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NASA NTRS2006

21st Century Lunar Exploration: Advanced Radiation Exposure Assessment

On January 14, 2004 President George W Bush outlined a new vision for NASA that has humans venturing back to the moon by 2020. With this ambitious goal, new tools and models have been developed to help define and predict the amount of space radiation astronauts will be exposed to during transit and habitation on the moon. A representative scenario is used that includes a trajectory from LEO to a Lunar Base, and simplified CAD models for the transit and habitat structures. For this study galactic cosmic rays, solar proton events, and trapped electron and proton environments are simulated using new dynamic environment models to generate energetic electron, and light and heavy ion fluences. Detailed calculations are presented to assess the human exposure for transit segments and surface stays.

Anderson, Brooke↗

NASA NTRS2009

Droplet-Based Production of Liposomes

A process for making monodisperse liposomes having lipid bilayer membranes involves fewer, simpler process steps than do related prior methods. First, a microfluidic, cross junction droplet generator is used to produce vesicles comprising aqueous solution droplets contained in single layer lipid membranes. The vesicles are collected in a lipid-solvent mix that is at most partially soluble in water and is less dense than is water. A layer of water is dispensed on top of the solvent. By virtue of the difference in densities, the water sinks to the bottom and the solvent floats to the top. The vesicles, which have almost the same density as that of water, become exchanged into the water instead of floating to the top. As there are excess lipids in the solvent solution, in order for the vesicles to remain in the water, the addition of a second lipid layer to each vesicle is energetically favored. The resulting lipid bilayers present the hydrophilic ends of the lipid molecules to both the inner and outer membrane surfaces. If lipids of a second kind are dissolved in the solvent in sufficient excess before use, then asymmetric liposomes may be formed.

Ackley, Donald E.↗

NASA NTRS2010

MESSENGER Observations of Extreme Magnetic Tail Loading and Unloading During its Third Flyby of Mercury: Substorms?

During MESSENGER's third flyby of Mercury on September 29, 2009, a variable interplanetary magnetic field produced a series of several minute enhancements of the tail magnetic field hy factors of approx. 2 to 3.5. The magnetic field flaring during these intervals indicates that they result from loading of the tail with magnetic flux transferred from the dayside magnetosphere. The unloading intervals were associated with plasmoids and traveling compression regions, signatures of tail reconnection. The peak tail magnetic flux during the smallest loading events equaled 30% of the magnetic flux emanating from Mercury, and may have reached 100% for the largest event. In this case the dayside magnetic shielding is reduced and solar wind flux impacting the surface may be greatly enhanced. Despite the intensity of these events and their similarity to terrestrial substorm magnetic flux dynamics, no energetic charged particles with energies greater than 36 keV were observed.

Slavin, James A.↗

NASA NTRS1999

Reactivity of CF(n) (n = 1-3) Radicals with a Silica Surface

The trends in reactivity of CF(n) radicals with SiO2 and the site selectivity of the attack are studied using two different cluster models. The reaction barriers for the most energetically favorable reaction are computed. It is shown that CF(n) radicals are fairly unreactive towards SiO2.

Ricca, Alessandra↗

NASA NTRS1994

Solar influences on global change

Monitoring of the Sun and the Earth has yielded new knowledge essential to this debate. There is now no doubt that the total radiative energy from the Sun that heats the Earth's surface changes over decadal time scales as a consequence of solar activity. Observations indicate as well that changes in ultraviolet radiation and energetic particles from the Sun, also connected with the solar activity, modulate the layer of ozone that protects the biosphere from the solar ultraviolet radiation. This report reassesses solar influences on global change in the light of this new knowledge of solar and atmospheric variability. Moreover, the report considers climate change to be encompassed within the broader concept of global change; thus the biosphere is recognized to be part of a larger, coupled Earth system. Implementing a program to continuously monitor solar irradiance over the next several decades will provide the opportunity to estimate solar influences on global change, assuming continued maintenance of observations of climate and other potential forcing mechanisms. In the lower atmosphere, an increase in solar radiation is expected to cause global warming. In the stratosphere, however, the two effects produce temperature changes of opposite sign. A monitoring program that would augment long term observations of tropospheric parameters with similar observations of stratospheric parameters could separate these diverse climate perturbations and perhaps isolate a greenhouse footprint of climate change. Monitoring global change in the troposphere is a key element of all facets of the United States Global Change Research Program (USGCRP), not just of the study of solar influences on global change. The need for monitoring the stratosphere is also important for global change research in its own right because of the stratospheric ozone layer.

Source record↗

NASA NTRS1999

Solar Radiation and Cloud Radiative Forcing in the Pacific Warm Pool Estimated Using TOGA COARE Measurements

The energy budget of the tropical western Pacific (TWP) is particularly important because this is one of the most energetic convection regions on the Earth. Nearly half of the solar radiation incident at the top of atmosphere is absorbed at the surface and only about 22% absorbed in the atmosphere. A large portion of the excess heat absorbed at the surface is transferred to the atmosphere through evaporation, which provides energy and water for convection and precipitation. The western equatorial Pacific is characterized by the highest sea surface temperature (SST) and heaviest rainfall in the world ocean. A small variation of SST associated with the eastward shift of the warm pool during El-Nino/Souther Oscillation changes the atmospheric circulation pattern and affects the global climate. In a study of the TWP surface heat and momentum fluxes during the Tropical Ocean and Global Atmosphere Coupled Ocean-Atmosphere Response Experiment (TOGA COARE) Intensive observing period (IOP) from November 1992 to February have found that the solar radiation is the most important component of the surface energy budget, which undergoes significant temporal and spatial variation. The variations are influenced by the two 40-50 days Madden Julian Oscillations (MJOs) which propagated eastward from the Indian Ocean to the Central Pacific during the IOP. The TWP surface solar radiation during the COARE IOP was investigated by a number of studies. In addition, the effects of clouds on the solar heating of the atmosphere in the TWP was studied using energy budget analysis. In this study, we present some results of the TWP surface solar shortwave or SW radiation budget and the effect of clouds on the atmospheric solar heating using the surface radiation measurements and Japan's Geostationary Meteorological Satellite 4 radiance measurements during COARE IOP.

Chou, Ming-Dah↗

NASA NTRS1994

Interstellar Ice and Dust: The Feedstock of the Solar System

Studying the chemical and isotopic composition of interstellar ice and dust provides insight into the composition and chemical history of the solid bodies in the solar nebula and the nature of the material subsequently brought into the inner part of the solar system by comets and meteorites. It is now possible to probe the composition of these microscopic interstellar particles (some hundreds of light years away), thanks to substantial progress in two areas: astronomical spectroscopic techniques in the middle-infrared, the spectral region most diagnostic of composition; and laboratory simulations which realistically reproduce the critical conditions in various interstellar environments. High quality infrared spectra of many different astronomical sources, some associated with dark molecular clouds, and others in the diffuse interstellar medium (DISM) are now available. What comparisons of these spectra with laboratory spectra tell us about the complex organic components of these materials is the subject of this talk. Most interstellar material is concentrated in large molecular clouds where simple molecules are formed by gas phase and dust grain surface reactions. Gaseous species (except H2) striking the cold (10K) dust will stick, forming an icy grain mantle. This accretion, coupled with energetic particle bombardment and UV photolysis, will produce a complex chemical mixture containing volatile, non-volatile, and isotopically fractionated species. One can compare spectra of the diffuse and dense interstellar medium with the spectra of analogs produced in the laboratory under conditions which mimic those in these different environments. In this way one can determine the composition and abundances of the major constituents present and place general constraints on the types and relative abundances of organics coating the grains. Ices in dense clouds contain H2O, CH3OH, CO, perhaps some NH3 and H2CO, as well as nitriles and ketones or esters. There is some evidence that the later, more complex species, are also present on the grains in the DISM. The evidence for these materials, in addition to carbon rich materials such as amorphous carbon, microdiamonds, and polycyclic aromatic hydrocarbons will be reviewed and the possible connection with meteoritic organics will be discussed.

Allamandola, L. J.↗

NASA NTRS1995

Astronomical Problems and Laboratory Solutions

Studying the chemical and isotopic composition of interstellar ice and dust provides insight into the composition and chemical history of the solid bodies in the solar nebula and the nature of the material subsequently brought into the inner part of the solar system by comets and meteorites. It is now possible to probe the composition of these microscopic interstellar particles (some hundreds of light years away), thanks to substantial progress in two areas: astronomical spectroscopic techniques in the middle-infrared, the spectral region most diagnostic of composition; and laboratory simulations which realistically reproduce the critical conditions in various interstellar environments. High quality infrared spectra of many different astronomical sources, some associated with dark molecular clouds, and others in the diffuse interstellar medium (DISM) are now available. What comparisons of these spectra with laboratory spectra tell us about the complex organic components of these materials is the subject of this talk. Most interstellar material is concentrated in large molecular clouds where simple molecules are formed by gas phase and dust grain surface reactions. Gaseous species (except H2) striking the cold (10K) dust will stick, forming an icy grain mantle. This accretion, coupled with energetic particle bombardment and UV photolysis, will produce a complex chemical mixture containing volatile, non-volatile, and isotopically fractionated species. One can compare spectra of the diffuse and dense interstellar medium with the spectra of analogs produced in the laboratory under conditions which mimic those in these different environments. In this way one can determine the composition and abundances of the major constituents present and place general constraints on the types and relative abundances of organics coating the grains. Ices in dense clouds contain H2O, CH3OH, CO, perhaps some NH3 and H2CO, as well as nitriles and ketones or esters. there is some evidence that the later, more complex species, are also present on the grains in the DISM. The evidence for these materials, in addition to carbon rich materials such as amorphous carbon, microdiamonds, and polycyclic aromatic hydrocarbons will be reviewed and the possible connection with meteoritic organics will be discussed.

Allamandola, L. J.↗

NASA NTRS1998

Energetics of amino acid synthesis in hydrothermal ecosystems

Thermodynamic calculations showed that the autotrophic synthesis of all 20 protein-forming amino acids was energetically favored in hot (100 degrees C), moderately reduced, submarine hydrothermal solutions relative to the synthesis in cold (18 degrees C), oxidized, surface seawater. The net synthesis reactions of 11 amino acids were exergonic in the hydrothermal solution, but all were endergonic in surface seawater. The synthesis of the requisite amino acids of nine thermophilic and hyperthermophilic proteins in a 100 degreesC hydrothermal solution yielded between 600 and 8000 kilojoules per mole of protein, which is energy that is available to drive the intracellular synthesis of enzymes and other biopolymers in hyperthermophiles thriving in these ecosystems.

NASA Discipline Exobiology↗

NASA NTRS2003

Transmission measurement based on STM observation to detect the penetration depth of low-energy heavy ions in botanic samples

The penetration depth of low-energy heavy ions in botanic samples was detected with a new transmission measurement. In the measurement, highly oriented pyrolytic graphite (HOPG) pieces were placed behind the botanic samples with certain thickness. During the irradiation of heavy ions with energy of tens of keV, the energetic particles transmitted from those samples were received by the HOPG pieces. After irradiation, scanning tunneling microscope (STM) was applied to observe protrusion-like damage induced by these transmitted ions on the surface of the HOPG. The statistical average number density of protrusions and the minimum transmission rate of the low-energy heavy ions can be obtained. The detection efficiency of the new method for low-energy heavy ions was about 0.1-1 and the background in the measurement can be reduced to as low as 1.0 x 10(8) protrusions/cm2. With this method, the penetration depth of the energetic particles was detected to be no less than 60 micrometers in kidney bean slices when the slices were irradiated by 100 keVAr+ ion at the fluence of 5 x 10(16) ions/cm2. c2002 Elsevier Science Ltd. All rights reserved.

DNA Damage↗

NASA NTRS1981

Modification of spacecraft potentials by plasma emission

The ion engine operations on Applied Technology Satellite 6 (ATS-6) altered the charge state of the spacecraft, changing the spacecraft surface potentials with respect to the distant plasmas. Plasma emission in quiet environments (plasma temperatures below 1 keV) caused the spacecraft potential to shift from a few volts positive to a few volts negative. A net ion current is emitted in such cases. The emission of a plasma or beam in energetic environments (plasma temperatures in the 5-10-keV range) in sunlight caused larger changes. Typical equilibrium potentials for ATS-6 in such environments were on the order of a hundred volts negative, with variations in potential across the spacecraft surface of comparable magnitude. Engine operations under such conditions raised the mainframe potential to near zero volts, and discharged the differential potentials on the dielectric surfaces. Plasma emission by the plasma bridge was an effective method of discharging kilovolt potentials in eclipse.

Olsen, R. C.↗

NASA NTRS2023

SelenITA: A Dual Point Lunar Mission to Characterize the Near Surface Dust and Electromagnetic Plasma Environment

SelenITA is a dual CubeSat mission that will provide the first multi-point dust, plasma, and magnetic field measurements in lunar orbit. This mission will advance the understanding of the electromagnetic space environment at the Moon in support of the Artemis program, exploration, and the geosciences. Here we present the science rationale motivating the mission. The candidate mission science objectives include: (1) constrain the origins of crustal magnetic fields; (2) determine the nature of plasma interactions with crustal magnetic fields; (3) characterize plasma waves and turbulence at the Moon; (4) characterize the lunar surface electric potential in varying plasma environments; (5) constrain the composition, thermal state, and structure of the lunar upper mantle and crust; (6) characterize the ionizing radiation in lunar orbit; and lastly, (7) determine the density of the dust exosphere as a function of latitude, longitude, and altitude, including the lunar polar space environment. The measurement requirements include simultaneous two-point observations of the 3-component vector magnetic field, plasma distribution (flux, energy, density, temperature), and single-point observations of energetic particles (protons, electrons, gamma rays), and dust. These measurements are important because it helps us understand how future astronauts, robots, and space hardware will live and work on the lunar surface.

space weather↗

NASA NTRS2023

SelenITA: A Dual Point Lunar Mission to Characterize the Near Surface Dust and Electromagnetic Plasma Environment

space weather↗

NASA NTRS1989

Laboratory simulations of energetic atom interactions occurring in low earth orbit

The Space Shuttle flights provided the first significant data base on the environment experienced by a large space structure operating in LEO. A number of interesting and unanticipated effects were observed, including material erosion induced by ambient oxygen atoms, the visible Shuttle glow occurring above surfaces exposed to the ram flow, and large near-field perturbations and variability in the gaseous neutral and plasma environment about the Shuttle. This paper provides a brief overview of these observations and their phenomenological interpretation, and then discusses laboratory approaches to their investigation. The emphasis is on the state of the art in the development of energetic oxygen atoms sources and the variety of experiments presently being performed with such devices.

Caledonia, G. E.↗

NASA NTRS2002

Measurements of Optically Transparent and Mirrored Specimens from the POSA and EOIM III Space Flight Experiments

A selected set of optically transparent specimens and first surface mirror specimens have been examined subsequent to on-orbit exposure. Certain specimens were from the Passive Optical Sample Assembly I and II experiments flown on the MIR Space Station. Other specimens were from the Energetic Oxygen Interaction with materials III experiment flown on the STS in August 1992. A comparison of pre- and post-flight transmission of reflectance measurements, as appropriate, has been carried out. Data from different specimens includes results of measurements for IR, optical, UV and/or vacuum UV wavelength intervals. Results of these measurements clearly show the effects of molecular contamination deposits on the surfaces during the on-orbit exposures. Surface analysis on a attracted set of specimens provides and estimate of contaminant thickness and composition and provides an insight into on-orbit deposition rates and surface oxidation reactions. For both the EOIM III and POSA I & II experiments, the primary source of contamination were outgassed silicones. Both experiments received approximately the same fluence of atomic oxygen (approx. 1-2 x 1020 atoms per square centimeter). ROSA specimens received between approx. 400 and 580 equivalent sun hours (ESH) of solar radiation over an 18 month period in orbit. The EOIM specimens were on an STS flight of about 1 week duration and received only approx. 5-10 ESH of solar radiation.

Pippin, Gary↗

NASA NTRS2010

Plasma IMS Composition Measurements for Europa and the Other Galilean Moons

NASA and ESA are planning the joint Europa Jupiter System Mission (EJSM) to the Jupiter system with specific emphasis to Europa and Ganymede, respectively. The Japanese Space Agency is also planning an orbiter mission to explore Jupiter's magnetosphere and the Galilean satellites. For NASA's Jupiter Europa Orbiter (JEO) we are developing the 3D Ion Mass Spectrometer (IMS) with two main goals which can also be applied to the other Galilean moons, 1) measure the plasma interaction between Europa and Jupiter's magnetosphere and 2) infer the 4 pi surface composition to trace elemental and significant isotopic levels. The first goal supports the magnetometer (MAG) measurements, primarily directed at detection of Europa's sub-surface ocean, while the second gives information about transfer of material between the Galilean moons, and between the moon surfaces and subsurface layers putatively including oceans. The measurement of the interactions for all the Galilean moons can be used to trace the in situ ion measurements of pickup ions back to either Europa's or Ganymede's surface from the respectively orbiting spacecraft. The IMS instrument, being developed under NASA's Astrobiology Instrument Development Program, would maximally achieve plasma measurement requirements for JEO and EJSM while moving forward our knowledge of Jupiter system composition and source processes to far higher levels than previously envisaged. The composition of the global surfaces of Europa and Ganymede can be inferred from the measurement of ejected neutrals and pick-up ions using at minimum an in situ payload including MAG and IMS also fully capable of meeting Level 1 mission requirements for ocean detection and survey. Elemental and isotopic analysis of potentially extruded oceanic materials at the moon surfaces would further support the ocean objectives. These measurements should be made from a polar orbiting spacecraft about Europa or Ganymede at height 100 km. The ejecta produced by sputtering of the surfaces of Europa and Ganymede has been shown to be representative of the surface composition. Level 2 science on surface geology and composition can then be further enhanced by addition of the following: 3D Ion Neutral Mass Spectrometer (INNS), 3D plasma electron spectrometer (ELS), and hot plasma energetic particle instrument. The measurement approach is to alternate between times measuring pickup ions and times measuring plasma and magnetic field parameters along the spacecraft trajectory. By measuring the pickup ion energy, arrival direction and mass-per-charge, the ion can be traced back along the ejection trajectory to the approximate area of origin if the 3-D electric field and magnetic field are known. In situ observations of plasma flow velocities and vector magnetic fields can be used to determine the local convective electric field (E = -VXB) along the spacecraft trajectory. By combining this information with models of the magnetospheric interaction with Europa, one can generate 3D maps of the electric and magnetic field and compute the trajectories of the pickup ions back to the surface or exospheric points of origin. In the case of Ganymede there is the additional complexity of its own internal dipole magnetic field, while Io's volcanic activity introduces the complexity of a highly structured denser atmosphere. Callisto with its less globally extended exosphere will have a simpler interaction than for Europa (i.e., more like our moon). We will discuss these differences in light of the above proposed technique. Finally, the INNS observations and neutral exosphere models are needed to estimate production rates of pickup ions. The hot plasma measurements are needed to correct for sputtering rates which can be time dependent and electron plasma observations for electron impact ionization rates. Instrument characteristics, field-of-view requirements, modes of operation and effects of radiation on instrument functionality will be discussed.

Sittler, Edward↗

NASA NTRS1988

Effects of global atmospheric perturbations on forest ecosystems: Predictions of seasonal and cumulative effects

The physical effects of certain large events, such as giant impacts, explosive volcanism, or combined nuclear explosions, have the potential of inducing global catastrophes in our terrestrial environment. Such highly energetic events can inject substantial quantities of material into the atmosphere. In turn, this changes the amount of sunlight reaching the Earth's surface and modifies atmospheric temperatures to produce a wide range of global effects. One consequence is the introduction of serious stresses in both plants and animals throughout the Earth's biosphere. For example, recent studies predict that forest lands, crop lands, and range lands would suffer specific physical and biological degradations if major physical and chemical disruptions occurred in our atmosphere. Forests, which cover over 4 times 10 to the 9th power hectares (4 times 10 to the 7th power sq km) of our planet, or about 3 times the area now cultivated for crops, are critical to many processes in the biosphere. Forests contribute heavily to the production of atmospheric oxygen, supply the major volume of biomass, and provide a significant percentage of plant and animal habitats.

Tinus, R. W.↗

NASA NTRS1994

Infrared astronomy from the Moon

The purpose of this paper is to exhibit the advantages and limitations to infrared astronomical observations form the moon. The most obvious apparent advantage is the lack of a lunar atmosphere; radiation arriving from the universe is neither extinguished nor refracted as it approaches the lunar surface. However, the Earth's atmosphere's protection against cosmic rays is also lost, and infrared detectors are highly sensitive to irradiation by energetic particles. A second apparent advantage is the relative ease with which beams from an array of telescopes can be interferometrically combined; again the vacuum environment with constant refractive index of unity throughout, permits combination without phase delay across the entire spectral range. But thermal radiation from optical components and stray radiation from the lunar environment, just outside the light path, tend to lessen that advantage, except in narrow-spectral-band spatial interferometry, in which only the radiation in individual spectral lines is mapped, and broad-band thermal emission can be effectively filtered out. On the Moon's night side, and in polar craters on the Moon, radiative cooling should permit the attainment of high sensitivity with large telescopes. Just as the proposed Edison spacecraft primary mirror is expected to reach temperatures around 40 K, so also large lunar primary mirrors might be expected to reach temperatures in that range, making the zodiacal glow the main source of noise at wavelengths shortward of 25 micrometers. The slow rota tion of the Moon, and the lack of vibrations from natural sources such as winds, should provide advantages in guiding on specific astronomical sources. To learn as much as possible about the difficulties of remote observations in a hostile environment, Antarctic observatories should be used as test beds for the rigors of lunar observations. The strenuous requirements for successful astronomical observations from the South Pole are similar to those expected to be encountered in observations conducted from the Moon.

Harwit, Martin↗