Investigation and improvement of zinc elec- trodes for electrochemical cells quarterly report no. 3, 1 jan. - 31 mar. 1965
Zinc electrodes for electrochemical cells
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Zinc electrodes for electrochemical cells
Sealed electrochemical cell with flexible casing for varying electrolyte level in cell
An electrochemical cell having a water/gas porous separator prepared from a polymeric material and one or more conductive cell components that pass through, or are located in close proximity to, the water/gas porous separator, is provided. The inventive cell provides a high level of in-cell electrical conductivity.
Leak resistant bonded elastomeric seal for secondary electrochemical cells
Dendrite deposits on zinc electrodes of electrochemical cell and substrate effects
Influence of separator and surfactant on growth rate of zinc deposits in electrochemical cells
Absorption and transport of zincate in separator membranes for improved electrodes in spacecraft electrochemical cells
Improvement of zinc electrodes for zinc-silver oxide batteries - electrochemical cells
Piezoresistive transducer measures gas pressure inside sealed secondary electrochemical cells without breaking the seal. This method is based on the observed fact that the force exerted by the cell faces on the clamp tightening them against the transducer is a function of the gas pressure inside the cell.
External source supplies power to electrochemical cells containing internal resistive heater element. Each cell plate is individually contained in its own Pellon bag, enabling the heater element to be arranged in a continuous, parallel circuit.
The structure of a new separator material for electrochemical cells has been investigated. Investigation into details of the separator structure showed it to be multilayered and to consist mainly of a quasi-impervious organic skin, a porous region of mixed organic and inorganic material, and an area of nonuniformly treated substrate. The essential feature of the coating (slurry) is believed to be interconnected pores which allow ionic conductivity. The interconnected pores are believed to be formed by the interaction of the plasticizer and inorganic fibers. The major failure mode of silver zinc cells using such a separator (zinc nodules shorting adjacent plates) was investigated.
Environmental and reaction studies on electrochemical cells using metal electrodes and phenothiazine-iodine charge transfer complexes
The invention provides an improved proton exchange membrane for use in electrochemical cells having internal passages parallel to the membrane surface, an apparatus and process for making the membrane, membrane and electrode assemblies fabricated using the membrane, and the application of the membrane and electrode assemblies to a variety of devices, both electrochemical and otherwise. The passages in the membrane extend from one edge of the membrane to another and allow fluid flow through the membrane and give access directly to the membrane for purposes of hydration.
Initial pressure and void volume strongly affect subsequent dependence of pressure on temperature. Semiempirical method calculates operating conditions in electrochemical storage cells equipped with pressure-relief vents. Used to design cells to discharge safely and completely. Conceived for Li/SOCI2 cells, method applicable to other electrochemical cells.
Equilibrated cellulose ether membranes of increased electrolytic conductivity for use as separators in concentrated alkaline electrochemical cells are investigated. The method of making such membranes by equilibration to the degree desired in an aqueous alkali solution mantained at a temperature below about 10 C is described.
Apparatus consisting of a pressure plate unit, four springs of known spring constant and a micrometer measures the swelling and force exerted by the polymer membranes of alkaline electrochemical cells.
To maximize performance in starved, multiplate cells, the cell design should rely on techniques which widen the volume tolerance characteristics. These involve engineering capillary pressure differences between the components of an electrochemical cell and using these forces to promote redistribution of electrolyte to the desired optimum values. This can be implemented in practice by prescribing pore size distributions for porous back-up plates, reservoirs, and electrodes. In addition, electrolyte volume management can be controlled by incorporating different pore size distributions into the separator. In a nickel/hydrogen cell, the separator must contain pores similar in size to the small pores of both the nickel and hydrogen electrodes in order to maintain an optimum conductive path for the electrolyte. The pore size distributions of all components should overlap in such a way as to prevent drying of the separator and/or flooding of the hydrogen electrode.
The feasibility of electrochemical impedance spectroscopy as a method for analyzing battery state of health and state of charge was investigated. Porous silver, zinc, nickel, and cadmium electrodes as well as silver/zinc cells were studied. State of charge could be correlated with impedance data for all but the nickel electrodes. State of health was correlated with impedance data for two silver/zinc cells, one apparently good and the other dead. The experimental data were fit to equivalent circuit models.