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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Projecting Recent Advancements in Battery Technology to Next–Generation Electric Vehicles

Electric vehicles (EVs) have seen rapid growth in adoption over the last several years. Advancements to increase battery life and performance, policy shifts, and high charging rate are expected to further accelerate the development of next generation of EVs. Battery improvements continue to emerge, enabling increased driving range, total distance driven over the life of vehicles, and ability to charge at high rates. Herein, an analysis framework to provide insights into inclusive design metrics, such as specific energy of batteries, energy consumption of vehicles, and charging power infrastructure development, is developed. Various cell-level fast charge protocols to realistic battery designs to understand the infrastructure needs associated with achieving range replacement of 32.25 km min -1 (20 mi min -1 ) are also scaled. Additionally, by calculating scaled power and peak to average power ratio, it is found that there needs to be more distinct alignment between the research efforts focused at the cell level and what is being developed for EV charging infrastructure needs. Finally, impact of high direct current voltage architecture in next-generation EVs is discussed. The findings in this work provide an insight into recent advancements in battery technology to next-generation EVs.

20 mi/min↗
DOE OSTI2026

Comparative Assessment of Battery Carbon Footprint Calculation Frameworks to Support U.S. Battery Manufacturing

A “battery passport” is a digital record that provides comprehensive information about an individual battery across its life cycle. This concept has been introduced by Battery Regulation (EU) 2023/1542 [1], which applies to batteries for electric vehicles (EVs), industrial batteries with a capacities greater than 2 kWh, and batteries for light means of transport (LMT) greater than 2kWh sold in the European Union (EU) market – impacting manufacturers and exporters across multiple jurisdictions globally. Among its reporting mandates, a key feature of battery passports is the requirement for a carbon footprint (CF) calculation methodology supported by enhanced data granularity to enable traceable and verifiable CF results. While no other jurisdictions have yet adopted formal battery passport requirements like the EU’s, some are developing CF calculation methods to comply with the EU Battery Regulation or are creating CF-related regulations that could evolve in a similar direction, reflecting the growing importance of battery CF guidelines for manufacturers seeking to remain competitive in global markets.

Zhang, Jingyi [Argonne National Laboratory (ANL), ↗
DOE OSTI2020

Battery system management through non-linear estimation of battery state of charge

Systems, methods, and computer media for battery system management and non-linear estimation of battery state of charge are provided herein. Battery data is received for a time period over which a battery system has operated. The battery data represents the actual performance of the battery system over the time period. Sub-periods of charging or discharging can be identified in the time period. For the sub-periods of time, a curve can be fit to the battery data. Using the curves for the battery data for the sub-periods of time, an expected performance of the battery system, over a range of states-of-charge, can be determined. Operating instructions for the battery system can be provided based on the expected performance.

25 ENERGY STORAGE↗
DOE OSTI2021

Battery system management through non-linear estimation of battery state of charge

Systems, methods, and computer media for battery system management and non-linear estimation of battery state of charge are provided herein. Battery data is received for a time period over which a battery system has operated. The battery data represents the actual performance of the battery system over the time period. Sub-periods of charging or discharging can be identified in the time period. For the sub-periods of time, a curve can be fit to the battery data. Using the curves for the battery data for the sub-periods of time, an expected performance of the battery system, over a range of states-of-charge, can be determined. Operating instructions for the battery system can be provided based on the expected performance.

Crawford, Alasdair James↗
DOE OSTI2021

Energy, greenhouse gas, and water life cycle analysis of lithium carbonate and lithium hydroxide monohydrate from brine and ore resources and their use in lithium ion battery cathodes and lithium ion batteries

Life cycle analyses (LCAs) were conducted for battery-grade lithium carbonate (Li 2 CO 3 ) and lithium hydroxide monohydrate (LiOH·H 2 O) produced from Chilean brines (Salar de Atacama) and Australian spodumene ores. The LCA was also extended beyond the production of Li 2 CO 3 and LiOH·H 2 O to include battery cathode materials as well as full automotive traction batteries to observe the effect that the lithium production pathways had on these end products. The LCA here covers material, water, and energy flows associated with lithium acquisition; lithium concentration; production of lithium chemicals, battery cathode powders, and batteries; and associated transportation activities along the supply chain. Based on battery cathode material, the difference in lithium source represents a difference of up to 20% for NMC811 cathode greenhouse gases (GHGs) and up to 45% for NMC622 cathode GHGs. For full batteries, this represents a difference of up to 9% for NMC811 batteries and 20% for NMC622 batteries. Production of Li 2 CO 3 from brine-based resources had less life cycle GHG emissions and freshwater consumption per tonne of Li 2 CO 3 than Li 2 CO 3 from ore-based resources. And LiOH·H 2 O produced from brine-based lithium also had less life cycle GHG emissions and freshwater consumption per tonne of LiOH·H 2 O than LiOH·H 2 O from ore-based resources.

25 ENERGY STORAGE↗
DOE OSTI2020

A Comparative Study of Redox Mediators for Improved Performance of Li-Oxygen Batteries.

Redox meditators (RMs) are soluble catalysts located in an electrolyte that can improve the energy efficiency (reduced overpotential) and cyclability of Li-oxygen (Li-O-2) batteries. In this work, 20 RMs within a Li-O-2 system with dimethyl sulfoxide and tetraethylene glycol dimethyl ether electrolytes are studied and their electrochemical features such as redox potential, the separation of cathodic and anodic peaks, and their current intensities are measured using cyclic voltammetry (CV) experiments. Six RMs are selected as "primary" choices based on their electrochemical performance, and stability tests are then performed to examine their electrochemical responses after consecutive cycles. Moreover, galvanostatic cycling tests are performed within a Li-O-2 battery system assembled with selected six RMs for real case consistency investigations. It is found that results from CV to galvanostatic cycling tests are consistent for halides and organometallic RMs, where the former exhibit much higher stability. However, the organic RMs show high reversibility in CV but low in battery cycling results. Density functional theory calculations are carried out to gain more understanding of the stability and redox potentials of the RMs. This study provides comparative information to select the most reliable RMs for Li-O-2 batteries along with new fundamental understanding of their electrochemical activity and stability.

cyclic voltammetry↗
DOE OSTI2020

A High-Performance Na-Al Battery Based on Reversible NaAlCl4 Catholyte

This work demonstrates a high-capacity and safe Na-Al battery pairing sodium metal anode and reversible NaAlCl4 catholyte for grid scale energy storage applications. The energy-rich sodium anode allows the full play of the aluminum cathode, resulting in a full-cell capacity of 308 mAh/g at a discharge voltage of 1.6 V. Benefiting from the use of ??-alumina solid electrolyte (BASE), molten sodium anode and reversible Al deposition/stripping from NaAlCl4 catholyte, the battery presents a stable Coulombic efficiency of 100% and energy efficiency of ~95%. At a rate of C/3 (6.77 mA/cm2), the cell maintains 282 mAh/g (447 Wh/kg) after 200 cycles with an excellent capacity retention of 97.6%. Moreover, we elucidate pathways to build sodium-anode-free cells from the discharged state under dry air, which further extends the feasibility of this battery for stationary storage applications. These findings are expected to provide a new platform for the development of practical Al batteries.

Zhan, Xiaowen↗
DOE OSTI2023

Important Factors for the Reliable and Reproducible Preparation of Non-aqueous Electrolyte Solutions for Lithium Batteries

Electrolyte solutions play a crucial role in rechargeable lithium batteries. Driven by an ever-increasing demand for better batteries, more and more stringent performance requirements are being asked of electrolytes. This demand to achieve electrolytes beyond the state-of-the-art has driven an increasing number of publications over the past decade. Nevertheless, a detailed description of electrolyte preparation is frequently missing when reporting new electrolytes for batteries, creating a barrier for others to reproduce important findings. In addition, false or misleading information in a paper may result from unintentional inaccuracies during the electrolyte preparation process. This article highlights important factors for the reliable and reproducible preparation of non-aqueous electrolyte solutions for lithium batteries, with the aim of encouraging researchers to follow more rigorous reporting standards.

Cao, Xia↗
DOE OSTI2022

Concentration-dependent ion correlations impact the electrochemical behavior of calcium battery electrolytes.

Ion interactions strongly determine the solvation environments of multivalent electrolytes even at concentrations below that required for practical battery-based energy storage. This statement is particularly true of electrolytes utilizing ethereal solvents due to their low dielectric constants. These solvents are among the most commonly used for multivalent batteries based on reactive metals (Mg, Ca) due to their reductive stability. Recent developments in multivalent electrolyte design have produced a variety of new salts for Mg2+ and Ca2+ that test the limits of weak coordination strength and oxidative stability. Such electrolytes have great potential for enabling full-cell cycling of batteries based on these working ions. However, the ion interactions in these electrolytes exhibit significant and non-intuitive concentration relationships. In this work, we investigate a promising exemplar, calcium tetrakis(hexafluoroisopropoxy)borate (Ca(BHFIP)(2)), in the ethereal solvents 1,2-dimethoxyethane (DME) and tetrahydrofuran (THF) across a concentration range of several orders of magnitude. Surprisingly, we find that effective salt dissociation is lower at relatively dilute concentrations (e.g. 0.01 M) than at higher concentrations (e.g. 0.2 M). Combined experimental and computational dielectric and X-ray spectroscopic analyses of the changes occurring in the Ca2+ solvation environment across these concentration regimes reveals a progressive transition from well-defined solvent-separated ion pairs to de-correlated free ions. This transition in ion correlation results in improvements in both conductivity and calcium cycling stability with increased salt concentration. Comparison with previous findings involving more strongly associating salts highlights the generality of this phenomenon, leading to important insight into controlling ion interactions in ether-based multivalent battery electrolytes.

Hahn, Nathan T.↗
DOE OSTI2021

Keep it short: Exploring the impacts of configuration choices on the recent economics of solar-plus-battery and wind-plus-battery hybrid energy plants

Coupled renewable-battery powerplants differ from the traditional concept of independent siting of electricity resources within transmission networks. Prior research on the value proposition and cost savings from coupling did not consider the geographic constraint of co-location. This paper fills the gap by assessing how pricing volatility differences between nodes within electricity markets impact the system value of coupled renewable-battery projects as compared to independent VRE and battery installations. We use wholesale power market prices from 2012–2019 across the seven main U.S. independent system operators (ISOs) with a linear optimization program to compare the electricity market value of coupled projects to the value of the same underlying sub-components, deployed separately. We find that additional value from adding a 4-hour battery sized to 50% of renewable-plant nameplate capacity is $\$10$/MWh across ISOs on average. The highest boost occurs in California ($\$15$/MWh), where the value of adding storage to solar rises over time in tandem with increased solar penetration in the region. If renewables and batteries are deployed independently, we estimate that $\$12.5$/MWh of additional value could be achieved because of more flexibility on battery siting and operation. The $\$12.5$/MWh coupling penalty is reduced to $\$1.6$/MWh when considering alternative approaches to integrating battery storage. This result implies that renewable-battery power plants will play an increasing role in electricity systems if they can be built for $\$2$–$\$13$/MWh less than independent projects of comparable size. However, the wide regional variation in coupling penalties, along with the importance of conditions captured in our sensitivity cases, suggests the tradeoff between coupling penalties and savings will vary by situation. Therefore, roles exist for independent and coupled projects from a system optimization perspective.

14 SOLAR ENERGY↗
DOE OSTI2026

Africa Battery Energy Storage Systems (BESS) Capacity Building Li-Ion Battery Degradation and Performance [Slides]

This presentation is intended for power system engineers, operators, and planners who work on isolated power systems that have (or may soon have) high levels of power generation coming from wind turbines, solar farms, and battery energy storage, which are collectively referred to as inverter-based resources. It describes the basics of lithium-ion battery energy storage systems and lithium-ion battery degradation. Battery degradation at the cell-level is explained, and then the structure and degradation of battery energy storage systems is also explained. This is intended to help power system engineers, operators, and planners to understand and effectively utilize battery energy storage systems.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2025

Impact of electric vehicle battery recycling on reducing raw material demand and battery life-cycle carbon emissions in China

The rapid growth of electric vehicles (EVs) in China challenges raw material demand. This study evaluates the impact of recycling and reusing EV batteries on reducing material demand and carbon emissions. Integrating a national-level vehicle stock turnover model with life-cycle carbon emission assessment, we found that replacing nickel-cobalt-manganese batteries with lithium iron phosphate batteries with battery recycling can reduce lithium, cobalt, and nickel demand between 2021 and 2060 by up to 7.8 million tons (Mt) (67%), 12.4 Mt (96%), and 37.2 Mt (93%), respectively, significantly decreasing reliance on import. Moreover, battery recycling coupled with reuse can reduce carbon emissions by up to 6,532-6,864 Mt (36.0-37.9%), depending on four recycling methods employed. However, this reuse strategy delays battery recycling and risks lithium supply shortage, necessitating trade-offs between carbon reduction and material supply. Future technologies, such as lithium-sulfur and all-solid-state batteries, despite their energy efficiency, might exacerbate lithium shortage, underscoring the crucial need for increased lithium supply.

25 ENERGY STORAGE↗
DOE OSTI2022

Battery Energy Storage Scenario Analyses Using the Lithium-Ion Battery Resource Assessment (LIBRA) Model

Meeting aggressive carbon emission goals will entail widespread deployment of renewable sources of electricity. Because these sources are variable, there is a need to develop scalable energy storage technologies. The U.S. Department of Energy is supporting efforts to increase U.S. manufacturing and recycling capabilities for LIBs and to decrease costs of stationary storage batteries. Many factors influence the domestic manufacturing and cost of stationary storage batteries, including availability of critical raw materials (lithium, cobalt, and nickel), competition from various demand sectors (consumer electronics, vehicles, and battery energy storage), resource recovery (recycling), government policies, and learning in the industry, among other factors. Understanding how these factors interact and identifying synergies and bottlenecks is important for developing effective strategies for the LIB stationary energy storage system. We developed the Lithium-Ion Battery Resource Analysis (LIBRA) model as a tool to help stakeholders better understand the following types of questions: What are the roles of R&D, industrial learning, and scaling of demand in lowering the cost of battery energy storage system production? How do the intersections between the EV and stationary storage sectors affect the battery supply chain? For various stationary storage and EV penetration scenarios, what volumes of critical materials might be required and what role can resource recovery play? What does expected demand for both EVs and stationary storage portend for mineral resources and overall mineral scarcity? The LIBRA model is developed using a System dynamics (SD) modeling approach to represent interactions across the segments of the battery materials supply chain. System dynamics models can capture the complex interactions and feedback between the various system components that influence supply and demand. The LIBRA model is comprised of several interacting modules that represent specific portions of the LIB supply chain. The model tracks the buildout of the domestic LIB industry over time (2020 - 2050) and in the context of competing demands for raw materials, recycling, and markets for LIBs. The LIBRA model represents major systemic feedback loops and delays across the supply chain. This report provides a complete documentation for the LIBRA model, including model assumptions, data, scenario analysis results, and sensitivity analysis of the model's input space.

25 ENERGY STORAGE↗
DOE OSTI2021

Supporting the Li-Ion Battery Supply Chain via PEV Battery Reuse

The electric vehicle market is growing rapidly and there is significant need for lithium ion batteries and their materials. There is growing concern about the supply chain issues of lithium ion batteries in the US as most of the materials and components come from overseas. The concern about supply chain would be even more of a concern as more lithium ion systems will be installed in the renewable grid. By 2025, it is estimated that 3.5 million used PEVs may be retiring worldwide with commutative capacity of around 150 GWh. The question is what the is best way to deal with these batteries: recycle them right away for re-introduction of valuable materials into the battery supply chain or reused and then recycle them. These batteries usually have between 70-80% of their original capacity and studies have shown second use of these batteries are technically and environmentally – the question has been the economic viability. Most of LIBs has been going into the growing electric vehicle market. Rather than using new LIBs in the future grid, the second-life batteries is a significant resource and could alleviate supply chain issues.

47 OTHER INSTRUMENTATION↗
DOE OSTI2023

Impact of automated battery sorting for mineral recovery from lithium-ion battery recycling in the United States

The United States has identified several lithium-ion battery materials as critical for reaching the national emission reduction targets that have been set in accordance with the 2015 Paris Agreement. However, with few natural resources available domestically, there is a rapidly growing focus on the development of a domestic recycling industry to recover these materials from end-of-life batteries. Here, we use the Lithium-Ion Battery Resources Assessment (LIBRA) system dynamics model to evaluate the impact of automated battery sorting technology in terms of the shares of cobalt and nickel that are recovered through recycling. Findings show that automated sorting has clear benefits over manual sorting methods by helping recyclers selectively process high-cobalt batteries. By maximizing cobalt recovery, recycling becomes more profitable and drives greater investment in recycling capacity, resulting in a higher share of nickel and cobalt recovered from EOL batteries over time.

25 ENERGY STORAGE↗