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At least 37 records · Page 2

Characterization of the Benefit of APS Flash Coatings in Improving TBC Lifetime

The addition of an air plasma sprayed (APS) “flash” layer on top of a high velocity oxygen fuel (HVOF) bond coating has been shown to extend the lifetime of thermal barrier coatings. A series of furnace cycle tests (FCTs) has been conducted at 1100 °C in air + 10% H 2 O to study the benefit of flash coatings on rod and disk alloy 247 specimens and provide a better mechanistic understanding of their benefit. Flash coatings of NiCoCrAlY and NiCoCrAlYHfSi both improved the FCT lifetime of rod specimens tested in 100-h cycles and disk specimens tested in 1-h cycles. In 1-h cycles, the NiCoCrAlY flash coating significantly outperformed an HVOF-only NiCoCrAlYHfSi bond coating and a NiCoCrAlYHfSi flash coating. Both flash coatings increased the bond coating roughness compared to HVOF. During exposure, the flash layer formed an intermixed alumina-metal layer that appeared to inhibit crack formation. Using a time series of observations, the lower Y + Hf content in the Y-only flash coating appeared to reduce Al consumption. The HVOF layer acted as a source of Al for the adjacent mixed zone. A second series of specimens included a fully APS bond coating where oxide had penetrated through the entire coating to the substrate after only 100, 1-h cycles and lifetime was similar to an HVOF-only bond coating. The inner HVOF layer with the outer APS flash coating prevented this complete penetration from occurring.

Pint, Bruce↗

Hypervelocity impact flash expansion geometry under various spacecraft surface electrical conditions

A more congested space environment due to increasing space activities introduces new threats to spacecraft operators. Among these threats include hypervelocity impacts from microparticles (< 1 µg) in the form of meteoroids and space debris. These microparticles travel at speeds between 11.2 and 72.8 km/s with respect to the Earth and can impact spacecraft forming a small (~1 µm) and dense (~ 10 26 m -3 ) plasma. This plasma can generate a strong optical emission (impact flash) and a radio frequency (RF) emission. These emissions can lead to spacecraft electrical anomalies when the impacted spacecraft surface (target) carries high electrical potential due to various space weather effects. To understand the microparticle hypervelocity impact plasma and its associated threat to spacecraft electronics, we studied the hypervelocity impact flash expansion geometry under various spacecraft surface electrical conditions. Three high-speed broadband photomultiplier tubes (PMT) are used to capture the temporal evolution of the impact flash and the temporal evolution of the angular distribution of the impact flash expansion geometry in a 3 MV electrostatic dust accelerator during a ground-based experiment. Overall, results indicate that the impact surface electrical condition has a statistically significant influence on the impact flash geometry, and a strong similarity between the impact plasma and flash expansion geometry. Thus, this paper provides new experimental support for the impact flash origin from and connection with the impact plasma, and serves as the first impact flash expansion geometry characterization under various impact surface electrical conditions in a collisionless environment (< 10 -5 Torr).

42 ENGINEERING↗

Changes to the Appearance of Optical Lightning Flashes Observed From Space According to Thunderstorm Organization and Structure

Optical lightning observations from space reveal a wide range of flash structure. Lightning imagers such as the Geostationary Lightning Mapper and Lightning Imaging Sensor measure flash appearance by recording transient changes in cloud top illumination. The spatial and temporal optical energy distributions reported by these instruments depend on the physical structure of the flash and the distribution of hydrometeors within the thundercloud that scatter and absorb the optical emissions. This study reported herein explores how flash appearance changes according to the scale and organization of the parent thunderstorms with a focus on mesoscale convective systems. Clouds near the storm edge are frequently illuminated by large optical flashes that remain stationary between groups. These flashes appear large because their emissions can reflect off the exposed surfaces of nearby clouds to reach the satellite. Large stationary flashes also occur in small isolated thunderstorms. Optical flashes that propagate horizontally, meanwhile, are most frequently observed in electrified stratiform regions where extensive layered charge structures promote lateral development. Highly radiant “superbolts” occur in two scenarios: embedded within raining stratiform regions or in nonraining boundary/anvil clouds where optical emissions can take a relatively clear path to the satellite.

54 ENVIRONMENTAL SCIENCES↗

Assessing the Impact of Lightning NOx Emissions in CMAQ Using Lightning Flash Data from WWLLN over the Contiguous United States

Comparison of lightning flash data from the National Lightning Detection Network (NLDN) and from the World Wide Lightning Location Network (WWLLN) over the contiguous United States (CONUS) for the 2016–2018 period reveals temporally and spatially varying flash rates that would influence lightning NO x (LNO x ) production due to known detection efficiency differences especially during summer months over land (versus over ocean). However, the lightning flash density differences between the two networks show persistent seasonal patterns over geographical regions (e.g., land versus ocean). Since the NLDN data are considered to have higher accuracy (lightning detection with >95% efficiency), we developed scaling factors for the WWLLN flash data based on the ratios of WWLLN to NLDN flash data over time (months of year) and space. In this study, sensitivity simulations using the Community Multiscale Air Quality (CMAQ) model are performed utilizing the original data sets (both NLDN and WWLLN) and the scaled WWLLN flash data for LNO x production over the CONUS. The model performance of using the different lightning flash datasets for ambient O 3 and NO x mixing ratios that are directly impacted by LNO x emissions and the wet and dry deposition of oxidized nitrogen species that are indirectly impacted by LNO x emissions is assessed based on comparisons with ground-based observations, vertical profile measurements, and satellite products. During summer months, the original WWLLN data produced less LNO x emissions (due to its lower lightning detection efficiency) compared to the NLDN data, which resulted in less improvement in model performance than the simulation using NLDN data as compared to the simulation without any LNO x emissions. However, the scaled WWLLN data produced LNO x estimates and model performance comparable with the NLDN data, suggesting that scaled WWLLN may be used as a substitute for the NLDN data to provide LNO x estimates in air quality models when the NLDN data are not available (e.g., due to prohibitive cost or lack of spatial coverage).

54 ENVIRONMENTAL SCIENCES↗

Reactive flash sintering of TiZrN and TiAlN ternary metal nitrides

Here, this study demonstrated the reactive flash sintering (RFS) for two powder mixtures: TiN-ZrN (both conducting) and AlN-TiN (TiN conducting but AlN insulating), targeting ternary metal nitrides (TMN) of Ti 0.5 Zr 0.5 N and Ti 0.5 Al 0.5 N, respectively. A constant volage and pressure (e.g., 8 V DC, ∼15 MPa) at room temperature triggered the flash (current density up to 27 A/mm 2 ) without pre-heating, and the entire RFS process finished in a few minutes. For TiZrN, the flash was instantaneous whereas for TiAlN, there was a long incubation before the flash followed by a quick and dramatic flash. Both conventional ex situ XRD and in situ synchrotron study had been carried out. They showed a uniform Ti 0.57 Zr 0.43 N solution formed in RFS and persisted upon cooling, while (Ti, Al) N solid solution formed at high temperature was not stable and likely went through a very quick phase separation in the cooling process. The final products from RFS had been characterized using SEM/EDS for microstructure. Both TiZrN and TiAlN were dense. Distribution of Ti, Zr, and N was uniform for TiZrN; for TiAlN, Ti and N distribution was uniform, while association of Al with oxygen was observed. TGA-DSC revealed the onset oxidation temperature for TiZrN was comparable to TiN and ZrN, while it was higher by ∼200 °C for TiAlN, likely due to the formation of Al 2 O 3 . In terms of mechanical properties such as hardness or fracture toughness, forming a single-phase solid solution (like TiZrN) does not offer obvious benefits. while large grain size from RFS seemed to be unfavorable. Future optimization of RFS condition and in-depth study by both experiments and simulation are needed to fully understand the composition-processing-structure-property relationships for such TMN from the reactive flash sintering process.

Flash Sintering↗

Detecting flash drought events to inform adaptive water management

Abstract: Flash droughts are characterized by a rapid onset of drought conditions, a common feature among various indicators of these events. The lack of a standardized definition and indicator makes flash droughts particularly challenging to predict and manage. We test six state-of-the-art flash drought indicators using 41 years of daily data across all Hydrological Unit Code 4 (HUC4) regions in the contiguous United States. Our results show substantial disagreements among indicators, suggesting that the detection of a flash drought event strongly depends on the choice of indicator. From the perspective of informing management and operations, an open challenge remains: which flash drought indicator should be used to trigger operational adaptations? To this end, we propose a methodological framework that informs adaptive actions by regionally assessing the level of agreement between different indicators. The regional differences in hydroclimatic conditions are expected to be reflected in the level of agreement between indicators. To better inform adaptive actions, the framework will also consider the impacted sectoral water uses and their varying response times. The insights gained from this study improve the understanding of how these different flash drought indicators capture the different aspects of regional differences and impacted sectors. Furthermore, this information can support more targeted adaptive actions to mitigate adverse impacts through improved preparedness and response strategies.

climate resilience↗

Combined Optical and Radio-Frequency Perspectives on a Hybrid Cloud-To-Ground Lightning Flash Observed by the FORTE Satellite

In this work, we use the coincident optical and radio-frequency (RF) measurements taken by the Fast On-orbit Recording of Transient Events (FORTE) satellite to shed light on common optical signatures recorded by NASA and NOAA lightning imagers during Cloud-to-Ground (CG) lightning. We build flash cluster data for FORTE using the same techniques as the NASA/NOAA instruments to document the optical/RF evolution of an oceanic hybrid -CG flash. The flash began with strong Very High Frequency (VHF)-band emission from a Narrow Bipolar Event (NBE) that initiated a period of normal bilevel intracloud (IC) activity in two vertical layers (8 and 12 km) that lasted for 490 ms. VHF waveforms show step leader activity ahead of the return stroke. All impulsive VHF sources after the stroke come from the lower (8 km) layer. K-changes are noted following the return stroke, but no subsequent strokes are detected. The optical flash began 136 ms after the NBE RF pulse. Twenty-two of the 33 optical groups were dim and occurred during the in-cloud phase of the flash. This activity included both isolated pulses and sustained periods of illumination over tens of milliseconds. Initial cloud pulses accounted for 23% of the total optical radiance from the flash. Illumination during the return stroke contributed 58% of the total radiance, and the K-changes and cloud pulses after the stroke supplied the remaining 19%. These results highlight the benefit of having RF alongside optical lightning measurements for clarifying signatures in the optical data and providing information on their physical origins.

54 ENVIRONMENTAL SCIENCES↗

A pronounced decline in northern vegetation resistance to flash droughts from 2001 to 2022

Climate change has led to the transition of droughts into rapid and intensified phenomena known as flash droughts, presenting considerable challenges for risk management, particularly concerning their impact on ecosystem productivity. Quantifying the ecosystem’s capacity to maintain productivity during flash droughts, referred to as ecosystem resistance, is crucial to assess drought impacts. However, it remains uncertain how the resistance of ecosystem productivity to flash drought changes over time. Here we show that vegetation resistance to flash droughts declines by up to 27% (±5%) over the Northern Hemisphere hotspots during 2001-2022, including eastern Asia, western North America, and northern Europe. The notable decline in vegetation resistance is mainly attributed to increased vapour pressure deficit and temperature, and enhanced vegetation structural sensitivity to water availability. Flash droughts pose higher ecological risks than slowly-developing droughts during the growing seasons, where ecosystem productivity experiences faster decline rates with a shorter response time. Our results underscore the limited ecosystem capacity to resist flash droughts under climate change.

54 ENVIRONMENTAL SCIENCES↗

Flash electropolishing for TEM: Reducing FIB‐induced defects in tungsten with protocols for new materials

Focused ion beam (FIB) milling has become the dominant approach for site-specific transmission electron microscopy (TEM) specimen preparation; however, FIB damage remains a critical limitation for reliable microstructural characterisation, particularly in radiation effects studies. Tungsten is especially susceptible to FIB damage due to its high nuclear stopping power, which promotes the formation and strong diffraction contrast of FIB-induced ‘black spot’ defects that are indistinguishable from very fine irradiation-induced loops/defects resulting from low to intermediate temperature neutron irradiation. In this work, flash electropolishing is systematically evaluated as a post-FIB treatment for minimising preparation-induced artefacts for TEM analysis of tungsten-based alloys. Using a range of non-, ion-, and neutron-irradiated tungsten materials, the effectiveness of flash electropolishing has been assessed through direct comparison with conventional FIB and plasma-FIB preparation including low-energy Ga, Ar, Xe ion cleaning. The results demonstrate that flash electropolishing effectively removes FIB-damaged layers and ‘black spot’ defects, thereby enabling reliable observation of irradiation-induced dislocation structures. Key processing parameters governing flash electropolishing quality – including lamella thickness, applied voltage, polishing duration, electrolyte chemistry, and cathode geometry – have been systematically evaluated, and clear criteria were established for determining when flash electropolishing is required to ensure reliable microstructural analysis. This work also provides practical guidance for implementing flash electropolishing as an artefact-controlled specimen-preparation approach for TEM characterisation of FIB-produced specimens. The systematic protocol can be extended to other, non-tungsten materials.

TEM sample preparation↗

Navigating Epistemic Uncertainty in the Management of Flash Droughts

Abstract: Flash droughts, characterized by their rapid onset, sharply contrast with the typically gradual development of traditional droughts. These events are triggered by a combination of low rainfall and high evaporation rates, driven by elevated temperatures, making them particularly challenging to predict and prepare for. As a relatively new concept, flash drought is not well understood, which introduces significant epistemic uncertainties regarding their nature and detection methods. This under-detection hinders planners' ability to effectively manage these events. Despite these uncertainties, flash droughts can have significant impacts, raising the question: how can decision-makers prepare for such events given the current knowledge gaps? To address this, we propose a methodological framework aimed at enhancing flash drought preparedness by guiding the selection of appropriate indicators based on their detection capabilities and the decision-makers' level of risk aversion. Our approach involves evaluating six different flash drought indicators and analyzing the level of agreement among them. Additionally, we consider the decision-makers' risk aversion, distinguishing between those who require consensus across all methods (risk-takers) and those who act based on a single method's indication (risk-averse). The insights gained from this study offer a pathway towards more informed decision-making processes regarding flash droughts, potentially mitigating their adverse effects through better preparedness and response strategies.

climate resilience↗

Machine Learning Guided Synthesis of Flash Graphene

Advances in nanoscience have enabled the synthesis of nanomaterials, such as graphene, from low-value or waste materials through flash Joule heating. Though this capability is promising, the complex and entangled variables that govern nanocrystal formation in the Joule heating process remain poorly understood. In this work, machine learning (ML) models are constructed to explore the factors that drive the transformation of amorphous carbon into graphene nanocrystals during flash Joule heating. An XGBoost regression model of crystallinity achieves an r 2 score of 0.8051 ± 0.054. Feature importance assays and decision trees extracted from these models reveal key considerations in the selection of starting materials and the role of stochastic current fluctuations in flash Joule heating synthesis. Furthermore, partial dependence analyses demonstrate the importance of charge and current density as predictors of crystallinity, implying a progression from reaction-limited to diffusion-limited kinetics as flash Joule heating parameters change. Finally, a practical application of the ML models is shown by using Bayesian meta-learning algorithms to automatically improve bulk crystallinity over many Joule heating reactions. Furthermore, these results illustrate the power of ML as a tool to analyze complex nanomanufacturing processes and enable the synthesis of 2D crystals with desirable properties by flash Joule heating.

01 COAL, LIGNITE, AND PEAT↗

New Total-Ionizing-Dose Resistant Data Storing Technique for NAND Flash Memory

This paper describes a new non-charge-based data storing technique in NAND flash memory called watermark that encodes read-only data in the form of physical properties of flash memory cells. Unlike traditional charge-based data storing method in flash memory, the proposed technique is resistant to total ionizing dose (TID) effects. To evaluate its resistance to irradiation effects, we analyze data stored in several commercial single-level-cell (SLC) flash memory chips from different vendors and technology nodes. These chips are irradiated using a Co-60 gamma-ray source array for up to 100 krad(Si) at Sandia National Laboratories. Experimental evaluation performed on a flash chip from Samsung shows that the intrinsic bit error rate (BER) of watermark increases from 0.8% for TID = 0 krad(Si) to 1% for TID = 100 krad(Si). Conversely, the BER of charge-based data stored on the same chip increases from 0% at TID = 0 krad(Si) to 1.5% at TID = 100 krad(Si). Overall, the results imply that the proposed technique may potentially offer significant improvements in data integrity relative to traditional charge-based data storage for very high radiation (TID > 100 krad(Si)) environments. These gains in data integrity relative to the charge-based data storage are useful in radiation-prone environments, but they come at the cost of increased write times and higher BERs before irradiation.

36 MATERIALS SCIENCE↗

Quantitative Comparisons of Image Quality for Flash X-Ray Detectors

Due to X-rays’ ability to penetrate materials, flash X-ray radiography can be used for high-speed measurements where direct optical access is not possible. Choice of detector has a pronounced impact on resulting image quality. Four different detector systems were evaluated with a 450kVp flash source to quantitatively compare image quality metrics. The scintillating digital detector had less image noise than the three different storage phosphor computed radiography detectors across all transmission levels, but lacked the spatial resolution of the computed radiography detectors. For the screens tested here, the HPX-DR digital system had the highest signal to noise ratio of 68.24 and contrast to noise ratio of 35.53, but had the lowest spatial resolution, resolving 2.5 line pairs per millimeter at 1.78% contrast. At a value of 37.59, the Flex GP imaging plate had a signal to noise value above its storage phosphor counterparts under a 450kVp flash source. For radiographic setups typically used for dynamic experiments, the Flex XL Blue and Flex HR detectors had signal to noise ratios of 18.44 and 26.56 respectively. The highest resolved spatial frequencies of the Flex GP, Flex XL Blue, and Flex HR with the flash source are 3.85, 5.00, and 3.85 line pairs per millimeter, respectively. In conclusion, the Flex GP detector had the best combination of signal to noise ratio, contrast to noise ratio, and spatial resolution under a flash source.

computed radiography↗

Model development for flash boiling spray and validations with isooctane, hexane, ethanol and their binary mixtures

The objective of this study is to develop a comprehensive model for spray atomization under the consideration of flash boiling, which includes nucleation, bubble growth, and droplet breakup. Although flash boiling has been previously studied, there is still no well-established analytical and numerical model of their mechanisms, or general guidelines on the implementation of this atomization strategy. In this study, detailed formulations are elaborated for the unified spray atomization model under both non-flash and flash boiling conditions. Next, the model was implemented into CFD software and 3-D simulations were performed for model validations. Two fuel blends are tested: ethanol-isooctane blends and hexane-isooctane blends. Simulation results were compared with the experimental measurements conducted using two methodologies, DBI (Diffuse Backlight Imaging) system for spray images captured by a high-speed camera, and a PDA (Phase Doppler Anemometry) system for droplet size measurement during the spray injection process. It was found that the current flash boiling model can accurately capture the spray characteristics under different environment conditions, such as the spray plume interactions and liquid penetration. The averaged Sauter mean diameter (SMD) calculations match the measurement sufficiently well. The spray structures for both single- and multi-component fuels during the injection process are well represented by current model.

42 ENGINEERING↗

Towards understanding the development and characteristics of under-expanded flash boiling jets

Here in this research, the n-hexane jets discharged from a straight channel were studied numerically to reveal the development and characteristics of under-expanded flashing jets. Firstly, the development of flash boiling jets was investigated and compared to that of two-phase jets without phase transition. It was shown that the two-phase jets without phase transition can be under-expanded only if the flow is choked. In contrast, flash boiling jets can be under-expanded whether or not the choked conditions are verified. Secondly, the factors affecting the flashing jet behaviors were discussed. The relaxation time in phase transition, the expansion ratio, and the injection pressure have been identified as three key factors determining the jet characteristics. With high enough expansion ratio and low enough relaxation time, the expansion was so strong that the flow became transonic and shock structures similar to those of under-expanded gaseous jets appeared near the orifice exit. Finally, two types of choking have been identified for flash boiling jets, i.e., vaporization-induced choking and expansion-induced choking. The former one is mainly ascribed to the vapor formation in the orifice which reduces the local speed of sound, while the latter one is due to the expansion of under-expanded two-phase flow and the resultant flow acceleration.

42 ENGINEERING↗

Megavolt bremsstrahlung measurements from linear induction accelerators demonstrate possible use as a FLASH radiotherapy source to reduce acute toxicity

Abstract Recent studies indicate better efficacy and healthy tissue sparing with high dose-rate FLASH radiotherapy (FLASH-RT) cancer treatment. This technique delivers a prompt high radiation dose rather than fractional doses over time. While some suggest thresholds of > 40 Gy s −1 with a maximal effect at > 100 Gy s −1 , accumulated evidence shows that instantaneous dose-rate and irradiation time are critical. Mechanisms are still debated, but toxicity is minimized while inducing apoptosis in malignant tissue. Delivery technologies to date show that a capability gap exists with clinic scale, broad area, deep penetrating, high dose rate systems. Based on these trends, if FLASH-RT is adopted, it may become a dominant approach except in the least technologically advanced countries. The linear induction accelerator (LIA) developed for high instantaneous and high average dose-rate, species independent charged particle acceleration, has yet to be considered for this application. We review the status of LIA technology, explore the physics of bremsstrahlung-converter-target interactions and our work on stabilizing the electron beam. While the gradient of the LIA is low, we present our preliminary work to improve the gradient by an order of magnitude, presenting a point design for a multibeam FLASH-RT system using a single accelerator for application to conformal FLASH-RT.

42 ENGINEERING↗

Machine learning-assisted ultrafast flash sintering of high-performance and flexible silver–selenide thermoelectric devices

Flexible thermoelectric generators (TEGs) have shown immense potential for serving as a power source for wearable electronics and the Internet of Things. A key challenge preventing large-scale application of TEGs lies in the lack of a high-throughput processing method, which can sinter thermoelectric (TE) materials rapidly while maintaining their high thermoelectric properties. Herein, we integrate high-throughput experimentation and Bayesian optimization (BO) to accelerate the discovery of the optimum sintering conditions of silver–selenide TE films using an ultrafast intense pulsed light (flash) sintering technique. Due to the nature of the high-dimensional optimization problem of flash sintering processes, a Gaussian process regression (GPR) machine learning model is established to rapidly recommend the optimum flash sintering variables based on Bayesian expected improvement. For the first time, an ultrahigh-power factor flexible TE film (a power factor of 2205 μW m -1 K -2 with a zT of 1.1 at 300 K) is demonstrated with a sintering time less than 1.0 second, which is several orders of magnitude shorter than that of conventional thermal sintering techniques. Further, the films also show excellent flexibility with 92% retention of the power factor (PF) after 10 3 bending cycles with a 5 mm bending radius. In addition, a wearable thermoelectric generator based on the flash-sintered films generates a very competitive power density of 0.5 mW cm -2 at a temperature difference of 10 K. This work not only shows the tremendous potential of high-performance and flexible silver–selenide TEGs but also demonstrates a machine learning-assisted flash sintering strategy that could be used for ultrafast, high-throughput and scalable processing of functional materials for a broad range of energy and electronic applications.

25 ENERGY STORAGE↗

Measurement of DC Arc-Flash Incident Energy in Large-Scale Photovoltaic Plants: A Basis for Standardization

The deployment of high-power dc equipment is increasing in solar photovoltaic (PV) plants, but very few studies have quantified dc arc-flash risks. Currently, PV plant owners and operators rely on theoretical, simplified models, such as those in NFPA-70E and other publications, for the assessment of risk associated with dc arc-flash. Here, this article presents an overview of arc-flash risks in a PV system based on a series of field experiments based on IEEE-1584 in two large-scale ground-mounted PV plants. The experiments include various high-power dc equipment of a PV plant, such as central inverters, combiner boxes, recombiner boxes, string inverters, and multiple configurations of electrodes in a 20-in calibration cube. The study reveals that none of the available dc arc-flash models are applicable for a PV plant. This work is an important first step toward developing an improved model that more accurately assesses dc arc-flash risk in a PV plant.

14 SOLAR ENERGY↗