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Results for “GAS COMPOSITION”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS2009

Application of carbon nanotube hold-off voltage for determining gas composition

Method and system for determining chemical composition of a single-component or multiple-component gas, using a discharge holdoff mechanism. A voltage difference V between two spaced apart electrodes is brought to a selected value and held, the holdoff time interval .DELTA.t(V;ho) required before gas discharge occurs is measured, and the associated electrical current or cumulative electrical charge is measured. As the voltage difference V increases, the time interval length .DELTA.t(V;ho) decreases monotonically. Particular voltage values, V.sub..infin. and V.sub.0, correspond to initial appearance of discharge (.DELTA.t.apprxeq..infin.) and prompt discharge (.DELTA.t.apprxeq.0). The values V.sub..infin. and V.sub.0 and the rate of decrease of .DELTA.t(V;ho) and/or the rate of increase of current or cumulative charge with increasing V are characteristic of one or more gas components present.

Schipper, John F.↗
NASA NTRS1986

Spectroscopic aspects of differential method for sounding gas composition of the atmosphere

The problems concerning the dynamics of populations of the sounded atmospheric gas molecule levels taking into account the nonmonochromatic character of radiation, durations of exciting and sounding pulses, rates of relaxation of excited vibration-rotation states population along different channels in a natural multicomponent mixture of gases and air were investigated. The problems of spectroscopic software, completeness and accuracy of the initial spectroscopic information, information on channels and rates of relaxation from the viewpoint of developing specific schemes of sounding are discussed. The values of deviations of vibration-rotation level populations of some atmospheric molecules from their equilibrium value at simultaneous action of double frequency radiation on the sounding path and the corresponding dynamic variation of lidar return amplitude were estimated. The importance of nonlinear spectrosopic effects in the lidar return value variation at sounding radiation frequency equaling the resonance frequency of vibration-rotation transition in the problem on sounding the humidity profiles and concentrations of gaseous pollutants was also estimated.

Zuev, V. V.↗
NASA NTRS2008

Gas composition sensing using carbon nanotube arrays

A method and system for estimating one, two or more unknown components in a gas. A first array of spaced apart carbon nanotubes (''CNTs'') is connected to a variable pulse voltage source at a first end of at least one of the CNTs. A second end of the at least one CNT is provided with a relatively sharp tip and is located at a distance within a selected range of a constant voltage plate. A sequence of voltage pulses {V(t.sub.n)}.sub.n at times t=t.sub.n (n=1, . . . , N1; N1.gtoreq.3) is applied to the at least one CNT, and a pulse discharge breakdown threshold voltage is estimated for one or more gas components, from an analysis of a curve I(t.sub.n) for current or a curve e(t.sub.n) for electric charge transported from the at least one CNT to the constant voltage plate. Each estimated pulse discharge breakdown threshold voltage is compared with known threshold voltages for candidate gas components to estimate whether at least one candidate gas component is present in the gas. The procedure can be repeated at higher pulse voltages to estimate a pulse discharge breakdown threshold voltage for a second component present in the gas.

Li, Jing↗
NASA NTRS2016

The Impact of ENSO on Trace Gas Composition in the Upper Troposphere to Lower Stratosphere

The El Nino-Southern Oscillation (ENSO) is the dominant mode of interannual variability in the tropical troposphere and its effects extend well into the stratosphere. Its impact on atmospheric dynamics and chemistry cause important changes to trace gas constituent distributions. A comprehensive suite of satellite observations, reanalyses, and chemistry climate model simulations are illuminating our understanding of processes like ENSO. Analyses of more than a decade of observations from NASAs Aura and Aqua satellites, combined with simulations from the Goddard Earth Observing System Chemistry-Climate Model (GEOSCCM) and other Chemistry Climate Modeling Initiative (CCMI) models, and the Modern-Era Retrospective Analysis for Research and Applications, version 2 (MERRA-2) reanalysis have provided key insights into the response of atmospheric composition to ENSO. While we will primarily focus on ozone and water vapor responses in the upper troposphere to lower stratosphere, the effects of ENSO ripple through many important trace gas species throughout the atmosphere. The very large 2015-2016 El Nino event provides an opportunity to closely examine these impacts with unprecedented observational breadth. An improved quantification of natural climate variations, like those from ENSO, is needed to detect and quantify anthropogenic climate changes.

ENSO↗
NASA NTRS2018

The Gas Composition and Deep Cloud Structure of Jupiter's Great Red Spot

We have obtained high-resolution spectra of Jupiter's Great Red Spot (GRS) between 4.6-5.4 microns using telescopes on Mauna Kea to derive gas abundances and to constrain its cloud structure between 0.5-5 bars. We used line profiles of deuterated methane (CH3D) at 4.66 microns to infer the presence of an opaque cloud at 5 plus or minus 1 bars. From thermochemical models, this is almost certainly a water cloud. We also used the strength of Fraunhofer lines in the GRS to obtain the ratio of reflected sunlight to thermal emission. The level of the reflecting layer was constrained to be at 570 plus or minus 30 millibars based on fitting strong NH3 lines at 5.32 microns. We identify this layer as an ammonia cloud based on the temperature where gaseous NH3 condenses. We found evidence for a strongly absorbing but not totally opaque cloud layer at pressures deeper than 1.3 bars by combining Cassini/CIRS (Composite Infrared Spectrometer) spectra of the GRS at 7.18 microns with ground-based spectra at 5 microns. This is consistent with the predicted level of an NH4SH cloud. We also constrained the vertical profile of H2O and NH3. The GRS spectrum is matched by a saturated H2O profile above an opaque water cloud at 5 bars. The pressure of the water cloud constrains Jupiter's O/H ratio to be at least 1.1 times solar. The NH3 mole fraction is 200 plus or minus 50 ppm (parts per million) for pressures between 0.7-5 bars. Its abundance is 40 ppm at the estimated pressure of the reflecting layer. We obtained 0.8 plus or minus 0.2 ppm for PH3, which is a factor of 2 higher than in the warm collar surrounding the GRS. We detected all five naturally occurring isotopes ofgermanium in GeH4 in the GRS. We obtained an average value of 0.35 plus or minus 0.05 ppb (parts per billion) for GeH4. Finally, we measured 0.8 plus or minus 0.2 ppb for CO in the deep atmosphere.

Bjoraker, G. L.↗
NASA NTRS1982

Clouds and wet removal as causes of variability in the trace-gas composition of the marine troposphere

A modeling study of the effects of clouds and wet removal on the chemistry of the remote marine troposphere is described. Using a time-dependent model with parameterized vertical transport to calculate trace-gas concentrations, it is found that large variations in key species (e.g., HNO3, H2CO, and H2O2) result from simulations of sporadic rainfall, changes in cloud cover, and external inputs such as surface NO sources. Depending on the frequency and intensity of an event, the effects of these perturbations may persist for several days, thereby invalidating assumptions of photochemical equilibrium in the interpretation of measurements. Long-term integrations with fixed boundary conditions and regularly occurring cloud and rain episodes demonstrate a strong sensitivity of the mean concentration of longer-lived soluble gases to precipitation frequency but also confirm the validity of using properly chosen parameterizations of wet removal in steady state calculations.

Thompson, A. M.↗
NASA NTRS2012

Gas Composition Sensing Using Carbon Nanotube Arrays

This innovation is a lightweight, small sensor for inert gases that consumes a relatively small amount of power and provides measurements that are as accurate as conventional approaches. The sensing approach is based on generating an electrical discharge and measuring the specific gas breakdown voltage associated with each gas present in a sample. An array of carbon nanotubes (CNTs) in a substrate is connected to a variable-pulse voltage source. The CNT tips are spaced appropriately from the second electrode maintained at a constant voltage. A sequence of voltage pulses is applied and a pulse discharge breakdown threshold voltage is estimated for one or more gas components, from an analysis of the current-voltage characteristics. Each estimated pulse discharge breakdown threshold voltage is compared with known threshold voltages for candidate gas components to estimate whether at least one candidate gas component is present in the gas. The procedure can be repeated at higher pulse voltages to estimate a pulse discharge breakdown threshold voltage for a second component present in the gas. The CNTs in the gas sensor have a sharp (low radius of curvature) tip; they are preferably multi-wall carbon nanotubes (MWCNTs) or carbon nanofibers (CNFs), to generate high-strength electrical fields adjacent to the tips for breakdown of the gas components with lower voltage application and generation of high current. The sensor system can provide a high-sensitivity, low-power-consumption tool that is very specific for identification of one or more gas components. The sensor can be multiplexed to measure current from multiple CNT arrays for simultaneous detection of several gas components.

Li, Jing↗
NASA NTRS1993

Tropospheric gas composition and cloud structure of the Jovian North Equatorial Belt

Voyager IRIS observations of the NEB reveal longitudinal variability of 5-micron brightness temperatures of order 100 C. An anisotropic multiple scattering radiative transfer model is used to calculate synthetic spectra for comparison with the IRIS observations. Mie theory is used to model the spectral dependence of cloud extinction from 180 to 2300/cm. Cloud base locations within the model vary with assumed gas abundances according to thermochemical equilibrium. It is found that spatial variations in the abundance profiles of the condensible species, parahydrogen profiles and cloud optical depths can be used as tracers of the local and large-scale dynamics. The variation of cloud opacity is strongly correlated with the variation of relative humidity, which suggests that dynamic depletion of water vapor above the cloud forming level is the most plausible model to explain the spatial variation in the water profile within the NEB.

Carlson, Barbara E.↗
NASA NTRS1979

Venus upper atmosphere neutral gas composition - First observations of the diurnal variations

Measurements of the composition, temperature, and diurnal variations of the major neutral constituents in the thermosphere of Venus are being made with a quadrupole mass spectrometer on the Pioneer Venus Orbiter. Concentrations of carbon dioxide, carbon monoxide, molecular nitrogen, atomic oxygen, and helium are presented, in addition to an empirical model of the data. The concentrations of the heavy gases, carbon dioxide, carbon monoxide, and molecular nitrogen, rapidly decrease from the evening terminator toward the nightside; the concentration of atomic oxygen remains nearly constant and the helium concentration increases, an indication of a nightside bulge. The kinetic temperature inferred from scale heights drops rapidly from 230 K at the terminator to 130 K at a solar zenith angle of 120 deg, and to 112 K at the antisolar point.

Niemann, H. B.↗
NASA NTRS1979

Implications of the gas compositional measurements of Pioneer Venus for the origin of planetary atmospheres

Comparisons are made between the volatile inventories of the terrestrial planets, including Pioneer Venus data, and the predictions of three classes of theories for the origin of planetary atmospheres. Serious difficulties arise for the primary atmosphere and external source hypotheses. The grain accretion hypothesis can account for the trends in the volatile inventory from Venus to earth to Mars, if volatiles were incorporated into planet-forming grains at nearly the same temperature for all of these planets, but at systematically lower pressures in the regions of planet formation farther from the center of the solar nebula.

Pollack, J. B.↗
NASA NTRS1986

The gas composition of Jupiter derived from 5 micron airborne spectroscopic observations

It is pointed out that Jupiter's 5-micron spectrum is a very diagnostic observational tool to probe the troposphere of this giant planet. A report is presented of abundance analyses of NH3, PH3, CH4, CH3D, CO, and GeH4 in the 1- to 6-bar pressure range in Jupiter's troposphere. All the considered molecules have been previously detected in ground-based, airborne, and spacecraft observations of Jupiter. The contribution made by the present study is related to a self-consistent simultaneous determination of the abundances of all of these molecules at the same physical level in Jupiter's atmosphere using one high spectral resolution dataset and a radiative transfer model. It is found that most abundances deviate significantly from expectations based upon an atmospheric model assuming solar composition and chemical equilibrium. The D/H ratio in Jupiter is comparable to that measured in the interstellar medium.

Bjoraker, G. L.↗
DOE OSTI2025

Fabrication and Scale-Up of Porous Polybenzimidazole (PBI) Supports for Gas Separation Composite Membranes

Industrial gas separation often uses thin film composite (TFC) membranes comprising a porous support overlaid with a single-/multi-layer gas-selective thin film. An optimal porous support should possess high surface porosity to minimize gas transport resistance and nano-sized pores to ease pore penetration occurring during the thin film coating process. Good chemical and thermal stabilities are essential to withstand the aggressive solvents and heat required for the thin film coating and curing. However, few porous membranes satisfy all these requirements. This study presents a scalable membrane formation method of making highly porous polybenzimidazole (PBI) supports via non-solvent induced phase separation. This presentation also details the scale-up fabrication of PBI supports using a custom roll-to-roll membrane casting machine.

gas separation↗
NASA NTRSDate not supplied

A Study of the Kinetics of the CO Oxidation Catalyst in a Human Spaceflight Fire Cartridges as a Method to Understand and Predict Performance

Fire Cartridges (FC) are an integral part of fire response on ISS, Orion and Gateway. When a pair of FCs are integrated with an Emergency Mask, they can be used to provide safe breathing air on these vehicles in a post-fire environment. The FCs have two primary mechanisms for removing contaminants from the air, an activated carbon (AC) bed which adsorbs the majority of fire byproducts, and a catalyst bed consisting of gold nanoparticles supported on iron oxide which oxidized CO to CO2 under near ambient conditions. While the FC catalyst has proven its ability to convert CO under relevant conditions, this paper attempts to address the apparent inconsistent performance of the catalyst seen in testing. Numerous variables effect the performance of the catalyst, including but not limited to: reaction environment, reactant gas composition, inert gas composition, catalyst age, and catalyst lot. This paper discusses the importance of these variables and attempts a fundamental mechanistic explanation for the effects of each variable. The fundamental mechanisms are then used to establish the magnitude of expected performance variability, which were validated against real test data of flight quality FCs.

Fire Cartridge↗