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DOE OSTI2023

A practical method for modeling temporally-averaged ocean wave frequency-directional spectra for characterizing wave energy climates

Wave energy resource characterization investigations have been hindered because frequency-directional wave spectra are not broadly available for many coastal regions due to the insufficient spatial coverage of buoy observation networks and spectral wave model hindcast outputs. We address this problem by developing and validating a practical method for approximating temporally-averaged frequency-directional wave spectra averaged over periods of months or years from bulk wave parameters, which are available at a much greater coverage and resolution than frequency-directional wave spectra. While the temporally averaged frequency-directional wave spectrum over these periods cannot be used for analyzing a single sea state, it aggregates multiple sea states, identifies dominant wave energy systems representing wave climate, and resolves their spectral characteristics. Therefore, modelling temporally averaged frequency-directional wave spectra is of great value for planning and designing wave energy projects, e.g., resource characterization, site assessment, and conceptual design of wave energy converters. Temporally-averaged frequency-directional wave spectra and related important wave energy parameters approximated using this method are found to be more accurate than commonly used parametric wave spectrum models. This method can be applied to a wide range of wave climates given its universality and high accuracy. Also, the availability of bulk wave parameters from multi-decade high-resolution wave model hindcasts is increasing.

16 TIDAL AND WAVE POWER↗

DOE OSTI2025

Ocean Wave Energy Harvester with Oak Ridge Converter

Oceans can provide great potential for the American energy dominance. There is significant potential to utilize marine energy resources. In the United States, the total amount of marine energy available is equivalent to about 57% of the country's total power generation in 2019. Even if a fraction of this technical potential is harnessed, marine energy technologies could play a crucial role in fulfilling the nation's energy requirements. Marine energy resources are spread out geographically, and because more than 50% of the United States' population resides within 50 miles of the coastline, they are well-positioned to power local communities. These resources are also very dependable, making them a viable option for contributing to a consistent, trustworthy energy grid. Due to their predictable daily and seasonal patterns, marine energy resources can be integrated into our energy generation portfolio. On the other hand, ocean environment presents many challenges for cost-effective renewable energy conversion, including optimal control of ocean wave energy. This report presents a novel cost-effective energy conversion technique for ocean wave energy harvesters. The proposed system is simulated by using the Oak Ridge Converter to directly interface ocean wave energy source with the utility grid. The system description and simulation results are presented in detail. The results show that the proposed system is a cost effective and promising technology to reduce the infrastructure cost for ocean wave energy harvesters.

Sutton, Elizabeth [ORNL] (ORCID:0009000078885935)↗

DOE OSTI2022

CalWave - Open Water Demonstration - Field Testing Content Models (10/21 - 7/22)

Data for the CalWave - Open Water Demonstration, a submerged pressure differential Wave Energy Converter (WEC) Device. Device is moored to the seabed, and the motion of the waves causes the sea level to rise and fall above the device, inducing a pressure differential in the device. The alternating pressure pumps fluid through a system to generate electricity, which is transmitted to shore via bidirectional cables. Documentation and data here includes: Open Water Demonstration, including field testing content models for nearly 10 months of continuous ocean operation, from October 2021 through July 2022.

16 TIDAL AND WAVE POWER↗

DOE OSTI2024

Rotating cylinder electrode in reactive CO 2 capture: Identifying active C species via transport, VLE models and kinetics

Here, this article explores technical challenges and potential methodologies for understanding electrochemical Reactive CO 2 Capture (RCC) mechanisms. RCC offers potential energy cost advantages by directly converting captured CO 2 into fuels and chemicals, unlike traditional carbon capture and utilization (CCU) processes that require sequential capture, concentration, and compression. However, direct conversion of captured CO 2 introduces complexity due to additional equilibrium buffer reactions, making it challenging to identify active species for reduction in electrochemical studies. This article discusses methods to integrate transport, thermodynamics, and kinetics concepts to identify active carbon sources in RCC. Vapor‐Liquid Equilibrium (VLE) and transport models are validated against experimental results obtained in a gastight rotating cylinder electrode reactor and are shown as useful tools for studying RCC in heterogeneous electrocatalysts across different capture agents, solvents, and temperatures. This article establishes an experimental framework for advancing research in electrochemical RCC.

Electrocatalysis↗

DOE OSTI2023

Characterization of high-temperature figure of merit for solar-thermal absorbers

The figure of merit (FOM) is a widely used metric to characterize the solar-thermal conversion performance of solar absorber layers. Many of previous works have reported FOMs estimated from the radiative properties measured at room temperature. However, advanced concentrated solar power (CSP) plants operate at very high temperatures (~750°C), which can strongly affect the absorber’s radiative properties. Here, the present work proposes using a 1-D conduction-based reference bar technique to directly measure the converted thermal energy to determine the FOM at high absorber temperatures (≳ 750°C) while operating under a large solar concentration (~ 1200 x suns). Using the finite difference method, we carefully analyze several key parameters influencing the design of the experimental setup, such as temperature distribution, material properties, heat loss, and sensor accuracy. In addition, a rigorous uncertainty analysis is incorporated into the FOM to ascertain the confidence level of the result. We validate this new technique on a custom-built tungsten reference bar with an oxidized Inconel 625 solar-thermal absorber. A good agreement between the model and the experiment shows the reliability of the FOM measurement with a well-defined uncertainty. The same method can be implemented to measure the high-temperature FOM of most surface or volumetric solar absorbers for CSP.

14 SOLAR ENERGY↗

DOE OSTI2023

Light-Induced Spin Trapping in Transition Metal Compounds (DOE-DE-SC0017889-Final-Report)

In solar cells, devices that convert the energy of light directly into electricity, dye sensitized solar cells (DSSC) are some of the most capable devices for energy conversion. Ruthenium is a key component for these high-power conversion efficiencies in DSSC. Ruthenium, unfortunately, is among one of the rarest elements, and, thus, more earth-abundant replacements are needed. Though the properties of ruthenium are unique, these properties may be possible to mimic with other elements. To do this, the ability to control how other more earth-abundant elements like iron behave is essential. In this work, a method was developed to enable better control over iron species, for example, and their interaction with light.

14 SOLAR ENERGY↗

DOE OSTI2022

A Medium Voltage Three-Stage Power Converter Topology for Distribution Grid Scale Energy Storage Systems

This work proposes a three-stage converter topology with a medium frequency isolation transformer for direct integration of energy storage systems into medium voltage distribution grids. The distributed architecture of the topology, using standard AC/DC converters, has been developed with the aim of plug-and-play capability and voltage and power scalability. The medium frequency transformer facilitates improved power density, while its 20:1 voltage translation capability enables the use of limited voltage level (500 Vdc) of the commercially available batteries. This paper presents the topology structure and details how it can be scaled to reach the full range of the distribution grid voltages and the required power levels. A transformer design for 500 Hz rated frequency is discussed. The control scheme of the converter equipped with voltage support, frequency support, and black start capabilities is also presented. Control hardware-in-the-loop results using OPAL-RT, with converter switching models connected to a weak IEEE-4 node test feeder modified for the aforementioned grid services, are provided to show the topology feasibility.

Chinthavali, Madhu Sudhan↗

DOE OSTI2019

Adaptive harnessing damping in hydrokinetic energy conversion by two rough tandem-cylinders using flow-induced vibrations

Alternating lift technology (ALT) harnesses hydrokinetic energy from currents and tides and is different from conventional steady lift technologies (turbines). ALT is still under development with an important research issue being the mitigation of wake effect on downstream cylinders in Flow Induced Oscillations (FIO) of multi-cylinder Current Energy Converters (CEC). Rather than adjust the configuration/parameters of the converter, a more direct and effective way is to actively adjust the harnessed power. In this paper, a hydrokinetic energy converter using FIO of two cylinders in tandem in one-degree-of-freedom oscillators, with nonlinear adaptive damping and linear spring stiffness, is tested experimentally. FIO include Vortex Induced Vibrations (VIV), galloping, and their coexistence. Introducing adaptive damping into the tandem cylinders overcomes the shielding effect, which previous research on two tandem cylinders has shown to reduce power output by the downstream cylinder. Shielding along with fixed damping result either in ceasing motion due to excessive damping, or in low harnessed energy due to insufficient damping. In this experimental study, damping-to-velocity rate, linear spring-stiffness, cylinder spacing, and flow-velocity are the parameters with Reynolds number 30,000 ≤ Re ≤ 120,000. Comparison to linear-oscillators in FIO shows that this nonlinear converter, with velocity-proportional damping coefficient, is more effective over the entire FIO range but especially in galloping, where both flow and cylinder speeds are higher. Experimental results for energy harvesting, efficiency and instantaneous energy of the converter are presented and discussed supported by amplitude and frequency response data. Here the results show that the nonlinear, adaptive, velocity-proportional damping coefficient is an effective way to increase the overall harnessed power and the power of downstream cylinder. The harnessed power in the VIV to galloping transition increases by up to 94%. The most significant improvement is in the galloping region, where the increase in harnessed power and efficiency is around 33%.

13 HYDRO ENERGY↗

DOE OSTI2020

The Future of Renewable Energy Generation: Photovoltaic Materials

There are myriad ways to harness solar energy, including, but not limited to: solar thermal, solar fuels, and photovoltaics (PV). Across the portfolio of solar energy technologies, PV is unique in that collected photons are directly converted to electricity. Traditionally, the dominant materials in PV are also the dominant semiconductor and optoelectronic materials. The cost of solar energy from PV is a product of a complex combination of non-material related factors, known as soft costs, e.g., permitting, zoning, and of balance-of-systems (BOS) costs, like inverters or other components needed to utilize cells and modules. While the soft costs are due to administrative/regulatory concerns, BOS costs are driven by details of cell/module fabrication, mounting, power electronics, and other concerns, which touch on a range of basic material science issues. There is some overlap of BOS and soft cost, as a lighter weight solar panel can reduce installations costs, as an example. At the PV-system level, the materials considerations span both electronic and structural components. The focus of this paper is the solar cell, which is the minimum operational unit device that converts light into electricity.

30 DIRECT ENERGY CONVERSION↗

DOE OSTI2020

Perovskite Electronic Ratchets for Energy Harvesting

Electronic ratchets are energy-harvesting devices that can utilize spatially asymmetric potential distributions to convert nondirectional/random sources of energy into direct current. The potential asymmetry can be generated in a number of ways, but one purported mechanism is to redistribute ions directly within the active material. Utilizing the known propensity for ion migration in lead-halide perovskites (LHP), the first LHP flashing electronic ratchet is demonstrated by using a voltage stress to intentionally redistribute halide ions within a prototypical 2D perovskite. The resulting asymmetric potential distribution across the 2D perovskite allows for conversion of both electronic noise and unbiased square-wave potentials into current. Furthermore, simultaneous application of light illumination and voltage stress enhances the asymmetric potential distribution, enabling higher current than the nonilluminated device. This work presents an electronic ratchet system that exploits facile ion migration, which can be modified by both electrical and optical stimuli, providing a model system with the potential to test outstanding mechanistic questions for electronic ratchets.

36 MATERIALS SCIENCE↗

DOE OSTI2022

Magnetic cores with high reluctance differences in flux paths

Embodiment of the present invention includes a magnetic structure and a magnetic structure used in a direct current (DC) to DC energy converter. The magnetic structure has an E-core and a plate, with the plate positioned in contact or in near contact with the post surfaces of the E-core. The E-core has a base, a no-winding leg, a transformer leg, and an inductor leg. The no-winding leg, the transformer leg, and the inductor leg are perpendicular and magnetically in contact with the base. The plate is a flat slab with lateral dimensions generally larger than its thickness. The plate has a plate nose that overlaps a top no-winding leg surface of the no-winding leg with a no-winding gap area to form a no-winding gap with a no-winding gap reluctance. The plate also has a plate end that overlaps a top inductor leg surface of the inductor leg with an inductor gap area to form an inductor gap with an inductor gap reluctance. In some embodiments, e.g., where the duty cycle is less than 50 percent, the inductor gap reluctance will be designed to be less than the no-winding gap reluctance. In these cases, the majority of the magnetic flux that passes through the transformer leg will return through the inductor leg, instead of through the no-winding leg. The inductor and no-winding gap reluctances can he adjusted, so that the electromotive force applied to a charge passing through the inductor will partially cancel the electromotive force applied by the transformer secondary. The gap reluctance ratio can be defined, so that the difference in secondary and inductor electromotive forces is equal to the output voltage defined by an optimal no-ripple duty cycle. In this way no changing current is required through the inductor to create a dI/dt inductive voltage drop across the output inductor. Zero output current ripple is achieved.Various embodiments of the plate, plate shape, and no-winding leg are disclosed. These embodiments allow achieving a high ratio of no-winding gap reluctance to inductor gap reluctance, for practical, affordable magnetic material structures and aspect ratios. A high gap reluctance ratio enables zero output current ripple for the high transformer turns ratios that are needed to achieve high input to output voltage ratios. The embodiments therefore allow achieving low output current ripple for 48 V or higher input voltages, 1 V or lower output voltages, and high output currents.

Yao, Yuan↗

DOE OSTI2022

Sensitivity analysis of the technical and economic feasibility of converter-interfaced CHP System

The adoption of small-to-medium sized (1MW~20MW) combined heat and power (CHP) system is lagging, especially in industrial and commercial applications. Our prior research has proved that interfacing CHP with grid-ready converters can increase its economic value and technical benefits; this paper is focused on investigating the critical parameters impacting profitability of converter-interfaced CHP, including CHP sizing scenario, energy price, generator cost, converter cost, voltage support price, converter to engine size ratio and interconnection delay. An automatic toolkit for evaluating CHP return on investment (ROI) is developed to enhance the computation capability and efficiency. Based on varying the value of critical parameters, 975 use cases are analyzed. Results show that the profitability of converter-interfaced CHP over directly-coupled CHP is more sensitive to energy price, delays in interconnection process, converter cost and much less to generator cost or voltage support price.

converter, CHP, ROI, economic feasibility, sensiti↗

DOE OSTI2021

Prototype and Codesign of Nascent Flexible Wave Energy Converter Concepts

Prevailing mainstream ocean wave energy converter (WEC) archetypes are often relatively large monolithic rigid bodies with singular means of power take-off (e.g., relative motion between rigid bodies) and solo prime mover mechanisms (e.g. a rotary generator, a hydraulic piston). These mainstream WEC archetypes have existed for decades with some having histories spanning more than a century of significant investments and interests. As an alternative to the domain of mainstream WEC archetypes is the domain of distributed embedded energy converter technologies (also known as DEEC-Tec). Use of DEEC-Tec to create WECs - often called flexWECs - is a nascent domain of research and development that centers itself upon the interconnection of many relatively small energy converters - very small energy transducers - that interconnect and combine to create a much larger, overall, energy converting structure. The DEEC-Tec domain enables promising possibilities such as: direct in situ ocean wave energy harvesting and conversion throughout the volume of an entire flexWEC; inherent broad-banded ocean wave energy capture and conversion arising from near semi-continuous structural degrees of freedom; an innate absence of focusing and concentrating of ocean wave energy into a single prime mover and/or transmission system; and built-in implicit redundancy. As such, the DEEC-Tec domain could revolutionize how we conceptualize ocean wave energy conversion - both in terms of ocean wave energy converter design and what we view as viable environments and circumstances for ocean wave energy conversion. The research and development opportunities for the DEEC-Tec domain, therefore, are vast compared to the prevailing mainstream ocean wave energy converter domain. Correspondingly, there are ample opportunities to invest time and money into the DEEC-Tec domain with an aim to enable a paradigm shift in how ocean waves can be utilized as a more viable form of renewable energy. To that end, two seedling efforts have been enacted providing a very cursory investigation into the DEEC-Tec domain: (1) a preliminary simple fabrication/prototyping effort and (2) a preliminary co-design effort. The prototype seedling centers upon the design of a fabrication and evaluation rig for individual DEEC-Tec transducers; e.g., dielectric elastomer generators. The co-design seedling centers upon the analysis of those methods suitable for DEEC-Tec, ocean wave energy conversion, and fluid-structure interaction co-design efforts.

50 EE - Wind and Water Power Program - Water (EE-4↗

DOE OSTI2026

Modeling and Experimental Validation of a Direct-Contact Counter-Flow Fluidized Bed Heat Exchanger for Thermal Energy Storage (TES) Applications

Particle-based thermal energy storage (TES) systems are an emerging energy storage technology. The technological advances have reduced costs, making TES more competitive and reliable in the marketplace but an efficient and reliable operation is heavily dependent on coherent heat transfer between air to particles or vice versa. The particle-based TES technologies provide an intermediate system that can store energy for short (0-10 h), long (10-200 h) and seasonal (> 200 h) timescales. The TES systems store energy by converting electricity to thermal energy; electricity can be directly sourced intermittent generation technologies and/or the grid, helping manage peak loads and other mismatches in supply and demand. The overall efficiency of the TES system depends on the performance of system components (particle storage silos and particle transfer mechanism etc.). The particle heat exchanger is one of the key system components that affects the system efficiency. The pressurized fluidized bed heat exchanger (PFB HX) performance is challenging to predict due to the chaotic behavior of particle and fluid interaction. This research presents a computational study of a novel direct-contact, counter-flow and air-to-particles PFB HX, that contributes in advancing the particle-based long-duration TES technologies. For the current analysis an unsteady Eulerian-Eulerian CFD model was developed and validated against experiments performed at the National Laboratory of the Rockies for two particle sizes (600 ..mu..m and 825 ..mu..m ). Following validation, parametric simulations were conducted to evaluate the effects of interphase drag models (Syamlal-O'Brien and Gidaspow), particle size, bed height and the influence of a frictional-viscosity term on hydrodynamics and heat transfer between the air & particles. The key findings from the analysis are: (1) for the studied operating window Syamlal-O'Brien provides superior agreement with measured gas temperatures (errors generally < 10%) while Gidaspow shows large deviations for the coarse particle case; (2) model predictions are most sensitive in the lower 0.2 m above the air distributor where bubble initiation and local mixing dominate interphase heat transfer; (3) representation of the distributor (number of inlet ports) materially affects predicted local mixing and temperature stratification; and (4) the Eulerian-Eulerian framework reproduces bulk thermal trends but shows regime dependent limitations for coarse particles, motivating mesoscale informed closures for scale-up analysis for future studies. These results provide validated guidance for drag selection and distributor design in particle-based thermal energy storage applications. Collectively, the validated model and parametric results quantify key drivers of PHB-HX performance and provide practical guidance for design and optimization. The results provide confidence in the model predictability and provide a step forward to improve on heat exchange performance. The demonstrated performance and modeling approach support the deployment and further development of this novel PHB-HX concept for robust, particle-based long-duration thermal energy storage systems.

25 ENERGY STORAGE↗

DOE OSTI2020

Feasibility Analysis of Converter-Interfaced Combined Heat and Power System

As a promising new design concept, the converter-interfaced combined heat and power (CHP) system is coupled to the bulk grid through a rectifier and a grid-ready tied inverter. Compared to the traditional directly-coupled CHP system, it removes the requirement for oversizing the CHP generator, limits the short-circuit contribution of the generator and simplifies the grid integration process of CHP system. This paper evaluates the economic benefits of this concept by calculating the annualized Return-on-Investment (ROI) and comparing it to the directly-coupled system. The economic analysis includes timeseries simulations to compute energy transactions with the bulk grid as well as sizing the equipment to calculate the capital and operational costs. Obtained results indicate that in majority of user cases evaluated, the converter-interfaced CHP systems can provide better ROI than directly-coupled systems. Given the additional technical benefits provided by inverter-based distributed energy resources (DERs), the proposed concept is proved to be technically viable and economically feasible.

03 NATURAL GAS↗

DOE OSTI2023

Distributed Embedded Energy Converter Technologies for Marine Renewable Energy (A Technical Report)

The domain of distributed embedded energy converter technologies (DEEC-Tec) is a nascent and underexplored paradigm for harvesting and converting marine renewable energy. The paradigm distinguishes itself through its use of many small distributed embedded energy converters (DEECs) that, ultimately, are assembled through the creation of "DEEC-Tec metamaterials" to create an overall larger marine renewable energy harvesting and converting structure. As an example, such a structure could be an ocean wave energy converter - a converter whose structure is made from various types of DEEC-Tec metamaterials that harvests ocean wave energy and converts that energy into something more useful such as electricity. To that end, DEEC-Tec can be viewed at three different technology levels: (1) individual distributed embedded energy converters, also known as DEECs; (2) DEEC-Tec metamaterials-essentially, pseudo-materials made from the interconnection of many DEECs; and (3) overall larger complete marine renewable energy harvesting-converting structures-these structures being made from DEEC-Tec metamaterials. Arising directly from the application of DEEC-Tec to harvest and convert ocean wave energy are several noteworthy benefits, some of which include: (1) the lack of load concentrations into singular components or subsystems, (2) broad-banded ocean wave energy frequency harvesting and conversion, and (3) inherent redundancy-failure of some individual DEECs does not represent a failure of an entire DEEC-Tec-based WEC. This report describes DEEC-Tec by way of descriptions of those three technology levels: individual DEECs, DEEC-Tec metamaterials, and DEEC-Tec-based WECs. Moreover, the report describes corresponding research approaches and methodologies for related concepts such as DEEC-Tec-based WEC topologies and morphologies in addition to manufacturing and fabrication techniques found suitable for the application of DEEC-Tec within the general domain of marine renewable energy-moving beyond only ocean wave energy conversion.

16 TIDAL AND WAVE POWER↗

DOE OSTI2023

Experimental investigation of a reverse osmosis desalination system directly powered by wave energy

Powering desalination processes with renewable energy is a promising solution to address the global issue of water shortage with minimum carbon footprint and environmental impact. Here, we experimentally investigate a sustainable reverse osmosis (RO) desalination system directly powered by wave energy. In this system, seawater is pressurized and pumped to a RO desalination module via a piston pump directly driven by an oscillating surge wave energy converter (OSWEC). An accumulator is adopted on the feed inlet to mitigate the pressure fluctuations under time-varying ocean conditions. Meanwhile, a needle valve on the brine outlet is used to adjust the system pressure and water recovery. A 1:10 scaled model was designed, fabricated, and tested in a wave tank based on the Froude scaling law. Further, the optimal specific water productivity (SWP) obtained in the tank tests with 3.5 g/L feed salinity was 2.23m 3 /kWh, indicating a full-scale specific water productivity of 0.22m 3 /kWh for 35g/L seawater salinity. The influence of needle valve tuning on the specific water productivity was experimentally investigated and analyzed. Under a specific operational condition, tuning this valve improved specific water productivity by about 17% and reduced the system pressure by 24%, thereby avoiding extreme pressure and improving the system’s capability. This pilot study demonstrates that ocean wave energy is a promising source to sustainably power reverse osmosis desalination and provide freshwater water for coastal regions.

16 TIDAL AND WAVE POWER↗

DOE OSTI2022

Demonstration of photoreactor platform for on-sun unassisted photoelectrochemical hydrogen generation with tandem III–V photoelectrodes

Photoelectrochemical (PEC) water splitting is a direct solar-driven technology that converts solar energy to storable chemical energy in the form of hydrogen. In addition to semiconductor and catalyst development for improved photoelectrodes, designing reactors for testing and operation of PEC systems under inherently dynamic outdoor solar illumination is necessary to further the commercial viability of PEC technology. Herein, we present a versatile photoreactor system mounted on a solar tracker for outdoor PEC testing and demonstrate unassisted PEC water splitting under real world on-sun conditions. GaInP 2 /GaAs tandem absorber photoelectrodes with a MoS 2 catalyst were fabricated and exhibit >8% solar-to-hydrogen efficiency. On-sun efficiency and stability of the photoelectrodes were characterized on both sunny and partly cloudy days with continuous monitoring of insolation and weather conditions. Furthermore, the versatile photoreactor and outdoor PEC testing capabilities and methods presented here can accelerate the development of other solar fuel generating systems and technologies.

solar fuels↗