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At least 37 records · Page 2

Suboxic diagenesis in banded iron formations

Anomalous isotopic composition has been reported for the carbon in carbonate minerals of banded iron formations. Well studied examples show an enrichment in the light isotope of carbon, C-12. This enrichment presumably reflects unusual circumstances in the deposition of these sedimentary rocks. It is suggested here that the isotopically light carbonate results from early diagenetic oxidation by bacteria of substantial amounts of isotopically light organic carbon. The electron acceptor that permits oxidation in the absence of free oxygen is presumed to be Fe(III), which may have been significantly more abundant in the initial chemical precipitate than in the postdiagenetic sedimentary rock.

Walker, J. C. G.↗

Properties of mantles on cometary nuclei

The formation, structure, and properties of dusty mantles on cometary nuclei are investigated using various theoretical arguments and experimental data. It is shown how the growth of the mantle is affected by the varying thermal conductivity and how an initial chemically undifferentiated surface layer changes into a mechanically rather weak, less than 10 to the 7th dyn /sq cm, mantle which then strengthens to reach values of the order of 10 to the 8th dyn/sq cm. Organic CHON decomposition products may lower the porosity below the expected value of about 0.5 and lead to an increase of the surface temperature. They may also further strengthen the overall bonding of the mantle.

Smoluchowski, R.↗

Measurement of the absolute solar UV irradiance and variability

Radiation in the wavelength interval 150-350 nm initiates chemical reactions in the lower mesosphere and the stratosphere through the photodissociation of ambient molecular species. This experiment measures the total solar irradiance, above the Earth's atmosphere, in this wavelength interval, using three spectrometers. Measurements are made from rockets on a once-a-year basis and are used with satellite observations to determine both the absolute irradiance and the long term variability of the sun in the UV. A fourth spectrometer is being added to the payload to measure the emission in the hydrogen Lyman-alpha emission at 121.67 nm.

Mentall, James E.↗

Magma ocean formation due to giant impacts

The effect of giant impacts on the initial chemical and thermal states of the terrestrial planets is just now being explored. A large high speed impact creates an approximately hemispherical melt region with a radius that depends on the projectile's radius and impact speed. It is shown that giant impacts on large planets can create large, intact melt regions containing melt volumes up to a few times the volume of the projectile. These large melt regions are not created on asteroid sized bodies. If extruded to the surface, these regions contain enough melt to create a magma ocean of considerable depth, depending on the impact speed, projectile radius, and gravity of the target planet.

Tonks, W. B.↗

On the X-ray spectrum of Kepler's supernova remnant

We have devised a method to do nonequilibrium ionization calculations on the results of two-dimensional hydrodynamical simulations, based on the algorithm of Hughes & Helfand (1985). We have calculated the ionization structure and X-ray emission for a two-dimensional numerical hydrodynamical simulation for the remnant of Kepler's supernova (SN); the hydrodynamical model was presented in a previous paper. In this model, the progenitor of Kepler's SN is assumed to have been a massive runaway star ejected from the Galactic plane. In its red supergiant stage, its dense stellar wind was distorted and compressed into a bow shock by the ram pressure of the tenuous interstellar medium. The subsequent interaction of the supernova ejecta with this asymmetric circumstellar matter produced a strongly asymmetric supernova remnant (SNR). In this paper, we present calculated X-ray spectra for this hydrodynamical model. A comparison with observations implies a moderate overabundance of Fe in Kepler's SNR (only 50% larger than its cosmic value), in contrast to a large (6 to 15) Fe overabundance derived previously. However, we confirm earlier conclusions that Si and S abundances are 2 to 3 times solar. These modest enhancements of Si, S, and Fe may be attributed either to heavy-element enriched SN ejecta or to the initial chemical abundances of the SN progenitor, which originated in the metal-rich inner Galaxy. The comparison of our models with the observed spectra confirm theoretical predictions that moderate electron heating occurs at strong collisionless shock fronts, with the implied electron/mean temperature ratio of approximately 0.5.

Borkowski, Kazimierz J.↗

Magnetogasdynamic Power Extraction and Flow Conditioning for a Gas Turbine

An extension of the Russian AJAX concept to a turbojet is being explored. This magnetohydrodynamic (MHD) energy bypass engine cycle incorporating conventional gas turbine technology has MHD flow conditioning at the inlet to electromagnetically extract part of the inlet air kinetic energy. The electrical power generated can be used for various on-board vehicle requirements including plasma flow control around the vehicle or it may be used for augmenting the expanding flow in the high speed nozzle by MHD forces to generate more thrust. In order to achieve this interaction, the air needs to be ionized by an external means even up to fairly high flight speeds, and the leading candidates may be classified as electrical discharge devices. The present kinetic modeling calculations suggest that the use of electron beams with characteristics close to the commercially available e-beam systems (electron energy approx. 60 keV, beam current approx. 0.2 mA/sq cm) to sustain ionization in intermediate pressure, low-temperature (P = 0.1 atm, T = 300 K) supersonic air flows allows considerable reduction of the flow kinetic energy (up to 10 to 20 percent in M = 3 flows). The calculations also suggest that this can be achieved at a reasonable electron beam efficiency (eta approx. 5), even if the e-beam window losses are taken into account. At these conditions, the exit NO and O atom concentrations due to e-beam initiated chemical reactions do not exceed 30 ppm. Increasing the beam current up to approx. 2 mA/sq cm, which corresponds to a maximum electrical conductivity of sigma(sub max) approx. 0.8 mho/m at the loading parameter of K = 0.5, would result in a much greater reduction of the flow kinetic energy (up to 30 to 40 percent). The MHD channel efficiency at these conditions would be greatly reduced (to eta approx. 1) due to increased electron recombination losses in the channel. At these conditions, partial energy conversion from kinetic energy to heat would result in a significant total pressure loss (P(sub 0)/P(sub 0i) approx. 0.3). The total pressure loss can be reduced operating at the loading parameter closer to unity, at the expense of the reduced electrical power output. Raising the beam current would also result in the increase of the exit O atom concentrations (up to 600 ppm) and NO (up to 150 ppm).

Adamovich, Igor V.↗

The Carbon Monoxide Tape Recorder

Using Aura MLS data we have identified the stratospheric tape recorder in carbon monoxide (CO). Unlike the water vapor tape recorder, which is controlled by upper troposphere processes, the CO tape recorder is linked to seasonal biomass burning. Since CO has a lifetime of only a few months, the CO tape recorder barely extends above 20 km. The tape head for CO appears to be close to 360K near the same location as the water vapor tape head [Read et al, 20041. Both tape heads are below the equatorial cold point tropopause but above the base of the tropical tropopause layer. The tape recorder signal becomes more distinct from 360K to 380K suggesting that convective detrainment of plays a decreasingly important role with altitude. The Global Modeling Initiative chemical transport model forced by the climatology of biomass burning reproduces the CO tape recorder.

Schoeberl, M. R.↗

Exploring the Predictability of the High-Energy Tail of MEE Precipitation Based on Solar Wind Properties

Medium Energy Electron (MEE) precipitation (≳30 keV) ionizes the mesosphere and initiates chemical reactions, which ultimately can reduce mesospheric and stratospheric ozone. Currently, there are considerable differences in how existing parameterizations represent flux response, timing, and duration of MEE precipitation, especially considering its high-energy tail (≳300 keV). This study compares the nature of ≳300 to ≳30 keV electron fluxes to better understand differences within MEE precipitation. The MEE fluxes are estimated from measurements by the Medium Energy Proton and Electron Detector (MEPED) onboard the Polar Orbiting Environmental Satellite (POES) from 2004 to 2014. The fluxes are explored in the context of solar wind drivers: corotating high-speed solar wind streams (HSSs) and coronal mass ejections (CMEs) alongside their associated solar wind properties. Three key aspects of ≳300 keV electron fluxes are investigated: maximum response, peak timing, and duration. The results reveal a structure-dependent correlation (0.89) between the peak fluxes of ≳30 and ≳300 keV electrons. The epsilon coupling function correlates well (0.84) with the ≳300 keV peak flux, independent of solar wind structure. The ≳300 keV flux peaks 0–3 days after the ≳30 keV flux peaks. The highest probability (∼42%) occurs for a 1-day delay, while predictive capabilities increase when accounting for solar wind speed. The ≳300 keV flux response has the highest probability of lasting 4 days for both CMEs and HSSs. The results form a base for a stochastic MEE parameterization that goes beyond the average picture, enabling realistic flux variability on both daily and decadal scales.

J A Salice↗

Enstatite Chondrite Outgassing and Condensate Formation: Implications for Early Atmosphere Development

Early atmospheres on rocky planets where life may develop form through outgassing of their original starting blocks, likely a mixture of chondritic material (carbonaceous chondrites (CC), ordinary chondrites (OC), and enstatite chondrites (EC)). However, there is limited experimental data to inform models connecting a planet’s bulk composition to its early atmospheric properties and thus its possibility for life. Thompson et al. (2021) took a major step for-ward in exploring this knowledge gap by measuring outgassing of 3 volatile-rich CCs, providing important experimental constraints on the initial chemical com-position of early rocky planet atmospheres. These data provided novel insights into the gas chemistry released into evolving atmospheres early in a rocky planet’s history and differed from those currently assumed by many theoretical models of rocky planet atmosphere formation. In this study, we focused on the outgassing and condensation reactions of a primitive EC3, which has a lower intrinsic oxygen fugacity ( ƒ O 2 ) and lower volatile content than the CCC meteorites investigated by. We selected the EC to explore differences between EC and CC in low-pressure, high-temperature outgassing and condensation including S, Cl, Na, and C species.

B A Anzures↗

Parametric analysis of performance and design characteristics for advanced earth-to-orbit shuttles

Performance, trajectory, and design characteristics are presented for (1) a single-stage shuttle with a single advanced rocket engine, (2) a single-stage shuttle with an initial parallel chemical engine and advanced engine burn followed by an advanced engine sustainer burn, (3) a single-stage shuttle with an initial chemical engine burn followed by an advanced engine burn, and (4) a two-stage shuttle with a chemical propulsion booster stage and an advanced propulsion upper stage. The ascent trajectory profile includes a brief initial vertical rise; zero-lift flight through the sensible atmosphere; variational steering into an 83-kilometer by 185-kilometer intermediate orbit; and a fixed, 460-meter per second allowance for subsequent maneuvers. Results are given in terms of burnout mass fractions (including structure and payload), trajectory profiles, propellant loadings, and burn times. These results are generated with a trajectory analysis that includes a parametric variation of the specific impulse from 800 to 3000 seconds and the specific engine weight from 0 to 1.0.

Willis, E. A., Jr.↗

Solutions of the chemical kinetic equations for initially inhomogeneous mixtures.

Following the recent discussions by O'Brien (1971) and Donaldson and Hilst (1972) of the effects of inhomogeneous mixing and turbulent diffusion on simple chemical reaction rates, the present report provides a more extensive analysis of when inhomogeneous mixing has a significant effect on chemical reaction rates. The analysis is then extended to the development of an approximate chemical sub-model which provides much improved predictions of chemical reaction rates over a wide range of inhomogeneities and pathological distributions of the concentrations of the reacting chemical species. In particular, the development of an approximate representation of the third-order correlations of the joint concentration fluctuations permits closure of the chemical sub-model at the level of the second-order moments of these fluctuations and the mean concentrations.

Hilst, G. R.↗

Ionospheric chemical releases

Ionospheric plasma density irregularities can be produced by chemical releases into the upper atmosphere. F-region plasma modification occurs by: (1) chemically enhancing the electron number density; (2) chemically reducing the electron population; or (3) physically convecting the plasma from one region to another. The three processes (production, loss, and transport) determine the effectiveness of ionospheric chemical releases in subtle and surprising ways. Initially, a chemical release produces a localized change in plasma density. Subsequent processes, however, can lead to enhanced transport in chemically modified regions. Ionospheric modifications by chemical releases excites artificial enhancements in airglow intensities by exothermic chemical reactions between the newly created plasma species. Numerical models were developed to describe the creation and evolution of large scale density irregularities and airglow clouds generated by artificial means. Experimental data compares favorably with theses models. It was found that chemical releases produce transient, large amplitude perturbations in electron density which can evolve into fine scale irregularities via nonlinear transport properties.

Bernhardt, Paul A.↗

Chemical consequences of the initial diffusional growth of cloud droplets - A clean marine case

A simple microphysical cloud parcel model and a simple representation of the background marine aerosol are used to predict the concentrations and compositions of droplets of various sizes near cloud base. The aerosol consists of an externally-mixed ammonium bisulfate accumulation mode and a sea-salt coarse particle mode. The difference in diffusional growth rates between the small and large droplets as well as the differences in composition between the two aerosol modes result in substantial differences in solute concentration and composition with size of droplets in the parcel. The chemistry of individual droplets is not, in general, representative of the bulk (volume-weighted mean) cloud water sample. These differences, calculated to occur early in the parcel's lifetime, should have important consequences for chemical reactions such as aqueous phase sulfate production.

Twohy, C. H.↗

Theory of flame propagation

The mechanism of flame propagation has been qualitatively formulated. In accordance with this formulation, the chemical reaction initiated in some layer brings about an increase in the temperature; because of the heat conduction, the temperature is raised in the neighboring layer where in turn the chemical reaction is initiated. In this manner the flame is propagated.

THEORIES - FLAME-PROPAGATION↗

Initiation with an electron beam of chemical reactions of interest for visible wavelength lasers

A description is given of the first results obtained with a new shock tube-electron beam facility designed to provide a versatile means for the systematic search for laser operation among several candidate metal atom-oxidizer systems. According to the current experimental approach, metal atoms are obtained in the vapor phase by the dissociation of metal compounds. A shock tube is employed to provide a short duration flow through an array of 29 supersonic flow-mixing nozzles. A high energy electron accelerator is used for the rapid initiation of chemical reaction in a mixed flow of encapsulated metal and oxidizer.

Whittier, J. S.↗

Chemical processes involved in the initiation of hot corrosion of B-1900 and NASA-TRW VIA

Sodium surface-induced hot corrosion of B-1900 and NASA-TRW VIA alloys at 900 C has been studied, with special attention to the chemical reactions during and immediately after the induction period. Thermogravimetric tests were run and data were obtained by chemical analysis of water soluble metal salts and of residual sulfate. Surface analyses of hot corroded samples were obtained by spectroscopic techniques (ESCA). A chemical mechanism for elucidating Na2SO4-induced hot corrosion is proposed indicating that hot corrosion is initiated by basic fluxing of the protective Al2O3 scale. The sequential, catastrophic corrosion results from molybdenum content. The self-sustaining feature is a consequence of the cyclic nature of the acidic fluxing. It is believed that the mechanism is applicable not only to laboratory results, but also to the practical problem of hot corrosion encountered in gas turbine engines.

Fryburg, G. C.↗

Chemical processes involved in the initiation of hot corrosion of B-1900 and NASA-TRW VIA

Sodium sulfate induced hot corrosion of B-1900 and NASA-TRW VIA at 900 C was studied with special emphasis on the chemical reactions occurring during and immediately after the induction period. Thermogravimetric tests were run for set periods of time after which the samples were washed with water and water soluable metal salts and/or residual sulfates were analyzed chemically. Element distributions within the oxide layer were obtained from electron microprobe X-ray micrographs. A third set of samples were subjected to surface analysis by X-ray photoelectron spectroscopy. Evolution of SO2 was monitored throughout many of the hot corrosion tests. Results are interpreted in terms of acid-base fluxing mechanisms.

Fryburg, G. C.↗