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At least 37 records · Page 2

Optical signatures of multifold fermions in the chiral topological semimetal CoSi

Significance We present a comprehensive combined experimental and theoretical study of optical conductivity in the chiral topological semimetal CoSi based on the development of high-quality crystals. We reveal the presence and the energy range of various exotic multifold quasiparticles in the optical responses and provide experimental evidence for the realization of fourfold spin-3/2 fermions, which were not directly observed previously. Our work is critical to interpreting future optical and transport responses of multifold fermion materials. We believe the methods used in this work will not only stimulate future research in this class of materials but will also provide a strategy for addressing optical signatures of chiral topological fermions in solids.

36 MATERIALS SCIENCE↗

COSIE: The Coronal Spectrographic Imager in the EUV

COSIE is a solar-observing instrument (currently proposed for mounting onto the ISS) which obtains wide field images of the corona and full Sun spectral images with high sensitivity and rapid cadence. The primary purpose of the instrument is to constrain the global field topology and to track coronal mass ejections from the disk through the inner heliosphere.

solar↗

Materials Data on Sm(CoSi)2 by Materials Project

SmCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Sm3+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Sm–Si bond lengths are 3.06 Å. Co+2.50+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.29 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Sm3+, four equivalent Co+2.50+, and one Si4- atom. The Si–Si bond length is 2.59 Å.

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Materials Data on Np(CoSi)2 by Materials Project

NpCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Np4+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Np–Si bond lengths are 2.96 Å. Co2+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.28 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Np4+, four equivalent Co2+, and one Si4- atom. The Si–Si bond length is 2.36 Å.

36 MATERIALS SCIENCE↗

Materials Data on U(CoSi)2 by Materials Project

UCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. U4+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All U–Si bond lengths are 2.99 Å. Co2+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.28 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent U4+, four equivalent Co2+, and one Si4- atom. The Si–Si bond length is 2.40 Å.

36 MATERIALS SCIENCE↗

Materials Data on Pu(CoSi)2 by Materials Project

PuCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Pu4+ is bonded in a body-centered cubic geometry to eight equivalent Si4- atoms. All Pu–Si bond lengths are 3.01 Å. Co2+ is bonded to four equivalent Si4- atoms to form a mixture of corner and edge-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.28 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Pu4+, four equivalent Co2+, and one Si4- atom. The Si–Si bond length is 2.52 Å.

36 MATERIALS SCIENCE↗

Materials Data on Er(CoSi)2 by Materials Project

ErCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Er3+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Er–Si bond lengths are 3.00 Å. Co+2.50+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.27 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Er3+, four equivalent Co+2.50+, and one Si4- atom. The Si–Si bond length is 2.47 Å.

36 MATERIALS SCIENCE↗

Materials Data on Tm(CoSi)2 by Materials Project

TmCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Tm3+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Tm–Si bond lengths are 2.99 Å. Co+2.50+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.27 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Tm3+, four equivalent Co+2.50+, and one Si4- atom. The Si–Si bond length is 2.46 Å.

36 MATERIALS SCIENCE↗

Materials Data on Tb(CoSi)2 by Materials Project

TbCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Tb4+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Tb–Si bond lengths are 3.02 Å. Co2+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.28 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Tb4+, four equivalent Co2+, and one Si4- atom. The Si–Si bond length is 2.52 Å.

36 MATERIALS SCIENCE↗

Materials Data on Ce(CoSi)2 by Materials Project

CeCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Ce4+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Ce–Si bond lengths are 3.06 Å. Co2+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.29 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Ce4+, four equivalent Co2+, and one Si4- atom. The Si–Si bond length is 2.56 Å.

36 MATERIALS SCIENCE↗

Materials Data on Nd(CoSi)2 by Materials Project

NdCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Nd3+ is bonded in a body-centered cubic geometry to eight equivalent Si4- atoms. All Nd–Si bond lengths are 3.09 Å. Co+2.50+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.29 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Nd3+, four equivalent Co+2.50+, and one Si4- atom. The Si–Si bond length is 2.66 Å.

36 MATERIALS SCIENCE↗

Materials Data on Pr(CoSi)2 by Materials Project

PrCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Pr3+ is bonded in a body-centered cubic geometry to eight equivalent Si4- atoms. All Pr–Si bond lengths are 3.11 Å. Co+2.50+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.29 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Pr3+, four equivalent Co+2.50+, and one Si4- atom. The Si–Si bond length is 2.71 Å.

36 MATERIALS SCIENCE↗

Materials Data on La(CoSi)2 by Materials Project

LaCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. La3+ is bonded in a body-centered cubic geometry to eight equivalent Si4- atoms. All La–Si bond lengths are 3.14 Å. Co+2.50+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.30 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent La3+, four equivalent Co+2.50+, and one Si4- atom. The Si–Si bond length is 2.81 Å.

36 MATERIALS SCIENCE↗

Materials Data on Zr(CoSi)2 by Materials Project

ZrCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Zr4+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Zr–Si bond lengths are 2.90 Å. Co2+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.25 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Zr4+, four equivalent Co2+, and one Si4- atom. The Si–Si bond length is 2.36 Å.

36 MATERIALS SCIENCE↗

Materials Data on Ho(CoSi)2 by Materials Project

HoCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Ho3+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Ho–Si bond lengths are 3.01 Å. Co+2.50+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.27 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Ho3+, four equivalent Co+2.50+, and one Si4- atom. The Si–Si bond length is 2.49 Å.

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Materials Data on Dy(CoSi)2 by Materials Project

DyCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Dy3+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Dy–Si bond lengths are 3.01 Å. Co+2.50+ is bonded to four equivalent Si4- atoms to form a mixture of corner and edge-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.27 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Dy3+, four equivalent Co+2.50+, and one Si4- atom. The Si–Si bond length is 2.50 Å.

36 MATERIALS SCIENCE↗

Materials Data on Eu(CoSi)2 by Materials Project

EuCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Eu3+ is bonded in a body-centered cubic geometry to eight equivalent Si4- atoms. All Eu–Si bond lengths are 3.10 Å. Co+2.50+ is bonded to four equivalent Si4- atoms to form a mixture of corner and edge-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.30 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Eu3+, four equivalent Co+2.50+, and one Si4- atom. The Si–Si bond length is 2.66 Å.

36 MATERIALS SCIENCE↗

Materials Data on Th(CoSi)2 by Materials Project

ThCo2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Th4+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Th–Si bond lengths are 3.13 Å. Co2+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing CoSi4 tetrahedra. All Co–Si bond lengths are 2.31 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Th4+, four equivalent Co2+, and one Si4- atom. The Si–Si bond length is 2.58 Å.

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