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At least 37 records · Page 2

Fabrication of Tantalum and Hafnium Carbide Fibers via Forcespinning TM for Ultrahigh‐Temperature Applications

In this work, a novel method for producing ultrafine tantalum and hafnium carbide fibers using the Forcespinning TM technique via a nonhalide‐based sol‐gel process was investigated. An optimal solution viscosity range was systematically determined via rheological studies of neat PAN/DMF as a function of fiber formation. Subsequently, Forcespinning TM parameters were also systemically studied to determine the optimal rotational velocity and spinneret‐to‐collecting rod distance required for ideal fiber formation. TaC and HfC fibers were synthesized via Forcespinning TM utilizing a mixture of PAN and refractory transition metal alkoxides (i.e., tantalum (V) ethoxide and hafnium (IV) tert‐butoxide) in DMF solution based on optimal conditions determined from the neat PAN/DMF. In all instances after calcination, powder X‐ray diffraction (PXRD) and energy dispersive spectroscopy (EDS) indicated that TaC and HfC fibers were produced. TGA/DSC confirmed the chemical stability of the resulting fibers.

Lee, Harold O.↗

Development of a Fuel Cell for the Perhydrodibenzyltoluene / Dibenzyltolluene Fuel Pair

An experimental study of the performance of an LFC with H-DBT and other cyclic hydrogenated aromatic fuels was carried out, along with a characterization of the fuel cell conversion products. A technoeconomic analysis (TEA) of the LFC operating in a class 8 truck powertrain using the H-DBT / DBT fuel pair was completed to determine the total cost of ownership (TCO), comparing LFC vehicles (LFCVs) to HFC vehicles (HFCVs), battery electric vehicles (BEVs), and diesel trucks on a pro-forma basis assuming the LFC could be developed to HFC benchmarks.

08 HYDROGEN↗

South Africa National Cooling Plan

South Africa is committed to preserving the environment and addressing climate change related issues based on science and equity. In 2019, South Africa ratified the Kigali Amendment to the Montreal Protocol to reduce the consumption and production of hydrofluorocarbons (HFCs) to simultaneously protect the ozone layer and contribute to mitigating climate change. In 2015, South Africa also signed the United Nations Framework Convention on Climate Change (UNFCCC) Paris Agreement to fight against climate change and committed to achieve a “peak, plateau and decline” greenhouse gas (GHG) trajectory at a level between 398 and 614 MtCO2e/year by 20301. In 2021 revised target ranges of 398-510 Mt CO 2 -eq for 2025, and 398-440 Mt CO 2 -eq for 2030 were issued, as well as aspiring to reach a net zero carbon economy by 2050. Addressing the environmental impacts of cooling products converges the objectives of these two treaties. Cooling products are the main source of HFC use and they consume a significant amount of electricity produced from emission intensive coal fired power plants. South Africa’s efforts to mitigate global warming can therefore be amplified if the energy efficiency (EE) of cooling products is improved at the same time a refrigerant transition from HFC is considered. Synergistic actions with respect to sustainable cooling access across sectors will have a higher impact than actions taken in isolation.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Performance Assessment of High-Efficiency Refrigerated Display Cases with Low-GWP Refrigerants: Preprint

As California policy makers enforce new regulations such as SB 1383 to achieve state greenhouse gas (GHG) reduction goals, it will be critical to understand the energy efficiency implications of low global warming potential (GWP) refrigerants in commercial refrigeration applications. The goal of this research project, funded by Commonwealth Edison was to assess the energy performance of two high efficiency medium-temperature, self-contained, reach-in display cases that utilized natural refrigerant propane (R-290), and hydrofluorocarbon (HFC) drop-in hydrofluoroolefin R-513a, respectively. Performance of these display cases were compared to a baseline fixture using HFC (R-134a) under equal conditions in a controlled environment chamber. These display cases were selected due to their widespread use in convenience stores, and small supermarkets. The high efficiency cases were equipped with energy efficient lighting, improved panel insulation, high efficiency evaporator and condenser fan motors, and high effectiveness heat exchangers. The test method used in this project was foundationally inspired by the ANSI/ASHRAE 72-2018 standard method to evaluate each case under equivalent conditions. However, minor modifications to this methodology were implemented to better represent more realistic operation of the units. While maintaining target product temperature, the energy efficient fixtures containing R-290 and R-513a consumed 61.8% to 32.6% less energy, respectively, than a baseline case using R-134a refrigerant. The daily energy consumption of the R-290, R-513a, and baseline display cases at the upper limit of environmental conditions was 4.30, 7.59, and 11.26 kWh/day, respectively.

alternative refrigerants↗

Performance Assessment of High-Efficiency Refrigerated Display Cases With Low Global Warming Potential Refrigerants

As California policy makers enforce new regulations such as SB 1383 to achieve state greenhouse gas reduction goals, it will be critical to understand the energy efficiency implications of low global warming potential (GWP) refrigerants in commercial refrigeration applications. The goal of this research project, funded by Commonwealth Edison, was to assess the energy performance of two high-efficiency medium-temperature, self-contained, reach-in display cases that utilized natural refrigerant propane (R-290, GWP = 3), and hydrofluorocarbon (HFC) drop-in hydrofluoroolefin R-513A (GWP = 573). Performance of these display cases was compared to a baseline fixture using HFC (R-134A, GWP = 1301) under equal conditions in a controlled environment chamber. These display cases were selected due to their widespread use in convenience stores and small supermarkets. The high-efficiency cases were equipped with energy-efficient lighting, improved panel insulation, high-efficiency evaporator and condenser fan motors, and high-effectiveness heat exchangers. The test method used in this project was foundationally inspired by the ANSI/ASHRAE 72-2018 standard method to evaluate each case under equivalent conditions (ASHRAE 2018). However, minor modifications to this methodology were implemented to better represent more realistic operation of the units. While maintaining equivalent target product temperature, the energy-efficient fixtures A (containing R-290, improved insulation, heat exchangers with a higher overall heat transfer coefficient (higher UA), and more efficient lighting and fan motors) and B (containing R-513A, improved fans, and higher UA-heat exchangers, and more efficient lighting and fan motors) consumed 61.8% to 32.6% less energy, respectively, than a baseline case using R-134A refrigerant. The daily energy consumption of the R-290, R-513A, and baseline display cases at the upper limit of environmental conditions was 4.30, 7.59, and 11.26 kWh/day, respectively.

alternative refrigerants↗

Initiation and Carbene Induced Radical Chain Reactions in CH 2 F 2 Pyrolysis

High temperature dissociations of organic molecules typically involve a competition between radical and molecular processes. In this work, we use a modeling, experiment, theory (MET) framework to characterize the high temperature thermal dissociation of CH 2 F 2 , a flammable hydrofluorocarbon (HFC) that finds widespread use as a refrigerant. Initiation in CH 2 F 2 proceeds via a molecular elimination channel; CH 2 F 2 →CHF+HF. Here we show that the subsequent self-reactions of the singlet carbene, CHF, are fast multichannel processes and a facile source of radicals that initiate rapid chain propagation reactions. These have a marked influence on the decomposition kinetics of CH 2 F 2 . The inclusion of these reactions brings the simulations into better agreement with the present and literature experiments. Additionally, flame simulations indicate that inclusion of the CHF+CHF multichannel reaction leads to a noticeable enhancement in predictions of laminar flame speeds, a key parameter that is used to determine the flammability of a refrigerant.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effects of radiation heat loss on planar and spherical hydrofluorocarbon/air flames

Hydrofluorocarbons (HFC), which are mildly flammable and pose potential fire risks, have received greater attention as a viable low global warming potential alternative to traditional refrigerant and fire-suppressant compounds. Therefore, there is a demand to accurately quantify their flammability and re-activity to establish proper safety metrics. Here, this study investigates the effects of radiation heat loss on slowly-propagating HFC/air laminar flames. Planar 1-D simulations of R-32/air and R-1234yf/air flames show significant reductions in laminar flame speed due to radiative heat losses from the flame zone. Simulations of spherically expanding flames (SEF) revealed that the radiation-induced flow needs to be considered when interpreting data from experiments. To this end, a Spherical-flame RADiation-Induced Flow (SRADIF) model was developed to estimate the burned gas inward flow velocities in constant-pressure SEFs, utilizing the optically thin limit assumption to model radiation heat loss. The model was validated against results from detailed numerical simulations of SEFs, from which radiation-induced inward flow was derived using a new formulation considering both the radiation heat loss and convective flow effects. Results show that SRADIF accurately predicts the inward flow velocity for R-32/air mixtures over a range of conditions and performs significantly better compared to existing analytical models. However, the model was unable to accurately predict flow velocities for R-1234yf/air flames and the reason for this is discussed. (224 words)

42 ENGINEERING↗

Review of the potential and challenges of MOF-based adsorption heat pumps for sustainable cooling and heating in the buildings

Heat pumps are regarded as the most suitable means to meet the future demand of heating and cooling in the building, as they require small input of electrical energy and output high thermal energy. Vapor compression heat pump (VCHP) and transcritical-CO 2 heat pump are the two major heat pump technologies currently dominating the market. However, VCHP system suffers from its fugitive emission of hydrofluorocarbon (HFC) refrigerants, and transcritical-CO 2 system requires high operating pressure (typically 9–13 MPa). For low-to-medium temperature heating and cooling applications thermally driven adsorption heat pump (AHP) provides a better alternative to VCHP and transcritical-CO 2 system as AHP uses natural refrigerants and operates at a much lower pressure. But currently available AHP technology has the limitation of low coefficient of performance (COP). Advances in synthesizing metal-organic frameworks (MOF) with high gas adsorption capacity have created an opportunity to address the problem of low COP of current AHP technology. Here, this article reviews the progress made in the past decade in utilizing MOF and conventional adsorbents with different working fluids in AHP technology and compares their performance. The article also summarizes the key challenges for the MOF-based AHP technology and provides the authors’ perspective to address these challenges.

30 DIRECT ENERGY CONVERSION↗

A Performance analysis of the Claridge-Culp-Liu dehumidification process: A novel approach for drying moist air based on membrane separation, vacuum compression and sub-atmospheric condensation

This article covers a basic model for analyzing the performance of the Claridge-Culp-Liu dehumidification process. The fundamental process efficiency limit for dehumidification is close to COP Carnot , but for the eight dehumidification cases examined, the limiting or ideal energy use required is 26% to 56% that of a Carnot condensing system as shown in an earlier paper. The model presented in this paper is used to show the membrane system performance reduction caused by finite membrane area, finite water vapor permeance, non-zero air permeance, non-zero system air pressure drop, non-ideal compressors, vacuum pumps, and condensers. The performance of a “conservative” membrane system based on the use of existing components is computed for eight specific conditions along with that of a “target” system that assumes expected component performance after additional future component development. The “conservative” membrane system would use 36% to 66% as much energy as a system with a COP=7 chiller to produce the same dehumidification for the eight cases examined while the “target” system would use 15% to 40% the energy of a system with a COP=7 chiller. In addition to the significant energy reduction over conventional technology, the membrane system offers the advantages of: 1) no HFC refrigerant use; 2) direct isothermal control over humidity ratio setpoint; 3) maximum capacity occurs at design conditions; and 4) system generates pure water extracted from air as a by-product.

42 ENGINEERING↗

Enhanced pool boiling heat transfer using novel inverted trapezoid microgroove structures

Pool boiling heat transfer improvements with enhanced surfaces have been extensively studied for various hydrofluorocarbon (HFC) refrigerants. However, there is a limited number of studies in the open literature that focus on the pool boiling heat transfer characteristics of hydrofluoroolefin (HFO) refrigerants on enhanced surfaces. This study aims to address this gap by analyzing the pool boiling behavior of HFO refrigerants, specifically R1234yf and R1234ze(E). Experiments were conducted on both plain surfaces and novel inverted trapezoid microgroove structures. Further, the experimental results indicate that the microgroove structures can improve heat transfer coefficients by up to 80% compared to plain surfaces. Additionally, the performance of R1234yf and R1234ze(E) was compared to that of R134. It was observed that R1234yf exhibited comparable performance to R134a, while R1234ze(E) showed slightly lower performance. To assess the influence of saturation temperature on pool boiling heat transfer, tests were conducted at different saturation temperatures of 15℃, 25℃, and 35℃. The findings revealed that the pool boiling heat transfer coefficient increases with rising saturation temperature.

42 ENGINEERING↗

Enhancing Selective Hydrofluorocarbon Greenhouse Gas Capture via Halogenation of Metal–Organic Frameworks

Hydrofluorocarbons (HFCs) are anthropogenically produced greenhouse gases with longer atmospheric lifetimes and higher global warming potentials than those of carbon dioxide. General strategies to abate their emissions from industrial point sources, such as via adsorptive capture, remain scarce. Herein, we uncover the key structure–property relationships that lead to strong binding of HFCs such as fluoroform (CHF 3 ) and difluoromethane (CH 2 F 2 ) in metal–organic frameworks (MOFs) under the low pressures relevant to flue gas scrubbing. Extensive gas sorption and computational studies support that the Zr-based microporous framework MOF-801-Br or HHU-2-Br (HHU = Heinrich-Heine-University Düsseldorf) strongly binds HFCs due to its synergistic combination of Zr-OH sites on the nodes and bromine sites on the linkers. As such, MOF-801-Br demonstrates a record-setting performance for separating CHF 3 from N 2 under dilute conditions. Our work highlights that the combination of multiple hydrogen-bonding sites in microporous MOFs represents a generalizable strategy for HFC capture, enabling their selective removal from industrial waste streams.

adsorption↗

Phase controlled synthesis of transition metal carbide nanocrystals by ultrafast flash Joule heating

Nanoscale carbides enhance ultra-strong ceramics and show activity as high-performance catalysts. Traditional lengthy carburization methods for carbide syntheses usually result in coked surface, large particle size, and uncontrolled phase. Here, a flash Joule heating process is developed for ultrafast synthesis of carbide nanocrystals within 1 s. Various interstitial transition metal carbides (TiC, ZrC, HfC, VC, NbC, TaC, Cr 2 C 3 , MoC, and W 2 C) and covalent carbides (B 4 C and SiC) are produced using low-cost precursors. By controlling pulse voltages, phase-pure molybdenum carbides including β-Mo 2 C and metastable α-MoC 1-x and η-MoC 1-x are selectively synthesized, demonstrating the excellent phase engineering ability of the flash Joule heating by broadly tunable energy input that can exceed 3000 K coupled with kinetically controlled ultrafast cooling (>10 4 K s –1 ). Theoretical calculation reveals carbon vacancies as the driving factor for topotactic transition of carbide phases. The phase-dependent hydrogen evolution capability of molybdenum carbides is investigated with β-Mo 2 C showing the best performance.

01 COAL, LIGNITE, AND PEAT↗

Unveiling enhanced oxidation resistance and mechanical integrity of multicomponent ultra–high temperature carbides

The development of a new class of multicomponent ultra-high temperature ceramics (MC-UHTCs), often referred to as high-entropy UHTCs, has gained increased interest due to the possibility of improved thermomechanical and oxidation properties. In this study, a systematic approach by gradual addition in the UHTC components ranging from a binary to a dense quaternary (Ta,Nb,Hf,Ti)C is synthesized using spark plasma sintering (SPS). The solid solutioning was the critical factor in homogenizing the composition in the multicomponent system. The segregation of NbC and HfC was seen in binary and ternary UHTC systems, while a single-phase homogeneity was observed in the quaternary UHTC improving its hardness up to 34.8 GPa. The presence of closely spaced slip lines in the MC-UHTCs enhances resistance to indentation damage up to 72% at an applied load of 200 N. The formation of complex mixed oxide phase of Hf6Ta2O17 ensued in the lower to negligible oxidation even up to 3 min of plasma exposure with temperature exceeding 2800°C. In sum, though the entropy remains medium (0.96R) for the selected system, the quaternary UHTC system undoubtedly has significantly better thermomechanical performance when compared to established baseline UHTCs. Furthermore, this raises the debate on the justification for calling a multicomponent system a “high entropy” to be seen in a new light. The developed MC-UHTCs elicits the paradigm of this new class of UHTCs expanding their potential in thermal protection systems for hypersonic applications.

36 MATERIALS SCIENCE↗

Energy Efficiency and Performance Evaluation of Self-Contained, Medium Temperature, Reach-In Refrigerated Display Cases

This project was part of an effort by Commonwealth Edison Company (ComEd) to evaluate the energy and peak demand saving potential of emerging technologies in the Chicago area. This document focuses on the assessment of energy-efficient, medium-temperature, self-contained refrigerated display cases utilizing environmentally friendly refrigerants. The results of this evaluation will be considered by CLEAResult to develop a new energy efficiency rebate measure for ComEd's incentive programs. This rebate measure will become an addition to the Technical Reference Manual (TRM). In 2016, the United Nations passed the Kigali Montreal Protocol Amendment which placed restrictions on certain types of refrigerants. In compliance with this amendment, the US Environmental Protection Agency (EPA) placed a ban on the manufacture of refrigeration systems using hydrofluorocarbons including R134a starting in January 2020. Although the ban has halted manufacture, the EPA continues to allow the use of these refrigerants. Therefore, it is critical to provide incentives for replacing these refrigerants with other environmentally friendly and energy-efficient alternatives. The energy-efficient refrigerator cases evaluated here (referred to as EE Case A and B) contain environmentally-friendly refrigerants in compliance with the EPA hydrofluorocarbon ban. These consist of natural refrigerant propane (R290), and HFC drop-in hydrofluoroolefin R513a, respectively. These cases also contain other energy-efficient components including efficient lighting, more robust evaporator and condenser fans and different-sized heat exchangers. EE Case A is also built with materials that better insulate the case, which improves energy efficiency. To ascertain the energy efficiency contribution of these design components, the consumption of the evaporator and condenser fan motors, compressor, and lighting/controller were evaluated individually. The medium-temperature, self-contained reach-in refrigerated display case was selected due to its widespread use in convenience stores and small supermarkets. Self-contained refrigeration has also seen increased use in restaurants due to curbside pickup during the COVID-19 pandemic. For this study, the refrigerated display cases' performance was evaluated in a controlled environmental chamber at representative indoor dry-bulb and humidity conditions found in supermarkets within ComEd's service territory climate zone. The test method used in this project was foundationally inspired by the ANSI/ASHRAE 72-2018 method of testing. However, modifications to the ANSI/ASHRAE test methodology were implemented to better represent customer operation of the units. In addition to the indoor supermarket conditions, the cases were also evaluated at the "upper target," or environmental conditions used in ANSI/ASHRAE 72-2018. The case total power and case components were metered to obtain their daily power (kW) and energy consumption(kWh). The cases were filled with thermal filler mass to replicate thermal mass of product loading. Additionally, product simulators were used to provide product temperature information. Door actuators were mounted to each of the cases' three doors to replicate regular door openings and effects of shopper traffic.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Assessment of the Performance of Hydrofluoroolefins, Hydrochlorofluoroolefins, and Halogen-Free Foam Blowing Agents in Cellular Plastic Foams

Oak Ridge National Laboratory has conducted a literature search to identify relevant information available on alternative materials and technologies that are proposed for foam blowing agents applications. For comparison, similar information was collected for available hydrofluorocarbons (HFC), hydrofluoroolefin (HFO), and hydrochlorofluoroolefins (HCFO) materials. The publicly available literature was analyzed and assessed for technical accuracy for each alternative, and a gap analysis was conducted to understand if additional studies are required to fully assess the viability of an alternative. In assessing these alternatives, this project focused on relevant performance and safety attributes. The performance attributes collected include insulation value per unit thickness, which impacts energy usage of buildings and insulated equipment such as refrigerators. We also assessed the impact of blowing agents on foam mechanical properties and flammability characteristics, and the ability of current processing equipment and techniques to utilize these alternatives. Diffusion of blowing agents through foam cells and its impact on foam aging was also examined. The applications covered in this study are spray foam, boardstock, panels, and appliances. Some of the most relevant findings are summarized below.

36 MATERIALS SCIENCE↗

Hot Isostatic Pressing Control of Tungsten-Based Composites

Metal-oxide composites are commonly used in high temperature environments for their thermal stability and high melting points. Commonly employed with refractory oxides or carbides such as ZrC and HfC, these materials may be improved with the use of a low density, high melting point ceramic such as CeO2. In this work, the consolidation of W-CeO2 metal matrix composites in the high CeO2 concentration regime is explored. The CeO2 concentrations of 50, 33, and 25 wt.%, the CeO2 particle size from nanometer to micrometer, and various hot isostatic pressing temperatures are investigated. Decreasing the CeO2 concentration is observed to increase the composite density and increase the Vickers hardness. The CeO2 oxidation state is observed to be a combination of Ce3+ and Ce4+, which is hypothesized to contribute to the porosity of the composites. The hardness of the metal-oxide composite can be improved more than 2.5 times compared to pure W processed by the same route. This work offers processing guidelines for further consolation of oxide-doped W composites.

36 MATERIALS SCIENCE↗

Low-GWP Refrigerants Status and Outlook

Refrigeration - including air conditioning (AC) – contributes substantially to the modern life of the 21st century and its economy. The food cold chain, air conditioning, healthcare and energy are examples of sectors for which refrigeration is indispensable. About 5 billion refrigeration systems – of different types and sizes– operate worldwide in different applications [1]. The dominant share of equipment providing refrigeration operate on the vapor-compression-cycle principle and use fluorocarbon refrigerants. Concerns about the environmental safety have become the driving force for refrigerant changes within the last 35 years. The phased-out schedule of stratospheric-ozone-depleting fluids was first formulated by the Montreal Protocol (MP) in 1987 and was made more stringent during the follow-up international meetings [2]. The affected chlorofluorocarbon (CFC) and hydrochlorofluorocarbon (HCFC) refrigerants were largely replaced by hydrofluorocarbons (HFCs).The 2016 Kigali Amendment to the MP [3] responses to the concerns about the Earth climate change. The refrigeration and AC sectors are attributed with about 7.8 % of global greenhouse gas emissions [4]. This contribution comes in the form of direct effect, which is related to refrigerant emissions from refrigeration systems (37 %), and in the form of indirect effect, which is related to CO2 emissions from fossil fuel power plants producing electricity to power refrigeration systems (63 %) [4]. The Kigali Amendment aims at reducing the direct effect. The effect a given molecule has on the climate change is quantified in a simplified manner by its Global Warming Potential (GWP), a relative index referencing the effect produced to that of the same mass of carbon dioxide released to the atmosphere. By definition, GWP of carbon dioxide is equal to one.While HFC refrigerants have on average a lower GWP than the CFCs and HCFCs they replaced, they are still potent greenhouse gases (GHGs). The Kigali Amendment phases down the use of HFCs by imposing a schedule for reducing a weighted GWP value to be implemented by a country through the year 2047 (Figure 1). It provides four paths depending on the country location and category assigned in the MP, and also prescribes a method for establishing the baseline consumption used for calculating GWP reductions. For developing countries, it is expected to bring the weighed GWP across all refrigeration applications down to about 300 from the baseline value of about 2000. The implementation of Kigali Amendment aims at reducing the future warming due to HFCs from the range of 0.3 °C to 0.5 °C to less than 0.1 °C [5]. While this reduction may seem to be small, it must be viewed in the context of the 2015 Paris Agreement [6], which calls for holding global warming to well below 2 °C and pursuing to limit global warming to 1.5 °C relative to pre-industrial levels [6]. Considering that average global temperatures reached 1 °C above pre-industrial levels for the first time in 2015 [7], the Earth is already within 1 °C of the “2 °C limit”.The low-GWP requirement narrows the pool of fluids that can be considered for application as a refrigerant [8]. This Informatory Note discusses low-GWP refrigerant options for major applications and presents their selection merits.

Yana Motta, Samuel↗

The Hydrofluorocarbon Phasedown and Commercial Space Conditioning: A Guide to the Transition

You may be aware of the hydrofluorocarbon (HFC) phasedown, but the details and its impact on your operations may still be unclear. Or perhaps this is the first you're hearing about the phasedown. In either case, this guide provides information to aid conversations with facility managers and engineers and provides an explanation of how the phasedown affects equipment in commercial buildings. It also includes actions you and your organization can take now to properly plan and prepare.

ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION↗