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Dielectric and magnetic properties of microwave-absorbing FeAl x O y catalysts fabricated via solution combustion synthesis

Iron-based alumina (FeAl x O y ) nanocomposites are microwave-absorbers and catalysts, which makes them promising for emerging microwave-assisted thermocatalytic technologies. Solution combustion synthesis (SCS) has been used to synthesize FeAl x O y powders, and prior work has demonstrated that adjusting SCS parameters significantly changes phase composition and specific surface area of the products. However, it is unclear how synthesis parameters affect their microwave-absorbing properties, which are essential for optimizing microwave-assisted technologies. To address this challenge, in the present work, twelve different FeAl x O y products were synthesized at different combinations of the SCS parameters such as two fuels (citric acid and glycine), two heating modes (hotplate and muffle furnace), and three Fe:Al molar ratios (2:1, 1:1, 1:2). Dielectric and magnetic properties of the products were characterized using a network analyzer and a vibrating sample magnetometer. Based on the measured permittivity and permeability, penetration depth and reflection loss were calculated as a function of frequency and bed thickness. The products were heated by microwaves at 2.45 GHz and then examined with X-ray diffraction (XRD) analysis. For all products, the magnetic saturation was lower than for bulk iron oxides because of the small crystallite size and aluminum substitution. The use of glycine induced high dielectric losses and enabled fast microwave-heating rates compared to citric acid. Higher Fe:Al ratio also led to higher dielectric and magnetic losses. With glycine fuel, SCS in a furnace induced larger penetration depth and lower microwave absorption than SCS on a hotplate. The minimization of reflected power was more sensitive to the thickness of the product bed than to the frequency of the electromagnetic field. Post-heating XRD analysis revealed different phase transformations in the FeAl x O y powders depending on the SCS parameters. As a result, an FeAl x O y material, synthesized via incipient wetness impregnation, lacked magnetic losses and did not heat well as compared to the SCS products.

Combustion synthesis

Part-body and multibody effects on absorption of radio-frequency electromagnetic energy by animals and by models of man

Fine structure in the whole-body resonant curve for radio-frequency energy deposition in man can be attributed to part-body resonances. As for head resonance, which occurs near 350 MHz in man, the absorptive cross section is nearly three times the physical cross section of the head. The arm has a prominent resonance at 150 MHz. Numerical solutions, antenna theory, and experimental results on animals have shown that whole-body energy deposition may be increased by 50 percent or more because of multiple bodies that are strategically located in the field. Empirical equations for SARs are also presented along with test data for several species of laboratory animals. Barbiturate anesthesia is sufficiently disruptive of thermoregulation that delta Ts of colonic temperature yield energy dose values in several mammals that compare quite favorably with those based on whole-body calorimetry.

Gandhi, O. P.

Atmospheric-water absorption features near 2.2 micrometers and their importance in high spectral resolution remote sensing

Selective absorption of electromagnetic radiation by atmospheric gases and water vapor is an accepted fact in terrestrial remote sensing. Until recently, only a general knowledge of atmospheric effects was required for analysis of remote sensing data; however, with the advent of high spectral resolution imaging devices, detailed knowledge of atmospheric absorption bands has become increasingly important for accurate analysis. Detailed study of high spectral resolution aircraft data at the U.S. Geological Survey has disclosed narrow absorption features centered at approximately 2.17 and 2.20 micrometers not caused by surface mineralogy. Published atmospheric transmission spectra and atmospheric spectra derived using the LOWTRAN-5 computer model indicate that these absorption features are probably water vapor. Spectral modeling indicates that the effects of atmospheric absorption in this region are most pronounced in spectrally flat materials with only weak absorption bands. Without correction and detailed knowledge of the atmospheric effects, accurate mapping of surface mineralogy (particularly at low mineral concentrations) is not possible.

Kruse, F. A.

Microwave absorption in compressed CO sub 2.

Induced microwave absorption in carbon dioxide studied at frequency of 9260 mc/sec over temperature range from 270 to 500 degrees K and pressures as high as 95 atm

CARBON DIOXIDE

Self-consistent Model of Magnetospheric Ring Current and Propagating Electromagnetic Ion Cyclotron Waves. 2. Wave Induced Ring Current Precipitation and Thermal Electron Heating

This paper continues presentation and discussion of the results from our new global self-consistent theoretical model of interacting ring current ions and propagating electromagnetic ion cyclotron waves [Khazanov et al., 2006]. To study the effects of electromagnetic ion cyclotron wave propagation and refraction on the wave induced ring current precipitation and heating of the thermal plasmaspheric electrons, we simulate the May 1998 storm. The main findings after a simulation can be summarized as follows. Firstly, the wave induced ring current precipitation exhibits quite a lot of fine structure, and is highly organized by location of the plasmapause gradient. The strongest fluxes of about 4 x 10(exp 6) (cm(raised dot) s(raised dot) sr(raised dot) (sup -1)) are observed during the maill and early recovery phases of the storm. The very interesting and probably more important finding is that in a number of cases the most intense precipitating fluxes are not connected to the most intense waves in simple manner. The characteristics of the wave power spectral density distribution over the wave normal angle are extremely crucial for the effectiveness of the ring current ion scattering. Secondly, comparison of the global proton precipitating patterns with the results from RAM [Kozyra et al., 1997a] reveals that although we observe a qualitative agreement between the localizations of the wave induced precipitations in the models, there is no quantitative agreement between the magnitudes of the fluxes. The quantitative differences are mainly due to a qualitative difference between the characteristics of the wave power spectral density distributions over the wave normal angle in RAM and in our model. Thirdly, the heat fluxes to plasmaspheric electrons caused by Landau resonate energy absorption from electromagnetic ion cyclotron waves are observed in the postnoon-premidnight MLT sector, and can reach the magnitude of 10(exp 11) eV/(cm(sup 2)(raised dot)s). The Coulomb energy degradation of the RC H(+) and O(+) ions maximizes at about 10(exp 11) (eV/(cm(sup 2) (raised dot) s), and typically leads to electron energy deposition rates of about 2(raised dot) 10(exp 10) (eV/(cm(sup 2)(raised dot)s) which are observed during two periods; 32-48 hours, and 76-86 hours after 1 May, 0000 UT. The theoretically derived spatial structure of the thermal electron heating caused by interaction of the ring current with the plasmasphere is strongly supported by concurrent and conjugate plasma measurements from the plasmasphere, ring current, and topside ionosphere [Gurgiolo et al., 2005]. Finally, the wave induced intense electron heating has a structure of the spot-like patches along the most enhanced density gradients in the plasmasphere boundary layer and can be a possible driver to the observed but still not explained small-scale structures of enhanced emissions in the stable auroral red arcs.

Khazanov, G. V.

The opacity of the universe and the strong equivalence principle

A possible explanation of why the advanced solutions of Maxwell's equations are not observed in nature is by way of absorption by an opaque universe. As Davies has shown, the ever expanding, general relativistic cosmological models fail to provide the needed absorption. The absorption mechanism calling for an interplay between local physics and cosmology, is usually developed adopting the strong equivalence principle, SEP, which precludes such interplay. It is shown that complete absorption of electromagnetic radiation by ionized intergalactic plasma is obtained provided a violation of the SEP, of the order of the Hubble's constant, is allowed to occur. The same degree of violation was previously found to be compatible with a large body of observational data.

Canuto, V. M.

Pressure broadening of rotational bands. I - A statistical theory

Absorption of electromagnetic waves by rotational transitions of molecules is formulated for the case in which the wave frequency is displaced from resonance by an amount large compared to the reciprocal duration of a typical binary collision, and also large compared to the differences between frequencies of the strong resonances of the gas. In this far-wing limit, Fano's relaxation operator is reduced to a scalar parameter which depends on the frequency displacement. This relaxation parameter is not symmetric with respect to reflection about resonance, but becomes symmetric when multiplied by the factor exp (h/2pi) (omega sub d)/2kT where omega sub d is the frequency displacement. The theory applies to dipolar molecules of any shape, in collisions with either dipolar or quadrupolar molecules.

Rosenkranz, P. W.

Methods of satellite oceanography

The theoretical basis for remote sensing measurements of climate and ocean dynamics is examined. Consideration is given to: the absorption of electromagnetic radiation in the atmosphere; scattering in the atmosphere; and satellite observations using visible light. Consideration is also given to: the theory of radio scatter from the sea; scatter of centimeter waves from the sea; and the theory of operation of synthetic aperture radars. Additional topics include: the coordinate systems of satellite orbits for oceanographic remote sensing applications; the operating features of the major U.S. satellite systems for viewing the ocean; and satellite altimetry.

Stewart, R. H.

Coupled structural/thermal/electromagnetic analysis/tailoring of graded composite structures

Accomplishments are described for the third years effort of a 5-year program to develop a methodology for coupled structural/thermal/electromagnetic analysis/tailoring of graded composite structures. These accomplishments include: (1) structural analysis capability specialized for graded composite structures including large deformation and deformation position eigenanalysis technologies; (2) a thermal analyzer specialized for graded composite structures; (3) absorption of electromagnetic waves by graded composite structures; and (4) coupled structural thermal/electromagnetic analysis of graded composite structures.

Mcknight, R. L.

On the preferred source location for the convective amplification of ion cyclotron waves

The propagation, growth, and absorption of electromagnetic ion cyclotron waves (EMICs) in the Pc1 range are studied using the HOTRAY ray tracing program for a realistic distribution of thermal plasma (H+, He+, O+), which is assumed to be in diffusive equilibrium inside the plasmasphere and collisionless in the low-density region outside the plasmapause. It is demonstrated that there are two principal source regions for the growth of EMIC waves. The theoretical results are related to the most recent satellite and ground-based observations.

Horne, Richard B.

System and Method for Determining Gas Optical Density Changes in a Non-Linear Measurement Regime

Each of two sensors, positioned to simultaneously detect electromagnetic radiation absorption along a path, is calibrated to define a unique response curve associated therewith that relates a change in voltage output for each sensor to a change in optical density. A ratio-of-responses curve is defined by a ratio of the response curve associated with the first sensor to the response curve associated with the second sensor. A ratio of sensor output changes is generated using outputs from the sensors. An operating point on the ratio-of-responses curve is established using the ratio of sensor output changes. The established operating point is indicative of an optical density. When the operating point is in the non-linear response region of at least one of the sensors, the operating point and optical density corresponding thereto can be used to establish an actual response of at least one of the sensors whereby the actual sensor output can be used in determining changes in the optical density.

Sachse, Glen W.

Space Power Facility Reverberation Chamber Calibration Report

This document describes the process and results of calibrating the Space Environmental Test EMI Test facility at NASA Plum Brook Space Power Facility according to the specifications of IEC61000-4-21 for susceptibility testing from 100 MHz to 40 GHz. The chamber passed the field uniformity test, in both the empty and loaded conditions, making it the world's largest Reverberation Chamber.

reverberation chambers

First-Principles Modeling Of Electromagnetic Scattering By Discrete and Discretely Heterogeneous Random Media

A discrete random medium is an object in the form of a finite volume of a vacuum or a homogeneous material medium filled with quasi-randomly and quasi-uniformly distributed discrete macroscopic impurities called small particles. Such objects are ubiquitous in natural and artificial environments. They are often characterized by analyzing theoretically the results of laboratory, in situ, or remote-sensing measurements of the scattering of light and other electromagnetic radiation. Electromagnetic scattering and absorption by particles can also affect the energy budget of a discrete random medium and hence various ambient physical and chemical processes. In either case electromagnetic scattering must be modeled in terms of appropriate optical observables, i.e., quadratic or bilinear forms in the field that quantify the reading of a relevant optical instrument or the electromagnetic energy budget. It is generally believed that time-harmonic Maxwell's equations can accurately describe elastic electromagnetic scattering by macroscopic particulate media that change in time much more slowly than the incident electromagnetic field. However, direct solutions of these equations for discrete random media had been impracticable until quite recently. This has led to a widespread use of various phenomenological approaches in situations when their very applicability can be questioned. Recently, however, a new branch of physical optics has emerged wherein electromagnetic scattering by discrete and discretely heterogeneous random media is modeled directly by using analytical or numerically exact computer solutions of the Maxwell equations. Therefore, the main objective of this Report is to formulate the general theoretical framework of electromagnetic scattering by discrete random media rooted in the Maxwell- Lorentz electromagnetics and discuss its immediate analytical and numerical consequences. Starting from the microscopic Maxwell-Lorentz equations, we trace the development of the first principles formalism enabling accurate calculations of monochromatic and quasi-monochromatic scattering by static and randomly varying multiparticle groups. We illustrate how this general framework can be coupled with state-of-the-art computer solvers of the Maxwell equations and applied to direct modeling of electromagnetic scattering by representative random multi-particle groups with arbitrary packing densities. This first-principles modeling yields general physical insights unavailable with phenomenological approaches. We discuss how the first-order-scattering approximation, the radiative transfer theory, and the theory of weak localization of electromagnetic waves can be derived as immediate corollaries of the Maxwell equations for very specific and well-defined kinds of particulate medium. These recent developments confirm the mesoscopic origin of the radiative transfer, weak localization, and effective-medium regimes and help evaluate the numerical accuracy of widely used approximate modeling methodologies.

Michael I Mishchenko

Scattering Properties and Brightness Temperatures Associated with Solid Precipitation

In the past few years, early solid precipitation detection and retrieval algorithms have been developed and shown to be applicable for snowing clouds and blizzards. NOAA has an operational snow versus rain classifier based on AMSU-B observations. Solid precipitation retrieval algorithms reported in the literature over the past two years include those that rely on neural nets, statistics, or physical relationships. All of the algorithms require the use of millimeter-wave radiometer observations. The millimeter-wave frequencies are especially sensitive to the scattering and emission properties of frozen particles due to the ice particle refractive index. Passive radiometric channels respond to both the integrated particle mass throughout the volume and field of view, and to the amount, location, and size distribution of the frozen (and liquid) particles with the sensitivity varying for different frequencies and hydrometeor types. This investigation probes the sensitivity of scattering and absorption coefficients, and hence computed brightness temperatures, resulting from variations in solid precipitation cloud profiles. The first study compares the single scattering, absorption, and asymmetry parameters associated with snow particles in clouds. Several methodologies are used to convert the physical characteristics (e.g., shape, size distributions, ice-air-water ratios) of ice particles to electromagnetic properties (e.g., absorption, scattering, and asymmetry factors). These methodologies include: conversion to solid ice particles, homogeneous dielectric mixing, or discrete dipole approximation. Changes in the conversion methodology can produce computed brightness temperature differences greater than 50 Kelvin.

Skofronick-Jackson, Gail M.