Engineering PapersSearch

SEARCH · Engineering Papers

Results for “ABSORPTIVE INDEX”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2

Atmospheric effects on CO2 laser propagation

An investigation was made of the losses encountered in the propagation of CO2 laser radiation through the atmosphere, particularly as it applies to the NASA/Marshall Space Flight Center Pulsed Laser Doppler System. As such it addresses three major areas associated with signal loss: molecular absorption, refractive index changes in a turbulent environment, and aerosol absorption and scattering. In particular, the molecular absorption coefficients of carbon dioxide, water vapor, and nitrous oxide are calculated for various laser lines in the region of 10.6 mu m as a function of various pressures and temperatures. The current status in the physics of low-energy laser propagation through a turbulent atmosphere is presented together with the analysis and evaluation of the associated heterodyne signal power loss. Finally, aerosol backscatter and extinction coefficients are calculated for various aerosol distributions and the results incorporated into the signal-to-noise ratio equation for the Marshall Space Flight Center system.

Murty, S. S. R.

Mariner-mars absorptance experiment.

Absorptivity standard instrument to investigate solar absorptance of four surfaces used for spacecraft temperature control for Mariner IV on Mars mission

ABSORPTIVE INDEX

Atmospheric aerosols: Their Optical Properties and Effects (supplement)

A digest of technical papers is presented. Topics include aerosol size distribution from spectral attenuation with scattering measurements; comparison of extinction and backscattering coefficients for measured and analytic stratospheric aerosol size distributions; using hybrid methods to solve problems in radiative transfer and in multiple scattering; blue moon phenomena; absorption refractive index of aerosols in the Denver pollution cloud; a two dimensional stratospheric model of the dispersion of aerosols from the Fuego volcanic eruption; the variation of the aerosol volume to light scattering coefficient; spectrophone in situ measurements of the absorption of visible light by aerosols; a reassessment of the Krakatoa volcanic turbidity, and multiple scattering in the sky radiance.

Source record

The Use of High Spectral Resolution Bands for Estimating Absorbed Photosynthetically Active Radiation (A Par)

Most remote sensing estimations of vegetation variables such as Leaf Area Index (LAI), Absorbed Photosynthetically Active Radiation (APAR), and phytomass are made using broad band sensors with a bandwidth of approximately 100 nm. However, high resolution spectrometers are available and have not been fully exploited for the purpose of improving estimates of vegetation variables. A study directed to investigate the use of high spectral resolution spectroscopy for remote sensing estimates of APAR in vegetation canopies in the presence of nonphotosynthetic background materials such as soil and leaf litter is presented. A high spectral resolution method defined as the Chlorophyll Absorption Ratio Index (CARI) was developed for minimizing the effects of nonphotosynthetic materials in the remote estimates of APAR. CARI utilizes three bands at 550, 670, and 700 nm with bandwidth of 10 nm. Simulated canopy reflectance of a range of LAI were generated with the SAIL model using measurements of 42 different soil types as canopy background. CARI obtained from the simulated canopy reflectance was compared with the broad band vegetation indices (Normalized Difference Vegetation Index (NDVI), Soil Adjusted Vegetation Index (SAVI), and Simple Ratio (SR)). CARI reduced the effect of nonphotosynthetic background materials in the assessment of vegetation canopy APAR more effectively than broad band vegetation indices.

Kim, Moon S.

Cryo-Infrared Optical Characterization at NASA GSFC

The development of large space infrared optical systems, such as the Next Generation Space Telescope (NGST), has increased requirements for measurement accuracy in the optical properties of materials. Many materials used as optical components in infrared optical systems, have strong temperature dependence in their optical properties. Unfortunately, data on the temperature dependence of most of these materials is sparse. In this paper, we provide a description of the capabilities existing in the Optics Branch at the Goddard Space Flight Center that enable the characterization of the refractive index and absorption coefficient changes and other optical properties in infrared materials at cryogenic temperatures. Details of the experimental apparatus, which include continuous flow liquid helium optical cryostat, and a Fourier Transform Infrared (FTIR) spectrometer are discussed.

Boucarut, Ray

Modeling Global Indices for Estimating Non-Photosynthetic Vegetation Cover

Non-photosynthetic vegetation (NPV) includes plant litter, senesced leaves, and crop residues. NPV plays an essential role in terrestrial ecosystem processes, and is an important indicator of drought severity, ecosystem disturbance, agricultural resilience, and wildfire danger. Current moderate spatial resolution multispectral satellite systems (e.g., Landsat and Sentinel-2) have only a single band in the 2000–2500 nm shortwave infrared “SWIR2” range where non-pigment biochemical constituents of NPV, including cellulose and lignin, have important spectral absorption features. Thus, these current systems have suboptimal capabilities for characterizing NPV cover. This research used simulated spectral mixtures accounting for variability among NPV and soils to evaluate globally-appropriate hyperspectral and multispectral indices for estimation of fractional NPV cover. The Continuum Interpolated NPV Depth Index (CINDI), a weighted ratio index measuring lignocellulose absorption near 2100 nm, was found to produce the lowest error in estimating NPV cover. CINDI was less sensitive to variability in soil spectra and green vegetation cover than competing indices. While CINDI was sensitive to the relative water content of soil and NPV, this sensitivity allowed for correcting error in estimated NPV cover as water content increased. CINDI bands were less capable than Dual Absorption NPV Index (DANI) bands for maintaining continuity with the heritage Landsat SWIR2 band, but combining multiple CINDI bands demonstrated adequate continuity. Three SWIR2 bands with band centers at 2038, 2108, and 2211 nm can provide superior capabilities for future moderate resolution multispectral/superspectral systems targeting NPV monitoring, including the next generation Landsat mission (Landsat Next). These bands and the associated CINDI index provide potential for global NPV monitoring using a constellation of future superspectral sensors and imaging spectrometers, with applications including improving soil management, preventing land degradation, evaluating impacts of drought, mapping ecosystem disturbance, and assessing wildfire danger.

Index optimization

Two-Flux Method for Transient Radiative Transfer in a Semitransparent Layer

The two-flux method was used to obtain transient solutions for a plane layer including internal reflections and scattering. The layer was initially at uniform temperature, and was heated or cooled by external radiation and convection. The two-flux equations were examined as a means for evaluating the radiative flux gradient in the transient energy equation. Comparisons of transient temperature distributions using the two-flux method were made with results where the radiative flux gradient was evaluated from the exact radiative transfer equations. Good agreement was obtained for optical thicknesses from 0.5 to 5 and for refractive indices of 1 and 2. Illustrative results obtained with the two-flux method demonstrate the effect of isotropic scattering coupled with changing the refractive index. For small absorption with large scattering the maximum layer temperature is increased when the refractive index is increased. For larger absorption the effect is opposite, and the maximum temperature decreases with increased refractive index .

Siegel, Robert

Structural, electronic, and optical-absorption properties of 2D Si thin films

Recent experimental studies highlighted the potential of thin-film crystalline silicon (Si) for high-efficiency solar cells. Using density functional theory, we investigated 2D Si thin films across various orientations, thicknesses, and surface structures to elucidate their structure–property relationships. Through surface-energy calculations and Wulff construction, we determined the crystal habit of Si, which aligns with available experimental observations. Electronic-structure calculations underscored the critical role of valence saturation on surfaces in enabling semiconducting behavior in Si thin films, essential for optical applications. From optical-absorption calculations, we identified the surface index exhibiting the highest absorption coefficients for thin films Si solar cell applications.

36 MATERIALS SCIENCE

Vegetation canopy PAR absorptance and the normalized difference vegetation index - An assessment using the SAIL model

Relationships are studied between the normalized-difference vegetation index (NDVI) and absorbed photosynthetically active radiation (APAR) in a vegetation canopy. The SAIL model of bidirectional canopy radiative transfer is employed to compare NDVI measurements that are instantaneous with diurnally integrated canopy APAR capacity. The NDVI measurements - taken at solar-zenith angles of more than 60 deg and sensor views of less than 40 deg from nadir - give stable near-linear estimates of diurnal APAR capacity. Discrepancies in the relations between APAR and NDVI are associated with variations in the optical properties of the canopy and with background spectral reflectance. The results are significant for the practical use of these remote sensing techniques but suggest that instantaneous observations can be used to characterize the diurnally integrated APAR in vegetation canopies.

Goward, Samuel N.

The PCM is Dead! Long Live O-PCM!

The ability to reconfigure the optical behavior of a device enables free-space applications ranging from imaging to sensing and signal control. Such optical devices can be compacted via meta-surfaces, patterned structures with feature sizes below the incident wavelength. Leveraging geometry in addition to material properties and CMOS fabrication techniques has allowed meta-surfaces for lenses, holograms, beam steerers and more. To incorporate multiple optical functions into one device, various methods of device control have been implemented, such as stretching of flexible substrates, tuning the refractive index of the comprising meta-atoms via the electro-optic or the thermo-optic effects, phase transition materials such as VO2 and more. Chalcogenide glasses used as optical phase change materials, such as Ge¬2Sb2Te5 (GST), have gained increased traction in the optics community for potential use in the near infrared (NIR) and mid infrared (MIR) bands, including the telecom bands. Various chalcogenides such as Sb2Se3, Sb2S3, Ge2Sb¬2Se5 and Ge2Sb2Se4Te (GSST) have been investigated due to their broad NIR or MIR transparency window and large changes in refractive index. In their amorphous phase, these materials usually display a lower refractive index and low absorption when compared to their crystalline state which display a higher refractive index and typically larger extinction coefficients. The amorphous-crystalline reversible switching can be done via fast melt-quenching thermal processes triggered by laser or electrical impulses, relying on a substrate as a heat sink. The potential of PCMs in photonic devices can be limited by intrinsic material limitations as well as by device fabrication issues. To explore the cyclability of GSST, a PCM with large refractive index contrast and on-chip electrothermal switching on a silicon-on-insulator platform has been done to analyze potential failure mechanisms from both a material and device perspective. A brief outline of the instrumentation and phase change contrast analysis is provided. Dewetting of the PCM, delamination of and damage in the PECVD SiNx protective layer, elemental migration in the PCM and optical contrast decay have been observed in cycled GSST devices. Guidelines for device performance improvement are proposed, and an improved design with larger endurance is shown in progress.

reconfigurable photonics

Interpreting the Ultraviolet Aerosol Index Observed with the OMI Satellite Instrument to Understand Absorption by Organic Aerosols: Implications for Atmospheric Oxidation and Direct Radiative Effects

Satellite observations of the ultraviolet aerosol index (UVAI) are sensitive to absorption of solar radiation by aerosols; this absorption affects photolysis frequencies and radiative forcing. We develop a global simulation of the UVAI using the 3-D chemical transport model GEOSChem coupled with the Vector Linearized Discrete Ordinate Radiative Transfer model (VLIDORT). The simulation is applied to interpret UVAI observations from the Ozone Monitoring Instrument (OMI) for the year 2007. Simulated and observed values are highly consistent in regions where mineral dust dominates the UVAI, but a large negative bias (-0.32 to -0.97) exists between simulated and observed values in biomass burning regions. We determine effective optical properties for absorbing organic aerosol, known as brown carbon (BrC), and implement them into GEOS-Chem to better represent observed UVAI values over biomass burning regions. The inclusion of absorbing BrC decreases the mean bias between simulated and OMI UVAI values from -0.57 to -0.09 over West Africa in January, from -0.32 to +0.0002 over South Asia in April, from -0.97 to -0.22 over southern Africa in July, and from -0.50 to +0.33 over South America in September. The spectral dependence of absorption after including BrC in the model is broadly consistent with reported observations for biomass burning aerosol, with absorbing Angstrom exponent (AAE) values ranging from 2.9 in the ultraviolet (UV) to 1.3 across the UV-Near IR spectrum. We assess the effect of the additional UV absorption by BrC on atmospheric photochemistry by examining tropospheric hydroxyl radical (OH) concentrations in GEOS-Chem. The inclusion of BrC decreases OH by up to 30% over South America in September, up to 20% over southern Africa in July, and up to 15% over other biomass burning regions. Global annual mean OH concentrations in GEOS-Chem decrease due to the presence of absorbing BrC, increasing the methyl chloroform lifetime from 5.62 to 5.68 years, thus reducing the bias against observed values. We calculate the direct radiative effect (DRE) of BrC using GEOS-Chem coupled with the radiative transfer model RRTMG (GC-RT). Treating organic aerosol as containing more strongly absorbing BrC changes the global annual mean all-sky top of atmosphere (TOA) DRE by +0.03Wm(exp -2) and all-sky surface DRE by -0.08Wm(exp -2). Regional changes of up to +0.3Wm(exp -2) at TOA and down to -1.5Wm(exp -2) at the surface are found over major biomass burning regions.

Air Pollution

Basic characteristics of high-frequency Stark-effect modulation of CO2 lasers.

The molecular Stark effect and its application to the modulation of infrared laser radiation have been investigated both theoretically and experimentally. Using a density matrix approach, a quantum mechanical description of the effect of a time-varying electric field on the absorption coefficient and refractive index of a molecular gas near an absorption line has been formulated. For modulation applications a quantity known as the ?modulation depth' is of prime importance. Theoretical expressions for the frequency dependence of the modulation depth show that the response to the frequency of a time-varying Stark field is separated into a nondispersive and a dispersive region, depending on whether the modulating frequency is less than or greater than the homogeneous absorption linewidth. Experimental results showing nondispersive modulation at frequencies to 30 MHz are presented. In addition it is shown that the response of modulation depth to Stark field amplitude is separated into linear and nonlinear regions, the field at which nonlinearities begin being determined by the absorption spectrum of the molecule being used.

Claspy, P. C.

Net Radiative Effects of Dust in the Tropical North Atlantic Based on Integrated Satellite Observations and in Situ Measurements

In this study, we integrate recent in situ measurements with satellite retrievals of dust physical and radiative properties to quantify dust direct radiative effects on shortwave (SW) and longwave (LW) radiation (denoted as DRESW and DRELW, respectively) in the tropical North Atlantic during the summer months from 2007 to 2010. Through linear regression of the CERES-measured top-of atmosphere (TOA) flux versus satellite aerosol optical depth (AOD) retrievals, we estimate the instantaneous DRESW efficiency at the TOA to be -49+/-7.1 W/sq.m AOD(exp -1) and -36+/-4:8W/sq.m AOD(exp -1) based on AOD from MODIS and CALIOP, respectively. We then perform various sensitivity studies based on recent measurements of dust particle size distribution (PSD), refractive index, and particle shape distribution to determine how the dust microphysical and optical properties affect DRE estimates and its agreement with the above-mentioned satellite-derived DREs. Our analysis shows that a good agreement with the observation-based estimates of instantaneous DRESW and DRELW can be achieved through a combination of recently observed PSD with substantial presence of coarse particles, a less absorptive SW refractive index, and spheroid shapes. Based on this optimal combination of dust physical properties we further estimate the diurnal mean dust DRE(sub SW) in the region of -10W/sq.m at TOA and -26W/sq.m at the surface, respectively, of which ~30% is canceled out by the positive DRE(sub LW). This yields a net DRE of about -6:9 and -18.3 W/sq.m at TOA and the surface, respectively. Our study suggests that the LW flux contains useful information on dust particle size, which could be used together with SW observations to achieve a more holistic understanding of the dust radiative effect.

Song, Qianqian