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Space Shuttle exhausted aluminum oxide - A measured particle size distribution

Aluminum oxide (A2O3) particles were collected from the Space Shuttle exhaust plume immediately following the launch of STS-34 on October 18, 1989. A2O3 samples were obtained at 2.4, 3.0, 3.2, and 7.4 km in altitude. The samples were analyzed using SEM to develope particle size distributions. There were no indications that the particle size distribution changed as a function of altitude. The particle number concentrations per cubic meter of air sampled for the four collections was found to fit an exponential expression.

Cofer, W. R., III

Pretreatment effects on the morphology and properties of aluminum oxide thermally grown on NiCoCrAlY

The effect of pretreatments on the morphology and properties of aluminum oxide thermally grown from NiCoCrAlY was investigated. The goal was to optimize process steps to produce a highly adherent, continuous, and insulating aluminum oxide. Two pretreatments were carried out, one in vacuum (about 0.0001 Torr) at 1350 K for 5 h, and the other consisting of deposition of a 1-micron thick Al2O3 film by activated reactive evaporation. Samples were subsequently oxidized thermally at 1000 C for 50 h at 0.5 Torr oxygen pressure. The two pretreatments were carried out on electron-beam evaporation NiCoCrAlY, about 120 microns thick, deposited on a superalloy turbine blade substrate. The results showed that the thermally grown oxide was significantly different in microstructure, surface topography and in its adherence to the NiCoCrAlY for the two pretreatments. Optimum results were obtained by combining the two pretreatments to produce an adherent, continuous, and insulating oxide film on the NiCoCrAlY-coated superalloy substrate.

Prakash, S.

Enhanced hydrophilicity of chlorided aluminum oxide particulates

An enhancement of hydrophilicity for chlorided aluminas was demonstrated by the results obtained from gaseous H2O sorptions at 70-, 80-, and 86-percent relative humidity on alpha and gamma aluminum oxide particulates and on alpha and gamma aluminum oxide particulates with a chemisorbed surface chloride phase (produced by reactions of gaseous HCl + H2O on alumina). Continuous sorption histories for H2O on chlorided aluminas having specific surface areas that range from 7 to 227 sq m/g before chloriding indicated that initial sorption rates were directly linked to the extent of chemisorbed chlorided coverage and implied the same relationship for sorption capacities. The initial sorption rate on chlorided aluminas was found to be slower for the first exposure to H2O than for subsequent exposures (which reached equilibrated H2O coverages much faster), suggesting that slow chemical reactions between H2O and chlorided alumina may have been operative during initial exposures. Chlorided alumina particles were found to remain very hydrophilic (relative to nonchlorided analogs) for several H2O sorption/desorption cycles.

Cofer, W. R., III

Aluminum oxide barriers in MCrAlY superalloy systems

An investigation was made of sputtered aluminum oxide diffusion barriers to protect gas turbine engine blade and vane alloys from their coatings. MAR M200 + Hf coated with sputtered NiCoCrAlY and MAR M509 coated with sputtered FeCrAlY were obtained both with and without 1 and 2 micron sputtered Al2O3 barrier layers. Electron dispersive X-ray analysis was used to determine the concentration profiles of as-received and heat treated samples.

Kreider, Kenneth G.