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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Regression and ratio estimators to integrate AVHRR and MSS data

Regression and ratio estimators are used to integrate AVHRR-Global Area Coverage (GAC) and Landsat MSS digital data to estimate forest area in the continental United States. Forestlands are enumerated for the 48 contiguous states using five different AVHRR-GAC data sets. Results indicated that the GAC and MSS forest estimates were not highly correlated. Although the ratio of means and linear regression corrections were, on the average, closer to national U.S. Forest Service forest area estimates, these correction procedures did not consistently improve GAC estimates of forest area. GAC forest area estimates tended to be high in densely forested regions such as the northeast and low in sparsely forested areas.

Nelson, Ross↗
DOE OSTI2022

PplD is a de-N-acetylase of the cell wall linkage unit of streptococcal rhamnopolysaccharides

The cell wall of the human bacterial pathogen Group A Streptococcus (GAS) consists of peptidoglycan decorated with the Lancefield group A carbohydrate (GAC). GAC is a promising target for the development of GAS vaccines. In this study, employing chemical, compositional, and NMR methods, we show that GAC is attached to peptidoglycan via glucosamine 1-phosphate. This structural feature makes the GAC-peptidoglycan linkage highly sensitive to cleavage by nitrous acid and resistant to mild acid conditions. Using this characteristic of the GAS cell wall, we identify PplD as a protein required for deacetylation of linkage N-acetylglucosamine (GlcNAc). X-ray structural analysis indicates that PplD performs catalysis via a modified acid/base mechanism. Genetic surveys in silico together with functional analysis indicate that PplD homologs deacetylate the polysaccharide linkage in many streptococcal species. We further demonstrate that introduction of positive charges to the cell wall by GlcNAc deacetylation protects GAS against host cationic antimicrobial proteins.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

Removal of radionuclides from acidic solution by activated carbon impregnated with methyl- and carboxy-benzotriazoles

The removal efficiencies of metals commonly used to model the fate and transport of aqueous uranium and radioactive its daughter products, were observed on activated carbons impregnated with different benzotriazole derivatives. Acidic solutions containing U(VI), Sr(II), Eu(III), and Ce(III) were used to determine the immobilization potential of carboxybenzotriazole (CBT) and methylbenzotriazole (MeBT), where these derivatives were sorbed to different types of granular activated carbon (GAC). This sorption behavior can be predicted by Redlich–Peterson model. Flow-through column tests showed that the immobilization of uranium and some of its daughter products, significantly improves in response to oxidized GACs saturated with carboxybenzotrzole (CBT), which reached a maximum elimination for U(VI) at 260 BV, Eu(III) at 114 BV, Ce(III) at 126 BV, and Sr(II) at 100. MeBT significantly desorbed from GAC under acidic conditions. Trace amounts of CBT were observed in some column effluents, but this did not appear to alter the effectiveness of metal removal, regardless of the model radionuclide studied. These results suggest that enhanced immobilization of selected metals on GAC, can be achieved by impregnating oxidized activated carbon with carboxylated benzotriazoles, and that metal removal efficiency on this media, is related to their valence and ionic radius in acidic environments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Changing bioavailability of per- and polyfluoroalkyl substances ($\mathrm{PFAS}$) to plant in biosolids amended soil through stabilization or mobilization

Biosolids containing per- and polyfluoroalkyl substances (PFAS) could contaminate the receiving environments once they are land applied. In this report, we evaluated the feasibility of controlling the bioavailability of PFAS in biosolids to timothy-grass through stabilization or mobilization approaches. Stabilization was accomplished by adding a sorbent (i.e. granular activated carbon (GAC), RemBind, biochar) to biosolids, while mobilization was achieved by adding a surfactant, sodium dodecyl sulphate (SDS), to biosolids. The results showed that the ΣPFAS concentration in grass shoots grown in biosolids amended soil treated by GAC or RemBind at 2% was only 2.77% and 3.35% of the ΣPFAS concentration detected in shoots grown in biosolids amended soil without a sorbent, respectively, indicating the effectiveness of GAC and RemBind for stabilizing PFAS and reduce their bioavailability. On the other hand, mobilization by adding SDS to biosolids at a dose range of 10–100 mg/kg significantly increased the plant uptake of ΣPFAS by 15.48%–108.57%. Thus, mobilization by adding SDS could be a valuable approach for enhancing the PFAS removal if phytoremediation is applied. Moreover, higher rate of PFAS uptake took place after grass cutting was observed in this study. Thus, proper mowing and regrowth of timothy-grass could lead to efficient and cost-effective removal of PFAS from biosolids amended soil through phytoremediation and leave the site clean to be used for other purposes.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

The efficacy and ecological impact of mercury sorbents on the physiology and reproductive fitness of Daphnia magna

Environmental mercury (Hg) contamination threatens ecosystems due to its bioaccumulation and toxicity. Effective and sustainable remediation strategies are essential, with carbon-based sorbents like biochar (BC) and activated carbon (AC) gaining attention for their high adsorption capacity and cost-effectiveness. However, their ecological impacts remain poorly understood. This study evaluates the Hg removal efficacy and ecological effects of three sorbents—BC, granular AC (GAC), and AC fiber (ACF)—in a flow-through column system with and without Hg additions. We tested Hg removal at two concentrations (1 and 4 µg/L Hg) and assessed chronic exposure effects on a sentinel and sensitive freshwater organism, Daphnia magna, over 30 days of exposure to the columns’ effluent. GAC removed 100 % of Hg, while BC and ACF achieved 99 % removal. The ACF + 4 µg/L Hg effluent induced 70 % lethality in D. magna after nearly three weeks of exposure, while the GAC effluent significantly reduced fecundity, even in the absence of Hg exposure. In contrast, the BC effluent enhanced reproductive output, likely due to inputs of carbon and nitrogen in the effluent. These findings highlight the need to balance Hg removal efficacy with ecological safety, emphasizing the importance of considering both remediation effectiveness and potential environmental impacts.

Activated carbon↗
DOE OSTI2024

An Ethics-Based Review of Generative Artificial Intelligence: Assuring Responsible Use (Version 1.0)

The rapid expansion of generative artificial intelligence (GenAI) has generated excitement regarding its potential benefits and concern over its ethical implications. Governments, corporations, and standards organizations have described ethical principles to direct GenAI's development and use; however, practical guidance for implementing these principles is limited. Addressing this gap is critical, especially considering the array of risks associated with GenAI, such as legal liabilities, privacy concerns, security threats, and potential misuse. Robust policies and procedures are critical to support responsible deployment of GenAI. This report examines Pacific Northwest National Laboratory (PNNL)’s approach to promoting responsible GenAI use. Proposed initiatives include developing policies based on ethical principles, creating a governance process to review projects relative to those principles, and implementing onboarding processes for training staff. The governance framework described in this report adapts the structure and principles of Institutional Review Boards (IRBs), traditionally used in human subjects research, for GenAI ethical review, providing oversight. Ethical principles guiding responsible GenAI usage include transparency and accountability, privacy, fairness, safety, security, and validity and reliability. To operationalize these principles, we propose forming a GenAI Assurance Council (GAC) that mirrors the IRB's structure. The GAC will evaluate GenAI projects across privacy, accountability, transparency, safety, security, fairness, and validity dimensions. Complementing policy and governance is AI literacy training to support staff understanding of GenAI's ethical implications. An initial training effort for AI Incubator Chat—a GenAI tool deployed at PNNL—showed promising results, underscoring the importance of clear guidelines and user accountability. Collaborative efforts and the dissemination of best practices are also discussed. The proposed GAC model and AI literacy training provide a blueprint for establishing ethical GenAI use and governance, offering practical tools to bridge the gap between ethical principles and real-world applications. The responsible integration of GenAI at PNNL entails a multifaceted approach involving policy development, ethical governance, and AI literacy training. The positive initial feedback and collaborative opportunities position PNNL to lead by example in GenAI's responsible use, reflecting a proactive stance in addressing the ethical, legal, and societal challenges associated with this emerging technology. PNNL's systematic and ethical approach to GenAI offers a model for other institutions to emulate, promoting safe and responsible technological advancements in the AI domain.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS1986

Identifying deforestation in Brazil using multiresolution satellite data

The use of multiresolution satellite data to monitor deforestation on a continental/subcontinental scale is examined. MSS, local area coverage (LAC), global area coverage (GAC), and GOES data were applied to the study of deforestation in Rondonia, Brazil; the characteristics of these sensors are described. The probability thresholding and vegetation-index thresholding procedures used to process the data in order to differentiate between forest from nonforest are analyzed. The LAC, GAC, and GOES data are compared to MSS data. It is observed that GOES data is not useful for monitoring colonization projects due to excessive noise in the data; the GAC data is only applicable in large areas of contiguous forest clearing; the MSS data when available is applicable as a ground data reference source for differentiating cleared areas from primary; the LAC data are capable of delineating colonization clearings; and the probability thresholding procedure differentiates forest from nonforest more accurately than the vegetation-index procedure. The data reveal that the LAC data combined with the probability threshold procedure provide the best data-source/classification-procedure combination.

Nelson, R.↗
NASA NTRS2012

Experimental Sonic Boom Measurements on a Mach 1.6 Cruise Low-Boom Configuration

A wind tunnel test has been conducted by Gulfstream Aerospace Corporation (GAC) to measure the sonic boom pressure signature of a low boom Mach 1.6 cruise business jet in the Langley Unitary Plan Wind Tunnel at Mach numbers 1.60 and 1.80. Through a cooperative agreement between GAC and the National Aeronautics and Space Administration (NASA), GAC provided NASA access to some of the experimental data and NASA is publishing these data for the sonic boom research community. On-track and off-track near field sonic boom pressure signatures were acquired at three separation distances (0.5, 1.2, and 1.7 reference body lengths) and three angles of attack (-0.26deg, 0.26deg, and 0.68deg). The model was blade mounted to minimize the sting effects on the sonic boom signatures. Although no extensive data analysis is provided, selected data are plotted to illustrate salient features of the data. All of the experimental sonic boom pressure data are tabulated. Schlieren images of the configuration are also included.

Wilcox, Floyd J., Jr.↗
NASA NTRS2019

The Effects of High-Temperature Fractional Crystallization on Calcium Isotopic Composition

We report Ca isotope fractionation among a co-genetic suite of samples from the Mauritanian Guelb el Azib ultramafic-mafic-anorthosite complex (GAC), which represents the fractional crystallization sequence of an igneous magma chamber. We investigate how the composition of an evolving crystallizing liquid and the resultant mineralogy of co-crystallizing assemblages affects inter-phase Ca isotope fractionation. Because the GAC is an Archean metamorphosed complex, we first investigate the resistance of the Ca isotope signature to secondary hydrothermal alteration and to metamorphism. While we cannot conclude here that Ca isotopes are undisturbed at the mineral scale, we show that they are preserved at the bulk rock scale. This is adequate for our study where several samples are almost monomineralic at the bulk scale level. The δ(exp 44/40)Ca (relative to NIST standard SRM 915a) of GAC layers range from −1.53 to 1.61‰, with the earliest-formed ultramafic cumulate layer being isotopically heaviest and the later, more felsic layers being isotopically lighter. For the first time, we show that plagioclase is much more enriched in light Ca isotopes compared to olivine and (Ca-) pyroxene. Monte Carlo simulations suggest that Ca isotopes are fractionated among co-existing silicate minerals during fractional crystallization, possibly in relation with the residual liquid composition. In qualitative agreement with computational models based on first principles lattice dynamics, we observe that Ca isotope fractionation is mineralogically controlled and importantly, that the degree of fractionation can vary according to the CaO composition of the residual liquid. While previous studies have aimed to understand partial melting as a source of Ca isotope fractionation, our results suggest that fractional crystallization is also a source of Ca isotope variability among co-genetic samples.

Maria C. Valdes↗
NASA NTRSDate not supplied

TPSAS-NF1676L-35283-DND

In this talk, we present a long-term burned area database that has been developed using Advanced Very High Resolution Radiometer (AVHRR) Global Area Coverage (GAC) data from 1979-2000. Burned area has been verified using Total Ozone Mapping Spectrometer data and validated using available Landsat imagery (160 scenes thus far representing 5.6 Mha of burned area, 219 fire events, and 11% of the total burned area in the AVHRR database). Visually the burned scar data compare well. Validation is in ongoing, though initial analyses show an intersection of 42% with commission and omission errors of 31% and 25%, respectively. Most commission and omission errors are related to spatial inconsistencies using imagery with significantly different spatial resolutions. Of the fire events missed by AVHRR (omissions), 86% are related to fires <10,000 ha (6 GAC pixels) and 44% are related to fires <3,000ha (2 GAC pixels). Total burned area compares well, with the AVHRR database under-representing burned area by 10% compared to the Landsat data analyzed. Correlation in burned scar area between the AVHRR and Landsat data is 0.98 for all fires and 0.68 for fires that are < 0.1 Mha.

Amber Soja↗
DOE OSTI2023

Application of electron beam technology to decompose persistent emerging drinking water contaminants: poly- and perfluoroalkyl substances (PFAS) and 1,4 dioxane.

Fermi Research Alliance, LLC (FRA) operates Fermilab under contract with the U.S. Department of Energy and has patents on technologies and applications of a novel mobile electron beam accelerator. A high-power version of this mobile accelerator based on FRA-developed SRF technology is under development at Illinois Accelerator Research Center (IARC) and can enable several new applications that have significant commercial potential. One such application is the e-beam treatment of persistent emerging contaminants in drinking water. The contaminants of concern are poly- and perfluoroalklyl substances (PFAS) and 1,4-dioxine. Both PFAS and 1,4-D are highly resistant to degradation and are not effectively removed by conventional drinking water treatment systems. Existing technologies, such as granular activated carbon (GAC) filters and reverse osmosis (RO) systems do not decompose. The Center for Clean Water Technology (CCWT) at Stony Brook University (SBU) is in the process of identifying and testing effective technologies to remove PFAS and/or 1,4-D from drinking waters. se PFAS, but rather concentrate them either by adsorption (GAC) or membrane rejection (RO). The Center for Clean Water Technology (CCWT) at Stony Brook University (SBU) is in the process of identifying and testing effective technologies to remove PFAS and/or 1,4-D from drinking waters to demonstrate the full-scale application of novel water treatment technologies and is experienced in conducting research to understand treatment performance with a particular focus on 1,4-D and PFAS contamination.

43 PARTICLE ACCELERATORS↗
NASA NTRS1976

Dynamic control of SRB thrust tailoff for separation

The use of the difference in chamber pressure between solid rocket booster engines as a controlling signal to the flight control system during booster thrust tailoff was examined. In addition, the control capability of the Generalized Attitude Control System (GACS) was compared to that of the baseline. Results indicate that the difference in chamber pressure signal provided essentially no improvement. However, the GACS is considerably better than the baseline in controlling during tailoff disturbances.

Webb, W. W.↗
NASA NTRS1986

Satellite remote sensing of rangelands in Botswana. II - NOAA AVHRR and herbaceous vegetation

The relation between the normalized difference vegetation index (NDVI) and the herbaceous vegetation in Tamasane, Shakwe, and Masama in eastern Botswana is studied using 1983-1984 AVHRR data. The procedures for Landsat MSS interpolation of ground measurements and the data processing of the AVHRR data are described. The temporal sequence AVHRR global-area coverage (GAC) composite NDVI is examined. The AVHRR GAC composite NDVI and biomass and Landsat MSS interpolations of field measurements are analyzed and compared.

Prince, S. D.↗
NASA NTRS1993

Climate Sensitivity Studies of the Greenland Ice Sheet Using Satellite AVHRR, SMMR, SSM/I and in Situ Data

The feasibility of using satellite data for climate research over the Greenland ice sheet is discussed. In particular, we demonstrate the usefulness of Advanced Very High Resolution Radiometer (AVHRR) Local Area Coverage (LAC) and Global Area Coverage (GAC) data for narrow-band albedo retrieval. Our study supports the use of lower resolution AVHRR (GAC) data for process studies over most of the Greenland ice sheet. Based on LAC data time series analysis, we can resolve relative albedo changes on the order of 2-5%. In addition, we examine Scanning Multichannel Microwave Radiometer (SMMR) and Special Sensor Microwave Imager (SSM/I) passive microwave data for snow typing and other signals of climatological significance. Based on relationships between in situ measurements and horizontally polarized 19 and 37 GHz observations, wet snow regions are identified. The wet snow regions increase in aerial percentage from 9% of the total ice surface in June to a maximum of 26% in August 1990. Furthermore, the relationship between brightness temperatures and accumulation rates in the northeastern part of Greenland is described. We found a consistent increase in accumulation rate for the northeastern part of the ice sheet from 1981 to 1986.

Steffen, K.↗
NASA NTRS2007

Quiet Spike Build-Up Ground Vibration Testing Approach

NASA's Dryden Flight Research Center uses a modified F-15B (836) aircraft as a testbed for a variety of flight research:experiments mounted underneath the aircraft fuselage. The F-15B was selected to fly Gulfstream Aerospace Corporation's (GAC)QuietSpike(TM)(QS) project; however, this experiment is very unique and unlike any of the previous testbed experiments flown on the F-15B. It involves the addition of a relatively long quiet spike boom attached to the radar bulkhead of the aircraft. This QS experiment is a stepping stone to airframe structural morphing technologies designed to mitigate sonic born strength of business jets over land. The QS boom is a concept in Which an aircraft's front-end would be extended prior to supersonic acceleration. This morphing would effectively lengthen the aircraft, reducing peak sonic boom amplitude, but is also expected to partition the otherwise strong bow shock into a series of reduced-strength, non-coalescing shocklets. Prior to flying the Quietspike(TM) experiment on the F-15B aircraft several ground vibration tests (GVT) were required in order to understand the QS modal characteristics and coupling effects with the F-15B. However, due to the project's late hardware delivery of the QS and the intense schedule, a "traditional" GVT of the mated F-1513 Quietspike(tm) ready-for-flight configuration would not have left sufficient time available for the finite element model update and flutter analyses before flight testing. Therefore, a "nontraditional" ground vibration testing approach was taken. The objective of the QuietSpike (TM) build-up ground testing approach was to ultimately obtain confidence in the F-15B Quietspike(TM) finite element model (FEM) to be used for the flutter analysis. In order to obtain the F15B QS FEM with reliable foundation stiffness between the QS and the F-15B radar bulkhead as well as QS modal characteristics, several different GVT configurations were performed. EAch of the four GVT's performed had a specific objective. The overall intent was to provide adequate data which would replicate a "traditional" F-15B QS GVT with actual ready-for-flight hardware. NASA Dryden was tasked with the conduct of the 1st, 2nd and 4th GVT and the 3rd GVT was GAC's responsibility. In order for this build-up GVT approach to be feasible, it was absolutely critical that each GVT configuration matched as closely as possible the connection interface configuration between the and aircraft bulkhead.

Spivey, Natalie D.↗
NASA NTRS2007

F15B-Quiet Spike Aeroservoelastic Flight Test Data Analysis

Airframe structural morphing technologies designed to mitigate sonic boom strength are being developed by Gulfstream Aerospace Corporation (GAC). Among these technologies is a concept in which an aircraft's frontend would be extended prior to supersonic acceleration. This morphing would effectively lengthen the vehicle, reducing peak sonic boom amplitude, but is also expected to partition the otherwise strong bow shock into a series of reduced-strength, non-coalescing shocklets. This combination of boom shaping techniques is predicted to transform the classic, high-impulse N-wave pattern typically generated by an aircraft traveling at supersonic speed into a signature more closely resembling a sinusoidal wave with a greatly reduced perceived loudness. 'QuietSpike' is GAC's nomenclature for its recently patented front-end vehicle morphing arrangement. The ability of Quiet Spike to effectively shape a vehicle's far- field sonic boom signature is highly dependent on the area distribution characteristics of the aircraft. The full aeroacoustic benefits of front-end morphing at farfield are only possible when the QuietSpike article and vehicle configuration are designed in consideration of each other. Adding QuietSpike technology to the airframe of an existing, non-boom-optimized supersonic vehicle is unlikely to result in an improved far-field signature due to the generally over-powering influence of wing- and inlet-generated shocks. Therefore, it is generally recognized within NASA and the industry that a clean-sheet vehicle design is required to demonstrate the theoretically predicted far-field aeroacoustic benefits of QuietSpike type morphing and other boom- mitigating concepts. NASA's Aeronautics Research Mission Directorate (ARMD) Supersonics Division has placed increased priority on near-term development and flight-testing of such a vehicle. To help achieve this objective, static and dynamic aerostructural proof-of-concept testing was considered a prudent step prior to a clean-sheet effort in order to reduce risk associated with a follow-on test program. Following a survey of potential test platforms, NASA Dryden's F-15B was selected as the target test vehicle primarily because of its unique ability to carry a largescale test apparatus to relevant supersonic flight speeds, so called the F15 -QS. The QuietSpike test article was constructed primarily of composite materials and attached to the forward fuselage of the F-1 5B bulkhead (see Figures 1,2). The QuietSpike test article replaces the current flight test noseboom and radome assembly. Power is supplied to the Quiet Spike motor assembly in order to extend and retract the Spike, and the Quiet Spike test article was appropriately instrumented with accelerometers, strain gages, pressure transducers, and thermocouples.

Brenner, Martin J.↗
NASA NTRS2006

Three-Function Logic Gate Controlled by Analog Voltage

The figure is a schematic diagram of a complementary metal oxide/semiconductor (CMOS) electronic circuit that performs one of three different logic functions, depending on the level of an externally applied control voltage, V(sub sel). Specifically, the circuit acts as A NAND gate at V(sub sel) = 0.0 V, A wire (the output equals one of the inputs) at V(sub sel) = 1.0 V, or An AND gate at V(sub sel) = -1.8 V. [The nominal power-supply potential (VDD) and logic "1" potential of this circuit is 1.8 V.] Like other multifunctional circuits described in several prior NASA Tech Briefs articles, this circuit was synthesized following an automated evolutionary approach that is so named because it is modeled partly after the repetitive trial-and-error process of biological evolution. An evolved circuit can be tested by computational simulation and/or tested in real hardware, and the results of the test can provide guidance for refining the design through further iteration. The evolutionary synthesis of electronic circuits can now be implemented by means of a software package Genetic Algorithms for Circuit Synthesis (GACS) that was developed specifically for this purpose. GACS was used to synthesize the present trifunctional circuit. As in the cases of other multifunctional circuits described in several prior NASA Tech Briefs articles, the multiple functionality of this circuit, the use of a single control voltage to select the function, and the automated evolutionary approach to synthesis all contribute synergistically to a combination of features that are potentially advantageous for the further development of robust, multiple-function logic circuits, including, especially, field-programmable gate arrays (FPGAs). These advantages include the following: This circuit contains only 9 transistors about half the number of transistors that would be needed to obtain equivalent NAND/wire/AND functionality by use of components from a standard digital design library. If multifunctional gates like this circuit were used in the place of the configurable logic blocks of present commercial FPGAs, it would be possible to change the functions of the resulting digital systems within shorter times. For example, by changing a single control voltage, one could change the function of thousands of FPGA cells within nanoseconds. In contrast, typically, the reconfiguration in a conventional FPGA by use of bits downloaded from look-up tables via a digital bus takes microseconds.

Zebulum, Ricardo↗