Rare earth fluorides and oxides - An exploratory study of their use as solid lubricants at temperatures to 1800 deg F /1000 deg C/
Rare earth fluorides and oxides used as solid lubricants at high temperatures
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Rare earth fluorides and oxides used as solid lubricants at high temperatures
A hypothesis that vaporization of a large amount of volatiles such as H2O and CO2 in the Martian surface by the impact of a large object could have accelerated solid ejecta to earth is examined. A hydrodynamic model is used to approximate a hemispherical gas cloud expanding into an atmosphere and entraining solid ejecta. Account is taken of the target material, the impactor materials, mass vaporized, impact velocity, drag coefficient, and crater sizes. A Martian crater larger than 30 km diam is found to be a necessary remnant of any impact that could have produced the shergottites, nakhlites and Chassigny meteorites which have been found on earth and possess similarities to analyzed Martian rocks.
Solid state circuit classifies satellite imagery by spectral signature of vegetation, bare land, water, clouds, or snow. Circuit can be used to sort and separate specific imagery by signature so that only useful data is transmitted to earth. Device saves time and costs involved in manual separation of data.
Part VI of the evolutionary system of mineralogy catalogs 262 kinds of minerals, formed by 18 different processes, that we suggest represent the earliest solid phases in Earth’s crust. All of these minerals likely formed during the first tens of millions of years following the global-scale disruption of the Moon-forming impact prior to ~4.4 Ga, though no samples of terrestrial minerals older than ~4.37 Ga are known to have survived on Earth today. Our catalog of the earliest Hadean species includes 80 primary phases associated with ultramafic and mafic igneous rocks, as well as more than 80 minerals deposited from immiscible S-rich fluids and late-stage Si-rich residual melts. Earth’s earliest crustal minerals also included more than 200 secondary phases of these primary minerals that were generated by thermal metamorphism, aqueous alteration, impacts, and other processes. In particular, secondary mineralization related to pervasive near-surface aqueous fluids may have included serpentinization of mafic and ultramafic rocks, hot springs and submarine volcanic vent mineralization, hydrothermal sulfide deposits, zeolite and associated mineral formation in basaltic cavities, marine authigenesis, and hydration of subaerial lithologies. Additional Hadean minerals may have formed by thermal metamorphism of lava xenoliths, sublimation at volcanic fumaroles, impact processes, and volcanic lightning. These minerals would have occurred along with more than 180 additional phases found in the variety of meteorites that continuously fell to Earth’s surface during the early Hadean Eon.
Space radiation environments for historically large solar particle events (SPE) and galactic cosmic rays (GCR) at solar minimum and solar maximum are simulated in order to characterize exposures to radio-sensitive organs for missions to low-Earth orbit (LEO), moon, and Mars. Primary and secondary particles for SPE and GCR are transported through the respective atmosphere of Earth or Mars, space vehicle, and astronaut s body tissues using the HZETRN/QMSFRG computer code. In LEO, exposures are reduced compared to deep space because particles are deflected by the Earth s magnetic field and absorbed by the solid body of the Earth. Geomagnetic transmission function as a function of altitude was applied for the particle flux of charged particles, and the shift or the organ exposures to higher velocity or lower stopping powers compared to those in deep space were analyzed. In the transport through Mars atmosphere, a vertical distribution of atmospheric thickness was calculated from the temperature and pressure data of Mars Global Surveyor, and the directional cosine distribution was implemented to describe the spherically distributed atmospheric distance along the slant path at each altitude. The resultant directional shielding by Mars atmosphere at solar minimum and solar maximum was used for the particle flux simulation at various altitudes on the Martian surface. Finally, atmospheric shielding was coupled with vehicle and body shielding for organ dose estimates. We made predictions of radiation dose equivalents and evaluated acute symptoms at LEO, moon, and Mars at solar minimum and solar maximum.
The nature of the interior of the primitive Earth was examined. The question is posted: was the Earth a cold solid or was it a hot liquid, much like a lava lakes seen in today's volcanic cauldrons. The various energy sources available to heat the primitive Earth to see if they are sufficient to cause melting were analyzed. The two largest contributors to the Earth's early heat appear to be the heat due to accretion and the heat of core formation. The Earth formed by the accretion of particles ranging in size from millimeters to hundreds of kilometers and each impact into the protoearth provided more energy to heat the body. It is found that early in the Earth's history, the sinking of iron to the center of the Earth to form the core released a substantial amount of energy; enough to heat the entire Earth an average 2000 deg C. Mechanisms for the removal of such a large amount of heat appear inadequate to prevent substantial melting, and it is assumed that the Earth was completely molten, i.e., a magma ocean at one time early in its history.
We review the current state of knowledge of the origin and early evolution of the three largest terrestrial planets - Venus, Earth, and Mars - setting the stage for the chapters on comparative climatological processes to follow. We summarize current models of planetary formation, as revealed by studies of solid materials from Earth and meteorites from Mars. For Venus, we emphasize the known differences and similarities in planetary bulk properties and composition with Earth and Mars, focusing on key properties indicative of planetary formation and early evolution, particularly of the atmospheres of all three planets. We review the need for future in situ measurements for improving our understanding of the origin and evolution of the atmospheres of our planetary neighbors and Earth, and suggest the accuracies required of such new in situ data. Finally, we discuss the role new measurements of Mars and Venus have in understanding the state and evolution of planets found in the habitable zones of other stars.
At 26Tb/day return average, NISAR (National Aero- nautics and Space Administration (NASA) and the In- dian Space Research Organization (ISRO) Synthetic Aperture Radar) will stress ground station facilities with a variable cadence of data generation observing nearly all of earth's land and ice to produce global time- series maps of cryospheric, solid-Earth and ecosystem phenomena. Between the instrument data generation source and downlink sink lies the primary science data bu er, the SSR (Solid State Recorder). The SSR has deferred, discrete le deletion events that occur only after a le is played back to all required ground segments (sometimes both NASA and ISRO). A forward dispatch, advancing frontier repropagation playback scheduler is proposed as a model of the SSR's greedy playback scheduling behavior. Schedules based on the existing low delity model and new intermediate delity model are compared to assess the impact of deferred, discrete deletion on planning. The low delity model is found to produce unfeasible schedules that exceed SSR capacity, causing 3.87% of all observations in a 12 day simulation to be removed by repair actions.
The present paper identifies the systems engineering aspects of applying solid-state technology to earth observations applications being traditionally performed by point (or multiple-point) detector line scanned mechanisms. It is shown that the translation from a basically serial data flow point-detector mechanically-scanned sensor to a solid state highly parallel linear-array pushbroom sensor results in minimizing mechanical complexity and maximizing electronics complexity, with increased demands upon optical performance in some applications. Technical aspects relevant to highly parallel photodiode linear-array pushbroom applications are discussed. Examples of systems engineering applications are provided.
The work done under NASA grant NAG5-485 included modelling the deformation of the earth caused by variations in atmospheric pressure. The amount of deformation near coasts is sensitive to the nature of the oceanic response to the pressure. The PSMSL (Permanent Service for Mean Sea Level) data suggest the response is inverted barometer at periods greater than a couple months. Green's functions were constructed to describe the perturbation of the geoid caused by atmospheric and oceanic loading and by the accompanying load-induced deformation. It was found that perturbation of up to 2 cm are possible. Ice mass balance data was used for continental glaciers to look at the glacial contributions to time-dependent changes in polar motion, the lod, the earth's gravitational field, the position of the earth's center-of-mass, and global sea level. It was found that there can be lateral, non-hydrostatic structure inside the fluid core caused by gravitational forcing from the mantle, from the inner core, or from topography at the core/mantle or inner core/outer core boundaries. The nutational and tidal response of a non-hydrostatic earth with a solid inner core was modeled. Monthly, global tide gauge data from PSMSL was used to look at the 18.6-year ocean tide, the 14-month pole tide, the oceanic response to pressure, the linear trend and inter-annual variability in the earth's gravity field, the global sea level rise, and the effects of post glacial rebound. The effects of mantle anelasticity on nutations, earth tides, and tidal variation in the lod was modeled. Results of this model can be used with Crustal Dynamics observations to look at the anelastic dissipation and dispersion at tidal periods. The effects of surface topography on various components of crustal deformation was also modeled, and numerical models were developed of post glacial rebound.
To estimate the earth's radiation budget at the top of the atmosphere (TOA) from satellite-measured radiances, it is necessary to account for the finite geometry of the earth and recognize that the earth is a solid body surrounded by a translucent atmosphere of finite thickness that attenuates solar radiation differently at different heights. As a result, in order to account for all of the reflected solar and emitted thermal radiation from the planet by direct integration of satellite-measured radiances, the measurement viewing geometry must be defined at a reference level well above the earth s surface (e.g., 100 km). This ensures that all radiation contributions, including radiation escaping the planet along slant paths above the earth s tangent point, are accounted for. By using a field-of- view (FOV) reference level that is too low (such as the surface reference level), TOA fluxes for most scene types are systematically underestimated by 1-2 W/sq m. In addition, since TOA flux represents a flow of radiant energy per unit area, and varies with distance from the earth according to the inverse-square law, a reference level is also needed to define satellite-based TOA fluxes. From theoretical radiative transfer calculations using a model that accounts for spherical geometry, the optimal reference level for defining TOA fluxes in radiation budget studies for the earth is estimated to be approximately 20 km. At this reference level, there is no need to explicitly account for horizontal transmission of solar radiation through the atmosphere in the earth radiation budget calculation. In this context, therefore, the 20-km reference level corresponds to the effective radiative top of atmosphere for the planet. Although the optimal flux reference level depends slightly on scene type due to differences in effective transmission of solar radiation with cloud height, the difference in flux caused by neglecting the scene-type dependence is less than 0.1%. If an inappropriate TOA flux reference level is used to define satellite TOA fluxes, and horizontal transmission of solar radiation through the planet is not accounted for in the radiation budget equation, systematic errors in net flux of up to 8 W/sq m can result. Since climate models generally use a plane-parallel model approximation to estimate TOA fluxes and the earth radiation budget, they implicitly assume zero horizontal transmission of solar radiation in the radiation budget equation, and do not need to specify a flux reference level. By defining satellite-based TOA flux estimates at a 20-km flux reference level, comparisons with plane-parallel climate model calculations are simplified since there is no need to explicitly correct plane-parallel climate model fluxes for horizontal transmission of solar radiation through a finite earth.
The optical spectra of rare earth ions in solids arise primarily from electric and magnetic dipole transitions between stark split multiplets of the 4f(sup N) electronic configuration. Electric dipole transitions are parity forbidden between levels of the 4f(sup N) configuration, while those of magnetic dipole origin are allowed. It is known from experiment, however, that the significant contributions to the intensities of most transitions are electric dipole in nature. Judd and Ofelt developed the theory of forced electric dipole transitions of rare-earth ions. This study is devoted to determining electric dipole transition probabilities and branching ratios for Tm(3+) and Ho(3+) ions in Yttrium Aluminum Garnet (YAG) and Yttrium Lithium Fluoride (YLF) using the theory of Judd and Ofelt. The radiative rates determined from the Judd-Ofelt analysis are used with measured lifetimes to find nonradiative rates of relaxation.
By exchanging angular momentum with the solid portion of the earth, the atmosphere plays a vital role in exciting small but measurable changes in the rotation of our planet. Recognizing this relationship, the International Earth Rotation Service invited the U.S. National Meteorological Center to organize a Sub-bureau for Atmospheric Angular Momentum (SBAAM) for the purpose of collecting, distributing, archiving, and analyzing atmospheric parameters relevant to earth rotation/polar motion. These functions of wind and surface pressure are being computed with data from several of the world's weather services, and they are being widely applied to the research and operations of the geodetic community. The SBAAM began operating formally in October 1989, and this article highlights its development, operations, and significance.
Thermophotovoltaic (TPV) systems are attractive possibilities for direct thermal-to-electric energy conversion, but have typically required the use of black body radiators operating at high temperatures. Recent advances in both the understanding and performance of solid rare-earth oxide selective emitters make possible the use of TPV at temperatures as low as 1500 K. Depending on the nature of parasitic losses, overall thermal-to-electric conversion efficiencies greater than 20 percent are feasible.
Thermophotovoltaic (TPV) systems are attractive possibilities for direct thermal-to-electric energy conversion, but have typically required the use of black body radiators operating at high temperatures. Recent advances in both the understanding and performance of solid rare-earth oxide selective emitters make possible the use of TPV at temperatures as low as 1200K. Both selective emitter and filter system TPV systems are feasible. However, requirements on the filter system are severe in order to attain high efficiency. A thin-film of a rare-earth oxide is one method for producing an efficient, rugged selective emitter. An efficiency of 0.14 and power density of 9.2 W/KG at 1200K is calculated for a hypothetical thin-film neodymia (Nd2O3) selective emitter TPV system that uses radioisotope decay as the thermal energy source.
The application of solid-state detector array imaging to the remote sensing of the earth as a follow-on to currently planned Landsat missions provides the opportunity to achieve significantly increased performance. First-order advantages to be anticipated are higher sensitivity resulting in greater radiometric accuracies and improved geometric fidelity. The Multispectral Mapper design concept is responsive to a broad range of user needs by incorporating in-flight selection of spectral bands, instantaneous fields of view, and swath width. This versatility is achieved by the use of an imaging spectrometer which permits both spatial and spectral sampling in the image plane using area array detectors. Other improvements over the current Landsat multispectral scanner and Thematic Mapper include higher spatial resolution and inherently precise registration of the spectral bands. The key technologies required in order to realize these improvements include short-wavelength infrared detectors, wide field of view, broad spectral coverage optics, focal plane cooling, and high-speed onboard signal processing. Significant development activities will be required if an advanced remote sensing capability is to be implemented.
Galileo's Solid-State Imaging (SSI) experiment acquired about 800 images of the Moon from the second Earth-Moon flyby (EM2) in December of 1992. Ten major sequences were acquired; each consists of mosaics of the entire or nearly entire visible and illuminated surface from each viewing geometry in at least six spectral filters (effective wavelengths for the Moon of 420, 564, 660, 756, 890, and 990 nm). The geometries of LUNMOS numbers 3, 4, 5, and 6 were designed to provide stereo data at the best possible resolutions. The purpose of this abstract is to describe the sequences, calibration, processing, and mosaicking, and to present a set of color products in a poster session.
Important confirmations that the Earth's inner core is solid have recently come from analyses of records of free Earth oscillations and from the apparent detection of the seismic phase PKJKP. Corresponding support is given to the theory which supplied the primary evidence for rigidity in the inner core. This theory requires the incompressibility and its gradient with respect to the pressure p to vary fairly smoothly with p inside planets, and supplies a potent restriction on the allowable variations of particular physical properties inside parts of planetary interiors. The theory is at present principally applicable to the Earth and Venus. The paper reviews some of the principal implications.