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At least 343 records · Page 19

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NASA NTRS1978

Study of iron-borate materials systems processed in space

It was calculated that an FeBO3B2O3 glass-ceramic containing only 1 mole% FeBO3 would be equivalent for magnetooptic application to a YIG crystal of equal thickness. An Fe2O3B2O3 composition containing 2 mole% FeBO3 equivalent (98B) could be converted largely to a dense green, though opaque, FeBO3 glass-ceramic through suitable heat treatments. However, phase separation (and segregation) and Fe+3 reduction could not be entirely avoided with the various procedures that were employed. From light scattering calculations, it was estimated that about 100 A to allow 90% light transmission through a 1 cm thick sample. However, the actual FeBO3 crystallite sizes obtained in 98B were of the order of 1 micron or greater.

Neilson, G. F.↗

NASA NTRS1978

Solidification (crystal growth) in the presence of gravitational forces

The surface tension behavior of doped and undoped InSb melts was investigated as well as their temperature and composition dependence. Surface tension in InSb melts was determined using the sessile-drop technique covering the temperature range from 530 C to 880 C. A linear regression of the data obtained shows that the temperature dependence of sigma is 392- (T-530) x (7000) plus or minus 10 dyne/cm. The d sigma/d Tau for intrinsics InSb is less than that previously reported. On the basis of the surface tension data obtained, it is concluded that surface tension induced convective flow velocities in InSb under reduced gravity conditions range from zero to at most 1 cm/sec. Accordingly, no interference with dopant segregation can be expected during growth in space because the momentum boundary layer (at the crystal melt interface) associated with any Marangoni-type convective flows would, at the given growth rate, be significantly larger than the predicted diffusion boundary layer thickness.

Gatos, H. C.↗

NASA NTRS1978

Metallurgical analysis of skylab M552 and M557 samples

The anomalous microstructures on the basis of phase equilibria, liquid/liquid phase separation, and liquid/solid segregation for the Skylab M557 and M552 flight samples were studied. All of the unknown diffraction spectra have been identified. The previously unknown crystal structure of the Zn3Sb2 phase the M577B Experiment was determined. Previously unreported effects due to the near-absence of the hydrostatic pressure head are documented for the M557C samples.

Larson, D. J., Jr.↗

NASA NTRS1979

Growth of silicon carbide crystals on a seed while pulling silicon crystals from a melt

A saturated solution of silicon and an element such as carbon having a segregation coefficient less than unity is formed by placing a solid piece of carbon in a body of molten silicon having a temperature differential decreasing toward the surface. A silicon carbide seed crystal is disposed on a holder beneath the surface of the molten silicon. As a rod or ribbon of silicon is slowly pulled from the melt, a supersaturated solution of carbon in silicon is formed in the vicinity of the seed crystal. Excess carbon is emitted from the solution in the form of silicon carbide which crystallizes on the seed crystal held in the cool region of the melt.

Ciszek, T. F.↗

NASA NTRS1979

The processing of semiconductor materials

Five experiments involving the processing of semiconductor materials were performed during the Skylab mission. After discussions on semiconductors and their unique electronic properties, and techniques of crystal growth, these five experiments are presented. Four melt growth experiments were attempted: (1) steady state growth and segregation under zero gravity (InSb); (2) seeded, containerless solidification of InSb; (3) influence of gravity-free solidification on microsegregation; and (4) directional solidification of InSb-GaSb alloys. One vapor growth experiment, crystal growth by vapor transport, was attempted.

Source record↗

NASA NTRS1979

Silicon Materials Task of the Low Cost Solar Array Project, Phase 3. Effect of Impurities and Processing on Silicon Solar Cells

The effects of impurities, various thermochemical processes, and any impurity process interactions on the performance of terrestrial silicon solar cells are defined. Determinations of the segregation coefficients of tungsten, tantalum, and cobalt for the Czochralski pulling of silicon single crystals are reported. Sensitive neutron activation analysis was used to determine the metal impurity content of the silicon while atomic absorption was used to measure the metal content of the residual liquid from which the doped crystals were grown. Gettering of Ti doped silicon wafers improved cell performance by one to two percent for the highest temperatures and longest times. The HCl is more effective than POCl3 treatments for deactivating Ti but POCl3 and HCl produced essentially identical results for Mo or Fe.

Hopkins, R. H.↗

NASA NTRS1977

Auger spectroscopy analysis in adhesion, friction and wear studies

The paper reviews the current use of Auger electron spectroscopy in adhesion, friction, wear and lubrication studies. Conventional Auger spectroscopy is adopted to complement LEED studies of the adhesion of metal single crystals. In addition, Auger cylindrical mirror analysis is applied to the study of changes in surface chemistry during dynamic friction and wear experiments on polycrystalline metals and alloys. Important conclusions are that (1) segregation of alloying elements to the surface of metals can alter adhesion behavior; (2) hydrocarbons are adsorbed readily to clean iron surfaces at 23 C; (3) transfer from one surface to another for dissimilar materials in contact can be followed in sliding or rubbing friction studies; and (4) the friction process can enhance surface activity for metals with hydrocarbons.

Buckley, D. H.↗

NASA NTRS1978

Fractographic analysis of gaseous hydrogen induced cracking in 18Ni maraging steel

Electron microscope fractographic analysis supplemented an extensive study of the kinetics of gaseous hydrogen assisted cracking in 18Ni maraging steel. Temperature determined the crack path morphology in each steel which, in turn, was directly related to the temperature dependence of the crack growth rate. Crack growth in the low temperature regime proceeded along prior austenite grain boundaries. Increasing the temperature above a critical value produced a continuously increasing proportion of transgranular quasi-cleavage associated with lath martensite boundaries. The amount of transgranular cracking was qualitatively correlated with the degree of temperature-induced deviation from Arrhenius behavior. Fractographic observations are interpreted in terms of hypothesized mechanisms for gaseous hydrogen embrittlement. It is concluded that hydrogen segregation to prior austenite and lath martensite boundaries must be considered as a significant factor in developing mechanisms for gaseous embrittlement of high strength steels.

Gangloff, R. P.↗

NASA NTRS1979

Ultraviolet spectroscopic measurements of globular clusters

Ultraviolet spectra of six globular clusters (M15, M92, NGC 1851, NGC 6624, 47 Tuc, and NGC 6752) have been taken with the International Ultraviolet Explorer satellite in order to investigate the surface brightness distributions in the central regions. The ultraviolet emission indicates composite stellar spectra. Short-wavelength emission (1200-1900 A) arises from blue horizontal-branch stars; long-wavelength emission (2100-3000 A) is characteristic of late-type horizontal-branch and giant stars. The surface brightness distribution is more compact at short wavelengths than at long wavelengths, suggesting a segregation of horizontal-branch stars. A dense core appears to be present in X-ray-emitting clusters and absent in those clusters without X-ray sources. The X-ray source in NGC 6624 may have been detected at short wavelengths (1300-1900 A).

Dupree, A. K.↗

NASA NTRS1979

Recent developments at JPL in the application of image processing to astronomy

Four applications of image processing to astronomy, automated location and analysis of star and galaxy images, geometric and radiometric decalibration of vidicon spectra, display of multiband radio images, and generation of high resolution polarization direction and magnitude maps from images are presented with illustrative examples. The technique by which a digital image can be analyzed automatically to locate and segregate between stars and galaxies and the steps performed by the classifier to determine the nature of each object are outlined. The classification program executed on a 48 inch Schmidt plate of the cluster of galaxies 655 is described. The calibration and decalibration steps to remove geometric and radiometric distortions from a silicon vidicon camera digital spectra are discussed. Three methods of displaying multispectral radio data, generating a mosaic of each image, producing a color coded image to depict radio velocity, and producing a stereo pair with radial velocity as depth are described. The generation of polarization information from images obtained through linear polarizing filters is illustrated, and it is concluded that in each case information was displayed using digital techniques which could not readily have been provided visually.

Lorre, J. J.↗

NASA NTRS1978

Magma production and migration within the moon

Partial melting is likely to have occurred throughout much of the moon due to heating during accretion and the volumetric heating of radioactive isotopes. Important problems that have received relatively little attention concern the migration of the resulting magmas to form surface or near surface volcanic rock. In the paper the basic mechanism for the migration of the magma through the lunar asthenosphere is considered. A porous flow model is proposed. The magma behaves like a liquid flowing through a porous matrix. The volume fraction of liquid present determines the saturated porosity. The differential buoyancy of the magma drives it upwards. It is shown that the per cent partial melt in the lunar interior will only slightly exceed that required to provide interconnecting porosity. Assuming that the radioactive isotopes are preferentially segregated into the magma, the time dependence of the partial melting of the lunar interior is found. It is shown that the total degree of partial melting of the deep lunar interior is likely to be between five and ten per cent.

Turcotte, D. L.↗

NASA NTRS1978

Experimental partitioning of rare earth elements and scandium among armalcolite, ilmenite, olivine and mare basalt liquid

An experimental study was carried out to measure partition coefficients for two rare-earth elements (Sm and Tm) and Sc among armalcolite, ilmenite, olivine and liquid coexisting in a system modeled on high-Ti mare basalt 74275. This 'primitive' sample was chosen for study because its major and trace element chemistry as well as its equilibrium phase relations at atmospheric pressure are known from previous studies. Beta-track analytical techniques were used so that partition coefficients could be measured in an environment whose bulk trace element composition is similar to that of the natural basalt. Partition coefficients for Cr and Mn were determined in the same experiments by microprobe analysis. The only equilibrium partial melting model appears to be one in which ilmenite is initially present in the source region but is consumed by melting before segregation of the high-Ti mare basalt liquid from the residue.

Irving, A. J.↗

NASA NTRS1978

The suppression of low-temperature intergranular brittleness in ferritic Fe-Mn alloys

A method for obtaining cryogenic toughness in an Fe-12Mn-0.2Ti alloy by a controlled cooling technique is presented. The intergranular fracture surface of the quenched alloy, using an AES, revealed no significant difference from that obtained by the bulk transgranular fracture surface, indicating the absence of large-scale grain boundary segregation during the austenitizing treatment. Attention is given to the step cooling method, using a furnace at temperatures of 100 to 120 C, followed by fast cooling to ambient temperature, which in turn produces a high-impact toughness without intergranular brittleness. It is concluded that the sources of brittle intergranular fracture in the alloy are both chemical, operating in martensitic structure, and nonchemical, active during quenching from the austenitizing treatment.

Hwang, S. K.↗

NASA NTRS1981

Two-headed bolt

Coarse, multi-ingredient suspensions are sprayed on surface smoothly and uniformly with aid of nozzle attachment for commercial spray gun. Nozzle attachment is contoured internally to suppress overspray and to prevent spray from segregating. From its conical inlet, nozzle converges smoothly to throat, then diverges in bell-shaped chamber that allows suspension to flow uniterruptedly without building up turbulently in nozzle. End of nozzle is adjustable and can be extended or retracted to avoid dripping when inlet pressure, pump pressure, or density of mixture changes.

Jeffers, G. W.↗

NASA NTRS1980

Effect of impurities and processing on silicon solar cells. Volume 1: Characterization methods for impurities in silicon and impurity effects data base

Two major topics are treated: methods to measure and evaluate impurity effects in silicon and comprehensive tabulations of data derived during the study. Discussions of deep level spectroscopy, detailed dark I-V measurements, recombination lifetime determination, scanned laser photo-response, conventional solar cell I-V techniques, and descriptions of silicon chemical analysis are presented and discussed. The tabulated data include lists of impurity segregation coefficients, ingot impurity analyses and estimated concentrations, typical deep level impurity spectra, photoconductive and open circuit decay lifetimes for individual metal-doped ingots, and a complete tabulation of the cell I-V characteristics of nearly 200 ingots.

Hopkins, R. H.↗

NASA NTRS1980

Detailed investigation of a vaporising fuel spray. Part 1: Experimental investigation of time averaged spray

A laser tomographic light scattering technique provides rapid and accurate high resolution measurements of droplet sizes, concentrations, and vaporization. Measurements using a computer interfaced thermocouple are presented and it is found that the potential exists for separating gas and liquid temperature measurements and diagnosing local spray density by in situ analysis of the response characteristics of the thermocouple. The thermocouple technique provides a convenient means for measuring mean gas velocity in both hot and cold two phase flows. The experimental spray is axisymmetric and has carefully controlled initial and boundary conditions. The flow is designed to give relatively insignificant transfer of momentum and mass from spray to air flow. The effects of (1) size-dependent droplet dispersion by the turbulence, (2) the initial spatial segregation of droplet sizes during atomization, and (3) the interaction between droplets and coherent large eddies are diagnosed.

Yule, A. J.↗

NASA NTRS1979

Ultraviolet observations of globular clusters

Ultraviolet spectra of six globular clusters (M15, M92, NGC 1851, NGC 6624, 47 Tuc, and NGC 6752) have been taken with the International Ultraviolet Explorer Satellite in order to investigate the surface brightness distributions in the central regions. The ultraviolet emission indicates composite stellar spectra. Short wavelength emission (1200-1900 A) arises from blue horizontal branch stars; long wavelength emission (2100-3000 A) is characteristic of late type horizontal branch and giant stars. The surface brightness distribution is more compact at short wavelengths than at long wavelengths, suggesting a segregation of horizontal branch stars. A dense core appears to be present in X-ray emitting clusters and absent in those clusters without X-ray sources. The X-ray source in NGC 6624 may have been detected at short wavelengths, (1300-1900 A).

Gursky, H.↗

NASA NTRS1979

XPS and SAM studies of the surface chemistry of lunar impact glasses including 12054

We report and discuss quantitative X-ray photoemission (XPS) analyses of mm size areas and qualitative scanning Auger microprobe (SAM) analyses of micron size areas on the surfaces of impact glass coatings found on fragments in the 14161 coarse fines and on the top surface, and a reentrant crack surface of rock 12054. The data suggest that some segregation occurs during impact glass formation leading to surface enrichments in Si and depletions in Mg, Al, Ca, and Ti. The magnitude of the effect appears fairly small, although the complexity of the surfaces severely complicates the data analysis. Because of the complexity of the surfaces, both XPS and SAM data were essential. A search for direct evidence of either solar wind sputter erosion or vapor deposition on the exposed top surface of 12054 provided interesting results which we cannot yet fully interpret. Both this surface and the surface from the re-entrant crack showed enrichments of more than a factor of two in Fe with respect to the bulk.

Housley, R. M.↗