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Sorption of noble gases by solids, with reference to meteorites. II - Chromite and carbon. III - Sulfides, spinels, and other substances; on the origin of planetary gases

The trapping of noble gases by chromite and carbon, two putative carriers of primordial noble gases in meteorites, was studied by synthesizing 19 samples in a Ne-Ar-Kr-Xe atmosphere at 440-720 K. Noble gas contents are found to approximately obey Henry's Law, but only slight correlations are found with composition, surface area, or adsorption temperature. Geometric mean distribution coefficients for bulk samples and HCl residues in 10 cu cm STP/g atm are: Xe 100, Kr 15, Ar 3.5, and Ne 0.62. Elemental fractionation data support the suggestion of Lewis et al. (1977) that chromite and carbon in C2 and C3 chondrites were formed by the reaction: Fe, Cr + 4CO yields (Fe, Cr)3O4 + 4C + carbides. In contrast to meteoritic minerals, the synthetic specimens show no isotopic fractionation of noble gases. In a subsequent study, attention is given to the cases of sulfides and spinels, on the way to consideration of the origin of planetary gases. Sulfides showed three distinctive trends relative to chromite or magnetite. The elemental fractionation pattern of Ar, Kr and Xe in meteorites, terrestrial rocks and planets resembles the adsorption patterns on the carbons, spinels, sulfides, and other solids studied. The high release temperature of meteoritic noble gases may be explained by transformation of the physisorbed or chemisorbed gas. The ready loss of meteoritic heavy gases on surficial oxidation is consistent with adsorption, as is the high abundance.

Yang, J.↗

Microgravity Flow Boiling Experiments With Liquid-Vapor Mixture Inlet Onboard the International Space Station

This article is part of a series of studies culminating from the multi-objective Flow Boiling and Condensation Experiment (FBCE) onboard the International Space Station, which utilized the Flow Boiling Module (FBM) for experiments between February and July 2022. This study investigates microgravity flow boiling of n-Perfluorohexane with liquid-vapor mixture (two-phase) inlet conditions to the FBM with either one or two opposite walls heated. The FBM’s channel has a rectangular cross-sectional area of 5.0 × 2.5 mm 2 and a heated length of 114.6 mm. Key parameters of interest include mass velocity (180 – 2400 kg/m 2 s), inlet quality (-0.01 – 0.87), inlet pressure (120 – 200 kPa), and heat flux (1.8 W/cm 2 to critical heat flux), and a large database is amassed. The flow is visualized via a high-speed video camera and photographs are recorded at each heating increment to assess the periodic flow patterns within the channel and the near-wall interfacial behavior. Flow patterns are complex and mainly characterized by high- and low-density fronts alternately traversing the channel to yield high- and low-density-dominant periods of boiling. At all operating conditions, high-density fronts are faster during high-density-dominant periods. At low inlet qualities, the flow is annular near the channel inlet with a central vapor core surrounded by an annular liquid layer. Each high-density front having a high liquid fraction leaves a thin liquid layer sheared onto the heated walls. Boiling occurs within the liquid layer and a vapor layer is formed next to the heated wall. Inlet quality and mass velocity most dictate the overall flow patterns followed by heating configuration, and to a much lesser extent, heat flux and inlet pressure. Heat transfer characteristics are assessed via averaged boiling curves, streamwise profiles of wall temperature and heat transfer coefficient, and parametric curves of local and averaged heat transfer coefficients. Inlet pressure has an insignificant effect on heat transfer. At similar operating conditions, both the heating configurations yield similar trends and values of heat transfer coefficient and critical heat flux (CHF, slightly higher for single-sided) even though double-sided heating adds twice the heat to the fluid and doubly raises local quality. The heat fluxes required for both onset of nucleate boiling degradation and CHF are larger at high mass velocities and low inlet qualities. For a fixed inlet quality, high mass velocities yield higher average heat transfer coefficients at both lower and higher heat fluxes, while the nucleate boiling regime at intermediate heat fluxes is unaffected. For a fixed mass velocity, higher inlet qualities yield higher and lower average heat transfer coefficients at lower and higher heat fluxes, respectively.

Microgravity↗

Shuttle Flight Experiment on USMP-4: In Situ Monitoring of Crystal Growth Using MEPHISTO

This reports on the MEPHISTO-4 experiment on the Space Shuttle Columbia, STS-87, November 19-December 5, 1997. Involved were NASA; the University of Florida at Gainesville; groups from France that developed and built the furnace; the National Institute of Standards and Technology; The University of New South Wales, Australia; and Purdue University. This was a solidification study in which three long rods of Bismuth- 1 at.% Tin were directionally solidified. The goals were to solidify in an environment free of natural convection; to determine the relationship among solidification growth velocity, growth mode, and temperature; and determine the diffusivity of Sn in Bi. The flight samples grew with a planar solid/liquid interface at velocities less than 3.4 gm/s, and cellular growth was present at velocities greater than 6.7 um/s; grain orientation influenced the planar to cellular transition. The temperature gradient in the liquid was 204 K/cm. The s/l interface was flat with slight concavity. Diffusion-dominated conditions were present during MEPHISTO-4. The Seebeck technique was used to determine the s/I interface temperature during growth, however, to date, analysis of the Seebeck results has not yielded a reliable measurement of the interface temperature. The partition coefficient for Bi alloyed with Sn was measured, k = 0.029.

Abbaschian, Reza↗

Free-Spinning-Tunnel Investigation of a 1/25-Scale Model of the McDonnell F3H-1N Airplane, TED No. NACA AD 3100

An investigation was conducted in the Langley 20-foot free-spinning tunnel on a 1/23-scale model of the McDonnell F3H-1N airplane. The effects of control settings and movements upon the erect and inverted spin and recovery characteristics of the model were determined for the clean condition. Spin-recovery parachute tests were also performed. The results indicated that erect spins obtained on the airplane for the take-off or combat loadings should be satisfactorily terminated if full rudder reversal is accompanied by moving the ailerons to full with the spin (stick full right in a right spin). The spins obtained should be oscillatory in pitch, roll, and yaw. Recoveries from inverted spins should be satisfactory by full reversal of the rudder. A 16.7-foot- diameter tail parachute with a towline length of 30 feet and a drag coefficient of 0.734 should be adequate for emergency recovery from demonstration spins.

Lee, Henry A.↗

An extended BET format for La RC shuttle experiments: Definition and development

A program for shuttle post-flight data reduction is discussed. An extended Best Estimate Trajectory (BET) file was developed. The extended format results in some subtle changes to the header record. The major change is the addition of twenty-six words to each data record. These words include atmospheric related parameters, body axis rate and acceleration data, computed aerodynamic coefficients, and angular accelerations. These parameters were added to facilitate post-flight aerodynamic coefficient determinations as well as shuttle entry air data sensor analyses. Software (NEWBET) was developed to generate the extended BET file utilizing the previously defined ENTREE BET, a dynamic data file which may be either derived inertial measurement unit data or aerodynamic coefficient instrument package data, and some atmospheric information.

Findlay, J. T.↗

Entry aeromaneuvering capabilities of transatmospheric vehicles

The landing footprint of a conceptual high-lift transatmospheric vehicle is defined for aeromaneuvering entry from a typical low-earth orbit. The flight strategy for trajectory construction to maximize the landing area by extending downrange and crossrange as far as possible is developed in four phases by optimal programming of the vehicle's roll angle. Trajectories that reach any given landing site were calculated with the corresponding heating rates at three critical vehicle locations (stagnation point, wing leading edge, and body centerline). An optimization methodology was developed that demonstrates the trades between crossrange, peak heating and total heat loads as a function of three key flight parameters (altitude, flight-path angle, and vehicle roll angle). The maximum extent of the landing footprint was found to be 29,690 km downrange and 6560 km crossrange. Large variations in the ballistic coefficient had negligible effect on the extent of the footprint but could significantly affect heating. However, the footprint's longitude was displaced downstream or upstream with increasing or decreasing ballistic coefficient, respectively.

Menees, Gene P.↗

Characteristics of Perforated Diffusers at Free-stream Mach Number 1.90

An investigation was conducted at Mach number 1.90 to determine pressure recovery and mass-flow characteristics of series of perforated convergent-divergent supersonic diffusers. Pressure recoveries as high as 96 percent were obtained, but at reduced mass flows through the diffuser. Theoretical considerations of effect of perforation distribution on shock stability in converging section of diffuser are presented and correlated with experimental data. A method of estimating relative importance of pressure recovery and mass flow on internal thrust coefficient basis is given and a comparison of various diffusers investigated is made.

FLOW, SUPERSONIC↗

Investigation of a Low-Drag Gun Port in the NACA Two-Dimensional Low-Turbulence Tunnel

Tests were made in the NACA two-dimensional low-turbulence tunnel of three gun ports with a height of approximately 4 percent of the chord faired into an NACA 66,2-213 low-drag-airfoil section by bulging the section at the gun port. Gun ports faired in this manner had practically no effect on the maximum lift and the critical compressibility speed of the section and showed only small increase in the drag in the range of lift coefficients for high-speed and cruising-flight conditions.

Horton, Elmer A.↗

1988-1991 photometry of the chromospherically active double-lined binary system HD 163621 = V835 Herculis

Photometry in V and B with a 16-inch automatic telescope from 1988 to 1991 confirms the synchronous rotation suspected earlier and reveals variability up to 0.1M in the B bandpass at one epoch. Five spots formed with lifetimes ranging from 0.15 to 0.77 years. As with other rapid rotators, the differential rotation coefficient (k = 0.03) is significantly smaller than that of the Sun (k = 0.19).

Hall, Douglas↗

Experimental Heat Transfer Results and Flow Visualization of Vertical Upflow Boiling in Earth Gravity with Subcooled Inlet Conditions – In Preparation for Experiments Onboard the International Space Station

Since 2012, researchers at the Purdue University Boiling and Two-Phase Flow Laboratory (PU-BTPFL) and NASA Glenn Research Center have been collaborating on a long-term effort to study flow boiling and condensation in microgravity. The ultimate goal has been to develop the Flow Boiling and Condensation Experiment (FBCE) for the International Space Station (ISS). Based on the findings from prior flow boiling experiments both at different orientations in Earth gravity and onboard parabolic flights simulating short durations of microgravity, a final refined experiment design, construction, and operating procedure have been arrived at for long-duration microgravity flow boiling experiments onboard the ISS. This study investigates flow boiling of n-Perfluorohexane with subcooled inlet in a rectangular channel of dimensions 114.6 mm heated length, 2.5 mm width, and 5 mm height. These pre-launch experiments (Mission Sequence Testing) were conducted in vertical upflow orientation in Earth gravity using the same experimental rig that was launched to the ISS in August 2021. The various operating parameters varied are heating configuration (single- and double-sided), mass velocity (180 – 3200 kg/m2s), inlet subcooling (+0 – 32°C, encompassing both highly subcooled and near-saturated inlet conditions), and inlet pressure (119 – 191 kPa). High-speed video flow visualization images are presented to explain the two-phase interfacial physics within the channel’s heated section. Heat transfer results in terms of flow boiling curves, streamwise profiles of wall temperature and heat transfer coefficient, and averaged heat transfer coefficients are analyzed and parametric effects elucidated. Severe temporal thermodynamic equilibrium is observed for near-saturated inlet at very low velocities. Nucleate boiling degradation starts at larger heat fluxes for single-sided heating than double sided at low mass velocities with highly subcooled inlet, and conversely at high mass velocities with near-saturated inlet. Nucleate boiling degradation can be delayed to higher heat fluxes by highly subcooling the inlet and increasing mass velocity. The entire local heat transfer coefficient profiles are degraded at higher heat fluxes for near-saturated inlet, but only the downstream part for highly subcooled inlet. This study also confirmed reliability of the upcoming ISS experimental data for subcooled inlet conditions and the collected Earth-gravity data will be used for comparison against the ISS data.

flow boiling↗

Solubilities of noble gases in magnetite - Implications for planetary gases in meteorites.

Solubilities of noble gases in magnetite were determined by growing magnetite in a noble-gas atmosphere between 450 and 700 K. Henry's law is obeyed at pressures up to .01 atm for He, Ne, Ar and up to .00001 atm for Kr, Xe, with the following distribution coefficients at 500 K: He 0.042, Ne 0.016, Ar 3.6, Kr 1.3, Xe 0.88, some 100 to 100,000 times higher than previous determinations on silicate and fluoride melts. Apparent heats of solution are in sharp contrast with earlier determinations on melts which were small and positive, but are comparable to the values for clathrates. Presumably the gases are held in anion vacancies.

Lancet, M. S.↗

Midlatitude oxygen ultraviolet nightglow

A rocket-borne spectrometer measured the weak UV nightglow from 1240 to 1670 A in the altitude range 180-345 km above White Sands, New Mexico. Detection of nightglow emissions at the atomic oxygen lines (1304 and 1356 A) confirmed the existence of a weak midlatitude oxygen nightglow similar to the tropical airglow. Radiative recombination appeared to be the principal cause of the peak observed intensities of the atomic oxygen line emissions, though a maximum 25% contribution from mutual neutralization of O(+) and O(-) could also be contemplated. Partial radiative recombination coefficients are derived from the data.

Brune, W. H.↗

Flow Boiling and Condensation Experiment (FBCE): Summary of Findings for Flow Boiling based on Completed ISS Experiments

Since 2011, researchers from Purdue University and NASA Glenn Research Center (GRC) have been collaborating to investigate the effects of gravity on several aspects of flow boiling and flow condensation. This massive research endeavor, termed the Flow Boiling and Condensation Experiment (FBCE), has culminated in development of NASA’s largest and most complex facility for investigation of two-phase fluid physics onboard the ISS. FBCE consists of two separate studies: flow boiling, using the Flow Boiling Module (FBM), and flow condensation, using the Condensation Module for Heat Transfer Measurements (CM-HT); this presentation concerns the FBM portion of FBCE. Fitted with FBM, FBCE was launched to the ISS in August 2021 and experiments were successfully performed starting in February 2022 to amass a large microgravity-flow-boiling database supported by extensive visualization of interfacial behavior using high-speed video. Based on FBCE experiments performed previously in Earth gravity and parabolic flight, along with the new ISS data, several empirical correlations, theoretical models, and CFD models have been developed, enabling the prediction of crucial flow boiling parameters, including heat transfer coefficient and critical heat flux (CHF). These predictive tools, which will be summarized in this presentation, are expected to serve as foundation for design of future space systems involving flow boiling.

Two-phase flow and phase transition↗

Partitioning REE between minerals and coexisting melts during partial melting of a garnet lherzolite

Partition coefficients for Ce, Sm, and Tm between garnet, clinopyroxene, orthopyroxene, olivine, and melt are determined at 35 kbar for 2.3, 8, 20, and 37.7% melting of a garnet lherzolite nodule with chondritic REE abundances. Partition coefficients are found to increase as the degree of partial melting increases. From 2.3 to 8% melting, this increase is for the most part a consequence of non-Henry's law behavior of REE in minerals.

Harrison, W. J.↗

A spectroscopic and photometric study of 12 BM Camelopardalis

Radial velocities from 1916.95 to 1991.95 and photometry from l979.25, both published and new in this paper, are presented and analyzed. A new solution of the radial velocity curve reveals a new period of 80.90 days and an eccentricity of e = 0.05 +/- 0.02, both very different from the 80.17 days and 0.35 found by Abt et al. (1969). An alternative solution with e = 0 is given because we cannot decide firmly whether or not the small eccentricity is real. We find V sin i = 11.3 +/- 0.3 km/s from Maidanak and 10 unequal depth. 0.048 mins and 0.026 mins. The orbital ephemeris for conjunction (K gisnt behind) is JD(hel.) 2,448,111.1 (+/- 0.4 days ) + 80.898 days (+/- 0.004 days ) E, consistent with both the radial velocities and the photometry. With the ellipticity effect removed, the light curve shows residual variability which we fit with a two-spot model. During the 13 years covered by photometry there were nine different starspots, the largest one producing a light loss of 0.19 mins. Rotation periods for the nine spots ranged from 78.6 +/- 0.5 days to 83.7 +/- 0.4 days from which we concluded that the K giant does rotate synchronously but with a differential rotation coefficient of k = 0.06 +/- 0.01. Lifetimes for the nine spots ranged from 1.1 to greater than 4.2 yr and were consistent with the empirical spot lifetime laws of Hall & Henry (1994). Use of the mass function, the orbital period, the V sin i, the two different ellipticity effect amplitudes, and various logical constraints led to ranges of possible masses, radii and inclinations. The most believable solution was around i = 90 deg, R(sub 1) = 24 solar radii, M(sub 1) = 1.1 solar mass, and M(sub 2) = 0.6 solar mass. THe Rossby number for the K giant is 0.48, small enough compared to the critical value of 0.65 to explain why, though rotating 'slowly', it does have large spots.

Hall, Douglas S.↗

Heat Transfer and Interfacial Flow Physics of Microgravity Flow Boiling in Single-Side-Heated Rectangular Channel with Subcooled Inlet Conditions – Experiments Onboard the International Space Station

This study is the culmination of a long-term collaborative effort between researchers from the Purdue University Boiling and Two-Phase Flow Laboratory (PU-BTPFL) and the NASA Glenn Research Center to investigate gravitational effects on flow boiling and flow condensation. The science and design concepts for this large-scale effort were initiated in 2011 and included several studies detailing various aspects of two-phase fluid physics in both Earth gravity and microgravity, culminating in construction of the large-scale experimental facility named “Flow Boiling and Condensation Experiment (FBCE)”. The experiment was launched to the International Space Station (ISS) in August 2021. Following the successful installation of FBCE, equipped with the Flow Boiling Module (FBM), onboard the ISS and completion of several safety checks, flow boiling experiments were performed for five months from February 2022 until July 2022. This resulted in a large flow boiling database covering broad ranges of operating parameters and heating configurations spanning several research objectives. This study investigates microgravity flow boiling of n-perfluorohexane with subcooled inlet in a single-side-heated rectangular channel of dimensions 114.6-mm heated length, 2.5-mm heated width, and 5.0-mm height. Key operating parameters investigated are mass velocity (199.90 – 3200.13 kg/m 2 s), inlet subcooling (0.10 – 45.76°C), and inlet pressure (113.30 – 164.29 kPa). Images and image sequences acquired via high-speed-video are presented to elucidate the interfacial flow physics. To analyze and explain the effects of various parameters in microgravity, heat transfer results are presented as flow boiling curves, streamwise profiles of wall temperature and heat transfer coefficient, and parametric trends of local and averaged heat transfer coefficient. Mass velocity and inlet subcooling significantly influenced most of the aforementioned aspects of flow boiling, whereas effects of inlet pressure were comparatively insignificant. Although the data and observed flow physics might be different, the parametric effects and trends in microgravity are similar to vertical upflow in Earth gravity. Some cases, especially low mass velocities, high heat fluxes, and large degrees of inlet subcooling, experienced temporally anomalous flow behaviors caused by two-phase flow instabilities manifesting as flow reversals and resulted in deviations in overall trends. Severe thermodynamic non-equilibrium is observed throughout the channel. Overall, FBCE’s ISS experiments were successful for subcooled inlet with single-sided heating of rectangular channel, and the collected data well established the various effects on flow boiling physics in highly controlled long-term microgravity conditions.

flow boiling↗

Sulfur-dioxide/water equilibria between 0 and 50 C - An examination of data at low concentrations

In order to resolve the discrepancy noted in values currently used for the first dissociation constant of SO2 in water, the pertinent literature was critically examined and a value of 0.0132 M at 25 C was recommended. An expression correlating this value as a function of temperature for zero-50 C has been developed. Attention is also given to the literature for the Henry's law constant, and a value of 1.242 M/atm at 25 C is recommended. Ionic activity corrections and speciation in more concentrated solutions are discussed, and recommendations are made for estimating the activity coefficients of the various ionic species in solutions of moderate ionic strength.

Maahs, H. G.↗