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NASA NTRS2024

Spectral Correlation in MODIS Water-Leaving Reflectance Retrieval Uncertainty

Spectral remote sensing reflectance, Rrs(λ) (sr−1), is the fundamental quantity used to derive a host of bio-optical and biogeochemical properties of the water column from satellite ocean color measurements. Estimation of uncertainty in those derived geophysical products is therefore dependent on knowledge of the uncertainty in satellite-retrieved R rs . Furthermore, since the associated algorithms require R rs at multiple spectral bands, the spectral (i.e., band-to-band)error covariance in R rs is needed to accurately estimate the uncertainty in those derived properties. This study establishes a derivative-based approach for propagating instrument random noise, instrument systematic uncertainty, and forward model uncertainty into R rs as retrieved using NASA’s multiple-scattering epsilon (MSEPS) atmospheric correction algorithm, to generate pixel-level error covariance in R rs . The approach is applied to measurements from Moderate Resolution Imaging Spectroradiometer (MODIS) on the Aqua satellite and verified using Monte Carlo (MC) analysis. We also make use of this full spectral error covariance in R rs to calculate uncertainty in phytoplankton pigment chlorophyll-a concentration (chl a , mg/m 3 ) and diffuse attenuation coefficient of downwelling irradiance at 490 nm (K d (490), m -1 ). Accounting for the error covariance in R rs generally reduces the estimated relative uncertainty in chl a by ∼1-2% (absolute value) in waters with chl a < 0.25 mg/m 3 where the color index (CI) algorithm is used. The reduction is ∼5-10% in waters with chl a > 0.35 mg/m 3 where the blue-green ratio (OCX) algorithm is used. Such reduction can be higher than 30% in some regions. For K d (490), the reduction by error covariance is generally ∼2%, but can be higher than 20% in some regions. The error covariance in R rs is further verified through forward-calculating chl a from MODIS-retrieved and in situ R rs and comparing estimated uncertainty with observed differences. An 8-day global composite of propagated uncertainty shows that the goal of 35% uncertainty in chl a can be achieved over deep ocean waters (chl a ≤ 0.1 mg/m3). While the derivative-based approach generates reasonable error covariance in R rs some assumptions should be updated as our knowledge improves. These include the inter-band error correlation in top-of-atmosphere reflectance, and uncertainties in the calibration of MODIS 869 nm band, in ancillary data, and in the in situ data used for system vicarious calibration.

Ocean color↗
NASA NTRS2003

Optical Reflectance and Fluorescence for Detecting Nitrogen Needs in Zea mays L.

Nitrogen (N) status in field grown corn (Zea mays L.) was assessed using spectral techniques. Passive reflectance remote sensing and, both passive and active fluorescence sensing methods were investigated. Reflectance and fluorescence methods are reported to detect changes in the primary plant pigments (chlorophylls a and b; carotenoids) in higher plant species. As a general rule, foliar chlorophyll a (Chl a) and chlorophyll b (Chl b) usually exist in approx.3:l ratio. In plants under stress, Chl b content is affected before Chl a reductions occur. For reflectance, a version of the chlorophyll absorption in reflectance index (CARI) method was tested with narrow bands from the Airborne Imaging Spectroradiometer for Applications (ASIA). CARI minimizes the effects of soil background on the signal from green canopies. A modified CARI (MCARI) was used to track total Chl a levels in the red dip of the spectrum from the corn canopy. A second MCARI was used to track the auxiliary plant pigments (Chl b and the carotenoids) in the yellow/orange/red edge part of the reflectance spectrum. The difference between these two MCARI indices detected variations in N levels across the field plot canopies using ASIA data. At the leaf level, ratios of fluorescence emissions in the blue, green, red and far-red wavelengths sensed responses that were associated with the plant pigments, and were indicative of energy transfer in the photosynthetic process. N stressed corn stands could be distinguish from those with optimally applied N with fluorescence emission spectra obtained from individual corn leaves. Both reflectance and fluorescence methods are sensitive in detecting corn N needs and may be especially powerful in monitoring crop conditions if both types of information can be combined.

McMurtrey, J. E.↗
NASA NTRS2011

Chlorophyll-a Algorithms for Oligotrophic Oceans: A Novel Approach Based on Three-Band Reflectance Difference

A new empirical algorithm is proposed to estimate surface chlorophyll-a concentrations (Chl) in the global ocean for Chl less than or equal to 0.25 milligrams per cubic meters (approximately 77% of the global ocean area). The algorithm is based on a color index (CI), defined as the difference between remote sensing reflectance (R(sub rs), sr(sup -1) in the green and a reference formed linearly between R(sub rs) in the blue and red. For low Chl waters, in situ data showed a tighter (and therefore better) relationship between CI and Chl than between traditional band-ratios and Chl, which was further validated using global data collected concurrently by ship-borne and SeaWiFS satellite instruments. Model simulations showed that for low Chl waters, compared with the band-ratio algorithm, the CI-based algorithm (CIA) was more tolerant to changes in chlorophyll-specific backscattering coefficient, and performed similarly for different relative contributions of non-phytoplankton absorption. Simulations using existing atmospheric correction approaches further demonstrated that the CIA was much less sensitive than band-ratio algorithms to various errors induced by instrument noise and imperfect atmospheric correction (including sun glint and whitecap corrections). Image and time-series analyses of SeaWiFS and MODIS/Aqua data also showed improved performance in terms of reduced image noise, more coherent spatial and temporal patterns, and consistency between the two sensors. The reduction in noise and other errors is particularly useful to improve the detection of various ocean features such as eddies. Preliminary tests over MERIS and CZCS data indicate that the new approach should be generally applicable to all existing and future ocean color instruments.

Hu, Chuanmin↗
NASA NTRS2000

Dependence of Photosynthetic Capacity, Photosynthetic Pigment Allocation, and Carbon Storage on Nitrogen Levels in Foliage of Aspen Stands

The role of foliar nitrogen (N) in the seasonal dynamics and vertical canopy distribution of photosynthetic pigments, photosynthetic capacity, and carbon (C) storage was investigated in boreal broadleaved species. The study was conducted at two different aged stands (60 y and 15 y) in 1994 and 1996 in Saskatchewan, Canada as part of the Boreal Ecosystem-Atmosphere Study (BOREAS). Foliage in upper and lower strata was examined for aspen (Populus tremuloides Michx.) and its associated hazelnut shrub (Corylus americana Walt.). We determined that C accumulation, expressed as dry mass per unit leaf area (mg C cm (exp -2)), was linearly dependent on N content (approximately 0.3- 3.5 mg N cm (exp -2))(r (exp 2) = 0.93, n=383, P less than 0.001) when eleven foliage groups were defined according to species, site, and developmental stage. C assembly was greatest in the upper aspen strata of both sites (seasonal average, 40.1 plus or minus 0.6 mg C cm (exp -2)), intermediate in the lower aspen strata (32.7 plus or minus 0.6), and considerably lower, and similar, in the hazelnut shrub layers (23.7 plus or minus 0.6) and in expanding aspen leaves (23.8 plus or minus 0.5); the lowest C assembly per unit N occurred in the two youngest, emerging leaf groups (17.1 plus or minus 0.6). Other relationships among physiological and biochemical variables were typically non-linear and were confounded by inclusion of the three groups of young (i.e., emerging or expanding) leaves, unless these were separately identified. Net C uptake, measured as photosynthetic capacity (A (sub max), micromole CO2 m (exp -2) s (exp -1)), was greater in aspen throughout the season, and optimal in mid-summer at a C:N ratio of approximately 18 (approximately 2.3 %N). When young leaves were excluded and logarithms of both variables were used, A (sub max) was approximately linearly dependent on N (mg N cm (exp-2) (r (exp 2) = 0.85, n= 193, P less than 0.001), attributed to incorporation of N into photosynthetic complexes and enzymes. In mature leaves, differences in pigment content vs. N among canopy strata were accentuated when N was expressed per unit leaf area (Mg cm (exp -2)) . However, the simplest log-linear relationship between a pigment variable and N was obtained for a ratio describing the relative allocation of photosynthetic pigment to Chl a (Chl a/[Chl b + carotenoids], microgram cm (exp -2)/ microgram cm-2) vs. %N (r (exp 2) = 0.90, n=343, P less than 0.001). Attainment of comparable A (sub max) Chl a content and relative Chl a allocation per unit N (mg cm (exp -2)) was achieved at different foliar N levels per canopy group: the lowest N requirement was for hazelnut leaves in the lowest, shaded stratum at the older, closed canopy site; the highest N requirement was in aspen leaves of the upper-most stratum at the younger, more open canopy site. These results highlight the differences in physiological responses between young and fully expanded leaves and show that sustaining those foliar constituents and processes important to C balance may require higher foliar N levels in leaves of establishing vs. mature aspen stands. There may be implications for remote-sensing assessments made for carbon balance in springtime, or over a landscape mosaic comprised of different aged stands.

Middleton, Elizabeth M.↗
NASA NTRS2007

Eddies Enhance Biological Production in the Weddell-Scotia Confluence of the Southern Ocean

Satellite data show that oceanic eddies generated in the Southern Antarctic Circumpolar Current Front (SACCF) are associated with increased phytoplankton biomass. Cyclonic eddies with high chlorophyll a concentration (Chl-a) retain phytoplankton within the eddy cores and increase the light available for photosynthesis in the upper mixed layer by limiting vertical mixing and lifting of the isopycnal surfaces. Anticyclonic eddies have low Chl-a in the core but increased Chl-a in the periphery. Cross-frontal mixing mediated by eddies transports nutrients (e.g., Fe and Si) to the north and contributes to the increased Chl-a in the frontal zone. Interannual variations in the cyclonic eddy activity are positively correlated with variations in Chl-a during the spring bloom in regions of the Antarctic Circumpolar Current around South Georgia.

Kahru, M.↗
NASA NTRS2015

Chlorophyll Variability in the Oligotrophic Gyres: Mechanisms, Seasonality and Trends

A 16-year (1998-2013) analysis of trends and seasonal patterns was conducted for the 5 subtropical ocean gyres using chlorophyll-a (Chl-a) retrievals from ocean color satellite data, sea surface temperature (SST) obtained from optimally interpolated Advanced Very High Resolution Radiometer (AVHRR) data, and sea-level anomaly (SLA) from Aviso multi-sensor altimetry data. Trend analysis was also performed on mixed-layer data derived from gridded temperature and salinity profiles (1998-2010) from the Simple Ocean Data Assimilation (SODA) model. The Chl-a monthly composites were constructed from the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) and Moderate-resolution Imaging Spectroradiometer (MODIS) on Aqua using two different algorithms: the standard algorithm (STD) that has been in use since the start of the SeaWiFS mission in 1997, and a more recently developed Ocean Color Index (OCI) algorithm that is purported to provide improved accuracy in low chlorophyll waters such as the oligotrophic regions of the subtropical gyres. Trends were obtained for all gyres using both STD and OCI algorithms, which demonstrated generally consistent results. The North Pacific, Indian Ocean, North Atlantic and South Atlantic gyres showed significant downward trends in Chl-a, while the South Pacific gyre has a much weaker upward trend with no statistical significance. Time series of satellite-derived net primary production (NPP) showed downward trends for all the gyres, while all 5 gyres exhibited positive trends in SST and SLA. The seasonal variability of Chl-a in each gyre is tightly coupled to the variability in mixed layer depth (MLD) with peak values in winter in both hemispheres when vertical mixing is more vigorous, reaching depths approaching the nutricline (ZNO3, here defined as the depth of the 0.2 micron nitrate concentration). On a seasonal basis, Chl-a concentrations increase when the MLD approaches or is deeper than the nutricline depth, in agreement with the concept that vertical mixing is the major driving mechanism for phytoplankton photosynthesis in the interior of the gyres. In addition, MLD and SST seasonal changes are well correlated indicating that SST is a reasonable index of vertical mixing in the gyres. The combination of surface warming trends and biomass reduction over the 16-year period has the potential to reduce atmospheric CO2 uptake by the gyres and therefore influence the global carbon cycle.

Long-term trends↗
NASA NTRS2022

Discovery of Chlorophyll d : Isolation and Characterization of a Far-Red Cyanobacterium from the Original Site of Manning and Strain (1943) at Moss Beach, California

We have isolated a chlorophyll-d-containing cyanobacterium from the intertidal field site at Moss Beach, on the coast of Central California, USA, where Manning and Strain (1943) originally discovered this far-red chlorophyll. Here, we present the cyanobacterium’s environmental description, culturing procedure, pigment composition, ultrastructure, and full genome sequence. Among cultures of far-red cyanobacteria obtained from red algae from the same site, this strain was an epiphyte on a brown macroalgae. Its Q y in vivo absorbance peak is centered at 704–705 nm, the shortest wavelength observed thus far among the various known Acaryochloris strains. Its Chl a /Chl d ratio was 0.01, with Chl d accounting for 99% of the total Chl d and Chl a mass. TEM imagery indicates the absence of phycobilisomes, corroborated by both pigment spectra and genome analysis. The Moss Beach strain codes for only a single set of genes for producing allophycocyanin. Genomic sequencing yielded a 7.25 Mbp circular chromosome and 10 circular plasmids ranging from 16 kbp to 394 kbp. We have determined that this strain shares high similarity with strain S15, an epiphyte of red algae, while its distinct gene complement and ecological niche suggest that this strain could be the closest known relative to the original Chl d source of Manning and Strain (1943). The Moss Beach strain is designated Acaryochloris sp. (marina) strain Moss Beach.

chlorophyll d↗
NASA NTRS2006

Bio-Optical Properties and Ocean Color Algorithms for Coastal Waters Influenced by the Mississippi River During a Cold Front Passage

During the passage of a cold front in March 2002, bio-optical properties examined in coastal waters impacted by the Mississippi River indicated westward advective flows and increasing river discharge containing a larger nonalgal particle content contributed significantly to surface optical variability. A comparison of seasonal data from three cruises indicated spectral models of absorption and scattering to be generally consistent with other coastal environments, while their parameterization in terms of chlorophyll a concentration (Chl) showed seasonal variability. The exponential slope of the colored dissolved organic matter (CDOM) averaged 0.0161 plus or minus 0.00054 per nanometer, and for nonalgal absorption it averaged 0.011 per nanometer with deviations from general trends observed due to anomalous water properties. Although the phytoplankton specific absorption coefficients varied over a wide range (0.02 to 0.1 square meters (mg Chl) sup -1)) being higher in offshore surface waters, values of phytoplankton absorption spectra at the SeaWiFS wavebands were highly correlated to modeled values. The normalized scattering spectral shapes and the mean spectrum were in agreement to observations in other coastal waters, while the backscattering ratios were on average lower in phytoplankton dominated surface waters (0.0101 plus or minus 0.002) and higher in near-bottom waters (0.0191 plus or minus 0.0045) with low Chl. Average percent differences in remote sensing reflectance R (sub rs) derived form modeled and in-eater radiometric measurements were highest in the blue wavebands (52%) and at sampling stations with a ore stratified water column. Estimates of Chl and CDOM absorption derived from SeaWiFS images generated using regional empirical algorithms were highly correlated to in situ data.

D'Sa Eurico J.↗
NASA NTRS2009

Time-Series Analysis of Remotely-Sensed SeaWiFS Chlorophyll in River-Influenced Coastal Regions

The availability of a nearly-continuous record of remotely-sensed chlorophyll a data (chl a) from the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) mission, now longer than ten years, enables examination of time-series trends for multiple global locations. Innovative data analysis technology available on the World Wide Web facilitates such analyses. In coastal regions influenced by river outflows, chl a is not always indicative of actual trends in phytoplankton chlorophyll due to the interference of colored dissolved organic matter and suspended sediments; significant chl a timeseries trends for coastal regions influenced by river outflows may nonetheless be indicative of important alterations of the hydrologic and coastal environment. Chl a time-series analysis of nine marine regions influenced by river outflows demonstrates the simplicity and usefulness of this technique. The analyses indicate that coastal time-series are significantly influenced by unusual flood events. Major river systems in regions with relatively low human impact did not exhibit significant trends. Most river systems with demonstrated human impact exhibited significant negative trends, with the noteworthy exception of the Pearl River in China, which has a positive trend.

Acker, James G.↗
NASA NTRS2014

Impacts of Light Use Efficiency and fPAR Parameterization on Gross Primary Production Modeling

This study examines the impact of parameterization of two variables, light use efficiency (LUE) and the fraction of absorbed photosynthetically active radiation (fPAR or fAPAR), on gross primary production(GPP) modeling. Carbon sequestration by terrestrial plants is a key factor to a comprehensive under-standing of the carbon budget at global scale. In this context, accurate measurements and estimates of GPP will allow us to achieve improved carbon monitoring and to quantitatively assess impacts from cli-mate changes and human activities. Spaceborne remote sensing observations can provide a variety of land surface parameterizations for modeling photosynthetic activities at various spatial and temporal scales. This study utilizes a simple GPP model based on LUE concept and different land surface parameterizations to evaluate the model and monitor GPP. Two maize-soybean rotation fields in Nebraska, USA and the Bartlett Experimental Forest in New Hampshire, USA were selected for study. Tower-based eddy-covariance carbon exchange and PAR measurements were collected from the FLUXNET Synthesis Dataset. For the model parameterization, we utilized different values of LUE and the fPAR derived from various algorithms. We adapted the approach and parameters from the MODIS MOD17 Biome Properties Look-Up Table (BPLUT) to derive LUE. We also used a site-specific analytic approach with tower-based Net Ecosystem Exchange (NEE) and PAR to estimate maximum potential LUE (LUEmax) to derive LUE. For the fPAR parameter, the MODIS MOD15A2 fPAR product was used. We also utilized fAPAR chl, a parameter accounting for the fAPAR linked to the chlorophyll-containing canopy fraction. fAPAR chl was obtained by inversion of a radiative transfer model, which used the MODIS-based reflectances in bands 1-7 produced by Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm. fAPAR chl exhibited seasonal dynamics more similar with the flux tower based GPP than MOD15A2 fPAR, especially in the spring and fall at the agricultural sites. When using the MODIS MOD17-based parameters to estimate LUE, fAPAR chl generated better agreements with GPP (r2= 0.79-0.91) than MOD15A2 fPAR (r2= 0.57-0.84).However, underestimations of GPP were also observed, especially for the crop fields. When applying the site-specific LUE max value to estimate in situ LUE, the magnitude of estimated GPP was closer to in situ GPP; this method produced a slight overestimation for the MOD15A2 fPAR at the Bartlett forest. This study highlights the importance of accurate land surface parameterizations to achieve reliable carbon monitoring capabilities from remote sensing information.

grossprimary↗
NASA NTRS2015

Toward Connecting Subtropical Algal Blooms to Freshwater Nutrient Sources Using a Long-Term, Spatially Distributed, In Situ Chlorophyll-A Record

Harmful algal blooms are increasing in tropical estuaries which can have complex morphologies and hydrologic regimes while being less well studied than temperate estuaries. Spatial and temporal patterns of algal bloom occurrence in Florida Bay were examined to evaluate the potential contribution of the various freshwater inputs to the subtropical bay as nutrient sources. Monthly water quality data, from 1989 to 2009, at 28 sampling stations across the bay were analyzed at the station-month level, aggregated into hydrologic Zones of Similar Influence and based on annual rainfall seasons. The Zones of Similar Influence are linked to the geomorphology of the bay with western areas being more directly connected to the Southwest Florida Shelf waters than eastern areas. Correlation analysis suggested that inputs of phosphorus were the predominant factor in the initiation of elevated chlorophyll a (chl-a) levels but was also consistent with higher nitrogen limitation in western Florida Bay as reported in literature. Differences in mean monthly chl-a indicated a seasonality of algal blooms with elevated chl-a concentrations following heavy precipitation months for stations in the north-central and western areas of the bay where algal blooms have been re-occurring. Differences in stations' chl-a concentrations showed stations to the northwest as having significantly higher concentrations than more interior stations during the dry season but not during the rainy season (when algal blooms are occurring). Mapping the sampling stations atop the bathymetry of Florida Bay highlighted the importance of coastal morphology in evaluation of potential nutrient pathways for estuarine algal bloom sources. The specific factors resulting in the seasonal cycles of blooms remained unresolved but portions of the bay and times of year were identified as important areas for further research. This study indicates that illustrating the interplay of geomorphology and winds and rains at fine temporal and spatial resolution is required to describe nutrient circulation for systems with complex morphologies such as those associated with reefs, island matrices and headlands.

Florida Bay↗
NASA NTRS2018

Assessing the Skill of Chlorophyll Forecasts: Latest Development and Challenges Ahead Using the Case of the Equatorial Pacific

Using a global ocean biogeochemical model combined with a forecast of physical oceanic and atmospheric variables from the NASA Global Modeling and Assimilation Office, we assess the skill of a chlorophyll concentrations forecast in the Equatorial Pacific for the period 2012-2015 with a focus on the forecast of the onset of the 2015 El Nino event. Using a series of retrospective 9-month hindcasts, we assess the uncertainties of the forecasted chlorophyll by comparing the monthly total chlorophyll concentration from the forecast with the corresponding monthly ocean chlorophyll data from the Suomi-National Polar-orbiting Partnership Visible Infrared Imaging Radiometer Suite (S-NPP VIIRS) satellite. The forecast was able to reproduce the phasing of the variability in chlorophyll concentration in the Equatorial Pacific, including the beginning of the 2015-2016 El Nino. The anomaly correlation coefficient (ACC) was significant (p less than 0.05) for forecast at 1-month (R=0.33), 8-month (R=0.42) and 9-month (R=0.41) lead times. The root mean square error (RMSE) increased from 0.0399 microgram chl L(exp -1) for the 1-month lead forecast to a maximum of 0.0472 microgram chl L(exp -1) for the 9-month lead forecast indicating that the forecast of the amplitude of chlorophyll concentration variability was getting worse. Forecasts with a 3-month lead time were on average the closest to the S-NPP VIIRS data (23% or 0.033 microgram chl L(exp -1)) while the forecast with a 9-month lead time were the furthest (31% or 0.042 microgram chl L(exp -1)). These results indicate the potential for forecasting chlorophyll concentration in this region but also highlights various deficiencies and suggestions for improvements to the current biogeochemical forecasting system. This system provides an initial basis for future applications including the effects of El Nino events on fisheries and other ocean resources given improvements identified in the analysis of these results.

El Nin↗
NASA NTRS2021

River streamflow, remotely-sensed water quality, and benthic composition of previously undescribed nearshore coral reefs in northern Puerto Rico

Land-based sediment stress represents a threat to many coral reefs in Puerto Rico primarily as a result of unrestricted land cover/land use changes and poor best management practices. The effects of such stresses have been documented along most coasts around the island. However, little attention has been paid to reefs located on the north coast, and very little is known about their composition and current state. Here, we present a study characterizing riverine inputs, water quality conditions, and benthic composition of two previously undescribed coral reefs (Tómbolo and Machuca reefs) located just eastward of the Río Grande de Manatí outlet in north-central Puerto Rico. This study utilizes a time series of remotely sensed ocean color products (diffuse vertical attenuation coefficient at 490 nm [Kd490] and chlorophyll-a concentration [Chl-a] estimated with data from the Visible Infrared Imaging Radiometer Suite [VIIRS]) to characterize water quality in this coastal region. In general, the months with relatively high mean daily river streamflow also coincide with months having the highest proportion of eastward wave direction, which can promote the eastward influence of river waters towards the two coral reefs sites. Kd490 and Chl-a showed a higher riverine influence closer to the watershed outlet. Kd490 and Chl-a monthly peaks also coincide with river streamflow highs, particularly at those pixels closer to shore. Tómbolo Reef, located farther eastward of the river outlet, shows a well-developed primary reef framework mainly composed of threatened reef-building species (Acropora palmata, Pseudodiploria) and high coral cover (19-51%). The benthos of Machuca Reef, located closer to the river outlet, is dominated by macroalgae with a significantly lower coral cover (0.2-2.7%) mainly composed of “weedy” coral species (Porites astroides, and S. radians). Cover of major benthic components correlates with distance from the river outlet, and with gradients in Kd490 and Chl-a, with higher coral cover and lower macroalgal cover farther from the river outlet. Coral cover at Tómbolo Reef is higher than what has been reported for similar sites around Puerto Rico and other Caribbean islands showing its ecological importance and, as up until now, an unrecognized potential refuge of reef-building threatened coral species.

benthic cover↗
NASA NTRS2021

Performance of JAXA’s SGLI standard ocean color products for oceanic to coastal waters: chlorophyll a concentration and light absorption coefficients of colored dissolved organic matter

We present the performance of JAXA’s SGLI standard algorithms for estimating chlorophyll a (chl a) concentration and the light absorption coefcients of colored dissolved organic matter (CDOM) using recently compiled high-quality data obtained from oceanic to coastal waters. Prior to the evaluation of the algorithms, we frst compare two forward models (Gordon et al. in J Geophys Res 93(D9):10909-10924, 1988: G88 and Park and Ruddick in Appl Opt 44(7):1236–1249, 2005: PR05) using a wide range of inherent optical properties (IOPs) to (1) examine if the water refectance is appropriately reproduced and (2) correct measured refectance in terms of its bidirectionality. Based on a good reproducibility of water refectance using the PR05, the optimized IOPs are further used for explaining errors in estimates of chl a concentration and CDOM absorption when using the SGLI, the GSM (Maritorena et al. in Appl Opt 41:2705–2714, 2002), and the QAA (Lee et al. in Appl Opt 41:5755, 2002) inversion algorithms. Results show that the mean error for estimating chl a concentration using the SGLI algorithm is 110% for our dataset. Although this error is lower than that of the GSM and the QAA algorithms, a signifcant underestimate at chl a higher than 2.0 mg m−3 is observed, which is further shown by independent match-up analyses. Another SGLI CDOM product includes the mean error of 50% and shows deviation at high CDOM range (>1.0 per m). A similar trend is observed for the GSM but not for the QAA when a global relationship of CDOM to colored detrital matter is applied. The sources of errors are discussed for potentially improving the retrievals

Second-generation GLobal Imager (SGLI)↗
NASA NTRS2022

Impact of Growth Phase, Pigment Adaptation, and Climate Change Conditions on the Cellular Pigment and Carbon Content of Fifty‐One Phytoplankton Isolates

Owing to their importance in aquatic ecosystems, the demand for models that estimate phytoplankton biomass and community composition in the global ocean has increased over the last decade. Moreover, the impacts of climate change, including elevated carbon dioxide (CO2), increased stratification, and warmer sea surface temperatures, will likely shape phytoplankton community composition in the global ocean. Chemotaxonomic methods are useful for modeling phytoplankton community composition from marker pigments normalized to chlorophyll a (Chl a). However, photosynthetic pigments, particularly Chl a, are sensitive to nutrient and light conditions. Cellular carbon is less sensitive, so using carbon biomass instead may provide an alternative approach. To this end, cellular pigment and carbon concentrations were measured in 51 strains of globally relevant, cultured phytoplankton. Pigment-to-Chl a and pigment-to-carbon ratios were computed for each strain. For 25 strains, measurements were taken during two growth phases. While some differences between growth phases were observed, they did not exceed within class differences. Multiple strains of Amphidinium carterae, Ditylum brightwellii and Heterosigma akashiwo were measured to determine whether time in culture influenced pigment and carbon composition. No appreciable trends in cellular pigment or carbon content were observed. Lastly, the potential impact of climate change conditions on the pigment ratios was assessed using a multistressor experiment that included increased mean light, temperature, and elevated pCO2 on three species: Thalassiosira oceanica, Ostreococcus lucimarinus, and Synechococcus. The largest differences were observed in the pigment-to-carbon ratios, while the marker pigments largely covaried with Chl a. The implications of these observations to chemotaxonomic applications are discussed.

Pigments↗
NASA NTRS1982

Leaf reflectance-nitrogen-chlorophyll relations among three south Texas woody rangeland plant species

Annual variations in the nitrogen-chlorophyll leaf reflectance of hackberry, honey mesquite and live oak in south Texas, were compared. In spring, leaf reflectance at the 0.55 m wavelength and nitrogen (N) concentration was high but leaf chlorophyll (chl) concentrations were low. In summer, leaf reflectance and N-concentration were low but lead chl concentrations were high. Linear correlations for both spring and summer of leaf reflectance with N and chl concentration or deviations from linear regression were not statistically significant.

Gausman, H. W.↗
NASA NTRS1983

The development, performance, and potential application of the copper halide laser

The copper halide laser (CHL) is an efficient gas discharge laser that emits short pulses at two discrete wavelengths in the yellow and green spectral region. The laser pulse results from transitions in excited copper atoms. The CHL has produced pulses of up to 10 mJ in a double-pulsed mode at low repetition rates and has been operated at very high repetition rates (8 to over 35 kHz) in a continuously pulsed mode with a maximum average-power of 15 watts. In this paper, the development of the copper halide laser is reviewed along with a brief description of the copper laser operating principles. In the final section, a number of applications of the CHL are identified.

Pivirotto, T. J.↗
NASA NTRS2001

Optical Measurements and Modeling to Estimate Concentrations and Fluxes of Organic Matter in the Southern Ocean

This project was a collaboration between two Principal Investigators, Dr. Dariusz Stramski and Dr. Greg Mitchell of Scripps Institution of Oceanography, University of California San Diego. Our overall goal was to conduct optical measurements and modeling to estimate concentrations of organic matter in the Southern Ocean in support of the U.S. JGOFS Process Study in this region. Key variables and processes of high relevance to accomplish the JGOFS goals include time and space resolution of phytoplankton pigments, particulate organic carbon, and the formation and export of organic carbon. Our project focused on establishing the fundamental relationships for parameterization of these variables and processes in terms of the optical properties of seawater, and developing understanding of why the Southern Ocean differs from other low-latitude systems, or has differentiation within. Our approach builds upon historical observations that optical properties provide a useful proxy for key reservoirs of organic matter such as chlorophyll alpha (Chl) and particulate organic carbon (POC) concentrations, which are of relevance to the JGOFS objectives. We carried out detailed studies of in situ and water sample optical properties including spectral reflectance, absorption, beam attenuation, scattering, and backscattering coefficients. We evaluated the ability to estimate Chl from the spectral reflectance (ocean color) in the Southern Ocean. We examined relationships between the ocean optical properties and particulate organic carbon. We developed, for the first time, an algorithm for estimating particulate organic carbon concentration in the surface ocean from satellite imagery of ocean color. With this algorithm, we obtained maps of POC distribution in the Southern Ocean showing the seasonal progression of POC in the austral spring-summer season. We also developed a semianalytical reflectance model for the investigated polar waters based on our field measurements of absorption and backscattering coefficients and Chl-dependent parameterizations of these coefficients. With this model, libraries of expected reflectance spectra for various chlorophyll concentrations can be generated with high spectral resolution for specific oceanic regions. In addition, our semianalytical reflectance model provided insight into the mechanisms which drive the empirical relationships between the ocean color and chlorophyll concentration. Our optical approach to the study of pigment and carbon concentrations will be directly relevant to development of system models and long-term monitoring of the Southern Ocean.

Stramski, Dariusz↗