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34 records · Page 2

Collective behavior of “flexicles”

In recent years the functionality of synthetic active microparticles has edged even closer to that of their biological counterparts. However, we still lack the understanding needed to recreate at the microscale key features of autonomous behavior exhibited by microorganisms or swarms of macroscopic robots. In this study, we propose a model for a three-dimensional deformable cellular composite particle consisting of self-propelled rod-shaped colloids confined within a flexible vesicle—representing a superstructure we call a “flexicle” that couples particle deformation to the internal dynamics of the internal active components. Using molecular dynamics simulations, we investigate the collective behavior of dense systems composed of many flexicles. We show that individual flexicles exhibit shape changes upon collisions with other flexicles that lead to rearrangements of the internal active rods, which slows flexicle motion. This shape deformability gives rise to a diverse set of motility-induced phase separation phenomena and the spontaneous flow of flexicles reminiscent of the migration of cells in dense tissues. Our findings establish a foundation for designing responsive, cell-like active particles and developing strategies for controlling swarm migration and other autonomous swarm behaviors at cellular and colloidal scales.

Science & Technology - Other Topics↗

Inventions Utilizing Microfluidics and Colloidal Particles

Several related inventions pertain to families of devices that utilize microfluidics and/or colloidal particles to obtain useful physical effects. The families of devices can be summarized as follows: (1) Microfluidic pumps and/or valves wherein colloidal-size particles driven by electrical, magnetic, or optical fields serve as the principal moving parts that propel and/or direct the affected flows. (2) Devices that are similar to the aforementioned pumps and/or valves except that they are used to manipulate light instead of fluids. The colloidal particles in these devices are substantially constrained to move in a plane and are driven to spatially order them into arrays that function, variously, as waveguides, filters, or switches for optical signals. (3) Devices wherein the ultra-laminar nature of microfluidic flows is exploited to effect separation, sorting, or filtering of colloidal particles or biological cells in suspension. (4) Devices wherein a combination of confinement and applied electrical and/or optical fields forces the colloidal particles to become arranged into three-dimensional crystal lattices. Control of the colloidal crystalline structures could be exploited to control diffraction of light. (5) Microfluidic devices, incorporating fluid waveguides, wherein switching of flows among different paths would be accompanied by switching of optical signals.

Marr, David W.↗

Microthrust Propulsion of the LISA Mission

We present the most recent propulsion requirements for the Laser Interferometer Space Antenna (LISA) Mission and describe potential microth ruster technology that can meet these requirements. LISA consists of three spacecraft in heliocentric orbits, forming a triangle with 5x l 0 (exp 6) km sides that are the arms of three Michelson-type interferometers. Reflective proof masses provide the reference surfaces at the end of the interferometer arms as part of the Gravitational Referenc e Sensor (GRS) designed to detect gravitational waves. The microthrus t propulsion system will be part of the Disturbance Reduction System (DRS), which is responsible for maintaining each spacecraft position w ithin approximately 10 nm around the proof masses. To provide the nec essary sensitivity, the GRS must not experience spurious acceleration s >15 (exp -10) m/ s(exp 2) in the 0.1 mHz to 1 Hz bandwidth, requiring precision formation flying and drag-free operation of the LISA spa cecraft. This leads to the following microthruster performance requir ements: a thrust range of 2-30 Micro N, a thrust resolution < 0.1 Mic ro N, and thrust noise <0.1 Hz(exp -1/2) over the LISA measurement bandwidth. The microthruster must provide this performance for 5 years c ontinuously, contain 10 years worth of propellant, and not disrupt th e science measurements. Potential microthruster technologies include Colloid, Field Emission Electric Propulsion (FEEP), and precision cold gas microthrusters. Each of these technologies is described in detai l with focus on the NASA microthruster development of the Busek Collo id Micro-Newton Thruster (CMNT).

Field Emission Electric Propulsion (FEEP)↗

Structural Modeling for the Terrestrial Planet Finder Mission

We present the most recent propulsion requirements for the Laser Interferometer Space Antenna (LISA) Mission and describe potential microth ruster technology that can meet these requirements. LISA consists of three spacecraft in heliocentric orbits, forming a triangle with 5x l o6 km sides that are the arms of three Michelson-type interferometers. Reflective proof masses provide the reference surfaces at the end of the interferometer arms as part of the Gravitational Reference Senso r (GRS) designed to detect gravitational waves. The microthrust propu lsion system will be part of the Disturbance Reduction System (DRS), which is responsible for maintaining each spacecraft position within approximately 10 nm around the proof masses. To provide the necessary sensitivity, the GRS must not experience spurious accelerations > 10 (exp -15) m/s(exp 2)# Hz (exp -1/2) in the 0.1 mHz to 1 Hz bandwidth, requiring precision formation flying and drag-free operation of the L ISA spacecraft. This leads to the following microthruster performance requirements: a thrust range of 2-30 microN, a thrust resolution < O .1 micro N, and thrust noise <0.1 micro N Hz (exp -1/2) over the LISA measurement bandwidth. The microthruster must provide this performanc e for 5 years continuously, contain 10 years worth of propellant, and not disrupt the science measurements. Potential microthruster techno logies include Colloid, Field Emission Electric Propulsion (FEEP), and precision cold gas microthrusters. Each of these technologies is des cribed in detail with focus on the NASA microthruster development of the Busek Colloid Micro-Newton Thruster (CMNT).

coronagraphs↗

Ion sources for electric propulsion

Ion systems, which accelerate ions of Cs, Hg, or colloid particles by electrostatic fields, are furthest advanced and ready for application. Four kinds of ion sources have been developed: The contact ionization source for Cs as propellants, the electron bombardment source for Cs or Hg, the RF ionization source for Hg, and the hollow needle spray nozzle for colloidal glycerol particles. In each case, the ion beam must be neutralized by injection of electrons shortly behind the exit orifice to avoid adverse space charge effects.

Stuhlinger, E.↗

Satellite auxiliary-propulsion selection techniques. Addendum: A survey of auxiliary electric propulsion systems

A review of electric thrusters for satellite auxiliary propulsion was conducted at JPL during the past year. Comparisons of the various thrusters for attitude propulsion and east-west and north-south stationkeeping were made based upon performance, mass, power, and demonstrated life. Reliability and cost are also discussed. The method of electrical acceleration of propellant served to divide the thruster systems into two groups: electrostatic and electromagnetic. Ion and colloid thrusters fall within the electrostatically accelerated group while MPD and pulsed plasma thrusters comprise the electromagnetically accelerated group. The survey was confined to research in the United States with accent on flight and flight prototype systems.

Holcomb, L. B.↗

20-mN Variable Specific Impulse (Isp) Colloid Thruster

Busek Company, Inc., has designed and manufactured an electrospray emitter capable of generating 20 mN in a compact package (7x7x1.7 in). The thruster consists of nine porous-surface emitters operating in parallel from a common propellant supply. Each emitter is capable of supporting over 70,000 electrospray emission sites with the plume from each emitter being accelerated through a single aperture, eliminating the need for individual emission site alignment to an extraction grid. The total number of emission sites during operation is expected to approach 700,000. This Phase II project optimized and characterized the thruster fabricated during the Phase I effort. Additional porous emitters also were fabricated for full-scale testing. Propellant is supplied to the thruster via existing feed-system and microvalve technology previously developed by Busek, under the NASA Space Technology 7's Disturbance Reduction System (ST7-DRS) mission and via follow-on electric propulsion programs. This project investigated methods for extending thruster life beyond the previously demonstrated 450 hours. The life-extending capabilities will be demonstrated on a subscale version of the thruster.

Demmons, Nathaniel↗

Nanoscopic Imaging of Self-Propelled Ultrasmall Catalytic Nanomotors

Ultrasmall nanomotors (<100 nm) are highly desirable nanomachines for their size-specific advantages over their larger counterparts in applications spanning nanomedicine, directed assembly, active sensing, and environmental remediation. While there are extensive studies on motors larger than 100 nm, the design and understanding of ultrasmall nanomotors have been scant due to the lack of high-resolution imaging of their propelled motions with orientation and shape details resolved. Here, we report the imaging of the propelled motions of catalytically powered ultrasmall nanomotors─hundreds of them─at the nanometer resolution using liquid-phase transmission electron microscopy. These nanomotors are Pt nanoparticles of asymmetric shapes (“tadpoles” and “boomerangs”), which are colloidally synthesized and observed to be fueled by the catalyzed decomposition of NaBH4 in solution. Statistical analysis of the orientation and position trajectories of fueled and unfueled motors, coupled with finite element simulation, reveals that the shape asymmetry alone is sufficient to induce local chemical concentration gradient and self-diffusiophoresis to act against random Brownian motion. Our work elucidates the colloidal design and fundamental forces involved in the motions of ultrasmall nanomotors, which hold promise as active nanomachines to perform tasks in confined environments such as drug delivery and chemical sensing.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Testing Fundamental Properties of Ionic Liquids for Colloid Microthruster Applications

NASA's New Millennium Program is scheduled to test a Disturbance Reduction System (DRS) on Space Technology 7 (ST7) as part of the European Space Agency's (ESA's) LISA Pathfinder Mission in late 2009. Colloid Micronewton Thrusters (CMNTs) will be used to counteract forces, mainly solar photon pressure, that could disturb gravitational reference sensors as part of the DRS. The micronewton thrusters use an ionic liquid, a room temperature molten salt, as propellant. The ionic liquid has a number of unusual properties that have a direct impact on thruster design. One of the most important issues is bubble formation before and during operation, especially during rapid pressure transitions from atmospheric to vacuum conditions. Bubbles have been observed in the feed system causing variations in propellant flow rate that can adversely affect thruster control. Bubbles in the feed system can also increase the likelihood that propellant will spray onto surfaces that can eventually lead to shorting high voltage electrodes. Two approaches, reducing the probability of bubble formation and removing bubbles with a new bubble eliminator device in the flow system, were investigated at Busek Co., Inc. and the Jet Propulsion Laboratory (JPL) to determine the effectiveness of both approaches. Results show that bubble formation is mainly caused by operation at low pressure and volatile contaminants in the propellant coming out of solution. A specification for the maximum tolerable level of contamination has been developed, and procedures for providing system cleanliness have been tested and implemented. The bubble eliminator device has also been tested successfully and has been implemented in recent thruster designs at Busek. This paper focuses on the propellant testing work at JPL, including testing of a breadboard level bubble eliminator device.

bubble formation↗

Non-Reciprocity, Metastability, and Dynamic Reconfiguration in Co-Assembly of Active and Passive Particles

Living organisms often exhibit non-reciprocal interactions where the forces acting on the objects are not equal in magnitude or opposite in direction. The combination of reciprocal and non-reciprocal interactions between synthetic building blocks remains largely unexplored. Here, out-of-equilibrium assemblies of non-motile isotropic passive and metal-patched motile active particles are formed by overlapping bulk interactions with directed self-propulsion. An external alternating current (AC) electric field generates concurrent dipolar and induced-charge electrophoretic forces between the particles which are evaluated using microscopy. The interaction force measurements allow to determine the degree of reciprocity in interactions, which is tunable by designing the active particle and its trajectory. While linearly-propelled active particles evade assembly with passive particles, helically propelled active particles form active-passive clusters with dynamic reconfiguration and long-lived metastability. Large clusters display programmable fluctuations and reconfigurability by controlling the fraction of active particles. The study establishes principles of integrating reciprocal and non-reciprocal interactions in guided colloidal assembly of reconfigurable metastable structures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Microthruster Propulsion for the Space Technology 7 (ST7) Technology Demonstration Mission

For future applications to precision formation flying missions, NASA's New Millennium Program is scheduled to test colloid micro-Newton thrusters (CMNTs) on the ST7 technology demonstration mission. These CMNTs are part of a disturbance reduction system (DRS) on the ESA SMART-2 Spacecraft or LISA Pathfinder. The goal of the ST7 DRS is to demonstrate technologies necessary to meet the nanometer precision positioning control requirements of the LISA mission. In order to achieve these goals, the CMNTs are required to demonstrate a thrust resolution of less than 0.1 micro-N and a thrust noise of less than 0.1 micro-N/[square root]Hz for thrust levels between 5 and 30 micro-N. Developed by Busek Co. with support from JPL in testing an design, the CMNT has been developed over the last four years into a flight-ready microthrust system. The development, validation testing, and flight unit production of the CMNTs are described. Development tests and analysis include preliminary wear tests, propellant loading process verification, flow testing, and performance verification. Validation and flight unit verification includes thermal and structural analysis, life testing, thermal and dynamic load testing, and performance verification. Final delivery of the units is planned in 2007 with and planned launch and flight demonstration 2009.

microthruster↗

Perspective on “Active Brownian particles moving in a random Lorentz gas”

Self-propelled active matter can exhibit vastly different behavior than systems with purely Brownian motion. In Eur. Phys. J. E 40, 23 (2017), Zeitz, Wolf, and Stark compared an active matter particle with a Brownian particle moving in a random obstacle array. They showed that near the obstacle percolation density, both Brownian and active particles exhibit the same subdiffusive behavior, but the active particle reaches a steady state more rapidly. They also found that for high activity, the active particle has a lower effective diffusion than the Brownian particle due to the increased self-trapping effect generated by the activity. This result opens new directions for the study of active matter in disordered media, including bacteria in porous media, active colloids on quenched disorder, and active particles in crowded environments.

36 MATERIALS SCIENCE↗