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35 records · Page 2

Quasi-Periodic Whistler Mode Emission in the Plasmasphere as Observed By the DSX Spacecraft

We describe the quasi-periodic (QP) whistler-mode emissions found in the plasmasphere as detected by electric and magnetic instrumentation onboard the Demonstration and Science Experiments (DSX) spacecraft in medium Earth orbit. Over the course of the nearly 2-year mission, at least 45 episodes of whistler mode QP emissions were detected by the Broad Band Receiver (BBR) onboard DSX. Episodes of QP emissions were identified by discrete events having a clear unambiguous periodic nature as detected by both the electric antennae and search coil magnetic sensor in the BBR survey data at 30 second temporal resolution. Most of the QP episodes occurred in a frequency range between 1- 4 kHz, in a band previously identified by Van Allen Probes and Cluster investigators. However, episodes were also detected by DSX at higher frequencies - events in these episodes extending all the way to 15 kHz. We present our findings on these unusual high frequency events in the presentation herein. Specifically, these high frequency QP episodes tended to be observed near dawn/dusk when the spacecraft was at relatively high magnetic latitudes and on magnetic L-shells between 3-5. Another unusual feature of these episodes is that individual up-drifting events making up the episode were found to sometimes occur concurrently in time: The high frequency portion of one up-drifting ‘polliwog-shaped’ event overlapped in time with the low frequency portion of the subsequent event. This behavior of the QP emissions has not been previously emphasized and we consider how this temporal concurrence relates to the source processes.

Quasi-periodic↗

Dual Feedstock Upcycling of α-Methylstyrene-Doped Poly(methyl methacrylate) and Biomass via the Telescope of Depolymerization and Diels–Alder Reaction

Nearly 90% of poly(methyl methacrylate) (PMMA) is not recycled and instead ends up in landfills. Conventional pyrolysis of PMMA recovers impure methyl methacrylate (MMA) with low economic value. Here, we present a telescoped dual upcycling strategy that integrates PMMA depolymerization, Diels–Alder cycloaddition, and aromatization to convert AMS-doped PMMA and biomass-derived 2,5-dimethylfuran (DMF) into 1,2,4-trimethylbenzene (pseudocumene), a valuable chemical feedstock. BBr 3 proved effective in promoting the challenging Diels–Alder reaction between MMA and DMF under high pressure of argon.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Throughput Measurements and Profile Analysis of Cloud Networks

Cloud networks utilize virtual connections to connect virtual machines distributed across cloud sites. They are increasingly deployed due to flexible provisioning using software and cost-effectiveness in not requiring to build physical network infrastructure. However, their extensive virtualization makes it unclear how well the established practices of conventional networks translate to them. Here, we study throughput measurements over a Google Cloud network using a matching hardware emulated conventional network, which provide production and exploratory conditions, respectively. The measurements span connections representing local, cross-continental and around the Earth distances. We study the effects of parallel flows, congestion control algorithms and retransmissions on the network throughput profile expressed as a function of RTT. We compare the throughput profile of Google Cloud network with those of emulated network under various loss conditions, including those too disruptive or expensive in the former. Our analysis based on the concave-convex shape and utilization-concavity coefficients of throughput profiles indicates an overall agreement of performance between the two networks, thereby justifying the use of conventional network emulations to analyze cloud networks. In terms of practical use, our study establishes that BBR and BBRv2 alpha TCP achieve higher throughput compared to loss-based congestion control algorithms under most network configurations, especially, under losses at large RTT.

Phanekham, Derek [Southern Methodist Univ., Dallas↗

Elephants Sharing the Highway: Studying TCP Fairness in Large Transfers over High Throughput Links

Escalating bandwidth demand strains high-performance data networks, posing potential performance risks. TCP congestion control algorithms enhance reliability and optimize bandwidth usage. Network performance is influenced by factors such as AQM algorithms and router buffer size. In the context of constrained network resources, understanding how TCP flows share networks and the resulting performance impact is essential. This paper introduces insights into TCP fairness and performance involving a comparison of TCP CUBIC, Reno, Hamilton, and BBR versions 1 and 2 across real-world networks supporting high bandwidths of up to 25 Gbps. The research explores TCP behaviors with AQM algorithms like FIFO, FQ_CODEL, and RED, alongside diverse buffer sizes. Notably, findings reveal that manipulating buffers and queuing methods yields contrasting outcomes based on bandwidth. BBRv2 emerges as a superior fair algorithm, pivotal for swift transfers, particularly in scientific data scenarios. These results provide crucial guidance for future network design, ensuring equitable performance optimization.

Kiran, Mariam↗

Materials Data on B11H9C(Br3O2)2 by Materials Project

B5C(BBr)6H9O4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty-four bromoborane molecules, four hydrogen tetrahydrate molecules, and four B5C clusters. In each B5C cluster, there are five inequivalent B+0.82+ sites. In the first B+0.82+ site, B+0.82+ is bonded in a single-bond geometry to one C4- atom. The B–C bond length is 1.63 Å. In the second B+0.82+ site, B+0.82+ is bonded in a single-bond geometry to one C4- atom. The B–C bond length is 1.57 Å. In the third B+0.82+ site, B+0.82+ is bonded in a single-bond geometry to one C4- atom. The B–C bond length is 1.62 Å. In the fourth B+0.82+ site, B+0.82+ is bonded in a single-bond geometry to one C4- atom. The B–C bond length is 1.63 Å. In the fifth B+0.82+ site, B+0.82+ is bonded in a single-bond geometry to one C4- atom. The B–C bond length is 1.59 Å. C4- is bonded in a 5-coordinate geometry to five B+0.82+ atoms.

36 MATERIALS SCIENCE↗

Materials Data on NaB6S4(Br3O4)2 by Materials Project

Na(SO2)4(BBr)6 crystallizes in the monoclinic P2_1/c space group. The structure is one-dimensional and consists of twenty-four bromoborane molecules and two Na(SO2)4 ribbons oriented in the (0, 0, 1) direction. In each Na(SO2)4 ribbon, Na1+ is bonded in a distorted pentagonal planar geometry to five O2- atoms. There are a spread of Na–O bond distances ranging from 2.43–2.91 Å. There are four inequivalent S+0.75- sites. In the first S+0.75- site, S+0.75- is bonded in a bent 120 degrees geometry to two O2- atoms. Both S–O bond lengths are 1.45 Å. In the second S+0.75- site, S+0.75- is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.45 Å) and one longer (1.46 Å) S–O bond length. In the third S+0.75- site, S+0.75- is bonded in a bent 120 degrees geometry to two O2- atoms. Both S–O bond lengths are 1.45 Å. In the fourth S+0.75- site, S+0.75- is bonded in a bent 120 degrees geometry to two O2- atoms. Both S–O bond lengths are 1.45 Å. There are eight inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to one Na1+ and one S+0.75- atom. In the second O2- site, O2- is bonded in a single-bond geometry to one S+0.75- atom. In the third O2- site, O2- is bonded in a distorted linear geometry to one Na1+ and one S+0.75- atom. In the fourth O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Na1+ and one S+0.75- atom. In the fifth O2- site, O2- is bonded in a bent 150 degrees geometry to one Na1+ and one S+0.75- atom. In the sixth O2- site, O2- is bonded in a single-bond geometry to one S+0.75- atom. In the seventh O2- site, O2- is bonded in a bent 150 degrees geometry to one Na1+ and one S+0.75- atom. In the eighth O2- site, O2- is bonded in a single-bond geometry to one S+0.75- atom.

36 MATERIALS SCIENCE↗

Materials Data on NaB24S6(Br2O)12 by Materials Project

Na(SO2)6(BBr)24 crystallizes in the trigonal P-31c space group. The structure is zero-dimensional and consists of forty-eight bromoborane molecules and two Na(SO2)6 clusters. In each Na(SO2)6 cluster, Na1+ is bonded in an octahedral geometry to six equivalent O2- atoms. All Na–O bond lengths are 2.44 Å. S+1.17- is bonded in a bent 120 degrees geometry to two O2- atoms. Both S–O bond lengths are 1.45 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one S+1.17- atom. In the second O2- site, O2- is bonded in a bent 150 degrees geometry to one Na1+ and one S+1.17- atom.

36 MATERIALS SCIENCE↗

Applications and Results of MODIS Lunar Observations

Both Terra and Aqua MODIS have been making periodic lunar observations since their launch in December 1999 and May 2002, respectively. The primary objective of the MODIS lunar observations is to monitor on-orbit response changes for the reflective solar bands (RSB) and to track long-term radiometric calibration stability. The Moon is an extremely stable surface reflectance reference and, together with the lunar radiometric model developed recently by the US Geological Survey (USGS), the applications of lunar observations for Earth remote sensing missions have been greatly enhanced and expanded. In particular, calibration inter-comparisons among sensors on different platforms and operated in different time frames have been enabled in the VIS/NIR/SWIR spectral regions. In this paper, we discuss various applications of MODIS lunar observations, such as monitoring the RSB radiometric stability and calibration consistency between the two sensors, evaluating the calibration differences among detectors within the same spectral band, and tracking the on-orbit changes of band-to-band registration (BBR). Other applications designed for the thermal emissive bands (TEB) and special sensor characterization purposes are also illustrated. Results from multi-year Terra and Aqua MODIS lunar observations demonstrate clearly that the two sensors have been calibrated consistently to within 1% for most RSB compared to the 2% radiometric calibration requirement. In addition the spatial characterization results derived from lunar observations are in good agreement with those derived from the instrument's on-board calibrator. The applications and results of MODIS lunar observations presented in this paper provide useful references for other sensors that also make use of lunar surface observations.

Xiong, X.↗

NPP VIIRS Early On-Orbit Geometric Performance

The NASA/NOAA Visible Infrared Imager Radiometer Suite (VIIRS) instrument on-board the Suomi National Polar-orbiting Partnership (NPP) satellite was launched in October, 2011. The instrument geometric performance includes sensor spatial response, band-to-band co-registration (BBR), and geolocation accuracy and precision. The geometric performance is an important aspect of sensor data record (SDR) calibration and validation. In this paper we will discuss geometric performance parameter characterization using the first seven-month of VIIRS' earth and lunar data, and compare with the at-launch performance using ground testing data and analysis of numerical modeling results as the first step in on-orbit geometric calibration and validation.

Wolfe, Robert E.↗

Suomi NPP VIIRS Prelaunch and On-orbit Geometric Calibration and Characterization

The Visible Infrared Imager Radiometer Suite (VIIRS) sensor was launched 28 October 2011 on the Suomi National Polarorbiting Partnership (SNPP) satellite. VIIRS has 22 spectral bands covering the spectrum between 0.412 m and 12.01 m, including 16 moderate resolution bands (M-bands) with a spatial resolution of 750 m at nadir, 5 imaging resolution bands (I-bands) with a spatial resolution of 375 m at nadir, and 1 day-night band (DNB) with a near-constant 750 m spatial resolution throughout the scan. These bands are located in a visible and near infrared (VisNIR) focal plane assembly (FPA), a short- and mid-wave infrared (SWMWIR) FPA and a long-wave infrared (LWIR) FPA. All bands, except the DNB, are co-registered for proper environmental data records (EDRs) retrievals. Observations from VIIRS instrument provide long-term measurements of biogeophysical variables for climate research and polar satellite data stream for the operational communitys use in weather forecasting and disaster relief and other applications. Well Earth-located (geolocated) instrument data is important to retrieving accurate biogeophysical variables. This paper describes prelaunch pointing and alignment measurements, and the two sets of on-orbit correction of geolocation errors, the first of which corrected error from 1,300 m to within 75 m (20 I-band pixel size), and the second of which fine tuned scan angle dependent errors, bringing VIIRS geolocation products to high maturity in one and a half years of the SNPP VIIRS on-orbit operations. Prelaunch calibration and the on-orbit characterization of sensor spatial impulse responses and band-to-band co-registration (BBR) are also described.

Geolocation↗

Sixteen Years of Terra MODIS On-Orbit Operation, Calibration, and Performance

Terra MODIS has successfully operated for more than 16 years since its launch in December 1999. From its observations, many science data products have been generated in support of a broad range of research activities and remote sensing applications. Terra MODIS has operated in a number of configurations and experienced a few anomalies, including spacecraft and instrument related events. MODIS collects data in 36 spectral bands that are calibrated regularly by a set of on-board calibrators for their radiometric, spectral, and spatial performance. Periodic lunar observations and long-term radiometric trending over well-characterized ground targets are also used to support sensor on-orbit calibration. Dedicated efforts made by the MODIS Characterization Support Team (MCST) and continuing support from the MODIS Science Team have contributed to the mission success, enabling well-calibrated data products to be continuously generated and routinely delivered to users worldwide. This paper presents an overview of Terra MODIS mission operations, calibration activities, and instrument performance of the past 16 years. It illustrates and describes the results of key sensor performance parameters derived from on-orbit calibration and characterization, such as signal-to-noise ratio (SNR), noise equivalent temperature difference (NEdT), solar diffuser (SD) degradation, changes in sensor responses, center wavelengths, and band-to-band registration (BBR). Also discussed in this paper are the calibration approaches and strategies developed and implemented in support of MODIS Level 1B data production and re-processing, major challenging issues, and lessons learned. (2016) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.

Xiong, X.↗

MODIS and VIIRS On-Orbit Calibration and Characterization Using Observations from Spacecraft Pitch Maneuvers

Two MODIS instruments (Terra and Aqua) and two VIIRS instruments (S-NPP and JPSS-1) are currently operated inspace, continuously making global earth observations in the spectral range from visible (VIS) to long-wave infrared(LWIR). These observations have enabled a broad range of environmental data records to be generated and distributed insupport of both operational and scientific community. Despite extensive pre-launch calibration and characterizationperformed for both MODIS and VIIRS instruments and routine on-orbit calibration activities carried out using their onboardcalibrators (OBC), various spacecraft maneuvers have also been designed and implemented to further enhance thesensor on-orbit calibration and data quality. This paper focuses on the use of observations made during spacecraft pitchmaneuvers of MODIS and VIIRS in support of their on-orbit characterization of thermal emissive bands (TEB) responseversus scan-angle (RVS). In the case of Terra MODIS, lunar observations made from instrument nadir view duringspacecraft pitch maneuvers are used to compare with that made regularly through instrument space view (SV) port toevaluate on-orbit changes in RVS and band-to-band registration (BBR) for the reflective solar bands (RSB). In additionto results derived from spacecraft pitch maneuvers performed for MODIS and VIIRS, discussion is provided on theadvantages, challenges, and lessons for future considerations and improvements.

Xiong, Xiaoxiong↗

Concept for a Far-infrared Outgoing Radiation Closure Experiment – Antarctica (FORCE-A)

The next decade promises to be an incredibly exciting time in climate science. There are two new space flight missions, PREFIRE and FORUM, that will open the far-infrared spectrum to direct, accurate observations for the first time. PREFIRE is planned to operate between 2022 and 2024 and FORUM will launch in late 2025 or early 2026. The TICFIRE instrument is also a candidate for the NASA A-CCP mission to be launched in the 2028 timeframe. A key focus of these missions and instruments is improved understanding of polar climates. In support of these missions we present a concept for a radiative closure experiment to be conducted in Antarctica during the PREFIRE mission lifetime and then again during the operational FORUM and TICFIRE/A-CCP missions. The main component of the campaigns would be a long-duration balloon flight launched from McMurdo Station with the potential of 1-2 months aloft. Candidate balloon flight instrumentation includes a far-IR Fourier transform spectrometer and far-IR radiometers. Ground based instrumentation includes zenith viewing infrared and far-infrared spectrometers, lidars, and microwave radiometers. The objective of the FORCE-A campaign is to demonstrate radiative closure in the infrared with the multiple campaign instruments combined with the numerous relevant satellite instruments that pass overhead every 30 minutes (AIRS, CrIS, IASI, MODIS, VIIRS, CERES, BBR, Libera). The campaign will serve to advance radiation sciences as well as to provide the means for validation of the new far-infrared observations.

Martin G Mlynczak↗

Lunar calibration and performance assessments of the NOAA-20 VIIRS reflective solar bands

The Moon has played a vital role in the radiometric stability monitoring of NASAs Earth Observing System sensors, such as MODIS on the Terra and Aqua spacecrafts. The lunar calibration methodologies developed for the two MODIS instruments were later extended to apply to the VIIRS instrument on the Suomi-NPP spacecraft. The follow-on VIIRS instrument on the NOAA-20 (N20) spacecraft (previously JPSS-1) has been successfully operating since its launch in November 2017. Fifteen VIIRS spectral bands are in the reflective solar spectral region, covering wavelengths from 0.4 to 2.3 μm. Similar to the previous MODIS and VIIRS instruments, the N20 VIIRS views the Moon via a spacecraft roll maneuver on a near-monthly basis at a confined phase angle range (-51.5° to -50.5°) to facilitate radiometric stability monitoring with reduced uncertainties. In this paper, we briefly present the lunar calibration methodology and also report the derived instrument gain parameters from the regularly scheduled lunar calibrations. The USGS Robotic Lunar Observatory (ROLO) model is used to provide the predicted lunar irradiance for each lunar measurement to account for the variation in the observation geometry. The spatial characterization algorithms using the Moon, previously developed for MODIS and SNPP VIIRS, have also been extended to N20 VIIRS to track its on-orbit band-to-band registration (BBR).

VIIRS↗

Spatial Characterization of PACE OCI ETU Using Time-Delay Mode

The OCI (Ocean Color Instrument) is the main sensor on the upcoming PACE (Plankton Aerosol Cloud ocean Ecosystem) mission. OCI has two hyperspectral CCD sensors covering 340nm to 885nm and 9 SWIR (Short Wave IR) bands from 940nm to 2260nm. SWIR bands have nominal 1km ground pixel size and CCD bands have native 1/8 km ground pixel size in diagnostic mode that will be aggregated into 1km pixels to improve SNR and meet the data rate constraints. OCI has a rotating telescope that is synchronized to the readout of the CCD and SWIR detectors. Full pre-launch system level testing for the OCI ETU (Engineering Test Unit) was completed in June 2021.With time-delayed scan mode, a sub-pixel level time-delay step is applied to the detector readout. This sub-pixel level time-delay step causes a sub-pixel level shift in the start of the data collection. After collecting time-delay step scans with different step sizes, a scan profile with sub-pixel resolution can be constructed. 1/8 and 1/4 of CCD pixel resolutions were achieved using this mode. In this paper, the OCI time-delayed scan mode will be described as well as how it was used to calculate OCI’s high spatial resolution PSF (Point Spread Function), IFOV (instantaneous Field of View), MTF (Modulation Transfer Function), and BBR (Band to Band Registration).

PACE↗

SuperDove Geometric Quality Assessment Summary

We have evaluated Planet’s SuperDove series spatial performance, relative geolocation accuracy over 25 globally distributed locations, band-to-band registration (BBR), and temporal stability at one USA city.

Alana G. Semple↗