Phase boundary motion and polyphase diffusion in binary metal-interstitial systems.
Polyphase diffusion and interface growth in binary metal interstitial systems via Fick first law, deriving parabolic growth law for interface motion
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Polyphase diffusion and interface growth in binary metal interstitial systems via Fick first law, deriving parabolic growth law for interface motion
Crack propagation model in linearly viscoelastic solid strip based on thermodynamics first law
Pressure-permeation experiments were performed with the concentration-clamp cell. Streaming potentials and hydraulic permeabilities were measured for an AMF C-103 cation-exchange membrane bounded by 0.1 N NaCl solutions. The streaming potential calculated from the slope of the recorded potential differences versus the applied pressure, yields a value of 1.895 millivolt/dekabar. When comparison with other membranes of similar characteristics could be made, good agreement was found. The values of the hydraulic permeability varied somewhat with the applied pressure difference and are between 1.3 x 10 to the minus 8th power and 3.9 x 10 to the minus 8th power sq cm/dekabar-sec. The specific hydraulic permeabilities were also calculated and compared with data from the literature. Fair agreement was found. The diffusion coefficient of the chloride ion in the AMF C-103 membrane was calculated, using Fick's first law of diffusion based on ion concentrations calculated from the Donnan equilibrium concentration of Cl(-).
Subcritical crack growth in a linear viscoelastic material subjected to cyclic loading is investigated starting with the thermodynamic power balance. Physically, it is supposed that the subcritical slow crack growth is due to local weakening of the material in the neighborhood of the crack tip. Under fatigue loading it is assumed that all energy dissipation goes into heat and that this heat build-up is the dominant irreversible process governing crack growth. The cycle averaged temperature distribution around the crack tip is obtained from local application of the first law of thermodynamics (i.e., conservation of energy). The analysis leads to the solution of a nonlinear integro-differential equation for crack length as a function of time which is coupled with the local energy equation. A regular perturbation technique is used to obtain an analytical solution which compares very well with experimental results.
A single station vertical velocity equation which considers ageostrophic and diabatic effects derived from the first law of thermodynamics and a generalized thermal wind relation is presented. An analysis and verification procedure which accounts for measurement and calculation errors as well as time and space continuity arguments and theoretical predictions are described. Vertical velocities are calculated at every kilometer between 25 and 60 km and for approximately every three hours for the above diurnal period at Kourou (French Guiana), Fort Sherman (Panama Canal Zone), Ascension Island, Antigua (British West Indies) and Natal (Brazil). The results, plotted as time series cross sections, suggest vertical motions ranging in magnitude from 1 or 2 cm/sec at 30 km to as much as 15 cm/sec at 60 km. Many of the general features of the results agree well with atmospheric tidal predictions but many particular features suggest that both smaller time scale gravity waves (periods less than 6 hours) and synoptic type waves (periods greater than 1 day) may be interacting significantly with the tidal fields. The results suggest that vertical motions can be calculated for the equatorial middle atmosphere and must be considered a significant part of the motion for time scales from 8 to 24 hours.
An expression is derived for the wave action flux of finite-amplitude Alfven waves in a multi-ion plasma. The expression is valid in the presence of dissipative forces and permits an arbitrary angle between the average magnetic field and the wave vector. Applying the conservation of wave action and the first law of thermodynamics yields, for a multi-ion plasma, an expression for the spatial evolution of Alfven wave amplitude in the absence of dissipation. It also gives the relationship between the wave amplitude and the dissipative heating, as well as an expression for the acceleration of an ion species by finite-amplitude Alfven waves. It is pointed out that the acceleration comprises a nondissipative wave pressure that is identical to that derived previously under more restrictive conditions and a new term giving the acceleration that must accompany dissipative heating. The results are discussed in the context of the observations of heavy ions in the solar wind.
The settling behavior of the liquid and gaseous phases of a fluid in a propellant and in a zero-g environment, when such settling is induced through the use of a dynamic device, in this particular case, a helical screw was studied. Particular emphasis was given to: (1) the description of a fluid mechanics model which seems applicable to the system under consideration, (2) a First Law of Thermodynamics analysis of the system, and (3) a discussion of applicable scaling rules.
The objective of this experiment and lesson intended for high school students in an engineering or materials science course or college freshmen is to demonstrate the relation between processing, structure, and thermodynamic and physical properties. The specific objectives are to show the effect of structure and structural changes on thermodynamic properties (specific heat) and physical properties (compressive strength); to illustrate the first law of thermodynamics; to compare boiling a potato in water with cooking it in a microwave in terms of the rate of structural change and the energy consumed to 'process' the potato; and to demonstrate compression testing.
A summary of research into on-orbit cryogenic fluid transfer at the NASA Lewis Research Center (LRC) is presented. Variable test parameters and liquid injection configurations elucidated the conditions necessary for a successful transfer of liquid hydrogen by the no-vent fill method. The model is based on conservation of mass and a first-law energy balance for a control volume. The ullage, the bulk liquid, and the tank wall are each represented by a single node. The magnitude of the maximum receiver tank pressure was found to be dependent on the liquid inlet temperature, the inlet mass flow rate, and the initial temperature. A comparison of the test data and the analytical results for a no-vent fill test with a small receiver tank is presented.
A study of the high-temperature oxidation of several aircraft construction materials was undertaken to assess the possibility of ignition under high-temperature flight conditions.Tests have been made both in open and closed jets, and, in addition, the burning of metals has been observed under static conditions in a pressurized vessel containing either air, oxygen, or nitrogen. When heated in an atmosphere of oxygen or when heated and plunged into a supersonic airstream, titanium, iron, carbon steel, and common alloys such as 4130 were found to have spontaneous-ignition temperatures in the solid phase (below melting) and they melted rapidly while burning. Inconel, copper, 18-8 stainless steel, Monel, and aluminum could not be made to ignite spontaneously at temperatures up to melting with the equipment available. Magnesium ignited spontaneously in either type of test at temperatures just above the melting temperature.A theory for the spontaneous ignition of metals, based on the first law of thermodynamics, is presented. Good correlation was obtained between calculated spontaneous-ignition temperatures and values measured in supersonic jet tests. There appears at the present time to be no need for concern regarding the spontaneous ignition of Inconel, the stainless steels, copper, aluminum, or magnesium for ordinary supersonic airplane or missile applications where the material temperature is kept within ordinary structural limits or at least below melting. For hypersonic applications where the material is to be melted away to absorb the heat of convection, the results of the present tests do not apply sufficiently to allow a conclusion.
Many articles have based the solution of trajectory optimization of a lunar lander on minimizing fuel consumption. This optimization is attempted by minimizing the burn-time of the descent engine, or by maximizing the total mass of the vehicle during the maneuver. The general myth, is that minimizing fuel is possible. However, the first law of thermodynamics cannot be violated. Therefore, the work that the descent engine must do to dissipate the energy of the vehicle from orbit to landing is constant. The higher the power setting of the engine, the less time it takes to dissipate the total mechanical energy, but it does not save any fuel.
We consider the discontinuous Galerkin (DG) finite element discretization of first order systems of conservation laws derivable as moments of the kinetic Boltzmann equation. This includes well known conservation law systems such as the Euler For the class of first order nonlinear conservation laws equipped with an entropy extension, an energy analysis of the DG method for the Cauchy initial value problem is developed. Using this DG energy analysis, several new variants of existing numerical flux functions are derived and shown to be energy stable.
A scale-invariant statistical theory of fields is presented that leads to invariant definition of density, velocity, temperature, and pressure, The definition of Boltzmann constant is introduced as k(sub k) = m(sub k)v(sub k)c = 1.381 x 10(exp -23) J x K(exp -1), suggesting that the Kelvin absolute temperature scale is equivalent to a length scale. Two new state variables called the reversible heat Q(sub rev) = TS and the reversible work W(sub rev) = PV are introduced. The modified forms of the first and second law of thermodynamics are presented. The microscopic definition of heat (work) is presented as the kinetic energy due to the random (peculiar) translational, rotational, and pulsational motions. The Gibbs free energy of an element at scale Beta is identified as the total system energy at scale (Beta-1), thus leading to an invariant form of the first law of thermodynamics U(sub Beta) = Q(sub Beta) - W(sub Beta) +N(e3)U(sub Beta-1).
The application of active control technology to suppress flutter was demonstrated successfully in the transonic dynamics tunnel with a delta-wing model. The model was a simplified version of a proposed supersonic transport wing design. An active flutter suppression method based on an aerodynamic energy criterion was verified by using three different control laws. The first two control laws utilized both leading-edge and trailing-edge active control surfaces, whereas the third control law required only a single trailing-edge active control surface. At a Mach number of 0.9 the experimental results demonstrated increases in the flutter dynamic pressure from 12.5 percent to 30 percent with active controls. Analytical methods were developed to predict both open-loop and closed-loop stability, and the results agreed reasonably well with the experimental results.
The effects of active controls on flutter suppression and gust alleviation of the Arava twin turboprop STOL transport and the Westwind twinjet business transport are investigated. The active control surfaces are introduced in pairs which include, in any chosen wing strip, a 20-percent chord leading-edge control and a 20-percent chord trailing-edge control. Each control surface is driven by a combined linear-rotational sensor system located on the activated strip. The control law is based on the concept of aerodynamic energy and utilizes previously optimized control law parameters based on two-dimensional aerodynamic theory. The best locations of the activated system along the span of the wing are determined for bending-moment alleviation, reduction in fuselage accelerations, and flutter suppression. The effectiveness of the activated system over a wide range of maximum control deflections is also determined. Two control laws are investigated. The first control law utilizes both rigid-body and elastic contributions of the motion. The second control law employs primarily the elastic contribution of the wing and leads to large increases in the activated control effectiveness as compared with the basic control law. The results indicate that flutter speed can be significantly increased (over 70 percent increase) and that the bending moment due to gust loading can be almost totally eliminated by a control system of about 10 to 20 percent span with reasonable control-surface rotations.
Several new computational algorithms are presented to compute the deadbeat predictive control law. The first algorithm makes use of a multi-step-ahead output prediction to compute the control law without explicitly calculating the controllability matrix. The system identification must be performed first and then the predictive control law is designed. The second algorithm uses the input and output data directly to compute the feedback law. It combines the system identification and the predictive control law into one formulation. The third algorithm uses an observable-canonical form realization to design the predictive controller. The relationship between all three algorithms is established through the use of the state-space representation. All algorithms are applicable to multi-input, multi-output systems with disturbance inputs. In addition to the feedback terms, feed forward terms may also be added for disturbance inputs if they are measurable. Although the feedforward terms do not influence the stability of the closed-loop feedback law, they enhance the performance of the controlled system.
The paper presents analytical and experimental comparison of two control laws for a laboratory structure designed to simulate large space structures. The first control law is the standard linear quadratic law, which is optimal but requires model reduction for practical implementation. The second control law is a new simple direct feedback control law designed to minimize control forces while guaranteeing stability. The optimal control law was found to be only slightly better than the direct feedback law even in terms of the quadratic performance index. Moreover, the optimal control law provided almost no margin of stability for the unmodeled modes while the direct feedback law provided significant stability margins to all modes. The above results were verified experimentally using a digital implementation of the control laws. Excellent agreement between the analytical prediction and experimental measurements was observed.
This paper presents analytical and experimental comparison of three control laws for a laboratory structure designed to simulate large space structures. The first control law is the standard time invariant linear quadratic regulator with state estimation, which requires model reduction for practical implementation. This model reduction is associated with the so-called spillover instability. Two new simple direct output feedback control laws guaranteeing stability are proposed. One minimizes the maximum control force, and the other minimizes the same quadratic performance index as the linear quadratic regulator. The three control laws are found to give comparable performance for the modes retained in the reduced model. However, the standard linear quadratic regulator with state estimation provides almost no margin of stability for the unmodeled modes, while the simpler direct feedback laws provide significant stability margins to all modes. The analytical results were verified experimentally using a digital implementation of the control laws. Good agreement between the analytical predictions and experimental measurements was observed.