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All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

One- and multi-component models of the upper photosphere based on molecular spectra. I - The violet system of CN /0, 0/

Spectroheliograms taken in the CN (0, 0) violet band near 3883 A show very small scale network and cell structures with high contrast. The bandhead itself, which is a broad feature due to overlap of several CN lines, allows the diagnostic simplicity of a continuum since motions, magnetic fields, and broadening mechanisms are unimportant. We have obtained spectroheliograms in the bandhead and center-to-limb photoelectric spectra of CN (0, 0) at Kitt Peak National Observatory. From the photoelectric spectra and a detailed analysis of the formation of the CN (0, 0) spectrum we derive a best-fit one-component upper photospheric model differing from that of the HSRA and recommend a change in solar carbon abundance from the HSRA value.

Mount, G. H.↗
NASA NTRS1980

Laser spectroscopy of the CN radical and astrophysical applications

The formation of CN radicals by flash photolysis of a number of parent molecules was monitored by laser induced fluorescence in the B2Sigma(plus)-X2Sigma(plus) transition of CN. The rotational and vibrational energy of the newly formed radicals in the X state was measured directly. Formation of CN(A2Pi) in the lower vibrational levels was determined by an indirect method based on resonant energy transfer to higher vibrational levels of the ground state. These laboratory studies have shown that high initial internal excitation of CN with rotational levels of maximum N equals 50-70 is the rule. In general, the formation of simple molecules in excited states is commonly the case. There appear to be astrophysical systems where radiation from these excited levels may be detectable. Such observations would serve as a probe of molecular formation.

Cody, R. J.↗
NASA NTRS1980

Neutral cometary atmospheres. III - Acceleration of cometary CN by solar radiation pressure

The acceleration of cometary CN radicals due to solar radiation pressure has been determined by fitting Monte Carlo models to nine observed sunward-tailward pairs of brightness profiles of the (0-0) band of CN at 3883 A. The profiles were determined from spectrograms of comets Bennett 1970 II and West 1976 VI. The values of the observed acceleration agree with those computed from resonance fluorescence calculations to within the expected uncertainties. This provides an independent confirmation of the identification of the observed scale lengths with the photochemical lifetimes and velocities associated with the production of observed cometary CN by the photodissociation of HCN. The ratio of the intensity of the (0-1) band of CN at 4216 A to the (0-0) band at 3883 A has been determined from spectrograms of comet West, and is compared with theoretical values.

Combi, M. R.↗
NASA NTRS1988

An investigation into periodicities in the morphology of CN jets in comet P/Halley

The paper presents an analysis of a set of CCD images of Comet Halley which were taken in the light of the CN radical to search for evidence of a 2.25-day and/or a 7.37-day periodicity in the evolution of the CN jets. It is found that, for a phase sorted set of CCD images, the geometry of the CN jets is more easily understood when a 7.37-day periodicity is assumed. The extent of the CN jets indicates a dominant periodicity that is greater than 2.25 days.

Hoban, S.↗
NASA NTRS1987

Theoretical study of the dissociation energy and the red and violet band systems of CN

The dissociation energy (D sub O) of CN is determined to be 7.65 + or - 0.06 eV. This corresponds to delta H sub f (CN) = 105.3 + or - 1.5 kcal/mole, in excellent agreement with Engleman and Rouse (1975), but considerably larger than the recent value deduced from shock-tube studies by Colket (1984). The result is obtained not only from extensive ab initio MRCI calculations using a very large Gaussian basis set, but also from extrapolation of the directly computed value by comparison of computed and experimental results fo NO, C2, and N2. As an additional calibration of the methods, the D sub O value for CN was computed from the corresponding value for CN(-) using the experimental electron affinity data. The lifetime of the nu prime = 0 level of the violet (B 2 sigma + yields X 2 sigma +) system was computed to be 62.4 ns, in good agreement with both experiment and previous calculations. Lifetimes for the red (A 2 pi yields X 2 sigma +) system decrease with increasing nu prime, which is consistent both with the recent experiment and calculations. While the computed lifetimes are significantly longer that those obtained from the experiment, they are shorter than those deduced from an analysis of the solar spectrum. However the D sub O and f (sub OO) are consistent with Lambert's model for the solar spectrum.

Bauschlicher, Charles W., Jr.↗
NASA NTRS1990

Spectrum synthesis of CN in comets

The CN B-X (0-0) R branch fluorescence spectra for three comets (Austin, Bennett, Halley) were calculated and compared to the observed spectra. The synthesized spectrum in each case was shifted to allow for the comparison of the individual line intensities. The Swings effect (excitation of CN band in comet spectra by solar fluorescence) is clearly visible. In addition to the R(0-0) band in the CN spectrum, the P(1-1) band also contributes lines in the spectral region of observation. This branch was calculated and compared to P/Halley. The overall agreement between observations and the CN spectral model is quite good. An exception to this statement would be the high J rotation lines intensities within the R(0-0) branch of P/Halley. Additional analysis is necessary to determine if this difference is due to mechanisms in addition to fluorescence (e.g., collisions).

Kleine, Marvin↗
NASA NTRS1991

CN and HCN in the infrared spectrum of IRC + 10216

The abundance of HCN in the inner circumstellar shell of IRC + 10216 has been remeasured using the 12-micron nu2 band. The 12-micron lines are less saturated than HCN 3-micron lines previously detected in the spectrum of IRC + 10216. The observed 12-micron HCN line is formed in the circumstellar shell from about 4 to 12 R sub * in accord with a photospheric origin for HCN. The derived HCN abundance in the 4 to 12 R sub* region is 4 x 10 exp-5 and the column density is 7 x 10 exp 18/sq cm. The 5-micron CN vibration-rotation fundamental band was detected for the first time in an astronomical source. Using four CN lines, the CN column density was determined to be 2.6 x 10 exp 15/sq cm and the rotational temperature to be 8 +/-2 K. The peal radial abundance is 1 x 10 exp -5. The values for the temperature and abundance are in good agreement with microwave results and with the formation of CN from the photolysis of HCN.

Wiedemann, G. R.↗
NASA NTRS1992

P/Halley: Spatial distribution and scale lengths for C2, CN, NH2, and H2O

From P/Halley, long slit spectroscopic exposures on 12 dates, extending from Oct. 1985 to May 1986, spatial profiles were obtained for emissions by C2, CN, NH2, and OI ((sup 1)D). Examples of our derived spatial profiles are given. The qualitative trend of the scale lengths for the different species is nicely exemplified in this example. C2 has the longest parent scale length followed by CN and NH2. OI which tracks the parent H2O distribution is quite narrow but slightly wider than the continuum profile which has a center essentially indistinguishable from the stellar seeing disk. Comparison of C2 and CN also shows that C2 is falling off faster in the wings so that the daughter scale length of CN must be larger than that of C2.

Fink, Uwe↗
NASA NTRS1972

Mean lifetimes and equilibrium abundances in the fast CN cycle.

It is shown that the production of small nitrogen to carbon ratios is possible, in contrast to the equilibrium production in the ordinary CN cycle. Associated with such a production are high ratios of C-13/C-12 and of N-15/N-14. The final ratios depend on the conditions under which cessation of hydrogen burning occurs under astrophysical circumstances. A table showing proton capture mean lifetimes of CN nuclei is provided together with tables of the equilibrium abundances in a fast CN cycle. The ratios of final abundances of nitrogen to carbon as functions of temperature are also presented.

Caughlan, G. R.↗
NASA NTRS1974

Laser measurements of the radiative lifetime of the B state of CN

A turnable dye laser was used to measure the radiative lifetime of the individual rotational levels of the B2 Sigma (+) state of CN. The radiative lifetime of the unperturbed rotational levels is 65.6 plus or minus 1.0 nsec. A longer radiative lifetime of 72 plus or minus 1 nsec is observed for the Kaon prime = 4 level of the B state. The measured values of the perturbed and unperturbed levels support the longer lifetimes for the A2 meson pion state of CN. The quenching cross section of the B2 Sigma state of CN is 41 plus or minus 20 Angstroms squared and is independent of the rotational energy of the B state.

Jackson, W. M.↗
NASA NTRS1977

On the detection of newly created CN radicals and comets

Laboratory investigations of CN radical formation by photodissociation of parent molecules have suggested the possibility of observing emission lines in cometary spectra from newly formed CN radicals. These laboratory studies have shown that high initial internal excitation of CN is the rule with excitation of rotational levels N up to 70. In the collisionless environment of the cometary atmosphere this initial excitation would yield a corresponding distribution for the lowest vibrational level of the ground X(2) Sigma (+) state. Our calculations show that it is feasible with present observational techniques to detect photochemically excited lines with N approx. equal to 30 in the 0-0 band of the violet system.

Donn, B.↗
NASA NTRS1978

On the detection of newly created CN radicals in comets

A description is presented of laboratory measurements concerning the amount and the distribution of energy released into newly formed radicals by the photodissociation process. The experimental method used involved flash photolysis of the parent compound followed by laser induced fluorescence detection of the CN fragment. This method allowed the detection of individual rotational lines and, thereby, a monitoring of the relative populations of the vibrational-rotational levels of the CN ground state. The results obtained in the investigation suggest the possibility of observing emission lines in cometary spectra from newly formed CN radicals. Calculations show that it is feasible with present observational techniques to detect photochemically excited lines in the 0-0 band of the violet system.

Donn, B.↗
NASA NTRS1978

Radio observations of interstellar CN toward diffuse clouds, dark clouds, black clouds, and circumstellar clouds

Emission at 113 GHz from the CN molecule has been searched for in a large number of interstellar regions, primarily dark dust clouds. Lines have been detected in four dark clouds, the first time CN has been observed in this type of object. Comparative CO observations were also performed. The CN/CO abundance ratio varies from cloud to cloud, even among objects which are apparently otherwise similar. This variation suggests that the chemistry of dark clouds may be time-dependent. A previously reported detection of CN emission from a diffuse cloud was not confirmed. Several black clouds and circumstellar clouds were reobserved to obtain better line parameters and to serve as comparative interstellar chemical systems.

Allen, M.↗
NASA NTRS1987

The photochemistry of some possible cometary CN parent species

Laboratory work on the photochemistry of HC3N, C4N2, and CH3CN in relation to their possible role as CN parent molecules in comets is discussed. Photodissociation of HC3N, photolysis of C4N2, and quantum yields of excited CN(B) and CN(A) radicals from the VUV photolysis of CH3CN are considered.

Halpern, Joshua B.↗
NASA NTRS1989

Interstellar C2, CH, and CN in translucent molecular clouds

Optical absorption-line techniques have been applied to the study of a number of translucent molecular clouds in which the total column densities are large enough that substantial molecular abundances can be maintained. Results are presented for a survey of absorption lines of interstellar C2, CH, and CN. Detections of CN through the A 2Pi-X 2Sigma(+) (1,O) and (2,O) bands of the red system are reported and compared with observations of the violet system for one line of sight. The population distributions in C2 provide diagnostic information on temperature and density. The measured column densities of the three species can be used to test details of the theory of molecule formation in clouds where photoprocesses still play a significant role. The C2 and CH column densities are strongly correlated with each other and probably also with the H2 column density. In contrast, the CN column densities are found to vary greatly from cloud to cloud. The observations are discussed with reference to detailed theoretical models.

Black, John H.↗
NASA NTRS1991

Electron densities and the excitation of CN in molecular clouds

In molecular clouds of modest density and relatively high fractional ionization, the rotational excitation of CN is controlled by a competition among electron impact, neutral impact and the interaction with the cosmic background radiation. The degree of excitation can be measured through optical absorption lines and millimeter-wave emission lines. The available, accurate data on CN in diffuse and translucent molecular clouds are assembled and used to determine electron densities. The derived values, n(e) = roughly 0.02 - 0.5/cu cm, imply modest neutral densities, which generally agree well with determinations by other techniques. The absorption- and emission-line measurements of CN both exclude densities higher than n(H2) = roughly 10 exp 3.5/cu cm on scales varying from 0.001 to 60 arcsec in these clouds.

Black, John H.↗
NASA NTRS1994

Time-dependent analysis of 8 days of CN spatial profiles in comet P/Halley

CN profiles in comet P/Halley were constructed from observations taken at three observatories during an 8 day period in April 1986. These data provide a time series of CN spatial profiles spanning just over one 7.37 day period from 1986 April 7 to April 15 and sample distances from the nucleus from just over 10(exp 3) km to 10(exp 6) km. The effect of the 7.37 day periodic variation on the CN distribution in P/Halley has been examined by using the time-dependent model applied earlier to a subset of the data. Because of the large spatial scale of the data on April 7, 8, and 9 (approx. 10(exp 6) km), and the corresponding transport time in the coma, information present in the spatial profiles regarding the gas production rate actually covers nearly two full periods. These spatially extended profiles clearly show the wavy structures outside 10(exp 5) km. Such structures were predicted in a previous analysis (Combi & Fink 1993) that was based solely on the photometric light curve and on profiles which only extended to distances less than 10(exp 5) km. We are now able to reproduce the highly variable Halley correction for the variation in gas production rate.

Combi, Michael↗
NASA NTRS1997

Differentiating Between H and F or H and CN on C(III) or Si(III) Surfaces

A Sc tipped probe molecule yields a larger difference for the probe-H vs probe-F interaction energies than our previously studied, electron-rich pyridine (C5H5N) and (CH3)3PO probes. However, the electron-deficient Sc tipped probe does not eliminate the probe-nearest data neighbor interaction problem associated with the C(III) surface. The difference in the probe-H and probe-F interaction energies is smaller for Si(III) than C(III), making it more difficult to differentiate between these two atoms on Si(III). The larger lattice constant for Si(III) significantly reduces the data atom-data atom interaction energy as well as the probe-neighbor interaction energies. This means that the H/CN system which is not practical for C(III) due to the CN-CN repulsion, is possible for Si(III). The difference in the probe-H and probe-CN interaction energies is very large for the H/CN data storage system, making this the best system studied to date. This system could be used on C(III) if a hydrogen 'fence' is built around each data site, which corresponds to using only one quarter of the surface sites for data storage.

Bauschlicher, Charles W.↗