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At least 37 records · Page 2

Utilizing Commercial Submersible Mixer Pumps for Sludge Removal in Savannah River Site's Tank 26 - 20289

The Savannah River Site (SRS) Liquid Waste System (LWS) safely manages, stores, treats, and dispositions liquid radioactive waste. The LWS consists of 51 underground waste storage tanks (eight of which are operationally closed and filled with grout), waste evaporators, treatment facilities, and solidification facilities, known as the Defense Waste Processing Facility (DWPF) and Saltstone Production Facility (SPF). One of the waste storage tanks, Tank 26, was placed into service in 1980 as an F Tank Farm (FTF) Evaporator Feed Tank. From 1980 to 2013, Tank 26 received F Canyon receipts and dilute supernate that was then transferred to the 242-16F FTF Evaporator for volume reduction. In 2013, the steam tube bundle failed in the FTF Evaporator, and the decision was made not to repair/resume evaporator operation. During operation of Tank 26, solids built up to a level of 2.03 m in the tank with a volume of 1062.9 kL. Due to the evaporator failure and subsequent shutdown, the solids in Tank 26 were selected to feed Sludge Batch 10, which is collected and prepped prior to being sent to DWPF for final disposition. To accomplish solids removal, Commercial Submersible Mixer Pumps (CSMPs) were selected to slurry the solids in preparation to be sent to Tank 51. Four CSMPs were installed in Tank 26 with each one installed in a separate quadrant of Tank 26. This work would mark the first deployment of CSMPs in an SRS waste tank. The CSMPs were developed in response to operational issues from previous mixing pumps and budgetary constraints. The CSMPs use the concept of modifying commercially available equipment for nuclear waste applications. The CSMPs consist of a 230-horsepower submersible mixing pump (manufactured by GPM, Inc.) joined to a mast fabricated at SRS. For this application, Savannah River Remediation (SRR) design services was challenged to provide a mast design that required no steel superstructure support system on top of Tank 26. Also, SRR design services provided a simplified Tank 26 riser interface that did not require extensive machine parts to adjust height of the suction screen of the CSMP within the tank. Other design improvements include no requirements for tank top radiation monitors and no requirements for flushing of the CSMPs during startup/shutdown operations. The CSMPs were operated at an initial height of 2.29 m above the Tank 26 bottom for 10 days. After sludge sounding, the CSMPs were lowered to a height of 1.52 m with no issues due to proper work planning and the simplified riser interface. With the CSMPs lowered to a level of 1.52 meters above the tank bottom, the CSMPs were operated for 12 days and another sounding was performed. The sounding level came back matching the disturbance depth results of the first pump run. Chemistry samples were analyzed while the tank was left to settle. The analysis revealed enough weight percent solids to provide good feed to Sludge Batch 10. Also, the results revealed the supernate within the mixture would provide good salt solution feed to Salt Waste Processing Facility (SWPF) Salt Batch 3. So, the plan was modified to let the disturbed solids settle and decant the salt solution for addition to SWPF Salt Batch 3. Then water will be added back to Tank 26, and the CSMPs run in order to wash the solids to decrease settling time prior to being sent to Tank 51 for Sludge Batch 10. Utilizing CSMPs for waste removal in an SRS Tank has provided a cost-effective means for further waste removal efforts. In addition, the CSMPs are easier to operate by utilizing a robust and simplified design. The CSMPs performed quite well with no process shutdown or delays during operation. As a result, CSMPs are integral to the future of removing radioactive waste from storage tanks at SRS. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Coupled uptake and conversion of C 12 H 26 and NO on Pd/SSZ-13: Experiments and modeling

The uptake of NO in the presence of C 12 H 26 (dodecane) and H 2 O over a Pd/SSZ-13 washcoated Passive NOx Adsorber (PNA) monolith is reported. When a co-feed containing C 12 H 26 and NO is supplied to an unsaturated (with C 12 H 26 ) sample, the NO uptake is unaffected but during the subsequent temperature ramp the release of trapped NO is delayed from 175°C to over 220°C. The release delay is beneficial for PNA performance as the primary NO x aftertreatment technology, Selective Catalytic Reduction (SCR), is not operated below 200°C. However, pre-saturation of C 12 H 26 followed by the same NO and C 12 H 26 co-feed results in a decrease in the NO uptake compared to the NO-only feed. We conjecture that C 12 H 26 pre-adsorbed on the exterior surface of the sample blocks NO access to the pores, decreasing the number of available sites for NO uptake. Oxidation of C 12 H 26 leads to the generation of partial oxidation product CO at lower temperatures (<250°C) and deep oxidation product CO 2 at higher temperatures. Carbon monoxide binds strongly to Pd sites with NO and can delay NO release. A Pd/SSZ-13 washcoated monolith model developed in an earlier study [Ambast et al., Appl. Catal. B. Environmental (2021)] is upgraded to include C 12 H 26 storage, release, and conversion. Through a systematic combination of judicious experiments, model tuning, and validation, we provide evidence for the underlying NO uptake and release mechanisms in the presence of C 12 H 26 .

42 ENGINEERING↗

Reevaluation of the 22 Ne(α,γ) 26 Mg and 22 Ne(α,n) 25 Mg reaction rates

The competing 22 Ne(α, γ) 26 Mg and 22 Ne(α,n) 25 Mg reactions control the production of neutrons for the weak s process in massive and asymptotic giant branch (AGB) stars. In both systems, the ratio between the corresponding reaction rates strongly impacts the total neutron budget and strongly influences the final nucleosynthesis. A number of experimental studies have been performed over recent years which necessitate the reevaluation of the 26 Mg and 22 Ne(α, γ) 25 Mg reactions control the production 26 Mg and 22 Ne(α, n) 25 Mg reaction rates. Evaluations of the reaction rates following the collection of new nuclear data presently show differences of up to a factor of 500, resulting in considerable uncertainty in the resulting nucleosynthesis. To reevaluate the 22 Ne(α, γ) 26 Mg and 22 Ne(α,n) 25 Mg reaction rates using updated nuclear data from a number of sources including updating spin and parity assignments. With updated spin and parity assignments, the levels which can contribute to the reaction rates are identified. The reaction rates are computed using a Monte Carlo method which has been used for previous evaluations of the reaction rates in order to focus solely on the changes due to modified nuclear data. The evaluated 22 Ne(α, γ) 26 Mg reaction rate remains substantially similar to that of Longland et al. but, including recent results from Texas A&M, the 22 Ne(α, n) 25 Mg reaction rate is lower at a range of astrophysically important temperatures. Stellar models computed with newton and mesa predict decreased production of the weak branch s process due to the decreased efficiency of 22 Ne as a neutron source. Using the new reaction rates in the mesa model results in 96 Zr / 94 Zr and 135 Ba / 136 Ba ratios in much better agreement with the measured ratios from presolar SiC grains. The 22 Ne + α reaction rates 22 Ne(α, γ) 26 Mg and 22 Ne(α, n) 25 Mg have been recalculated based on more recent nuclear data. The 22 Ne(α, γ) 26 Mg reaction rate remains substantially unchanged since the previous evaluation but the 22 Ne(α, γ) 25 Mg reaction rate is substantially decreased due to updated nuclear data. This results in significant changes to the nucleosynthesis in the weak branch of the s process.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗