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22 records · Page 2

Wet chemical passivation of YBa2Cu3O(7-x)

Wet chemical techniques are described for treatment of YBa2Cu3O(7-x) surfaces, which result in the formation of native compounds known to have little or no reactivity to water. Suitable native compounds include CuI, BaSO4, CuS, Cu2S, YF3, and the oxalates. Formation of surface layers in which these nonreactive native compounds are major constituents is verified with X-ray photoelectron spectroscopy (XPS) measurements on YBa2Cu3O(7-x) films treated with dilute solutions of HI, H2SO4, Na2S, HF, or H2C2O4. No significant changes are observed in the XPS spectra when the sulfide, sulfate, or oxalate films are dipped in water, while the iodide and fluoride films show evidence of reaction with water. X-ray diffraction measurements show that the superconducting phase is absent in the sulfide film, but is unaffected by the oxalate and sulfate treatments.

Vasquez, R. P.↗

Salts in two chondritic porous interplanetary dust particles

Grain-by-grain analytical electron microscope analyses of two micrometeorites, or interplanetary dust particles (IDPs) of the chondritic porous subtype show the presence of rare barite (BaSO4) and magnesium carbonate, probably magnesite. Salt minerals in chondritic porous (CP) IDPs give evidence for in situ aqueous alteration in their parent bodies. The uniquely high barium content of CP IDP W7029(asterisk)C1 is consistent with barite precipitation from a mildly acidic (pH above 5) aqueous fluid at temperatures below 417 K and low oxygen fugacity. The presence of magnesite in olivine-rich, anhydrous CP IDP W7010(asterisk)A2 is evidence that carbonate minerals occur in both the chondritic porous and chondritic smooth subtypes of chondritic IDPs. Citing Schramm et al. (1989) for putative asteroidal-type aqueous alteration in IDPs and probable sources of chondritic IDPs, salt minerals in CP IDPs could support low-temperature aqueous activity in nuclei of active short-period comets.

Rietmeijer, Frans J. M.↗

Development and Performance of a Filter Radiometer Monitor System for Integrating Sphere Sources

The NASA Goddard Space Flight Center (GSFC) Radiometric Calibration Laboratory (RCL) maintains several large integrating sphere sources covering the visible to the shortwave infrared wavelength range. Two critical, functional requirements of an integrating sphere source are short and long-term operational stability and repeatability. Monitoring the source is essential in determining the origin of systemic errors, thus increasing confidence in source performance and quantifying repeatability. If monitor data falls outside the established parameters, this could be an indication that the source requires maintenance or re-calibration against the National Institute of Science and Technology (NIST) irradiance standard. The GSFC RCL has developed a Filter Radiometer Monitoring System (FRMS) to continuously monitor the performance of its integrating sphere calibration sources in the 400 to 2400nm region. Sphere output change mechanisms include lamp aging, coating (e.g. BaSO4) deterioration, and ambient water vapor level. The Filter Radiometer Monitor System (FRMS) wavelength bands are selected to quantify changes caused by these mechanisms. The FRMS design and operation are presented, as well as data from monitoring four of the RCL s integrating sphere sources.

Ding, Leibo↗

Impact of Thermochromic Coatings on Thermal Management for Human Spacecraft Applications

Thermochromic variable emittance coatings (VECs) allow for passive, dynamic thermal management of space vehicles due to their temperature dependent optical properties. Ideally, a thermochromic material should exhibit low mid-IR emissivity for lower temperatures and switch to high mid-IR emissivity for higher temperatures; one promising material that demonstrates these characteristics is Lanthanum Strontium Manganite (LSM). The transition temperatures of LSM are dependent on the Lanthanum-to-Strontium ratio x, La1-xSrxMnO3. La0.8Sr0.2MnO3, which has an emittance of 0.5 for < 270 K, then a linear increase in emittance to 0.8 over an increase of 70 K where it will saturate at ~340K, is commonly utilized but this is tunable by changing the Sr concentration. The tunability of the transition temperature range of LSM motivates a need to understand the optimal thermal transition range for human spacecraft. Additionally, LSM has high solar absorptance and to combat this issue the VEC will be micropatterned on top of a highly solar reflective layer of Barium Sulfate (BaSO4). Consequently, this work will elucidate the tradeoffs between solar absorptance and variable emittance for this technology since the micropattern adversely couples the solar absorptance to the mid-IR emittance. This work develops a computational model using Thermal Desktop to study the utility of VECs on human spacecraft, such as Orion, subjected to mission phases such as lunar transit and Gateway docking. The model considers both external heat loads, from solar irradiation and planetary IR, as well as vehicle heat loads, from avionics and crew, as an input into the body mounted thermochromic radiators. There are several design targets for VECs, i.e. achieving the largest change in emittance, finding the optimal temperature range for the transition, and achieving the highest emittance in the high temperature phase. This work prioritizes these design targets for LSM to achieve the optimal heat rejection for a human spacecraft. The VECs are compared with static emittance coatings and the efficiency gains are quantified. Thermochromic VECs will ultimately lead to simplifications of active cooling systems which synergistically correlates to mass reduction and less energy consumption for space vehicles.

Joseph Peoples↗