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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

The effect of the London-van der Waals dispersion force on interline heat transfer

A theoretical procedure to determine the heat transfer characteristics of the interline region (junction of liquid-solid-vapor) from the macroscopic optical and thermophysical properties of the system is outlined. The analysis is based on the premise that the interline transport processes are controlled by the London-van der Waals dispersion force between condensed phases (solid and liquid). Numerical values of the dispersion constant are presented. The procedure is used to compare the relative size of the interline heat sink of various systems using a constant heat flux mode. This solution demonstrates the importance of the interline heat flow number, which is evaluated for various systems.

Wayner, P. C., Jr.↗
NASA NTRS1981

Effects of zero van der Waals and zero electrostatic forces on droplet sedimentation

The present investigation provides a confirmation of the dependence of droplet sedimentation on particle concentration. It is shown that it is possible to determine the maximum particle concentration which can remain stable on a given liquid from droplet sedimentation experiments. Droplet sedimentation can be reduced but not totally eliminated by the addition of appropriate amounts of dimethyl sulfoxide (DMSO) to reduce the van der Waals forces to zero. It was found that, at 12% DMSO, a maximum particle concentration of 6.3 x 10 to the 8th cells/ml of glutaraldehyde-fixed human erythrocytes suspended in physiological saline can remain stable on a D2O cushion.

Omenyi, S. N.↗
NASA NTRS1982

Power series expansions for the frequency and period of the limit cycle of the van der Pol equation

An equation reported by van der Pol (1926) in connection with relaxation-oscillations studies is considered. The equation contains the factor epsilon which can assume values in the range from zero to infinity. The period T(epsilon), or equivalently the frequency nu(epsilon) of the limit cycle has been studied. However, to date there has been little success in discovering the analytical structure of T(epsilon) as a function of epsilon. The present investigation has the objectives to present the Taylor series expansion of nu(epsilon), to locate the singularities which determine the radius of convergence of that expansion, to introduce a new damping variable in terms of which the expansion converges for all epsilon, to form a new expansion for the period T(epsilon) which improves the rate of convergence of the series, to attempt to 'complete' the series, and to compare the obtained results with the numerically determined values of T(epsilon) and with the asymptotic approximation valid for large epsilon.

Andersen, C. M.↗
NASA NTRS1983

Perturbation analysis of the limit cycle of the free van der Pol equation

A power series expansion in the damping parameter, epsilon, of the limit cycle of the free van der Pol equation is constructed and analyzed. Coefficients in the expansion are computed in exact rational arithmetic using the symbolic manipulation system MACSYMA and using a FORTRAN program. The series is analyzed using Pade approximants. The convergence of the series for the maximum amplitude of the limit cycle is limited by two pair of complex conjugate singularities in the complex epsilon-plane. A new expansion parameter is introduced which maps these singularities to infinity and leads to a new expansion for the amplitude which converges for all real values of epsilon. Amplitudes computed from this transformed series agree very well with reported numerical and asymptotic results. For the limit cycle itself, convergence of the series expansion is limited by three pair of complex conjugate branch point singularities. Two pair remain fixed throughout the cycle, and correspond to the singularities found in the maximum amplitude series, while the third pair moves in the epsilon-plane as a function of t from one of the fixed pairs to the other. The limit cycle series is transformed using a new expansion parameter, which leads to a new series that converges for larger values of epsilon.

Dadfar, M. B.↗
NASA NTRS1984

Perturbation analysis of the limit cycle of the free van der Pol equation

A power series expansion in the damping parameter, epsilon, of the limit cycle of the free van der Pol equation is constructed and analyzed. Coefficients in the expansion are computed in exact rational arithmetic using the symbolic manipulation system MACSYMA and using a FORTRAN program. The series is analyzed using Padeapproximants. The convergence of the series for the maximum amplitude of the limit cycle is limited by two pair of complex conjugate singularities in the complex epsilon-plane. A new expansion parameter is introduced which maps these singularities to infinity and leads to a new expansion for the amplitude which converges for all real values of epsilon. Amplitudes computed from this transformed series agree very well with reported numerical and asymptotic results. For the limit cycle itself, convergence of the series expansion is limited by three pair of complex conjugate branch point singularities. Two pair remain fixed throughout the cycle, and correspond to the singularities found in the maximum amplitude series, while the third pair moves in the epsilon-plane as a function of t from one of the fixed pairs to the other. The limit cycle series is transformed using a new expansion parameter, which leads to a new series that converges for larger values of epsilon.

Dadfar, M. B.↗
NASA NTRS1986

van der Waals force between positronium and hydrogenic atoms Finite-mass corrections

The Feshbach projection-operator formalism is used to derive the asymptotic effective interaction potential between two atoms. Beyond the usual van der Waals potential, falling like x exp -6, three x exp -8 terms are also obtained: an attractive dipole-quadrupole term (absent in the positronium-positronium case because of symmetry), a repulsive energy-dependent term, and a repulsive mass-dependent but energy-independent one. This last term was not obtained by Manson and Ritchie (1985) using an independent method.

Au, C. K.↗
NASA NTRS1988

Nonadiabatic corrections to the van der Waals potential

Closed-form expressions are derived for the finite-mass nonadiabatic corrections to the van der Waals potential in the electric-dipole approximations in terms of London-analog two-center atomic spectral sums. The nonadiabatic corrections to all orders at threshold energy and also those with first-order energy dependence are given.

Au, C. K.↗
NASA NTRS1989

A Van der Waals-like theory of plasma double layers

A theory describing plasma double layers in terms of multiple roots of the charge density expression is presented. The theory presented uses the fact that equilibrium plasmas shield small potential perturbations linearly; for high potentials, the shielding decreases. The approach is analogous to Van der Waals' theory of simple fluids in which inclusion of approximate expressions for both excluded volume and long range attractive forces sufficiently describes the first-order liquid-gas phase transition.

Katz, Ira↗
NASA NTRS1996

Van der Waals Interactions Involving Proteins

Van der Waals (dispersion) forces contribute to interactions of proteins with other molecules or with surfaces, but because of the structural complexity of protein molecules, the magnitude of these effects is usually estimated based on idealized models of the molecular geometry, e.g., spheres or spheroids. The calculations reported here seek to account for both the geometric irregularity of protein molecules and the material properties of the interacting media. Whereas the latter are found to fall in the generally accepted range, the molecular shape is shown to cause the magnitudes of the interactions to differ significantly from those calculated using idealized models. with important consequences. First, the roughness of the molecular surface leads to much lower average interaction energies for both protein-protein and protein-surface cases relative to calculations in which the protein molecule is approximated as a sphere. These results indicate that a form of steric stabilization may be an important effect in protein solutions. Underlying this behavior is appreciable orientational dependence, one reflection of which is that molecules of complementary shape are found to exhibit very strong attractive dispersion interactions. Although this has been widely discussed previously in the context of molecular recognition processes, the broader implications of these phenomena may also be important at larger molecular separations, e.g., in the dynamics of aggregation, precipitation, and crystal growth.

Roth, Charles M.↗
NASA NTRS2007

Finite-Size Effects on the Behavior of the Susceptibility in van der Waals Films Bounded by Strongly Absorbing Substrates

We study critical point finite-size effects in the case of the susceptibility of a film in which interactions are characterized by a van der Waals-type power law tail. The geometry is appropriate to a slab-like system with two bounding surfaces. Boundary conditions are consistent with surfaces that both prefer the same phase in the low temperature, or broken symmetry, state. We take into account both interactions within the system and interactions between the constituents of the system and the material surrounding it. Specific predictions are made with respect to the behavior of 3He and 4He films in the vicinity of their respective liquid-vapor critical points.

phase-transition↗
NASA NTRS2016

Grippers Based on Opposing Van Der Waals Adhesive Pads

Novel gripping structures based on van der Waals adhesive forces are disclosed. Pads covered with fibers can be activated in pairs by opposite forces, thereby enabling control of the adhesive force in an ON or OFF state. Pads can be used in groups, each comprising a group of opposite pads. The adhesive structures enable anchoring forces that can resist adverse forces from different directions. The adhesive structures can be used to enable the operation of robots on surfaces of space vehicles.

Parness, Aaron↗
NASA NTRS1964

Stellar evolution. i. a program for the solution of the time-dependent basic equations <sternentwicklung. i. ein program zur losung der zeitabhingigen aufbaugleichungen<

In this paper a program is described for stellar evolution computations, based on the Henyey method. The program shall be used for very different phases of stellar evolution. Therefore, the main program for the solution of the time dependent basic equations is kept as general as possible, while all assumptions about special physical conditions in the star occur only in subprograms. Hence the range of applicability of the program can easily be extended. The system of difference equations and details of the integration method used in the program are given in two appendices. For a first test the program has been applied to the post-main sequence evolution of a star of 7 M; the results will appear in part II and III. Some technical details of these calculations are given and discussed here. The program turned out to be applicable to calculations of the evolution near the main sequence, of phases of core contraction and of nuclear burning in shell sources.

STELLAR EVOLUTION↗