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NASA NTRS1987

Chemical effects in ion mixing of a ternary system (metal-SiO2)

The mixing of Ti, Cr, and Ni thin films with SiO2 by low-temperature (- 196-25 C) irradiation with 290 keV Xe has been investigated. Comparison of the morphology of the intermixed region and the dose dependences of net metal transport into SiO2 reveals that long range motion and phase formation probably occur as separate and sequential processes. Kinetic limitations suppress chemical effects in these systems during the initial transport process. Chemical interactions influence the subsequent phase formation.

Banwell, T.↗

NASA NTRS1988

Processing Welding Images For Robot Control

Image data from two distinct windows used to locate weld features. Analyzer part of vision system described in companion article, "Image Control in Automatic Welding Vision System" (MFS-26035). Horizontal video lines define windows for viewing unwelded joint and weld pool. Data from picture elements outside windows not processed. Widely-separated local features carry no significance, but closely spaced features indicate welding feature. Image processor assigns confidence level to group of local features according to spacing and pattern.

Richardson, Richard W.↗

NASA NTRS1987

Use of hydrophilic polymer coatings for control of electroosmosis and protein adsorption

The purpose of this project was to examine the utility of polyethylene glycol (PEG) and dextran coatings for control of electroosmosis and protein adsorption; electroosmosis is an important, deleterious process affecting electrophoretic separations, and protein adsorption is a factor which needs to be controlled during protein crystal growth to avoid multiple nucleation sites. Performance of the project required use of X-ray photoelectron spectroscopy to refine previously developed synthetic methods. The results of this spectroscopic examination are reported. Measurements of electroosmotic mobility of charged particles in appropriately coated capillaries reveals that a new, one-step route to coating capillaries gives a surface in which electroosmosis is dramatically reduced. Similarly, both PEG and dextran coatings were shown by protein adsorption measurements to be highly effective at reducing protein adsorption on solid surfaces. These results should have impact on future low-g electrophoretic and protein crystal growth experiments.

Harris, J. Milton↗

NASA NTRS1992

Nonlinear Maneuver Autopilot

Trajectory-control laws based on singular-perturbation theory and nonlinear dynamical modeling. Nonlinear maneuver autopilot commands flight-test trajectories of F-15 airplane. Underlying theory of controller enables separation of variables processed in fast and slow control loops, reducing amount of computation required.

Menon, P. K. A.↗

NASA NTRS1992

Controlling nucleation in protein solutions

A simple one-step technique for controlling the nucleation stage in protein solutions without the use of a seed crystal was developed using a specially designed apparatus in which the nucleation and growth processes can be separated. The method can be applied only to species that have a temperature-dependent solubility. The effectiveness of this 'thermonucleating' device was demonstrated with the nucleation and growth of ice, Rochelle salt, and lysozyme.

Demattei, R. C.↗

NASA NTRS1991

Mesoscale characteristics of a monsoon rainband

A Doppler-radar-based case study of a monsoonal rainband (MRB) observed on the evening of January 12, 1990 near Darwin, Austrialia, is presented. Convective and mesoscale circulation features of this system are elucidated. The structure of the MRB is similar to the conceptual model of Houze (1989). The convergence profiles observed in the stratiform region differed considerably from the classical Houze model. Divergence and not convergence existed at heights of 3-6 km. It is suggested that in the MRB stratiform region, consistent with the observed rearward advection of decaying convective cells, the observed mesoscale updraft/downdraft configuration is a result of decaying convection and not a separately evolving mesoscale process.

Keenan, T. D.↗

NASA NTRS1993

Comment on 'Summary and implications of reported amino acid concentrations in the Murchison meteorite' by E. L. Shock and M. D. Schulte

A criticism of the claim by Shock and Schulte (1990) that there is a correlation between the amino acid abundances (relative to glycine) in the Murchison meteorite and their aqueous solubilities is presented. Their suggestion that 'the same factors which control the aqueous solubility of many amino acids also control their relative abundances in the Murchison meteorite is argued to be incorrect. It is proposed that even though the water/meteorite ratio would have been less during meteorite aqueous alteration than that in the 100-C laboratory extraction procedure, amino acids are simply too soluble. The distribution of other meteorite organic components such as PAHs may have been affected by alteration because they are only slightly soluble in water and can be easily separated by geochromatographic processes. In their reply Shock and Schulte contend that the critics argue against a point not made in their paper and that their argument was supported with several unsubstantiated assertions, including an unfounded claim that the temperature dependence of amino acid solubilities are 'not greatly different', a misrepresentation of isopiestic studies on concentration solutions as equilibrium solubility measurements.

Miller, Stanley L.↗

NASA NTRS1994

Observations of cloud liquid water path over oceans: Optical and microwave remote sensing methods

Published estimates of cloud liquid water path (LWP) from satellite-measured microwave radiation show little agreement, even about the relative magnitudes of LWP in the tropics and midlatitudes. To understand these differences and to obtain more reliable estimate, optical and microwave LWP retrieval methods are compared using the International Satellite Cloud Climatology Project (ISCCP) and special sensor microwave/imager (SSM/I) data. Errors in microwave LWP retrieval associated with uncertainties in surface, atmosphere, and cloud properties are assessed. Sea surface temperature may not produce great LWP errors, if accurate contemporaneous measurements are used in the retrieval. An uncertainty of estimated near-surface wind speed as high as 2 m/s produces uncertainty in LWP of about 5 mg/sq cm. Cloud liquid water temperature has only a small effect on LWP retrievals (rms errors less than 2 mg/sq cm), if errors in the temperature are less than 5 C; however, such errors can produce spurious variations of LWP with latitude and season. Errors in atmospheric column water vapor (CWV) are strongly coupled with errors in LWP (for some retrieval methods) causing errors as large as 30 mg/sq cm. Because microwave radiation is much less sensitive to clouds with small LWP (less than 7 mg/sq cm) than visible wavelength radiation, the microwave results are very sensitive to the process used to separate clear and cloudy conditions. Different cloud detection sensitivities in different microwave retrieval methods bias estimated LWP values. Comparing ISCCP and SSM/I LWPs, we find that the two estimated values are consistent in global, zonal, and regional means for warm, nonprecipitating clouds, which have average LWP values of about 5 mg/sq cm and occur much more frequently than precipitating clouds. Ice water path (IWP) can be roughly estimated from the differences between ISCCP total water path and SSM/I LWP for cold, nonprecipitating clouds. IWP in the winter hemisphere is about 3 times the LWP but only half the LWP in the summer hemisphere. Precipitating clouds contribute significantly to monthly, zonal mean LWP values determined from microwave, especially in the intertropical convergence zone (ITCZ), because they have almost 10 times the liquid water (cloud plus precipitation) of nonprecipitating clouds on average. There are significant differences among microwave LWP estimates associated with the treatment of precipitating clouds.

Lin, Bing↗

NASA NTRS1994

Monte Carlo simulation of the terrestrial hydrogen exosphere

Methods for Monte Carlo simulation of planetary exospheres have evolved from early work on the lunar atmosphere, where the regolith surface provides a well defined exobase. A major limitation of the successor simulations of the exospheres of Earth and Venus is the use of an exobase surface as an artifice to separate the collisional processes of the thermosphere from a collisionles exosphere. In this paper a new generalized approach to exosphere simulation is described, wherein the exobase is replaced by a barometric depletion of the major constitents of the thermosphere. Exospheric atoms in the thermosphere-exosphere transition region, and in the outer exosphere as well, travel in ballistic trajectories that are interrupted by collisons with the background gas, and by charge exchange interactions with ionospheric particles. The modified simulator has been applied to the terrestrial hydrogen exosphere problem, using velocity dependent differential cross sections to provide statistically correct collisional scattering in H-O and H-H(+) interactions. Global models are presented for both solstice and equinox over the effective solar cycle range of the F(sub 10.7) index (80 to 230). Simulation results show significant differences with previous terrestrial exosphere models, as well as with the H distributions of the MSIS-86 thermosphere model.

Hodges, R. Richard, Jr.↗

NASA NTRS1992

Dynamic Optimization

We distinguish static and dynamic optimization of programs: whereas static optimization modifies a program before runtime and is based only on its syntactical structure, dynamic optimization is based on the statistical properties of the input source and examples of program execution. Explanation-based generalization is a commonly used dynamic optimization method, but its effectiveness as a speedup-learning method is limited, in part because it fails to separate the learning process from the program transformation process. This paper describes a dynamic optimization technique called a learn-optimize cycle that first uses a learning element to uncover predictable patterns in the program execution and then uses an optimization algorithm to map these patterns into beneficial transformations. The technique has been used successfully for dynamic optimization of pure Prolog.

Laird, Philip↗

NASA NTRS1998

Synergistic Airframe-Propulsion Interactions and Integrations: A White Paper Prepared by the 1996-1997 Langley Aeronautics Technical Committee

This white paper addresses the subject of Synergistic Airframe-Propulsion interactions and integrations (SnAPII). The benefits of SnAPII have not been as extensively explored. This is due primarily to the separateness of design process for airframes and propulsion systems, with only unfavorable interactions addressed. The question 'How to design these two systems in such a way that the airframe needs the propulsion and the propulsion needs the airframe?' is the fundamental issue addressed in this paper. Successful solutions to this issue depend on appropriate technology ideas. This paper first details some ten technologies that have yet to make it to commercial products (with limited exceptions) and that could be utilized in a synergistic manner. Then these technologies, either alone or in combination, are applied to both a conventional twin-engine transonic transport and to an unconventional transport, the Blended Wing Body. Lastly, combinations of these technologies are applied to configuration concepts to assess the possibilities of success relative to five of the ten NASA aeronautics goals. These assessments are subjective, but they point the way in which the applied technologies could work together for some break-through benefits.

Yaros, Steven F.↗

NASA NTRS2002

Design and Stress Analysis of Low-Noise Adjusted Bearing Contact Spiral Bevel Gears

An integrated computerized approach for design and stress analysis of low-noise spiral bevel gear drives with adjusted bearing contact has been developed. The computation procedure is an iterative process, requiring four separate steps that provide: (a) a parabolic function of transmission errors that is able to reduce the effect of errors of alignment, and (b) reduction of the shift of bearing contact caused by misalignment. Application of finite element analysis permits the contact and bending stresses to be determined and investigate the formation of the bearing contact. The design of finite element models and boundary conditions is automated and does not require an intermediate CAD computer program. A commercially available finite element analysis computer program with contact capability was used to conduct the stress analysis. The theory developed is illustrated with numerical examples.

Litvin, Faydor L.↗

NASA NTRS2002

Disentangling X-Ray Emission Processes In Vela-Like Pulsars

This grant is to support analysis of data from the X-ray Multi-mirror Mission (XMM). Specifically, we have been awarded time to observe two young neutron stars, B1823-13 and B1046-58, whose X-ray emission is expected to be a complicated combination of emission from an associated supernova remnant, from a wind-powered synchrotron nebula, from magnetospheric pulsations, and from the surface of the neutron star itself. It is only with XMM's unique combination of spectral, temporal and angular resolution that all these different processes can be separated and studied. Observations of B1823-13 have been conducted and analyzed. We interpret the data as follows: The unpulsed extended non-thermal nature of the central core argues that the extended source of emission corresponds to synchrotron emission from a nebula powered by the pulsar. The temperature of the diffuse component is too high to be interpreted as thermal emission; we rather argue that this extended component is non-thermal emission from a surrounding supernova remnant shell.

Gaensler, Bryan↗

NASA NTRS2003

An Efficient and Robust Singular Value Method for Star Pattern Recognition and Attitude Determination

A new star pattern recognition method is developed using singular value decomposition of a measured unit column vector matrix in a measurement frame and the corresponding cataloged vector matrix in a reference frame. It is shown that singular values and right singular vectors are invariant with respect to coordinate transformation and robust under uncertainty. One advantage of singular value comparison is that a pairing process for individual measured and cataloged stars is not necessary, and the attitude estimation and pattern recognition process are not separated. An associated method for mission catalog design is introduced and simulation results are presented.

Juang, Jer-Nan↗

NASA NTRS2003

Multiyear Simulations of the Martian Water Cycle with the Ames General Circulation Model

Mars atmosphere is carbon dioxide dominated with non-negligible amounts of water vapor and suspended dust particles. The atmospheric dust plays an important role in the heating and cooling of the planet through absorption and emission of radiation. Small dust particles can potentially be carried to great altitudes and affect the temperatures there. Water vapor condensing onto the dust grains can affect the radiative properties of both, as well as their vertical extent. The condensation of water onto a dust grain will change the grain s fall speed and diminish the possibility of dust obtaining high altitudes. In this capacity, water becomes a controlling agent with regard to the vertical distribution of dust. Similarly, the atmosphere s water vapor holding capacity is affected by the amount of dust in the atmosphere. Dust is an excellent green house catalyst; it raises the temperature of the atmosphere, and thus, its water vapor holding capacity. There is, therefore, a potentially significant interplay between the Martian dust and water cycles. Previous research done using global, 3-D computer modeling to better understand the Martian atmosphere treat the dust and the water cycles as two separate and independent processes. The existing Ames numerical model will be employed to simulate the relationship between the Martian dust and water cycles by actually coupling the two cycles. Water will condense onto the dust, allowing the particle's radiative characteristics, fall speeds, and as a result, their vertical distribution to change. Data obtained from the Viking, Mars Pathfinder, and especially the Mars Global Surveyor missions will be used to determine the accuracy of the model results.

R M Haberle↗

NASA NTRS2003

Radiated Sound Power from a Curved Honeycomb Panel

The validation of finite element and boundary element model for the vibro-acoustic response of a curved honeycomb core composite aircraft panel is completed. The finite element and boundary element models were previously validated separately. This validation process was hampered significantly by the method in which the panel was installed in the test facility. The fixture used was made primarily of fiberboard and the panel was held in a groove in the fiberboard by a compression fitting made of plastic tubing. The validated model is intended to be used to evaluate noise reduction concepts from both an experimental and analytic basis simultaneously. An initial parametric study of the influence of core thickness on the radiated sound power from this panel, using this numerical model was subsequently conducted. This study was significantly influenced by the presence of strong boundary condition effects but indicated that the radiated sound power from this panel was insensitive to core thickness primarily due to the offsetting effects of added mass and added stiffness in the frequency range investigated.

Robinson, Jay H.↗

NASA NTRS2002

Capillary electrophoresis-electrochemistry microfluidic system for the determination of organic peroxides

A microfluidic analytical system for the separation and detection of organic peroxides, based on a microchip capillary electrophoresis device with an integrated amperometric detector, was developed. The new microsystem relies on the reductive detection of both organic acid peroxides and hydroperoxides at -700 mV (vs. Ag wire/AgCl). Factors influencing the separation and detection processes were examined and optimized. The integrated microsystem offers rapid measurements (within 130 s) of these organic-peroxide compounds, down to micromolar levels. A highly stable response for repetitive injections (RSD 0.35-3.12%; n = 12) reflects the negligible electrode passivation. Such a "lab-on-a-chip" device should be attractive for on-site analysis of organic peroxides, as desired for environmental screening and industrial monitoring.

NASA Discipline Life Sciences Technologies↗

NASA NTRS2010

Search for Organic Nanoglobules in Carbonaceous Chondrites Using Microtomography

Primitive solar materials have various organic matters. In recent years, novel organic materials called organic nanoglobules of a few hundred micrometers in typical size were discovered in carbonaceous chondrites, IDPs, and comet 81P/Wild 2. The organic globules are spherical shape and in many cases with hollow structures. Composition of the globules are mainly aromatic carbon. The isotopic anomalies of SD and 6N 15 observed in the globules indicate that they were formed from photochemical reaction to ice particles at very low temperature environment, such as molecular clouds or outer protosolar disk. Aqueous alteration of organic matters and the gamma-ray irradiation to PAH are also suggested as alternative possible formation processes. If the globules are made from organic ice particles, the hollow regions of the globules are suggested to be once filled with volatile H20-rich organic ices, while if they were formed by aqueous alteration, the hollow regions should be filled with a fluid which caused the aqueous alteration. However, fluids in the globules have not been detected so far in the previous studies. If fluids were originally preserved in the hollows, they might be lost during destructive processes of sample separation or preparation for TEM observation. X-ray computed tomography (CT) is a nondestructive method which can determine 3-D internal structures of objects. SR (synchrotron radiation)-based imaging microtomography can give submicron spatial resolution [8] and was applied to micro textures in extraterrestrial materials, such as cometary grains captured by the Stardust mission [9]. If organic globules are observed non-destructively in carbonaceous chondrites by tomography, we can check the presence of fluids in the hollows. If fluids are preserved, we may analyze chemical and isotopic compositions of the fluids. The purpose of this study is to observe organic nanoglobules using imaging tomography for future analysis.

Matsumoto, T.↗