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At least 343 records · Page 19

Experimentally derived resistivity for dielectric samples from the CRRES internal discharge monitor

Resistivity values were experimentally determined using charge storage methods for six samples remaining from the construction of the Internal Discharge Monitor (IDM) flown on the Combined Release and Radiation Effects Satellite (CRRES). Three tests were performed over a period of four to five weeks each in a vacuum of -5x10^-6 torr with an average temperature of -25 (deg)C to simulate a space environment.

spacecraft charging↗

Exploration for Blind Geothermal Resources in the State of Hawaii Utilizing Dissolved Noble Gasses in Well Waters

This study is an extension of the Hawaii Play Fairway Analysis (PFA), a statewide geothermal exploration project funded by the United States Department of Energy. Based on results from prior phases of the PFA, this project targeted 66 wells on the islands of Hawaii, Maui, Lanai, Oahu, and Kauai for sampling of dissolved noble gases, trace metals, common ions, and the stable isotopes 2H and 18O. Ultimately, 23 of the 66 well targets were sampled. The noble gas helium is used as an indicator of geothermal heat when excess 3He and/or 4He is present when compared to the atmospheric ratio of those isotopes (R/Ra). R/Ra is minimally affected by dilution and transport, allowing even those wells not perfectly situated over a geothermal system to indicate a geothermal anomaly. R/Ra anomalies are present on every island in this study. There is a strong correlation between R/Ra anomalies and proximity to rift zones and calderas. Across the islands R/Ra ranged from 15-16 on Kilauea's lower east rift zone, which is a mantle plume value, to 0.37 on Lanai, which is a crustal value. The majority of anomalous well samples had R/Ra values consistent with an upper mantle source. Mixing between upper mantle and crustal helium is evident on all islands. Geographically, R/Ra decreases from the high at Kilauea to upper mantle values at Mauna Loa, and remains at upper mantle values for all wells across the other volcanoes, with the exception of two of four sampled wells on Lanai.

15 GEOTHERMAL ENERGY↗

Examining the Role of Environment in a Comprehensive Sample of Compact Groups

Compact groups, with their high number densities, small velocity dispersions, and an interstellar medium that has not been fully processed, provide a local analog to conditions of galaxy interactions in the earlier universe. The frequent and prolonged gravitational encounters that occur in compact groups affect the evolution of the constituent galaxies in a myriad of ways, for example, gas processing and star formation. Recently, a statistically significant "gap" has been discovered in the mid-infrared (MIR: 3.6-8 μm) IRAC color space of compact group galaxies. This gap is not seen in field samples and is a new example of how the compact group environment may affect the evolution of member galaxies. In order to investigate the origin and nature of this gap, we have compiled a larger sample of 37 compact groups in addition to the original 12 groups studied by Johnson et al. (yielding 174 individual galaxies with reliable MIR photometry). We find that a statistically significant deficit of galaxies in this gap region of IRAC color space is persistent in the full sample, lending support to the hypothesis that the compact group environment inhibits moderate specific star formation rates. Using this expanded sample, we have more fully characterized the distribution of galaxies in this color space and quantified the low-density region more fully with respect to MIR bluer and MIR redder colors. We note a curvature in the color-space distribution, which is fully consistent with increasing dust temperature as the activity in a galaxy increases. This full sample of 49 compact groups allows us to subdivide the data according to physical properties of the groups. An analysis of these subsamples indicates that neither projected physical diameter nor density shows a trend in color space within the values represented by this sample. We hypothesize that the apparent lack of a trend is due to the relatively small range of properties in this sample, whose groups have already been pre-selected to be compact and dense. Thus, the relative influence of stochastic effects (such as the particular distribution and amount of star formation in individual galaxies) becomes dominant. We analyze spectral energy distributions of member galaxies as a function of their location in color space and find that galaxies in different regions of MIR color space contain dust with varying temperatures and/or polycyclic aromatic hydrocarbon emission.

Environment↗

Soil Sampling Techniques For Alabama Grain Fields

Characterizing the spatial variability of nutrients facilitates precision soil sampling. Questions exist regarding the best technique for directed soil sampling based on a priori knowledge of soil and crop patterns. The objective of this study was to evaluate zone delineation techniques for Alabama grain fields to determine which method best minimized the soil test variability. Site one (25.8 ha) and site three (20.0 ha) were located in the Tennessee Valley region, and site two (24.2 ha) was located in the Coastal Plain region of Alabama. Tennessee Valley soils ranged from well drained Rhodic and Typic Paleudults to somewhat poorly drained Aquic Paleudults and Fluventic Dystrudepts. Coastal Plain s o i l s ranged from coarse-loamy Rhodic Kandiudults to loamy Arenic Kandiudults. Soils were sampled by grid soil sampling methods (grid sizes of 0.40 ha and 1 ha) consisting of: 1) twenty composited cores collected randomly throughout each grid (grid-cell sampling) and, 2) six composited cores collected randomly from a -3x3 m area at the center of each grid (grid-point sampling). Zones were established from 1) an Order 1 Soil Survey, 2) corn (Zea mays L.) yield maps, and 3) airborne remote sensing images. All soil properties were moderately to strongly spatially dependent as per semivariogram analyses. Differences in grid-point and grid-cell soil test values suggested grid-point sampling does not accurately represent grid values. Zones created by soil survey, yield data, and remote sensing images displayed lower coefficient of variations (8CV) for soil test values than overall field values, suggesting these techniques group soil test variability. However, few differences were observed between the three zone delineation techniques. Results suggest directed sampling using zone delineation techniques outlined in this paper would result in more efficient soil sampling for these Alabama grain fields.

Thompson, A. N.↗

Hydrothermal liquefaction of Cyanidioschyzon merolae and Salicornia bigelovii Torr.: The interaction effect on product distribution and chemistry

Hydrothermal liquefaction (HTL) has proven to be a promising technology for processing wet biomass into valuable biofuel intermediates. We investigated the influence of HTL process parameters on the individual and co-liquefaction of Salicornia bigelovii Torr. (SL) and Cyanidioschyzon merolae (CM) biomass and their respective product properties and characteristics. SL and CM biomasses were subjected to HTL conditions of process temperatures (250–350 °C), 10 wt% solid loading, 30 min reaction time, and co-liquefaction ratios (80–20, 50–50, 20–80, CM-SL, respectively). The individual maximum HTL biocrude yields for CM (34.63 wt%) and SL (7.63 wt%) were obtained at 300 °C. In both cases, biocrude oils had a higher carbon and hydrogen content relative to those of the original biomass. The HHV (higher heating value) values for the biocrude samples ranged from 24.2 to 33.12 MJ/kg, which were significantly higher than those of the original biomasses. A positive synergistic effect was observed during the co-liquefaction of two biomasses, where the experimental yield of biocrude oil was higher than the theoretical value. During the co-liquefaction experiments, a maximum biocrude yield of 32.95 wt% was obtained at 300 °C and 80–20 CM-SL biomass mix ratio. Co-liquefaction led to an increase in the energy content of the co-liquefied biocrude oil and a higher energy recovery rate. Finally, the properties of HTL products and biomasses were determined with TGA, CHN elemental analyzer, GC/MS, bomb calorimeter, HACH Spectrophotometer, and ICP OES.

09 BIOMASS FUELS↗

Contactless method of measuring resistivity

A method is described for measuring the conductivity of materials without having to make electrical contact with the material. Currents which are magnetically induced in the conducting sample are measured by means of the magnetic fields they produce. Although induction techniques have been used in the past for this type of measurement, the configuration presented here makes it possible to perform absolute measurements of resistivity over a wide range of values for relatively small samples. The theory of the technique, the results of measurements made with it, and a comparison of the technique with other methods are presented.

Crowley, J. D.↗

Some statistical problems inherent in measuring precipitation

A formula permitting calculation of the mean-square error of the mean value of a random variable due to periodic sampling is derived and applied to estimating the sampling error for satellite observation of the mean rainfall during the GARP Atlantic Tropical Experiment (GATE). The effects of both spatial resolution and frequency of observation on the sampling error are summarized in graphs. It is found that four observations per day are sufficient to determine the monthly mean rainfall over an area of 2.5 deg square (280km x 280km) to within a standard deviation of 5 percent of its mean value; two samples per day would yield an error with a standard deviation slightly less than 10 percent of the mean. A satellite instrument with less frequent sampling may produce significantly greater error in the estimate of monthly mean rainfall.

Flueck, J. A.↗

Segmentation of RDX and TNT in X‐Ray Computed Tomography Reconstructions of Melt‐Cast Explosives

ABSTRACT Three‐dimensional mesoscale characterization of heterogeneous melt‐cast high explosives is challenging because of the difficulty differentiating binder from explosive crystals: two functionally different materials which are typically similar in density by design. Here, we report an algorithm which can differentiate hexahydro‐1,3,5‐trinitro‐1,3,5‐triazine (RDX) from 2,4,6‐trinitrotoluene (TNT) in x‐ray computed tomography (CT) volumes with tens of microns resolution. This method allows us to quantify RDX/TNT content, porosity, and RDX domain size. We calibrated the segmentation algorithm using simulated x‐ray CT volumes containing object models of RDX crystals within a TNT matrix. We then segmented and analyzed CT data for Composition B (Comp B), a 60/40 RDX/TNT mixture, and Cyclotol, a 75/25 RDX/TNT mixture. We examined melt‐cast samples fabricated with 100% theoretical maximum density (TMD) and 85% TMD. For the 100% TMD Comp B and Cyclotol samples, the RDX content values calculated by segmentation were 3% and 9% lower, respectively, than the values measured by high‐performance liquid chromatography on material from the same synthesis lots. This result is consistent with the expected underreporting of RDX content resulting from x‐ray CT resolution limits on RDX particles with diameters smaller than 25 µm. The 85% TMD samples were less accurately segmented with our algorithm due to the confounding presence of voids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A review of imputation strategies for isobaric labeling-based shotgun proteomics

The throughput efficiency and increased depth of coverage provided by isobaric-labeled proteomics measurements have led to increased usage of these techniques. However, the structure of missing data is uniquely different than unlabeled studies. In this review, we compare the efficacy of nine imputation methods on a CPTAC proteomics iTRAQ dataset. Imputation methods were evaluated with regard to accuracy, variability, statistical hypothesis test inference and run time over datasets consisting of varying number of iTRAQ plexes and percentages of missing data. In general, expectation maximization and random forest imputation methods yielded the best performances, and constant-based methods performed poorly consistently across all dataset sizes and percentages of missing values. For datasets with small sample sizes and higher percentages of missing data, results indicate that statistical inference with no imputation may be preferable. Based on the findings in this review, there are core imputation methods that perform higher for isobaric-labeled proteomics data, but great care and consideration as to whether imputation should be used should be given for datasets comprised of a small number of samples, as well as to factors such as computational time and reproducibility of imputation values.

Bramer, Lisa M.↗

Study of isotopic composition of helium in the fine fraction of Luna 16 lunar surface material

The content of He isotopes is measured in two samples of the lunar surface material returned by the Luna 16 automatic station. Both samples consist of a fine fraction of lunar surface material and were samples from zone A (sample 3-2k) and from zone V (sample 9-1r). The value of He4/He3 and the concentration of the He isotopes are identical for both samples, within the limits of experimental error.

Boltenkov, B. S.↗

Simulated effects of sample size and grain neighborhood on the modeling of extreme value fatigue response

Assessing the size of representative volume elements (RVEs) for fatigue-related applications is challenging. A RVE relevant to random microstructure requires a volume of material that is sufficiently large to capture the grain/phase heterogeneity that captures all statistical moments of the distribution of the driving force for fatigue crack formation at “hot spot” grains. Consequently, the large size of a microstructure RVE required to study fatigue phenomena is largely computationally intractable and difficult to explore. A more realistic objective in this work is to systematically study, as a function of the size of a statistical sample of microstructure, trends towards convergence of the simulated distribution of driving force for fatigue crack formation. Our present work accordingly leverages the recently developed open-source PRISMS-Fatigue framework to examine the trends in convergence of extreme value distributions (EVD) of Fatigue Indicator Parameters (FIPs) in progressively larger polycrystalline microstructure realizations of FCC Al alloy 7075-T6 using crystal plasticity finite element method simulations. The results are compared to the traditional method in which ensembles of statistical volume elements (SVEs) are simulated to build up statistics intended to approximate those associated with a larger volume of material. The convergence of EVDs with increase of size of a SVE of microstructure is closely related to the extent of grain nearest neighbor (NN) interactions. Accordingly, the sensitivity of the local micromechanical response at hot spot grains is quantitatively investigated by systematically varying the orientations of NN grains. Results indicate that SVEs with cubic crystallographic texture tend towards convergence of the EVD of FIPs with tens of thousands of grains while the random and rolled textures require larger volumes. Simple relationships based on microstructure parameters (e.g., Schmid Factor, grain size, NN misorientation) do not completely correlate to fatigue hot spot grains. Finally, the sensitivity of the extreme value fatigue response at hot spot grains extends to the 3rd NN when a single neighborhood grain orientation is altered.

36 MATERIALS SCIENCE↗

The redshift-space neighborhoods of 36 loose groups. 2: Analysis

We explore the kinematics of 36 rich RGH89 groups identified from the first two complete slices of the CfA redshift survey. These groups have more than five members identified by a friends-of-friends algorithm at a number density contrast delta rho/rho greater than or equal to 80. To examine the stability of the determination of the velocity dispersion for these systems, we compare results for the original 232 members with results for a larger redshift sample, including 334 fainter members in the redshift neighborhoods. On average, we double the number of group members in each system. The observed distribution of velocity dispersions is stable. In fact, the velocity dispersion based on the original members identified in the CfA redshift survey is a reliable predictor of the value for the enlarged sample in an individual group. The velocity dispersion is thus a stable physical parameter for discrimination among systems galaxies. A larger sample of groups, particularly one selected from a distance limited catalog, should provide an interesting constraint on models for the formation of large-scale structure. We take H(sub 0) = km/s/Mpc.

Ramella, Massimo↗

Considerations for Defining G-Values for Aluminum-Clad Spent Nuclear Fuel

Sealed-canister dry storage of aluminum-clad spent nuclear fuel (ASNF) generated by research reactors is an alternative to current storage and disposition pathways as directed by the U.S. Department of Energy. The major challenge faced for this storage approach is radiolytic H 2 generation, including from the aluminum (oxy)hydroxide layers on the surface of ASNF. Experimental and modeling activities have been carried out to characterize the radiolytic yield as part of a DOE-sponsored research program to develop the technical basis for ASNF dry storage. The G-value is a commonly way to report results of radiolysis testing and is defined as the radiolytic yield of a species (e.g. molecular hydrogen) per unit radiation energy deposited into the material system. An independent technical review of the ASNF dry storage technical basis performed by Pacific Northwest National Laboratory raised questions about differences in G-value definitions used for experiments on ASNF surrogates consisting of aluminum samples with adherent (oxy)hydroxides compared to G-values reported in prior literature and how the magnitudes compared between different studies. Material systems resembling ASNF pose complications for measuring/defining G-values to predict the evolution of H 2 in a sealed canister, including i) accounting for radiolytic yields potentially arising from multiple sources, i.e., residual free (vapor), physisorbed, and chemisorbed/chemically bound waters; ii) deciding what portions of the multi-material system to include in the absorbed energy (radiation dose) calculation, considering possible energy exchange between materials as well as measurement limitations, and iii) capturing variations in G-value associated with non-linear yield vs. dose curves and/or dependence on the cover gas. This report summarizes previous literature information on radiolytic H 2 generation and associated G-values from mixed-material systems (generally oxides in contact with water or organic compounds) and from (oxy)hydroxides/hydrates to compare with the definitions and values for ASNF surrogate samples containing adherent aluminum (oxy)hydroxides.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

First direct 7 Be electron-capture $\mathrm{Q}$-value measurement toward high-precision searches for neutrino physics beyond the Standard Model

Here, we report the first direct measurement of the nuclear electron-capture (EC) decay Q value of 7 Be → 7 Li via high-precision Penning trap mass spectrometry (PTMS). This was performed using the LEBIT Penning trap located at the National Superconducting Cyclotron Laboratory/Facility for Rare Isotope Beams (NSCL/FRIB) using the newly commissioned Batch-Mode Ion-Source (BMIS) to deliver the unstable 7 Be + samples. With a measured value of Q EC = 861.963(23) keV, this result is three times more precise than any previous determination of this quantity. This improved precision and accuracy of the 7 Be EC decay Q value is critical for ongoing experiments that measure the recoiling nucleus in this system as a signature to search for beyond the Standard Model (BSM) neutrino physics using 7 Be-doped superconducting sensors. This experiment has extended LEBIT capabilities, using the first low-energy beam delivered by BMIS at FRIB for PTMS, as well as measuring the lightest-mass isotopes so far with LEBIT.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

A simple model of electron beam initiated dielectric breakdown

A steady state model that describes the internal charge distribution of a planar dielectric sample exposed to a uniform electron beam was developed. The model includes the effects of charge deposition and ionization of the beam, separate trap-modulated mobilities for electrons and holes, electron-hole recombination, and pair production by drifting thermal electrons. If the incident beam current is greater than a certain critical value (which depends on sample thickness as well as other sample properties), the steady state solution is non-physical.

Beers, B. L.↗

Detailed Design of an Earth Entry Vehicle for Comet Surface Sample Return

The 2013 Decadal Survey for New Frontiers missions identifies several high-value science missions, including Comet Surface Sample Return (CSSR). A CSSR mission will advance the scientific community's fundamental understanding of the origin of the solar system and the contribution of comets to the volatile inventory of the Earth. An entry capsule, or earth entry vehicle (EEV), is be required to protect the scientific payload from the extreme conditions of atmospheric entry, descent, and landing. The Decadal Survey Mission Concept Study along with an APL (Johns Hopkins University Applied Physics Lab) 2007-2008 Comet Surface Sample Mission Study details several of the driving requirements for a CSSR EEV; these include a payload volume and mass and inertial entry velocity of 9 kilometers per second. The mission concept study selected a Multi-Mission Earth Entry Vehicle (MMEEV) design concept derived from the Mars Sample Return (MSR) entry capsule design because of its increased reliability over a parachute-based vehicle. This presentation will explore detailed design of a CSSR-capable Earth Entry Vehicle, including trajectories, aeroheating predictions and associated thermal protection system masses, and onboard instrumentation for entry science.

Trajectory Analysis↗

Mapping Surface Soil Organic Carbon for Crop Fields with Remote Sensing

The organic C concentration of surface soil can be used in agricultural fields to vary crop production inputs. Organic C is often highly spatially variable, so that maps of soil organic C can be used to vary crop production inputs using precision farming technology. The objective of this research was to demonstrate the feasibility of mapping soil organic C on three fields, using remotely sensed images of the fields with a bare surface. Enough soil samples covering the range in soil organic C must be taken from each field to develop a satisfactory relationship between soil organic C content and image reflectance values. The number of soil samples analyzed in the three fields varied from 22 to 26. The regression equations differed between fields, but gave highly significant relationships with R2 values of 0.93, 0.95, and 0.89 for the three fields. A comparison of predicted and measured values of soil organic C for an independent set of 2 soil samples taken on one of the fields gave highly satisfactory results, with a comparison equation of % organic C measured + 1.02% organic C predicted, with r2 = 0.87.

Chen, Feng↗

Predicting Rare Earth Element Potential in Produced and Geothermal Waters of the United States via Emergent Self-Organizing Maps

This work applies emergent self-organizing map (ESOM) techniques, a form of machine learning, in the multidimensional interpretation and prediction of rare earth element (REE) abundance in produced and geothermal waters in the United States. Visualization of the variables in the ESOM trained using the input data shows that each REE, with the exception of Eu, follows the same distribution patterns and that no single parameter appears to control their distribution. Cross-validation, using a random subsample of the starting data and only using major ions, shows that predictions are generally accurate to within an order of magnitude. Using the same approach, an abridged version of the U.S. Geological Survey Produced Waters Database, Version 2.3 (which includes both data from produced and geothermal waters) was mapped to the ESOM and predicted values were generated for samples that contained enough variables to be effectively mapped. Results show that in general, produced and geothermal waters are predicted to be enriched in REEs by an order of magnitude or more relative to seawater, with maximum predicted enrichments in excess of 1000-fold. Cartographic mapping of the resulting predictions indicates that maximum REE concentrations exceed values in seawater across the majority of geologic basins investigated and that REEs are typically spatially co-associated. The factors causing this co-association were not determined from ESOM analysis, but based on the information currently available, REE content in produced and geothermal waters is not directly controlled by lithology, reservoir temperature, or salinity.

Engle, Mark A. (ORCID:0000000152587374)↗