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At least 37 records · Page 2

Precise laser frequency scanning using frequency-synthesized optical frequency sidebands - Application to isotope shifts and hyperfine structure of mercury

Based on an efficient broadband electrooptic modulator producing RF optical sidebands locked to a stable cavity, a tunable dye laser can be scanned under computer control with frequency-synthesizer precision. Cavity drift is suppressed in software by using a strong feature in the spectrum for stabilization. Mercury isotope shifts are measured with a reproducibility of about 50 kHz. This accuracy of about 1/300 of the linewidth illustrates the power of the technique. Derived hyperfine-structure constants are compared with previous atomic-beam data.

Rayman, M. D.↗

High-resolution spectroscopy of barium monofluoride: Odd isotopologues, hyperfine structure, and isotope shifts

Barium monofluoride (BaF) is a promising molecular species for precision tests of fundamental symmetries and interactions. We present a combined theoretical and experimental study of BaF spectra and isotope shifts, focusing in particular on the poorly understood odd isotopologues 137 BaF and 135 BaF. By comparing state-of-the-art ab initio calculations with high-resolution fluorescence and absorption spectroscopy data, we provide a benchmark for electronic structure theory and disentangle the hyperfine and rovibrational spectra of the five most abundant isotopologues, from 138 BaF to 134 BaF. The comprehensive knowledge gained enables a King plot analysis of the isotope shifts that reveals the odd-even staggering of the barium nuclear charge radii. It also paths the way for improved laser cooling of rare BaF isotopologues and crucially supports future measurements of nuclear anapole and Schiff moments.

Kogel, Felix [Univ. of Stuttgart (Germany)] (ORCID↗

The optical depth of the 158 micron forbidden C-12 II line - Detection of the F = 1 - 0 forbidden C-13 II hyperfine-structure component

The detection of the F = 1 - 0 hyperfine component of the 158-micron forbidden C-13 II fine-structure line in the interstellar medium is reported. A 12-point intensity map was obtained of the forbidden C-13 distribution over the inner 190-arcsec (R.A.) X 190-arcsec (decl.) regions of the Orion Nebula using an imaging Fabry-Perot interferometer. The forbidden C-12 II/C-13 II line intensity ratio varies significantly over the region mapped. It is highest (86 +/-0) in the core of the Orion H II region, and significantly lower (62 +/-7) in the outer regions of the map, reflecting higher optical depth in the forbidden C-12 II line here. It is suggested that this enhanced optical depth is the result of limb brightening of the optically thin forbidden C-13 II line at the edges of the bowl-shaped H II region blister.

Stacey, G. J.↗

The optical depth of the 158 micrometer (C-12 II) line: Detection of the F=1 yields 0 (C-13 III) hyperfine-structure component

The first detection of the F = 1 yields 0 hyperfine component of the 158 micrometer (C-13 II) fine structure line in the interstellar medium is reported. A twelve point intensity map was obtained of the (C-13 II) distribution over the inner 190 inch (right ascension) by 190 inch (declination) regions of the Orion nebula using an imaging Fabry-Perot interferometer. The (C-12 II)/(C-13 II) line intensity ratio varied significantly over the region mapped. It is highest (86 plus or minus 9) in the core of the Orion H II region and significantly lower (62 plus or minus 7) in the outer regions of the map, reflecting higher optical depth in the (C-12 II) line here. It is suggested that this enhanced optical depth is the result of limb brightening of the optically thin (C-13 II) line at the edges of the bowl-shaped H II region blister. If the C-12/C-13 abundance ratio is 43, the (C-12 II) line in the inner regions of the Orion nebula, has a low optical depth: tau sub 12 approximately = 0.75 plus or minus 0.25. The optical depth together with the large brightness temperature of the (C-12 II) line (approximately 160 K) requires that the excitation temperature of the P-2 sub 3/2 level be approximately 310 K, in very good agreement with the previous analysis of the physical conditions of the Orion interface region based on fine structure line intensity ratios and photodissociation region models. If the C-12/C-13 abundance ratio is 67, the line optical depth is somewhat larger (tau sub 12 approximately = 1.85), and the transition excitation temperature is somewhat smaller (approximately 190 K) than that predicted by these models. The present results therefore support values approximately = 43 for the C-12/C-13 abundance ratio in the Orion nebula.

Stacey, G. J.↗

Laser Induced Optical Pumping Measurements of Cross Sections for Fine and Hyperfine Structure Transitions in Sodium Induced by Collisions with Helium Argon Atoms

Optical pumping of the ground states of sodium can radically alter the shape of the laser induced fluorescence excitation spectrum, complicating measurements of temperature, pressure, etc., which are based on these spectra. Modeling of the fluorescence using rate equations for the eight hyperfine states of the sodium D manifolds can be used to quantify the contribution to the ground state pumping of transitions among the hyperfine excited states induced by collisions with buffer gas atoms. This model is used here to determine, from the shape of experimental spectra, cross sections for (Delta)F transitions of the P(sub 3/2) state induced by collisions with helium and argon atoms, for a range of values assumed for the P(sub 1/2), (Delta)F cross sections. The hyperfine cross sections measured using this method, which is thought to be novel, are compared with cross sections for transitions involving polarized magnetic substates, m(sub F), measured previously using polarization sensitive absorption. Also, fine structure transition ((Delta)J) cross sections were measured in the pumped vapor, giving agreement with previous measurements made in the absence of pumping.

Dobson, Chris C.↗

Laser-Induced Optical Pumping Measurements of Cross Section for Fine- and Hyperfine-Structure Transitions in Sodium Induced by Collisions with Helium and Argon Atoms

Optical pumping of the ground states of sodium can radically alter the shape of the laser-induced fluorescence excitation spectrum, complicating measurements of temperature, pressure, etc., which are based on these spectra. Modeling of the fluorescence using rate equations for the eight hyperfine states of the sodium D manifolds can be used to quantify the contribution to the ground state pumping of transitions among the hyperfine excited states induced by collisions with buffer gas atoms. This model is used here to determine, from the shape of experimental spectra, cross sections lor DELTA.F transitions of the P(sub 3/2) state induced by collisions with helium and argon atoms, for a range of values assumed for the P(sub 1/2), DELTA.F cross sections. The hyperfine cross sections measured using this method, which to our knowledge is novel, are compared with cross sections for transitions involving polarized magnetic substates m(sub F) measured previously using polarization sensitive absorption. Also, fine-structure transition cross sections were measured in the pumped vapor, giving agreement with previous measurements made in the absence of pumping.

Dobson, Chris C.↗

Hyperfine structure of furan.

The hfs of five rotational transitions of furan (C4H4O) has been resolved with a beam maser spectrometer with a resolution of about 500 Hz. All significant details of the observed structure are accounted for by the spin-spin and spin-rotation interactions of the four protons, and the coupling constants for these interactions have been determined to high precision. In particular, the diagonal elements of the spin-rotation tensors have been determined to about 10 Hz.

Tomasevich, G. R.↗

Coherence and its application in the beam-foil light source

The beam-foil light source is shown to be very useful in spectroscopic work. Not only the lifetimes of highly excited, multiply charged atoms can be measured in a straightforward way, but also the fine-structure and hyperfine-structure separations and the Lande factors can be obtained due to the fact that the coherent excitations are created in the impulsive beam-foil collision. The theories suggested to explain the origin of coherence are presently incomplete.

Liu, C. H.↗