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At least 37 records · Page 2

Pure- and mixed-gas transport properties of a microporous Tröger's Base polymer (PIM-EA-TB)

Polymers of intrinsic microporosity (PIMs) offer tantalizing combinations of high selectivity and permeability in initial gas permeation measurements. Here, we report characterization of pure- and mixed-gas permeation properties of a thick (~80 μm) PIM consisting of Tröger's Base (TB) and Ethanoanthracene (EA) films. The effects of feed pressure and temperature on pure-gas permeabilities of CH 4 , N 2 , O 2 , H 2 , and CO 2 were investigated. The physical aging behavior of the thick film was tracked via pure-gas O 2 , N 2 , and CH 4 permeability at 35 °C. Gas permeability decreased noticeably and selectivity increased as aging time increased. Particular attention was given to mixed-gas measurements of CO 2 and CH 4 (50/50) permeabilities at 35 °C and fugacities ranging from 2 to 18 atm to explore whether the rigid, bridged, bicyclic TB and EA units could resist CO 2 -induced plasticization. These results are presented along with pure-gas CO 2 and CH 4 results for membrane samples aged at different times. PIM-EA-TB aged for ~24 h did not show signs of plasticization across the fugacity range considered. Furthermore, dual-mode competitive sorption presumably caused the CO 2 /CH 4 mixed-gas selectivity to be slightly higher than its corresponding pure-gas selectivity. However, as aging time increased, aged films underwent progressively more rapid and extensive CO 2 -induced plasticization with increasing fugacity, suggesting a systematic relationship between physical aging and plasticization in PIMs. Consequently, physical aging caused less improvement in mixed-gas CO 2 /CH 4 selectivity than it did in pure-gas selectivity, due mainly to plasticization effects.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Equitable and Affordable Solutions to Electrification (EAS-E) Home Electrification Prize

The Equitable and Affordable Solutions to Electrification (EAS-E) Home Electrification Prize, EAS-E Prize, seeks novel, cost-effective technology solutions for whole-home electrification of all types of residential buildings. EAS-E Prize competitors will develop and demonstrate "easy electrification" approaches that are faster and more affordable for homeowners and simplify electrification processes for contractors and implementers.

EAS-E↗

A comparison of QTP functionals against coupled-cluster methods for EAs of small organic molecules

EA-EOM-CCSD electron affinities and LUMO energies of various Kohn–Sham density functional theory (DFT) methods are calculated for an a priori IP benchmark set of 64 small, closed-shell molecules. The purpose of these calculations was to investigate whether the QTP KS-DFT functionals can emulate EA-EOM-CC with only a mean-field approximation. We show that the accuracy of DFT—relative to CCSD—improves significantly when elements of correlated orbital theory are introduced into the parameterization to define the QTP family of functionals. In particular, QTP(02), which has only a single range separation parameter, provides results accurate to a MAD of <0.15 eV for the whole set of 64 molecules compared to EA-EOM-CCSD, far exceeding the results from the non-QTP family of density functionals.

Chemistry↗

The muon content of EAS as a function of primary energy

The muon content of extensive air showers (EAS) was measured over the wide primary energy range 10 to the 16th power to 10 to the 20th power eV. It is reported that the relative muon content of EAS decreases smoothly over the energy range 10 to the 17th power to 10 to the 19th power eV and concluded that the primary cosmic ray flux has a constant mass composition over this range. It is also reported that an apparent significant change in the power index occurs below 10 to the 17th power eV rho sub c (250 m) sup 0.78. Such a change indicates a significant change in primary mass composition in this range. The earlier conclusions concerning EAS of energy 10 to the 17th power eV are confirmed. Analysis of data in the 10 to the 16th power - 10 to the 17th power eV range revealed a previously overlooked selection bias in the data set. The full analysis of the complete data set in the energy range 10 to the 16th power - 10 to the 17th power ev with the selection bias eliminated is presented.

Blake, P. R.↗

Sensitivity of depth of maximum and absorption depth of EAS to hadron production mechanism

Comparison of experimental data on depth of extensive air showers (EAS) development maximum in the atmosphere, T sub M and path of absorption, lambda, in the lower atmosphere of EAS with fixed particle number in the energy region eV with the results of calculation show that these parameters are sensitive mainly to the inelastic interaction cross section and scaling violation in the fragmentation and pionization region. The data are explained in a unified manner within the framework of a model in which scaling is violated slightly in the fragmentation region and strongly in the pionization region at primary cosmic rays composition close to the normal one and a permanent increase of inelastic interaction cross section. It is shown that, while interpreting the experimental data, disregard of two methodical points causes a systematic shift in T sub M: (1) shower selection system; and (2) EAS electron lateral distribution when performing the calculations on basis of which the transfer is made from the Cerenkov pulse FWHM to the depth of shower maximum, T sub M.

Antonov, R. A.↗

Observation of EAS using a large water tank

Using a large water tank (30 m in diameter, 4.5 m in depth) transition of extensive air showers (EAS) was investigated at Taro (200 m above sea level). There are set 150,0.4 sq m proportional counters on the bottom of the water tank. A conventional EAS array of 25 plastic scintillation detectors was arranged within several tens meter from the water tank. A proportional counter (10x10x200 cc x2) is made of a square shaped pipe of iron. Tungsten wire (100 mu m phi) is stretched tight in the center of the counter. A gas mixture of 90% argon and 10% methane is used at 760 mmHg. About 3000 EAS were obtained through 1 m of water since 1984.

Inoue, K.↗

Theoretical study of EAS hadronic structure

The structure of extensive air showers (EAS) is determined mainly by the energetic hadrons. They are strongly collimated in the core of the shower and essential difficulties are encountered for resolution of individual hadrons. The properties for resolution are different from the variety of hadron detectors used in EAS experiments. This is the main difficulty in obtaining a general agreement between actually registered data with different detectors. The most plausible source for disagreement is the uncertainty in determination of the energy of individual hadrons. This research demonstrates that a better agreement can be obtained with the average tendency of hadronic measurements if one assumes a larger coefficient of inelasticity and stronger energy increase of the total inelastic cross section in high energy pion interactions. EAS data above 10 to the 5th power GeV are revealing a faster development of hadronic cascades in the air then can be expected by extrapolating the parameters of hadron interactions obtained in accelerator measurements.

Popova, L.↗

Measuring the energy spectrum of primary cosmic rays with the Yakutsk EAS array

The Yakutsk Extensive Air Showers (EAS) array was designed for detecting the showers generated by the 10 to the 47th power to 10 to the 20th power eV primary cosmic rays and consists of numerous electron, muon, and Cerenkov light detectors arranged on a 20 sq km area terrain. The array is featured by the feasibility to detect the EAS-produced Cerenkov light, hence, as will be shown, to find the mean energy of the primary particles generating an ensemble of EAS of given size. Date collected is discussed.

Khristiansen, G. B.↗

Nuclear-Physics Model of the Knee in the EAS Spectrum

Spectra of the most energetic hadrons in cores of extensive air showers (EAS) were obtained for the first time in the HADRON hybrid experiment in Tien Shan mountains. The spectra in question exhibit a scaling violation, which requires invoking nontrivial effects in order to explain this circumstance. In the present article, unusual data on pp-interaction cross sections from recent experiments at the Large Hadron Collider are analyzed with this aim in view. A comparison with data at lower energies shows that the elastic cross section for pp interaction grows faster than the respective inelastic cross section. It would be natural to expect that a similar or a stronger effect is present in nucleus–nucleus interactions in cosmic rays. A possible change in the properties of nuclear cascades in the Earth’s atmosphere provides the possibility of discussing a new interpretation of the knee in the EAS spectrum and some exotic phenomena observed in cosmic-ray experiments. This interpretation is proposed for the first time. Particular attention is given to unique data from the HADRON hybrid experiment.

43 PARTICLE ACCELERATORS↗

Final Review of FY23 ASC ATDM L2 Milestone, MRT #8541, ATDM Multiphysics Scaling on EAS-3

As displayed in the FY23 ASC Implementation Plan (IP) and the Milestone Reporting Tool (MRT), the milestone description and completion criteria state: Demonstrate the capability to execute mission-relevant calculations with a multiphysics code from the Ristra project at scale on the pre-El Capitan Early Access System 3 (EAS-3). These calculations must use the GPU hardware available on EAS-3, the AMD MI-250s, to achieve any reasonable performance.

97 MATHEMATICS AND COMPUTING↗

Cosmic ray spectra measurements at the Yakutsk EAS array

The extensive air showers (EAS) spectra on rho 600 obtained at the Yakutak array for 38000 operation hours in 1974 to 1982 are presented. The refined value of the conversion factor from rho 600 to E sub is given and based on it the primary energy spectrum is obtained. The Yakutsk EAS array classifies the showers on parameters which are well measured in real showers: in the central part - on Rho sub 300 and on the whole array - on Rho sub 600. The shower spectra are constructed first on these parameters, than - a single spectrum on Rho sub 600. The RHO sub 300 and Rho sub 600 values are determined on the particle lateral distribution function (LDF) obtained in Yakutsk and on approximation Rho approx. R sup/n using the experimental points closest to R* (300 and 600 m).

Glushkov, A. V.↗

EAS accompanied by gamma-families at Mt. Norikura and comparison with Monte Carlo simulation

The experimental data of extensive air showers (EAS) accompanied by gamma-families, with total energy greater than 10 TeV, were compared with a Monte Carlo simulation with a rising cross section proportional to E sup 0.04 for the p-air inelastic cross section. It is found that the absolute intensity of size spectrum of such EAS is strongly affected by the primary protons intensity at 10 to the 15th power approx. 10 to the 16th power eV region and the experimental size spectrum agrees with the simulated spectra for the p-poor primary composition better than the p-rich one.

Shima, M.↗

Analysis of equi-intensity curves and NU distribution of EAS

The distribution of the number of muons in extensive air showers (EAS) and the equi-intensity curves of EAS are analyzed on the basis of Monte Carlo simulation of various cosmic ray composition and the interaction models. Problems in the two best combined models are discussed.

Tanahashi, G.↗

Tskhra-Tskaro complex intended for the investigations of EAS spatial characteristics near axis

Tskhra-Tskaro EAS complex located at the height of 2500 m above sea level is intended for a correlated investigation of three main components of the extended atmospheric showers (EAS) - hadron, muon and electro-proton ones - near the shower axis. This complex is aimed at the investigation of proton and primary cosmic radiation nucleus interactions with the nuclei of air atoms within the energy range 10 to the 14th power to 10 to the 16th power eV. Research equipment design and installation are discussed.

Berdzenishvili, O. L.↗

Muon fluctuation studies of EAS 10(17) eV

Fluctuation studies need to compare a parameter which is sensitive to longitudinal fluctuations against a parameter which is insensitive. Cascade calculations indicate that the shower size parameter at Haverah Park, rho (500), and the muon density are insensitive while parameters that significantly reflect the longitudinal development of a particular extensive air shower (EAS) include the muon/water Cerenkov response ratio and the muon arrival time dispersion. This paper presents conclusions based on muon fluctuation studies of EAS measured between 1976 and 1981 at Haverah Park.

Blake, P. R.↗

The identification of gamma ray induced EAS

Some of the penetrating particles in gamma-induced EAS from Cygnus X-3 observed by a single layer of flash-bulbs under 880 g cm/2 concrete, may be punched through photons rather than muons. An analysis of the shielded flash-tube response detected from EAS is presented. The penetration of the electro-magnetic component through 20 cm of Pb is observed at core distances approx. 10 m.

Blake, P. R.↗