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Results for “CARBON MONOXIDE”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Solid State Carbon Monoxide Sensor

A means for detecting carbon monoxide which utilizes an un-heated catalytic material to oxidize carbon monoxide at ambient temperatures. Because this reaction is exothermic, a thermistor in contact with the catalytic material is used as a sensing element to detect the heat evolved as carbon monoxide is oxidized to carbon dioxide at the catalyst surface, without any heaters or external heating elements for the ambient air or catalytic element material. Upon comparison to a reference thermistor, relative increases in the temperature of the sensing thermistor correspond positively with an increased concentration of carbon monoxide in the ambient medium and are thus used as an indicator of the presence of carbon monoxide.

Upchurch, Billy T.↗
DOE OSTI2021

Isolated copper single sites for high-performance electroreduction of carbon monoxide to multicarbon products

Electrochemical carbon monoxide reduction is a promising strategy for the production of value-added multicarbon compounds, albeit yielding diverse products with low selectivities and Faradaic efficiencies. Here, copper single atoms anchored to Ti 3 C 2 T x MXene nanosheets are firstly demonstrated as effective and robust catalysts for electrochemical carbon monoxide reduction, achieving an ultrahigh selectivity of 98% for the formation of multicarbon products. Particularly, it exhibits a high Faradaic efficiency of 71% towards ethylene at -0.7 V versus the reversible hydrogen electrode, superior to the previously reported copper-based catalysts. Besides, it shows a stable activity during the 68-h electrolysis. Theoretical simulations reveal that atomically dispersed Cu–O 3 sites favor the C–C coupling of carbon monoxide molecules to generate the key *CO-CHO species, and then induce the decreased free energy barrier of the potential-determining step, thus accounting for the high activity and selectivity of copper single atoms for carbon monoxide reduction.

36 MATERIALS SCIENCE↗
NASA NTRS1996

Experimental evaluation of the ignition process of carbon monoxide and oxygen in a rocket engine

Carbon monoxide and oxygen ignition boundaries were determined in a spark torch igniter as a function of propellant inlet temperatures. The oxygen temperature was varied from ambient to -258 F, and the carbon monoxide temperature was varied from ambient to -241 F. With the oxygen and carbon monoxide at -253 F and -219 F, respectively, they successfully ignited between mixture ratios of 2.42 and 3.10. Analysis of the results indicated that the lower ignition boundary was more sensitive to oxygen temperature than to carbon monoxide temperature. Another series of tests was performed in a small simulated rocket engine with oxygen at -197 F and carbon monoxide at -193 F. An oxygen/hydrogen flame was used to initiate combustion of the oxygen and carbon monoxide. Tests performed at the optimum operating mixture ratio of 0.55 obtained steady-state combustion in every test.

Linne, Diane L.↗
NASA NTRS1990

Mars in situ propellants: Carbon monoxide and oxygen ignition experiments

Carbon monoxide and oxygen were tested in a standard spark-torch igniter to identify the ignition characteristics of this potential Mars in situ propellant combination. The ignition profiles were determined as functions of mixture ratio, amount of hydrogen added to the carbon monoxide, and oxygen inlet temperature. The experiments indicated that the carbon monoxide and oxygen combination must have small amounts of hydrogen present to initiate reaction. Once the reaction was started, the combustion continued without the presence of hydrogen. A mixture ratio range was identified where ignition occurred, and this range varied with the oxygen inlet temperature.

Linne, Diane L.↗
NASA NTRS1990

Mars in situ propellants - Carbon monoxide and oxygen ignition experiments

Carbon monoxide and oxygen were tested in a standard spark-torch igniter to identify the ignition characteristics of this potential Mars in situ propellant combination. The ignition profiles were determined as functions of mixture ratio, amount of hydrogen added to the carbon monoxide, and oxygen inlet temperature. The experiments indicated that the carbon monoxide and oxygen combination must have small amounts of hydrogen present to initiate reaction. Once the reaction was started, the combustion continued without the presence of hydrogen. A mixture ratio range was identified where ignition occurred, and this range varied with the oxygen inlet temperature.

Linne, Diane L.↗
NASA NTRS1974

Shock-tube study of carbon monoxide dissociation kinetics

Carbon monoxide dissociation-rate data were obtained over the temperature range 5600-12,000 K. The experiments were conducted with undiluted CO to emphasize rate constants applicable to molecular gas systems. Data were obtained as time-resolved pressure measurements on the end wall of a shock tube and, in some cases, as emission histories of the C2 Swan system (0-0 band) behind incident shock waves. Results confirm the presence of C2 as an intermediate species in CO decomposition.

Hanson, R. K.↗
NASA NTRS1981

Analysis of GASP carbon monoxide data

Atmospheric carbon monoxide in the upper troposphere and lower stratosphere for the period March 1977 through October 1978 was analyzed. The CO data are summarized and the distribution and variations in space and time of this gas are presented. The data show that the CO mixing ratios are higher in the troposphere than those in the stratosphere. In the Northern Hemisphere the highest value of CO mixing ratio occurs in spring, although more data are needed to verify these findings. Correlation coefficients among CO, O3, air temperature (T) and winds were calculated for different regions under different seasons. It was found that the CO correlates negatively with O3 above 20 degrees latitude and positively below that latitude. Case studies using the data of CO, O3, and T measured simultaneously were performed. Discussions and suggestions are made. Ozone data on seasonal basis is also summarized.

Wu, M. F.↗
NASA NTRS1973

A large carbon monoxide cloud in Orion

Carbon monoxide line emission was observed at a wavelength of 2.6 mm in an area of L1630, a diffuse dark nebula forming a bridge between NGC 2024 and the reflection nebula NGC 2068. The absence of a 21-cm counterpart to this region of high visual extinction suggests that L1630 is predominantly molecular hydrogen. The molecular hydrogen mass, estimated from the carbon monoxide observations, is found to comprise a significant fraction of the total mass of stars and gas within the boundaries of I Ori association.

Tucker, K. D.↗
DOE OSTI2021

Energetics of polymeric carbon monoxide

The transformation of carbon monoxide (CO) from a molecular liquid to a polymeric solid under isothermal compression at room temperature is investigated using first principles theory. We report structural and thermodynamic properties from ambient density up to 2.45 g/cc obtained using density functional theory molecular dynamics simulations, including hybrid exchange corrections. The theoretical results are compared with newly obtained polymeric CO samples, synthesized in a large volume press. The explosive performance of polymeric CO is predicted and discussed. Under most favorable assumptions, it is found to be comparable to trinitrotoluene.

25 ENERGY STORAGE↗
NASA NTRS1976

Venus - Microwave detection of carbon monoxide

The 115-gigahertz microwave line of carbon monoxide has been detected in the spectrum of Venus. The measurement proves that the carbon monoxide mixing ratio increases above an altitude of 85 kilometers in the Venus stratosphere and provides quantitative information on carbon monoxide in the altitude region from 80 to 110 kilometers. This altitude region is well above that which has been previously sensed.

Kakar, R. K.↗
NASA NTRS1979

Circumpolar measurements of ozone, particles, and carbon monoxide from a commercial airliner

Trace constituent data are presented from the unique flight of an airliner around the world over both poles. Relatively high resolution and simultaneous measurements of ozone, carbon monoxide, light-scattering particles, condensation nuclei, and meteorological parameters were obtained. The mutual variations of the data in the polar stratospheres, and in the tropical upper troposphere, are discussed in their meteorological setting. The data from the Arctic lower stratosphere are consistent with a tropospheric source of condensation nuclei, but not of carbon monoxide. Carbon monoxide mixing ratios in the Antarctic stratosphere averaged 44 ppbv. In the tropical troposphere they averaged 66 ppbv over the Pacific versus 89 ppbv over Africa. A local area of higher concentration (115 ppbv) was encountered over tropical Africa; its possible relation to carbon monoxide production by vegetation and deep convection is discussed. Evidence was found in the tropical upper troposphere of distinct boundaries between air masses of different temperature, ozone content, and particle content.

Pratt, R.↗
NASA NTRS1972

A review of carbon monoxide sources, sinks, and concentrations in the earth's atmosphere

Carbon monoxide is a toxic pollutant which is continually introduced into the earth's atmosphere in significant quantities. There are apparently some mechanisms operating which destroy most of the CO in the atmosphere, i.e., a carbon monoxide sink. These mechanisms have not as yet been established in a quantitative sense. This report discusses the various possible removal mechanisms which warrant serious consideration. Particular emphasis is given to chemical reactions (especially that with OH), soil bacteria and other biological action, and transport effects. The sources of carbon monoxide, both natural and anthropogenic, are reviewed and it is noted that there is quite possibly a significant undefined natural source. Atmospheric CO concentrations are discussed and their implications on carbon monoxide lifetime, sinks and sources are considered.

Bortner, M. H.↗
NASA NTRS1971

Carbon monoxide gas dynamic laser

Carbon monoxide gas dynamic laser oscillation generation, observing maximum power and vibrational exchange among single diatomic species states

Watt, W. S.↗
NASA NTRS1973

Carbon monoxide detector

A sensitive carbon monoxide detector, developed specifically for spacecraft use, is described. An instrument range of 0 to 60 ppm CO in air was devised. The fuel cell type detector is used as a highly sensitive electrolysis cell for electrochemically detecting gases. The concept of an electrochemical CO detector is discussed and the CO oxidation behavior in phosphoric and sulfuric acid electrolytes is reported.

Holleck, G. L.↗
NASA NTRS1982

Measurements of the global distribution of carbon monoxide in the troposphere

Carbon monoxide and methane grab samples were obtained simultaneously with ozone, aerosol, nitric oxide and DACOM CO measurements. Eighty grab samples were collected at various altitudes up to 19,000 ft. along a north-south flight path from Wallops Flight Center, VA to 11 N. CO and CH were analyzed by flame ionization gas chromatography with cryogenic preconcentration. The relationship between CO and O3 concentrated is examined. A comparative analysis between trends in aerosol and CO concentration is performed.

Hinton, R. R.↗
NASA NTRS1986

Carbon monoxide in cometary ice

Carbon monoxide has been positively identified by means of ultraviolet fluorescence in the Fourth Positive System in two comets, West (1976 VI) and Bradfield (1979 X). In both cases, the spatial distribution of the emission is consistent with the CO being a 'parent' molecule, present in the cometary ice, rather than a dissociation product of a polyatomic species such as CO2 or HCOH. However, the abundance of CO relative to that of H2O is more than an order of magnitude smaller for comet Bradfield than for comet West. Further data on CO are expected with the use of more sensitive ultraviolet instruments such as the ASTRO spectrographs which will observe P/Halley in March 1986.

Feldman, P. D.↗