IFPI sensors. The fiber sensor shows a repetitive and reversible response when exposed to a low level (1–6%) of hydrogen gas. Uniform sensory behavior across all the sensing cavities is demonstrated and reported in this paper.

47 OTHER INSTRUMENTATION↗

A surface acoustic wave hydrogen sensor with tin doped indium oxide layers for intermediate temperatures

We report high temperature surface acoustic wave (SAW) gas sensors with conducting sensing layers require tuning of the sheet conductivity for optimal response. Conducting metal oxides are attractive sensing materials for their tunable electronic properties and high thermal stability, amongst others. Here, we have investigated the application of indium oxide (IO) and indium tin oxide (ITO) films on langasite (LGS)-based SAW reflective delay line sensor devices for monitoring hydrogen at 350 °C. Specifically, we modeled the effect of the IO and ITO sensing layer thickness on the wave velocity, attenuation, and effective electromechanical coefficient. This was followed by an experimental demonstration of tuning of the ITO film sheet conductivity by controlling the dopant concentration and yielding an improvement in the sensor sensitivity. The current study provides a pathway towards the development of conductivity-based sensing layers for high temperature SAW gas sensors with improved sensitivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Testing of In-Sodium Hydrogen Sensor

The goal of this project is to demonstrate diffusion-type in-sodium hydrogen meters (ISHMs) for real-time, in-situ monitoring of hydrogen concentration in molten sodium of a sodium-cooled fast reactor (SFR). The FY22 R&D efforts have been focused on (a) enhancement and fabrication of meshed ISHM prototype, (b) reconstruction of ISHM sodium test apparatus, (c) in-sodium test of meshed ISHM, and (d) ISHM performance and failure evaluations.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Color Changing Hydrogen Sensors

During the Space Shuttle Program, one of the most hazardous operation that occurred was the loading of liquid hydrogen (LH2) during fueling operations of the spacecraft. Due to hydrogen's low explosive limit, any amount leaked could lead to catastrophic event. Hydrogen's chemical properties make it ideal as a rocket fuel; however, the fuel is deemed unsafe for most commercial use because of the inability to easily detect the gas leaking. The increased use of hydrogen over traditional fossil fuels would reduce greenhouse gases and America's dependency on foreign oil. Therefore a technology that would improve safety at NASA and in the commercial sector while creating a new economic sector would have a huge impact to NASA's mission. The Chemochromic Detector for sensing hydrogen gas leakage is a color-changing detector that is useful in any application where it is important to know not only the presence but also the location of the hydrogen gas leak. This technology utilizes a chemochromicpigment and polymer matrix that can be molded or spun into rigid or pliable shapes useable in variable temperature environments including atmospheres of inert gas, hydrogen gas, or mixtures of gases. A change in color of the detector material indicates where gaseous hydrogen leaks are occurring. The irreversible sensor has a dramatic color change from beige to dark grey and remains dark grey after exposure. A reversible pigment changes from white to blue in the presence of hydrogen and reverts back to white in the presence of oxygen. Both versions of the sensor's pigments were comprised of a mixture of a metal oxide substrate and a hydro-chromic compound (i.e., the compound that changed color in the presence of hydrogen) and immediately notified the operator of the presence of low levels of hydrogen. The detector can be used in a variety of formats including paint, tape, caulking, injection molded parts, textiles and fabrics, composites, and films. This technology brings numerous benefits over the traditional hydrogen sensors: The technology has excellent temperature stability (4K to 373 K), it can be used in cryogenic fluid applications, it is easy to apply and remove; it requires no power to operate; it has a quick response time; the leak points can be detected visually or electronically; it is nonhazardous, thus environmentally friendly; it can be reversible or irreversible; it does not require on-site monitoring; has a long shelf life; the detector is very durable; and the technology is inexpensive to manufacture.

Chemochromic sensor↗

NREL Hydrogen Sensor Testing Laboratory

The NREL Sensor Laboratory supports the HFTO's mission for the safe and efficient implementation of hydrogen as an energy carrier. Sensors are a critical element for a facility safety system by providing an early indication of unintended releases. Sensors can be used in process control applications (e.g., FQ verification). The Sensor Laboratory provides developers and end-users with an unbiased resource to validate sensor performance to application requirements. The Sensor Laboratory facilitates deployment through support of codes and standards development and safety research. The Sensor Laboratory supports advanced strategies for early leak detection.

detection↗

Sodium Hydrogen Sensor and Acoustic Flow Sensor Development

This report documents the development of diffusion-type hydrogen meters (DTHMs) as part of a steam generator leak detection system (SGLDS) of sodium-cooled fast reactors (SFR) and the demonstration of the capabilities of acoustic flowmeters, including a commercial UTFM (Flexim FLUXUS F721) and an Argonne HT acoustic flowmeter running on shear-to-longitudinal mode. It also evaluates two Argonne permanent magnet flowmeters (PMFMs).

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Liquid Hydrogen Sensor Considerations for Space Exploration

The on-orbit management of liquid hydrogen planned for the return to the moon will introduce new considerations not encountered in previous missions. This paper identifies critical liquid hydrogen sensing needs from the perspective of reliable on-orbit cryogenic fluid management, and contrasts the fundamental differences in fluid and thermodynamic behavior for ground-based versus on-orbit conditions. Opportunities for advanced sensor development and implementation are explored in the context of critical Exploration Architecture operations such as on-orbit storage, docking, and trans-lunar injection burn. Key sensing needs relative to these operations are also examined, including: liquid/vapor detection, thermodynamic condition monitoring, mass gauging, and leak detection. Finally, operational aspects of an integrated system health management approach are discussed to highlight the potential impact on mission success.

Moran, Matthew E.↗

Development of Risk Mitigation Guidance for Hydrogen Sensor Placement Indoors and Outdoors

Guidance on Sensor Placement remains one of the top priorities for the safe deployment of hydrogen and fuel cell equipment in the commercial marketplace. Building on the success of Phase 1 work reported at ICHS2019 and published in IJHE, this paper discusses the consecutive steps to further develop and validate such guidance for mechanically ventilated enclosures. The key step included a more in-depth analysis of sensitivity to variation of physical parameters in a small enclosure, and finally, expansion of the developed approach to confined spaces in an outdoor environment.

codes and standards↗

New Gas Polarographic Hydrogen Sensor

Polarography is the measurement of the current that flows in solution as a function of an applied voltage. The actual form of the observed polarographic current depends upon the manner in which the voltage is applied and on the characteristics of the working electrode. The new gas polarographic H2 sensor shows a current level increment with concentration of the gaseous H2 similar to those relating to metal ions in liquid electrolytes in well-known polarography. This phenomenon is caused by the fact that the diffusion of the gaseous H2 through a gas diffusion hole built in the sensor is a rate-determining step in the gaseous-hydrogen sensing mechanism. The diffusion hole artificially limits the diffusion of the gaseous H2 toward the electrode located at the sensor cavity. This gas polarographic H2 sensor. is actually an electrochemical-pumping cell since the gaseous H2 is in fact pumped via the electrochemical driving force generated between the electrodes. Gaseous H2 enters the diffusion hole and reaches the first electrode (anode) located in the sensor cavity to be transformed into an H+ ions or protons; H+ ions pass through the electrolyte and reach the second electrode (cathode) to be reformed to gaseous H2. Gas polarographic 02 sensors are commercially available; a gas polarographic 02 sensor was used to prove the feasibility of building a new gas polarographic H2 sensor.

Dominguez, Jesus A.↗

The NREL Sensor Laboratory: Hydrogen Leak Detection for Large Scale Deployments: Preprint

The NREL Hydrogen Sensor Laboratory was commissioned in 2010 as a resource for sensor developers, end-users, and regulatory agencies within the national and international hydrogen community. The Laboratory continues to provide as its core capability the unbiased verification of hydrogen sensor performance to assure sensor availability and their proper use. However, the mission and strategy of the NREL Sensor Laboratory has evolved to meet the needs of the growing hydrogen market. The Sensor Laboratory program has expanded to support research in conventional and alternative detection methods as hydrogen use expands to large-scale markets as envisioned by the DOE National Clean Hydrogen Strategy and Roadmap. Current research encompasses advanced methods of hydrogen leak detection including stand-off and wide area monitoring approaches for large scale and distributed applications. In addition to safety applications, low-level detection strategies to support the potential environmental impacts of hydrogen and hydrogen product losses along the value chain are being explored. Many of these applications utilize detection strategies that supplement and may supplant the use of traditional point sensors. The latest results of the hydrogen detection strategy research at NREL will be presented.

detection↗

Ultra-fast and sensitive magneto-optical hydrogen sensors using a magnetic nano-cap array

Magnetism in curved nano-geometries has opened a new path to design novel characteristics and phenomena that could greatly impact the future fundamental and applied studies of materials. Here, in this report, a hexagonally-packed array of magnetic nano-caps (or nano-patches, NP) exhibiting unique magnetic anisotropy and optimal nanostructure for fast hydrogen kinetics is explored as a sensing element for the spark-free magnetic-circular-dichroism (MCD) H 2 sensor. The MCD H 2 sensor outperforms the state-of-the-art optical sensors reported to date and satisfies the most challenging performance targets imposed by US Department of Energy. In particular, a Pd 67 Co 33 NP sensor exhibits response time of t 90 < 0.9 s, recovery time of t 10 < 9.0 s over the 1-100 mbar H 2 partial pressure range, and limit of detection (LOD) of ~1 ppm. The LOD improves to <700 ppb, when the signal-to-noise ratio is enhanced by stacking three NP arrays. Using a 30-nm TAF (Teflon AF 2400) polymer coating, the sorption kinetics of the Pd 67 Co 33 /TAF sensor are significantly accelerated, with t 90 < 0.4 s and t 10 < 2.8 s over the same pressure range. When the Pd 67 Co 33 /TAF sensor is further coated with a 100-nm poly(methyl methacrylate) (PMMA) layer, a rapid sorption time of t 90 < 0.5 s, LOD < 1 ppm and excellent sensor accuracy (<2.5% full scale) are maintained, while the sensor obtains strong selectivity against interference gases and moisture and a negligible aging effect. The MCD nano-cap sensor platform may have a great impact on the future deployment of H 2 fuel, H 2 environmental monitoring sensors, and fast proton-based magneto-ionic devices.

Fast and sensitive hydrogen sensors↗