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At least 37 records · Page 2

Intensified silicon photodiode array detector linearity Application to coherent anti-Stokes Raman spectroscopy

The linearity of an intensified silicon photodiode array multichannel detector is studied with coherent anti-Stokes Raman and other similar signals. Studies with diffuse and focused (spherically and cylindrically) signals resolved apparent saturation problems which limit the dynamic range of the detector. In addition, it has been shown that there is no short-range wavelength (473-532-nm) dependence on this saturation. Theoretical explanations for these phenomena are also included.

Antcliff, R. R.↗

Nonequilibrium Supersonic Freestream Studied Using Coherent Anti-Stokes Raman Spectroscopy

Measurements were conducted at the University of Virginia Supersonic Combustion Facility of the flow in a constant-area duct downstream of a Mach 2 nozzle. The airflow was heated to approximately 1200 K in the facility heater upstream of the nozzle. Dual-pump coherent anti-Stokes Raman spectroscopy was used to measure the rotational and vibrational temperatures of N2 and O2 at two planes in the duct. The expectation was that the vibrational temperature would be in equilibrium, because most scramjet facilities are vitiated air facilities and are in vibrational equilibrium. However, with a flow of clean air, the vibrational temperature of N2 along a streamline remains approximately constant between the measurement plane and the facility heater, the vibrational temperature of O2 in the duct is about 1000 K, and the rotational temperature is consistent with the isentropic flow. The measurements of N2 vibrational temperature enabled cross-stream nonuniformities in the temperature exiting the facility heater to be documented. The measurements are in agreement with computational fluid dynamics models employing separate lumped vibrational and translational/rotational temperatures. Measurements and computations are also reported for a few percent steam addition to the air. The effect of the steam is to bring the flow to thermal equilibrium, also in agreement with the computational fluid dynamics.

Cutler, Andrew D.↗

Coherent Anti-stokes Raman Spectroscopy (CARS) of gun propellant flames

Temperature measurements were made in a slightly fuel rich, premixed propane/air reference flame and nitrate ester propellant flames burning in air at atmospheric pressure using coherent anti-stokes raman scattering (CARS). Both single and multiple pulse VARS spectra of nitrogen in the reference flame were in good agreement with calculated and reported values. Single pulse CARS nitrogen spectra obtained in the propellant flames were analyzed to give temperatures consistent with values calculated using the NASA-Lewis thermochemical calculation. Comparison of a 0.1 second separated sequence of single pulse CARS spectra indicate turbulent air mixing in these propellant flames. The CARS spectral results demonstrate that temporal and spatially resolved temperature measurements could be determined in transient, turbulent flames.

Mcilwain, M. E.↗

Measurement of detonation temperature of hydrogen-oxygen mixture by CARS (Coherent Anti-Stokes Raman Spectroscopy)

It was confirmed that CARS is very useful as a temperature measurement method of detonation. By revising the detecting system so that a lot of information can be handled simultaneously like an optical multi-channel analyzer, it is possible to obtain information concerning the detailed three dimensional structure of detonation which has never been obtained.

Tezaki, Atsumu↗

Amorphous silicon deposition diagnostics using coherent anti-Stokes Raman spectroscopy

This paper reports on an in situ silicon deposition process diagnostics, using CARS performed at state-of-the-art a-Si:H film deposition conditions in a reactor designed for a-Si:H solar cell fabrication. The diagnostics procedure measures the silane depletion in an RF plasma as a function of the silane flow rate (where the relationship is linear between 50-percent depletion, at a flow rate of 5.6 sccm, and about 8-percent depletion, at 80 sccm) and the RF power (where the silane depletion is linearly dependent on the RF power in the region of 4 to 12 W). The linear RF power dependence of the silane depletion is considered to be consistent with the mechanism of silane decomposition primarily by electron impact dissociations, while the flow rate dependence is interpreted in terms of the residence time of the SiH4 molecules in the glow discharge region, where an increase of the residence time at a low flow rate results in a high depletion ratio.

Shing, Y. H.↗

Nonintrusive spectroscopic techniques for supersonic/hypersonic aerodynamics and combustion diagnostics

This paper presents an overview of the primary nonintrusive diagnostic techniques being developed by the NASA Langley Research Center to address the validation needs of Computational Fluid Dynamic (CFD) codes. The techniques include absorption in the UV and IR, Laser Induced Fluorescence, electron beam fluorescence, and a number of scattering techniques including Rayleigh, spontaneous Raman, and several coherent Raman spectroscopies. Most of the techniques are highly specialized, require complex data interpretation, and can satisfy only a few of the CFD needs. For these reasons, the evolving trend in flowfield diagnostics appears to favor a mode in which the diagnostic researcher, the experimental aerodynamicist, and the CFD community jointly define experiments based on the aeronautical requirements and on available diagnostic techniques.

Exton, R. J.↗

Spectral line shapes. Volume 4 - Proceedings of the Eighth International Conference, College of William and Mary, Williamsburg, VA, June 9-13, 1986

The present conference discusses topics in line broadening and shift phenomena in low-to-moderately dense plasmas, resonances in the continuum, hot and dense laser-produced plasmas, collisional broadening and intermolecular potentials, molecular broadening and collision-induced spectroscopy, collisional redistribution and laser-assisted collision processes, coherent and nonlinear spectroscopy, astrophysical line-shapes, and short-wavelength lasers. Attention is given to the widths and shifts of Be ion lines, the Stark broadening of Xe II and Fe I lines, perturbed and unperturbed series in the line-shapes of autoionizing Rydberg series, the line-broadening of hydrogenic ions in dense plasmas, Doppler-free line-shapes, the Franck-Condon principle, the dynamics of laser-assisted reactive collisions, the gas-kinetic effects of light, collision-induced processes in nonlinear optics, and line-shaping phenomena in cool stars.

Exton, Reginald J.↗

Optical Stark effect in the four-wave mixing and stimulated Raman spectra of N2

The influence of the optical Stark effect on spectral line shapes in four-wave-mixing Raman spectroscopy (FWMRS) and stimulated Raman spectroscopy (SRS) is investigated experimentally and theoretically. Using an experimental setup capable of rapid alternation between the simultaneous measurement of coherent Stokes Raman spectroscopy and inverse Raman spectroscopy at low and high intensities, together with a sophisticated frequency reference scheme, it was possible to perform a rather direct comparison between Stark-broadened and non-Stark-broadened spectra of both classes of Raman spectroscopies. The results demonstrate that SRS spectra show more Stark shift and broadening than their FWMRS counterparts. A discrepancy with theoretical results is pointed out, and an attempt is made to explain it.

Moosmuller, H.↗

Dual Stokes cars measurements in supersonic combusting flow

Coherent antiStokes Raman spectroscopy (CARS) was used to make simultaneous measurements of temperature, nitrogen and oxygen density in a reacting supersonic flow. A supersonic burner (SSB) was designed to provide supersonic flow in which combustion can be studied in the laboratory. Measurements made with the CARS system will be used for validation of computational fluid dynamic (CFD) codes. Preliminary results of the CFD calculations are presented.

Jarrett, Olin, Jr.↗

CARS Temperature Measurements in Turbulent and Supersonic Facilities

This paper documents the development of the National Aeronautics and Space Administration s (NASA) Langley Research Center ( LaRC) Coherent Antistokes Raman Spectroscopy (CARS) systems for measurements of temperature in a turbulent subsonic or supersonic reacting hydrogen-air environment. Spectra data provides temperature data when compared to a precalculated library of nitrogen CARS spectra. Library validity was confirmed by comparing CARS temperatures derived through the library with three different techniques for determination of the temperature in hydrogen-air combustion and an electrically heated furnace. The CARS system has been used to survey temperature profiles in the simulated flow of a supersonic combustion ramjet (scramjet) model. Measurement results will be discussed.

Jarrett, O., Jr.↗

Ultra high resolution molecular beam cars spectroscopy with application to planetary atmospheric molecules

The measurement of high resolution pulsed and continuous wave (CW) coherent anti-Stokes Raman spectroscopy (CARS) measurements in pulsed and steady state supersonic expansions were demonstrated. Pulsed molecular beam sources were characterized, and saturation of a Raman transition and, for the first time, the Raman spectrum of a complex molecular cluster were observed. The observation of CW CARS spectra in a molecular expansion and the effects of transit time broadening is described. Supersonic expansion is established as a viable technique for high resolution Raman spectroscopy of cold molecules with resolutions of 100 MH2.

Byer, R. L.↗

Stimulated Rayleigh-Brillouin gain spectroscopy in pure gases

Stimulated Rayleigh-Brillouin gain spectra of pure gases are reported. Stimulated Rayleigh scattering is now clearly distinguishable from stimulated Brillouin scattering without the aid of induced absorption. As examples, spectral line shapes of Ar and SF6 at various pressures and the associated gain asymmetry are discussed. Potential applications of coherent Rayleigh-Brillouin spectroscopy are suggested.

She, C. Y.↗

Reflectance and Thermal Infrared Spectroscopy of Mars: Relationship Between ISM and TES for Compositional Determinations

Reflectance spectroscopy has demonstrated that high albedo surfaces on Mars contain heavily altered materials with some component of hematite, poorly crystalline ferric oxides, and an undefined silicate matrix. The spectral properties of many low albedo regions indicate crystalline basalts containing both low and high calcium pyroxene, a mineralogy consistent with the basaltic SNC meteorites. The Thermal Emission Spectrometer (TES) experiment on the Mars Geochemical Surveyor has acquired critical new data relevant to surface composition and mineralogy, but in a wavelength region that is complementary to reflectance spectroscopy. The essence of the completed research was to analyze TES data in the context of reflectance data obtained by the French ISM imaging spectrometer experiment in 1989. This approach increased our understanding of the complementary nature of these wavelength regions for mineralogic determinations using actual observations of the martian surface. The research effort focused on three regions of scientific importance: Syrtis Major-Isidis Basin, Oxia Palus-Arabia, and Valles Marineris. In each region distinct spatial variations related to reflectance, and in derived mineralogic information and interpreted compositional units were analyzed. In addition, specific science questions related to the composition of volcanics and crustal evolution, soil compositions and pedogenic processes, and the relationship between pristine lithologies and weathering provided an overall science-driven framework for the work. The detailed work plan involved colocation of TES and ISM data, extraction of reflectance and emissivity spectra from areas of known reflectance variability, and quantitative analysis using factor analysis and statistical techniques to determine the degree of correspondence between these different wavelength regions. Identified coherent variations in TES spectroscopy were assessed against known atmospheric effects to validate that the variations are due to surface properties. With this new understanding of reflectance and emission spectroscopy, mineralogic interpretations were derived and applied to the science objectives of the three regions.

Boyce, Joseph↗

Acoustic Pyrometry Applied to Gas Turbines and Jet Engines

Internal gas temperature is one of the most fundamental parameters related to engine efficiency and emissions production. The most common methods for measuring gas temperature are physical probes, such as thermocouples and thermistors, and optical methods, such as Coherent Anti Stokes Raman Spectroscopy (CARS) or Rayleigh scattering. Probes are relatively easy to use, but they are intrusive, their output must be corrected for errors due to radiation and conduction, and their upper use temperature is limited. Optical methods are nonintrusive, and they measure some intrinsic property of the gas that is directly related to its temperature (e.g., lifetime or the ratio of line strengths). However, optical methods are usually difficult to use, and optical access is not always available. Lately, acoustic techniques have been receiving some interest as a way to overcome these limitations.

Fralick, Gustave C.↗

Development of Supersonic Combustion Experiments for CFD Modeling

This paper describes the development of an experiment to acquire data for developing and validating computational fluid dynamics (CFD) models for turbulence in supersonic combusting flows. The intent is that the flow field would be simple yet relevant to flows within hypersonic air-breathing engine combustors undergoing testing in vitiated-air ground-testing facilities. Specifically, it describes development of laboratory-scale hardware to produce a supersonic combusting coaxial jet, discusses design calculations, operability and types of flames observed. These flames are studied using the dual-pump coherent anti- Stokes Raman spectroscopy (CARS) - interferometric Rayleigh scattering (IRS) technique. This technique simultaneously and instantaneously measures temperature, composition, and velocity in the flow, from which many of the important turbulence statistics can be found. Some preliminary CARS data are presented.

Baurle, Robert↗

Fundamental Mixing and Combustion Experiments for Propelled Hypersonic Flight

The first experiment is a study of a coaxial jet discharging into stagnant laboratory air, with center jet of a mixture of 5% oxygen and 95% helium by volume and coflow jet of air. The exit flow pressure of both center-jet and coflow nozzles is 1 atmosphere. The presence of oxygen in the center jet is to allow the use of an oxygen flow-tagging technique (RELIEF4) to obtain non-intrusive velocity measurements. Both jets are nominally Mach 1.8, but, because of the greater speed of sound, the center jet velocity is more than twice that of the coflow. The mixing layer which forms between the center jet and the coflow near the nozzle exit is compressible, with a calculated convective Mach number of approximately 0.7. This geometry has several advantages: The streamwise development of the flow is generally dominated by turbulent stresses (rather than pressure forces), and thus calculations are sensitive to turbulence modeling. It includes features present in supersonic combustors, including a compressible mixing layer near the nozzle exit and a light-gas/air plume downstream. Since it is a free jet, it provides easy access for both optical instrumentation and probes. Since it is axisymmetric, it requires fewer experimental measurements to fully characterize, and calculations can be performed with more modest computer resources. However, weak shock waves formed at the nozzle exit strengthen and turn normal as they approach the axis, complicating the flow. Care is thus taken in the design of the facility to provide as near as possible to 1-D flow at the exit of both center and coflow nozzles, and to minimize the strength of waves generated at the nozzle exit. Results from this experiment are compared to CFD solutions obtained by VULCAN, a previously developed code used in engine analysis. The second experiment is a study of a supersonic combustor consisting of a diverging duct with single downstream-angled wall injector. Thus, the geometry is relatively simple and large regions of subsonic recirculating flow are avoided. The nominal entrance Mach number is 2 and the enthalpy of the test gas (hot air "simulant") is nominally that of Mach 7 flight. It was believed, on the basis of calculations performed that this would produce mixing-limited flow, that is to say, one for which chemical reaction to equilibrium proceeds at a much greater rate than mixing. It later proved that this was not the case. The primary experimental technique employed is coherent anti-Stokes Raman spectroscopy, known by its acronym CARS. The species probed is molecular nitrogen and the quantity measured is temperature. Intrusive probes, such as Pitot, total temperature, hot-wire, etc., are not used due to access difficulty and high heat flux in the combustor, and because they may alter the flow. CARS has several advantages over other optical methods. It is a relatively mature and well-understood technique. Signal levels are relatively high and the signal is in the form of a coherent (laser) beam that can be collected through small windows. Incoherent (non-CARS) interferences are rejected by spatial filtering.

Diskin, G. S.↗

Investigation of the feasibility of CARS measurements in scramjet combustion

Results are presented of analytical and experimental investigations to determine the feasibility of using coherent anti-Stokes Raman Spectroscopy (CARS) to measure temperature and species concentration in supersonic combustion experiments. The CARS spectra of H2O, O2 and H2 were measured in laboratory flames. Computer code calculated spectra agree very well with the measured spectra. Temperature, and O2 and H2 concentration profiles have been determined from CARS spectra in a laboratory H2 air flat diffusion flame. Temperature measurements agree with radiation corrected thermocouple measurements within 5 to 10 percent, depending on species concentration. The feasibility of measuring O2 concentrations up to 10 percent, from the spectral shape was demonstrated. H2 concentrations determined from CARS intensities agree with spontaneous Raman measurements within a factor of two. Finally, a conceptual design was formulated for diagnostics in the Langley Research Center scramjet combustion facility.

Shirley, J. A.↗