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All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Value of Geothermal Energy Storage for Supply-Side and Demand-Side Applications

This report presents the results of a study examining the value potential for geothermal energy storage (GES), a long-duration energy storage resource that stores thermal and/or geomechanical energy in the subsurface. GES could benefit the overall U.S. power system by temporally shifting electricity generation (supply-side) or meeting building heating and cooling load (demand-side). This report analyzes supply-side and demand-side opportunities independently because of differences in applications and models. Currently there is significant uncertainty about the development costs for GES, with only a limited number of demonstration plants for electric energy storage and building heating and cooling storage developments. In this report, we estimate the value of supply-side and demand-side GES to the bulk power system in the contiguous United States. Because of the significant uncertainty about GES development costs, this analysis does not consider GES deployment costs but instead focuses on the value of GES to the U.S. electricity system. The estimated values of GES provide reference points for economically competitive commercial cost targets. Supply-side GES is modeled as part of an enhanced geothermal system (EGS) generation plant in NREL's Regional Energy Deployment System (ReEDS) capacity expansion model (Ho et al. 2021). In contrast to conventional geothermal plants, which generate constant power, EGS plants have unique features that may allow for in-reservoir energy storage for flexible generation. Demand-side GES for heating and cooling, including seasonal hot and cold storage and short-duration heat pump storage, is incorporated into a price-taker model using Cambium electricity marginal cost projections. To establish an upper bound for the value of GES, analysis focused on favorable scenarios for storage with high generation from zero marginal cost, variable renewable energy resources. High penetrations of variable renewable energy generation can increase hourly electricity price variability, which increases the value of temporal energy arbitrage for storage technologies like GES.

15 GEOTHERMAL ENERGY↗
DOE OSTI2022

Probing the Galactic halo with RR Lyrae stars – II. The substructures of the Milky Way

ABSTRACT We identify substructures of the Galactic halo using 3003 type ab RR Lyrae stars with six-dimensional position–velocity information from the Sloan Digital Sky Survey, the Large Sky Area Multi-Object Fiber Spectroscopic Telescope and the Gaia Early Data Release 3. Based on this information, we define the separation of any two of the stars in the integrals of motion space and we identify substructures by utilizing the friends-of-friends algorithm. We identify members belonging to several known substructures: the Sagittarius stream, the Gaia-Enceladus-Sausage (GES), the Sequoia and the Helmi streams. In addition to these known substructures, there are three other substructures possibly associated with globular clusters NGC 5272, 6656 and 5024, respectively. Finally, we also find three remaining unknown substructures, one of which has large angular momentum and a mean metallicity −2.13 dex, which may be a new substructure. As for the GES, we find that it accounts for a large part of substructures in the inner halo and the apocentre distance is in the range 10–34 kpc, which suggests that the GES is mainly distributed in the inner halo. The near one-third proportion of the GES and the peak value of 20 kpc of the apocentre distance suggest that the GES could account for the break in the density profile of the Galactic halo at the Galactocentric distance ~20–25 kpc. The similarity when comparing the kinematic properties of the GES with the Hercules–Aquila Cloud and Virgo Overdensity suggests that the three substructures may have similar origins.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Comparative life cycle assessment of woody biomass processing: air classification, drying, and size reduction powered by bioelectricity versus grid electricity

Sulfur accumulation during biofuel production is pollutive and toxic to conversion catalysts and causes the premature breakdown of processing equipment. Air classification is an effective preprocessing technology for ash and sulfur reduction from biomass feedstocks. Here, a life cycle assessment (LCA) sought to understand the environmental impact of implementing air classification as a sulfur-mitigation technique to improve feedstock quality for pine residues using a grid electricity scenario (GES) versus a bioelectricity scenario (BES). Global warming potential (GWP) for preprocessing was simulated using inventory databases embedded in SimaPro and the Argonne National Laboratory’s GREET model, specifically focusing on comparing the GWP of a GES versus a BES. Overall, the GES had a GWP impact over seven times that of the BES (136 versus 18 kg CO 2 equivalent per tonne of usable feedstock), with steam generation during rotary drying accounting for 57% of the GES’s GWP. Air classification represents 0.4% and 1.6% of the total GWP impact for the GES and BES, respectively. Therefore, air classification can facilitate a 30% reduction in feedstock sulfur content to improve feedstock quality for biofuel conversion and lessen corrosion of equipment while contributing minimal GWP impact during preprocessing.

Air classification↗
DOE OSTI2021

Geothermal Heat Recovery Complex: Large-Scale, Deep Direct-Use System in a Low-Temperature Sedimentary Basin (Final Report)

A feasibility study of using deep direct-use (DDU) geothermal energy to heat agricultural research facilities (ARFs) was conducted at the University of Illinois at Urbana-Champaign (U of IL) and its similar application to military facilities in the Illinois Basin (ILB). The geothermal energy system (GES) investigated utilizes low-temperature (30–90°C; 90–190°F) geothermal fluid (i.e., brine) from an extraction well that is part of a deep, two-well (doublet) system that extends to the bottom of the ILB. The geothermal reservoir modeled, the Mt. Simon Sandstone (MSS), is about 1,280 m (4,200 feet) deep and 457 m thick (1,500 feet) beneath the U of IL. The DDU GES surface infrastructure includes heat exchangers connected in-parallel to pipelines carrying the geothermal fluid and fresh cold and hot water. Analysis of the GES indicated that the MSS can provide a baseload of 2 MMBtu/hr to heat the ARFs by extracting 954 m³/d (6,000 barrels/day [bbl/d]) of geothermal fluid that has a temperature of 44–46 °C (111–115 °F). In addition to analyzing the levelized cost of heat (LCOH) and life cycle costs, the environmental effects of the DDU GES were evaluated, including reduced greenhouse gas (GHG) emissions and water consumption. Multiple system designs were evaluated and then ranked based on their maximum heating performance, energy efficiency, and cost recovery. This feasibility study identified the key components of the fully-integrated DDU technology that can be implemented, both technically and economically. The results and information from this study provides end-users and policy makers with guidance for additional research on the specific components of DDU technology such that its widespread use can provide an uninterruptible energy source, increase resilience from extreme weather conditions, reduce U.S. dependency on fossil fuels, and reduce greenhouse gas (GHG) emissions. The site-specific part of this study gives U of IL administrators a realistic and pragmatic assessment of the financial resources necessary to add a DDU GES in the MSS to the campus’ energy portfolio.

15 GEOTHERMAL ENERGY↗
DOE OSTI2023

Photonics in Multimaterial Lateral Heterostructures Combining Group IV Chalcogenide van der Waals Semiconductors

Abstract Lateral heterostructures combining two multilayer group IV chalcogenide van der Waals semiconductors have attracted interest for optoelectronics, twistronics, and valleytronics, owing to their structural anisotropy, bulk‐like electronic properties, enhanced optical thickness, and vertical interfaces enabling in‐plane charge manipulation/separation, perpendicular to the trajectory of incident light. Group IV monochalcogenides support propagating photonic waveguide modes, but their interference gives rise to complex light emission patterns throughout the visible/near‐infrared range both in uniform flakes and single‐interface lateral heterostructures. Here, this work demonstrates the judicious integration of pure and alloyed monochalcogenide crystals into multimaterial heterostructures with unique photonic properties, notably the ability to select photonic modes with targeted discrete energies through geometric factors rather than band engineering. SnS‐GeS 1− x Se x ‐GeSe‐GeS 1− x Se x heterostructures with a GeS 1− x Se x active layer sandwiched laterally between GeSe and SnS, semiconductors with similar optical constants but smaller bandgaps, were designed and realized via sequential vapor transport synthesis. Raman spectroscopy, electron microscopy/diffraction, and energy‐dispersive X‐ray spectroscopy confirm a high crystal quality of the laterally stitched components with sharp interfaces. Nanometer‐scale cathodoluminescence spectroscopy provides evidence for a facile transfer of electron–hole pairs across the lateral interfaces and demonstrates the selection of photon emission at discrete energies in the laterally embedded active (GeS 1− x Se x ) part of the heterostructure.

2D layered crystals↗
DOE OSTI2023

Comparative analysis of atmospheric parameters from high-resolution spectroscopic sky surveys: APOGEE, GALAH, Gaia -ESO

SDSS-IV APOGEE-2, GALAH, and Gaia-ESO are high-resolution, ground-based, multi-object spectroscopic surveys providing fundamental stellar atmospheric parameters and multiple elemental abundance ratios for hundreds of thousands of stars of the Milky Way. Data from these and other surveys contribute to investigations of the history and evolution of the Galaxy. We undertake a comparison between the most recent data releases of these surveys to investigate the accuracy and precision of derived parameters by placing the abundances on an absolute scale. We also discuss the correlations in parameter and abundance differences as a function of main parameters. Uncovering the variants provides a basis to continue the efforts of future sky surveys. Quality samples from the APOGEE-GALAH (15 537 stars), APOGEE-GES (804 stars), and GALAH-GES (441 stars) overlapping catalogs were collected. We investigated the mean variants between the surveys, and linear trends were also investigated. We compared the slope of correlations and mean differences with the reported uncertainties. The average and scatter of v rad , T eff , log g, [M/H], and v micro , along with numerous species of elemental abundances in the combined catalogs, show that in general there is a good agreement between the surveys. We find large radial velocity scatters ranging from 1.3 km s -1 to 4.4 km s -1 when comparing the three surveys. We observe some weak trends (e.g., in ΔT eff vs. Δlog g for the APOGEE-GES stars) and a clear correlation in the v micro - Δv micro planes in the APOGEE-GALAH common sample. For [α/H], [Ti/H] (APOGEE-GALAH giants), and [Al/H] (APOGEE-GALAH dwarfs) potential strong correlations are discovered as a function of the differences in the main atmospheric parameters, and we also find weak trends for other elements. In general we find good agreement between the three surveys within their respective uncertainties. However, there are certain regimes in which strong variants exist, which we discuss. There are still offsets larger than 0.1 dex in the absolute abundance scales.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Pure spin current injection of single-layer monochalcogenides

We compute the spectrum of pure spin current injection in ferroelectric single-layer SnS, SnSe, GeS, and GeSe. The formalism takes into account the coherent spin dynamics of optically excited conduction states split in energy by spin–orbit coupling. The velocity of the electron's spins is calculated as a function of incoming photon energy and angle of linearly polarized light within a full electronic band structure scheme using density functional theory. We find peak speeds of 520, 360, 270 and 370 Km s -1 for SnS, SnSe, GeS and GeSe, respectively which are an order of magnitude larger than those found in bulk semiconductors, e.g., GaAs and CdSe. Interestingly, the spin velocity is almost independent of the direction of polarization of light in a range of photon energies. Our results demonstrate that single-layer SnS, SnSe, GeS and GeSe are candidates to produce on demand spin-current in spintronics applications.

2D-monochalcogenides↗
DOE OSTI2022

The chemical characterization of halo substructure in the Milky Way based on APOGEE

Galactic haloes in a Λ-CDM universe are predicted to host today a swarm of debris resulting from cannibalized dwarf galaxies. The chemodynamical information recorded in their stellar populations helps elucidate their nature, constraining the assembly history of the Galaxy. Using data from APOGEE and Gaia , we examine the chemical properties of various halo substructures, considering elements that sample various nucleosynthetic pathways. The systems studied are Heracles, Gaia -Enceladus/Sausage (GES), the Helmi stream, Sequoia, Thamnos, Aleph, LMS-1, Arjuna, I’itoi, Nyx, Icarus, and Pontus. Abundance patterns of all substructures are cross-compared in a statistically robust fashion. Our main findings include: (i) the chemical properties of most substructures studied match qualitatively those of dwarf Milky Way satellites, such as the Sagittarius dSph. Exceptions are Nyx and Aleph, which are chemically similar to disc stars, implying that these substructures were likely formed in situ ; (ii) Heracles differs chemically from in situ populations such as Aurora and its inner halo counterparts in a statistically significant way. The differences suggest that the star formation rate was lower in Heracles than in the early Milky Way; (iii) the chemistry of Arjuna, LMS-1, and I’itoi is indistinguishable from that of GES, suggesting a possible common origin; (iv) all three Sequoia samples studied are qualitatively similar. However, only two of those samples present chemistry that is consistent with GES in a statistically significant fashion; (v) the abundance patterns of the Helmi stream and Thamnos are different from all other halo substructures.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

The detailed chemical abundance patterns of accreted halo stars from the optical to infrared

ABSTRACT Understanding the assembly of our Galaxy requires us to also characterize the systems that helped build it. In this work, we accomplish this by exploring the chemistry of accreted halo stars from Gaia-Enceladus/Gaia-Sausage (GES) selected in the infrared from the Apache Point Observatory Galactic Evolution Experiment (APOGEE) Data Release 16. We use high resolution optical spectra for 62 GES stars to measure abundances in 20 elements spanning the α, Fe-peak, light, odd-Z, and notably, the neutron-capture groups of elements to understand their trends in the context of and in contrast to the Milky Way and other stellar populations. Using these derived abundances we find that the optical and the infrared abundances agree to within 0.15 dex except for O, Co, Na, Cu, and Ce. These stars have enhanced neutron-capture abundance trends compared to the Milky Way, and their [Eu/Mg] and neutron-capture abundance ratios (e.g. [Y/Eu], [Ba/Eu], [Zr/Ba], [La/Ba], and [Nd/Ba]) point to r-process enhancement and a delay in s-process enrichment. Their [α/Fe] trend is lower than the Milky Way trend for [Fe/H] > −1.5 dex, similar to previous studies of GES stars and consistent with the picture that these stars formed in a system with a lower rate of star formation. This is further supported by their depleted abundances in Ni, Na, and Cu abundances, again, similar to previous studies of low-α stars with accreted origins.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Modeling Structured Electrodes and Graded Porosity for Improving Discharge Rate Capability in Ultra-Thick Graphite|LiNi 0.6 Mn 0.2 Co 0.2 O 2 Batteries

Long-range electric vehicles (EVs) require high-energy-density batteries that also meet the power demands of high current charge and discharge. Ultra-thick (>100 μm) Lithium-ion battery electrodes are critical to enable this need, but slow ion transport in conventional uniform electrodes (UEs) reduces battery capacity at increasing charge/discharge rates. We present a 3D computational analysis on the impact of structured electrode (SE) and graded electrode (GE) geometries on the discharge rate capability of ultra-thick graphite|LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC-622) battery cells based on the footprint of a commercial EV pouch cell. SE cathodes with either a “grid” or “line” geometry and GEs with two layers of porosity were modeled. Based on the results of 230 models, we found that the electrolyte volume fraction is a key parameter that impacts capacity improvements in UEs, GEs, and SEs at 2 C–6 C discharge rates. SEs have the greatest discharge rate capability, outperforming GEs and UEs due to reduced Lithium-ion concentration gradients across the electrode thickness, which mitigates electrolyte depletion at high rates. The best SE model has a “grid” geometry with gravimetric and volumetric energy density improvements of 0.9%–4% at C/2–2 C and 18%–24% at 4 C–6 C relative to UEs.

25 ENERGY STORAGE↗
DOE OSTI2024

Stellar Mergers or Truly Young? Intermediate-age Stars on Highly Radial Orbits in the Milky Way’s Stellar Halo

Reconstructing the mass assembly history of the Milky Way relies on obtaining detailed measurements of the properties of many stars in the galaxy, especially in the stellar halo. One of the most constraining quantities is stellar age, as it can shed light on the accretion time and quenching of star formation in merging satellites. However, obtaining reliable age estimates for large samples of halo stars is difficult. We report published ages of 120 subgiant halo stars with highly radial orbits that likely belong to the debris of the Gaia-Enceladus/Sausage (GES) galaxy. The majority of these halo stars are old, with an age distribution characterized by a median of 11.6 Gyr and a 16th (84th) percentile of 10.5 (12.7) Gyr. However, the distribution is skewed, with a tail of younger stars that span ages down to ~6–9 Gyr. All highly radial halo stars have chemical and kinematic/orbital quantities that associate them with the GES debris. Initial results suggest that these intermediate-age stars are not a product of mass transfer and/or stellar mergers, which can bias their age determination low. If this conclusion is upheld by upcoming spectrophotometric studies, then the presence of these stars will pose an important challenge for constraining the properties of the GES merger and the accretion history of the galaxy.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2023

The curious case of the structural phase transition in SnSe insights from neutron total scattering

Abstract At elevated temperatures SnSe is reported to undergo a structural transition from the low symmetry orthorhombic GeS-type to a higher symmetry orthorhombic TlI-type. Although increasing symmetry should likewise increase lattice thermal conductivity, many experiments on single crystals and polycrystalline materials indicate that this is not the case. Here we present temperature dependent analysis of time-of-flight (TOF) neutron total scattering data in combination with theoretical modeling to probe the local to long-range evolution of the structure. We report that while SnSe is well characterized on average within the high symmetry space group above the transition, over length scales of a few unit cells SnSe remains better characterized in the low symmetry GeS-type space group. Our finding from robust modeling provides further insight into the curious case of a dynamic order-disorder phase transition in SnSe, a model consistent with the soft-phonon picture of the high thermoelectric power above the phase transition.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Anomalous thermal transport in Eshelby twisted van der Waals nanowires

Dislocations in van der Waals (vdW) layered nanomaterials induce strain and structural changes that substantially impact thermal transport. Understanding these effects could enable the manipulation of dislocations for improved thermoelectric and optoelectronic applications, but experimental insights remain limited. Here, in this study, we use synthetic Eshelby twisted vdW GeS nanowires (NWs) with single screw dislocations as a model system to explore the interplay between dislocation-induced structural modifications and lattice thermal conductivity. Our measurements reveal a monoclinic structure stabilized by the dislocation, leading to a substantial drop in thermal conductivity for larger-diameter NWs (70% at room temperature), supported by first-principles calculations. Interestingly, we also find an anomalous enhancement of thermal conductivity with decreasing diameter in twisted NWs, contrary to typical trends in non-twisted GeS NWs. This is attributed to increased conductivity near the NW cores due to compressive strain around the central dislocations, and aligns with a density-functional-theory-informed core–shell model. Our results highlight the critical role of dislocations in thermal conduction, providing fundamental insights for defect and strain engineering in advanced thermal applications.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Chirality and dislocation effects in single nanostructures probed by whispering gallery modes

Nanostructures such as nanoribbons and -wires are of interest as components for building integrated photonic systems, especially if their basic functionality as dielectric waveguides can be extended by chiroptical phenomena or modifications of their optoelectronic properties by extended defects, such as dislocations. However, conventional optical measurements typically require monodisperse (and chiral) ensembles, and identifying emerging chiral optical activity or dislocation effects in single nanostructures has remained an unmet challenge. Here we show that whispering gallery modes can probe chirality and dislocation effects in single nanowires. Wires of the van der Waals semiconductor germanium(II) sulfide (GeS), obtained by vapor–liquid–solid growth, invariably form as growth spirals around a single screw dislocation that gives rise to a chiral structure and can modify the electronic properties. Cathodoluminescence spectroscopy on single tapered GeS nanowires containing joined dislocated and defect-free segments, augmented by numerical simulations and ab-initio calculations, identifies chiral whispering gallery modes as well as a pronounced modulation of the electronic structure attributed to the screw dislocation. Further, our results establish chiral light-matter interactions and dislocation-induced electronic modifications in single nanostructures, paving the way for their application in multifunctional photonic architectures.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Utah FORGE: Updated Seismic Event Catalogue from the April, 2022 Stimulation of Well 16A(78)-32

These are revised catalogs, related to the April, 2022 well 16A(78)-32 stimulation (phases 1,2, & 3), provided by Geo Energie Suisse (GES) that include additional events at the start of Stage 1 and some tidying up of some locations. These catalogs also include events for additional events that were auto-located to provide a larger dataset for statistical analyses, like b-value calculations. The actual auto-locations have been removed to prevent spurious location plots being created. Times are recorded in UTC (Coordinate Universal Time), and the coordinate reference system is UTM Zone 12N, NAD83.

15 GEOTHERMAL ENERGY↗
DOE OSTI2023

Co-Simulation of Electric Power Distribution Systems and Buildings including Ultra-Fast HVAC Models and Optimal DER Control

Smart homes and virtual power plant (VPP) controls are growing fields of research with potential for improved electric power grid operation. A novel testbed for the co-simulation of electric power distribution systems and distributed energy resources (DERs) is employed to evaluate VPP scenarios and propose an optimization procedure. DERs of specific interest include behind-the-meter (BTM) solar photovoltaic (PV) systems as well as heating, ventilation, and air-conditioning (HVAC) systems. The simulation of HVAC systems is enabled by a machine learning procedure that produces ultra-fast models for electric power and indoor temperature of associated buildings that are up to 133 times faster than typical white-box implementations. Hundreds of these models, each with different properties, are randomly populated into a modified IEEE 123-bus test system to represent a typical U.S. community. Advanced VPP controls are developed based on the Consumer Technology Association (CTA) 2045 standard to leverage HVAC systems as generalized energy storage (GES) such that BTM solar PV is better utilized locally and occurrences of distribution system power peaks are reduced, while also maintaining occupant thermal comfort. An optimization is performed to determine the best control settings for targeted peak power and total daily energy increase minimization with example peak load reductions of 25+%.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2020

Van der Waals Nanowires with Continuously Variable Interlayer Twist and Twist Homojunctions

Abstract Moiré patterns at van der Waals interfaces between twisted 2D crystals give rise to distinct optoelectronic excitations, as well as, narrowly dispersive bands responsible for correlated electron phenomena. Contrasting with the conventional, mechanically stacked planar twist moirés, recent work shows twisted van der Waals interfaces spontaneously formed in nanowires of layered crystals, where Eshelby twist due to axial screw dislocations stabilizes a chiral structure with small interlayer rotation. Here, the realization of tunable twist in germanium(II) sulfide (GeS) van der Waals nanowires is reported. Tapered nanowires host continuously variable interlayer twist. Homojunctions between dislocated (chiral) and defect‐free (achiral) segments are obtained by triggering the emission of axial dislocations during growth. Measurements across such junctions, implemented here using local absorption and luminescence spectroscopy, provide a convenient tool for detecting twist effects. The results identify a versatile system for 3D twistronics, probing moiré physics, and for realizing moiré architectures without equivalent in planar systems.

Sutter, Peter↗
DOE OSTI2021

Multilayer Lateral Heterostructures of Van Der Waals Crystals with Sharp, Carrier–Transparent Interfaces

Abstract Research on engineered materials that integrate different 2D crystals has largely focused on two prototypical heterostructures: Vertical van der Waals stacks and lateral heterostructures of covalently stitched monolayers. Extending lateral integration to few layer or even multilayer van der Waals crystals could enable architectures that combine the superior light absorption and photonic properties of thicker crystals with close proximity to interfaces and efficient carrier separation within the layers, potentially benefiting applications such as photovoltaics. Here, the realization of multilayer heterstructures of the van der Waals semiconductors SnS and GeS with lateral interfaces spanning up to several hundred individual layers is demonstrated. Structural and chemical imaging identifies {110} interfaces that are perpendicular to the (001) layer plane and are laterally localized and sharp on a 10 nm scale across the entire thickness. Cathodoluminescence spectroscopy provides evidence for a facile transfer of electron‐hole pairs across the lateral interfaces, indicating covalent stitching with high electronic quality and a low density of recombination centers.

36 MATERIALS SCIENCE↗