Results for “renewable fuels” — Page 19

DOE OSTI2024

Production of sugars from lignocellulosic biomass via biochemical and thermochemical routes

Sugars are precursors to the majority of the world’s biofuels. Most of these come from sugar and starch crops, such as sugarcane and corn grain. Lignocellulosic sugars, although more challenging to extract from biomass, represent a large, untapped, opportunity. In response to the increasing attention to renewable energy, fuels, and chemicals, we review and compare two strategies for extracting sugars from lignocellulosic biomass: biochemical and thermochemical processing. Biochemical processing based on enzymatic hydrolysis has high sugar yield but is relatively slow. Thermochemical processing, which includes fast pyrolysis and solvent liquefaction, offers increased throughput and operability at the expense of low sugar yields.

Energy & Fuels↗

DOE OSTI2024

Diesel Oxidation Catalyst Performance with Biodiesel Formulations

Biodiesel (i.e., mono-alkyl esters of long chain fatty acids derived from vegetable oils and animal fats) is a renewable diesel fuel providing life-cycle greenhouse gas emission reductions relative to petroleum-derived diesel. With the expectation that there would be widespread use of biodiesel as a substitute for ultra-low sulfur diesel (ULSD), there have been many studies looking into the effects of biodiesel on engine and aftertreatment, particularly its compatibility to the current aftertreatment technologies. The objective of this study was to generate experimental data to measure the effectiveness of a current technology diesel oxidation catalysts (DOC) to oxidize soy-based biodiesel at various blend levels with ULSD. Biodiesel blends from 0 to 100% were evaluated on an engine using a conventional DOC. In the steady-state performance test where fuel dosing rate was increased at fixed DOC inlet temperature, B20 performed similarly to ULSD at the lowest flow rate or exhaust temperature over 340 degrees C for medium and high flows. B50 blends performed nearly as well under most conditions. Higher blends exhibited reduced thermal efficiency and DOC outlet temperature with increasing dosing rate under most conditions and required exhaust temperatures over 400 degrees C to achieve or nearly achieve performance similar to ULSD. In the steady-state light of test where fuel dosing rate is fixed but exhaust temperature is increased incrementally, B20 generally performed similarly to ULSD at the highest inlet temperature, with only minor deficiencies at lower temperatures. Higher blends exhibited lower thermal efficiency and did not achieve as high DOC outlet temperatures. In the transient light-off test light-off temperature for ULSD was typically less than 225 degrees C, while for B100 it ranged from 290 degrees C to 330 degrees C. Based on the data set, it can be concluded that biodiesel fuels have a higher light-off temperature primarily because of their higher boiling points, with a minor secondary impact of their lower energy content.

ADVANCED PROPULSION SYSTEMS,BIOMASS FUELS↗

NASA NTRS2006

Seawater/Saline Agriculture for Energy, Warming, Water, Rainfall, Land, Food and Minerals

The combination of the incipient demise of cheap oil and increasing evidence of Global Warming due to anthropogenic fossil carbon release has reinvigorated the need for and efforts on Renewable energy sources, especially for transportation applications. Biomass/Bio-diesel appears to have many benefits compared to Hydrogen, the only other major renewable transportation fuel candidate. Biomass Production is currently limited by available arable land and fresh water. Halophyte Plants and seawater irrigation proffer a wholly new biomass production mantra using wastelands and very plentiful seawater. Such an approach addresses many-to-most of the major emerging Societal Problems including Land, Water, Food, Warming and Energy. For many reasons, including seawater agriculture, portions of the Sahara appear to be viable candidates for future Biomass Production. The apparent nonlinearity between vegetation cover and atmospheric conditions over North Africa necessitates serious coupled boundary layer Meteorology and Global Circulation Modeling to ensure that this form of Terra Forming is Favorable and to avoid adverse Unintended Consequences.

Bushnell, Dennis↗

NASA NTRS2014

Prediction of the Aero-Acoustic Performance of Open Rotors

The rising cost of jet fuel has renewed interest in contrarotating open rotor propulsion systems. Contemporary design methods offer the potential to maintain the inherently high aerodynamic efficiency of open rotors while greatly reducing their noise output, something that was not feasible in the 1980's designs. The primary source mechanisms of open rotor noise generation are thought to be the front rotor wake and tip vortex interacting with the aft rotor. In this paper, advanced measurement techniques and high-fidelity prediction tools are used to gain insight into the relative importance of the contributions to the open rotor noise signature of the front rotor wake and rotor tip vortex. The measurements include three-dimensional particle image velocimetry of the intra-rotor flowfield and the acoustic field of a model-scale open rotor. The predictions provide the unsteady flowfield and the associated acoustic field. The results suggest that while the front rotor tip vortex can have a significant influence on the blade passing tone noise produced by the aft rotor, the front rotor wake plays the decisive role in the generation of the interaction noise produced as a result of the unsteady aerodynamic interaction of the two rotors. At operating conditions typical of takeoff and landing operations, the interaction noise level is easily on par with that generated by the individual rotors, and in some cases is even higher. This suggests that a comprehensive approach to reducing open rotor noise should include techniques for mitigating the wake of the front rotor as well as eliminating the interaction of the front rotor tip vortex with the aft rotor blade tip.

VanZante, Dale↗

NASA NTRS2014

Prediction of the Aero-Acoustic Performance of Open Rotors

The rising cost of jet fuel has renewed interest in contrarotating open rotor propulsion systems. Contemporary design methods offer the potential to maintain the inherently high aerodynamic efficiency of open rotors while greatly reducing their noise output, something that was not feasible in the 1980's designs. The primary source mechanisms of open rotor noise generation are thought to be the front rotor wake and tip vortex interacting with the aft rotor. In this paper, advanced measurement techniques and high-fidelity prediction tools are used to gain insight into the relative importance of the contributions to the open rotor noise signature of the front rotor wake and rotor tip vortex. The measurements include three-dimensional particle image velocimetry of the intra-rotor flowfield and the acoustic field of a model-scale open rotor. The predictions provide the unsteady flowfield and the associated acoustic field. The results suggest that while the front rotor tip vortex can have a significant influence on the blade passing tone noise produced by the aft rotor, the front rotor wake plays the decisive role in the generation of the interaction noise produced as a result of the unsteady aerodynamic interaction of the two rotors. At operating conditions typical of takeoff and landing operations, the interaction noise level is easily on par with that generated by the individual rotors, and in some cases is even higher. This suggests that a comprehensive approach to reducing open rotor noise should include techniques for mitigating the wake of the front rotor as well as eliminating the interaction of the front rotor tip vortex with the aft rotor blade tip.

Van Zante, Dale E.↗

DOE OSTI2021

Enhancing Distribution Grid Resilience Through Model Predictive Controller Enabled Prioritized Load Restoration Strategy: Preprint

Effective resilience improvement strategies enable the power grid to cope with disruptive extreme events. Most power grid outages are caused by disruptions in distribution grids. Motivated by the urgent need for power system resilience research, this paper proposes a priority-weighted optimal load restoration technique to enhance the resilience of distribution grids against extreme events. The proposed technique is based on smart distribution technology and framed as sequential multi-step decision process (MDP) and mixed integer linear program (MILP). It is formulated as optimal control problem with a model predictive control (MPC) approach. We applied the devised MILP-MPC-based load restoration technique to a simplified single-bus version of the IEEE 13-bus distribution system with integrated distributed energy resources (DERs) such as wind turbine, photovoltaic array, microturbine, and energy storage device. The technique executes a reducing and rolling horizon optimization in each control step in real-time using the forecasted information of the renewables, the fuel status of the microturbine and the state of charge of the energy storage device. We consider an extreme event which triggered outage of the upstream utility grid and caused islanded operation of the distribution grid. We demonstrated the effectiveness of the proposed MPC approach in restoring the distribution grid loads based on their priority during the main grid outage-caused islanded operation.

61 RADIATION PROTECTION AND DOSIMETRY↗

DOE OSTI2021

Enhancing Distribution Grid Resilience Through Model Predictive Controller Enabled Prioritized Load Restoration Strategy

Effective resilience improvement strategies enable the power grid to cope with disruptive extreme events. Most power grid outages are caused by disruptions in distribution grids. Motivated by the urgent need for power system resilience research, this paper proposes a priority-weighted optimal load restoration technique to enhance the resilience of distribution grids against extreme events. The proposed technique is based on smart distribution technology and framed as sequential multi-step decision process (MDP) and mixed integer linear program (MILP). It is formulated as optimal control problem with a model predictive control (MPC) approach. We applied the devised MILP-MPC-based load restoration technique to a simplified single-bus version of the IEEE 13-bus distribution system with integrated distributed energy resources (DERs) such as wind turbine, photovoltaic array, microturbine, and energy storage device. The technique executes a reducing and rolling horizon optimization in each control step in real-time using the forecasted information of the renewables, the fuel status of the microturbine and the state of charge of the energy storage device. We consider an extreme event which triggered outage of the upstream utility grid and caused islanded operation of the distribution grid. We demonstrated the effectiveness of the proposed MPC approach in restoring the distribution grid loads based on their priority during the main grid outage-caused islanded operation.

61 RADIATION PROTECTION AND DOSIMETRY↗

DOE OSTI2021

Advancing Catalytic Fast Pyrolysis Through Integrated Experimentation and Multi-Scale Computational Modeling

This webinar will highlight recent results from a multi-disciplinary research effort in which integrated reaction testing was coupled with particle- and reactor-scale computational modeling to advance catalytic fast pyrolysis (CFP) for the production of renewable hydrocarbon fuels. Data will be presented from a series of ex situ CFP experiments in which a fixed bed of Pt/TiO2 was utilized with co-fed H2 to upgrade woody biomass pyrolysis vapors. Further discussion will include the application of these data towards the development of (1) a multiscale simulation framework to de-couple apparent kinetics from both intraparticle and reactor-scale transport phenomena and (2) a finite element computational model to understand and predict thermal excursions during catalyst regeneration. Throughout the presentation, the speakers will emphasize synergistic outcomes derived from the collaborative approach and highlight ongoing research efforts to accelerate technology maturation.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

DOE OSTI2023

FR8relay Phase I SBIR Final Report for the Department of Energy

Explore the source record for details and available documents.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2021

Performance of Hybrid Renewable Energy Power System for a Residential Building

Using fossil fuels as the primary way to generate electricity causes a significant effect on the environment. In 2019, more than 64% of the electricity in the United States of America was generated using fossil-fuel resources, while renewable energy (RE) resources contributed to only 17% of the U.S. electricity generation for the same year. Additionally, due to the complex terrain distribution of many states in the U.S., a massive opportunity of utilizing RE resources in rural and remote areas can reduce the cost of electrical grid installation for such areas. In this study, a typical residential building with an average energy utilization of 30.25 kWh/day with a demand peak of 5.34 kW was considered a case study in each state to optimize a hybrid RE system and find the best alternative electrical grid system. This study presents the best configuration between solar and wind energy with different types of energy storage. It was discovered the photovoltaic (PV) solar panels—diesel generators with battery best services in all states. The daily radiation and diesel prices substantially affect the levelized cost of energy (COE) values in each state.

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2021

BETO 2021 Peer Review - Biomethanation to Upgrade Biogas to Pipeline Grade Methane WBS 5.1.3.102

We are developing, innovating and de-risking a biomethanation process capable of megawatt-scale deployment that upgrades biogas waste streams to produce pipeline quality renewable natural gas (RNG). Biomethanation is a two-step process using a methanogenic microorganism to convert renewable hydrogen (H2) and waste carbon dioxide (CO2) to renewable methane (CH4) - the primary component in natural gas. Using biogenic CO2 from biogas sources like dairies, wastewater treatment plants, and landfills allows production of this drop-in direct replacement fuel to participate in the growing number of carbon markets; like California's Low Carbon Fuel Standard and the Federal Renewable Fuel Standard. The end-of-project goal is to demonstrate pipeline quality RNG production (> 95% CH4, < 4% H2, <1% CO2, < 0.2% O2 and < 4 parts per million hydrogen sulfide) using real biogas feedstocks. We will accomplish this goal by designing and building a pressurized (18 bar) mobile lab-scale (20L) bioreactor research platform, including integrated electrolyzer system, based on lessons learned from operating the 700L pilot system from Southern California Gas Company. In collaboration with Electrochaea, natural gas utilities and Argonne National lab, will provide the data to establish a preliminary range of carbon intensity to help accelerate the deployment of utility-scale H2 production and qualify the biomethanation pathway process for RNG production.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

DOE OSTI2023

Biomethanation to Upgrade Biogas to Pipeline Grade Methane

NREL is working closely with DOE, Electrochaea GmbH, and Southern California Gas Company (SoCalGas) to reduce costs of a biomethanation process capable of megawatt-scale deployment that upgrades organic biogas waste streams to produce pipeline quality renewable natural gas (RNG). Biomethanation is a two-step process using a single-celled methanogenic archaea that converts low-carbon low-cost hydrogen (H2) and waste carbon dioxide (CO2) to produce renewable methane (CH4). The process upgrades the biogenic CO2 - while allowing the CH4 to pass through - from biogas sources like dairies, wastewater treatment plants, and landfills. The CH4 produced is a drop-in direct replacement fuel and producers can participate in the growing number of carbon markets; like California's Low Carbon Fuel Standard and the Federal Renewable Fuel Standard. NREL and Argonne National Laboratory have completed a life cycle analysis using the GREET model to show that the biomethanation process produces RNG that is carbon negative even when H2 production via low-temperature water electrolysis is driven by the existing carbon intensity of California's electricity grid. And of course, even further carbon negative (-233 kg CO2e/kWh) when the electricity is produced from low-carbon sources like wind and solar. Leveraging lessons learned from operating SoCalGas' 700L 18-bar bioreactor system, NREL is designing and building a flexible RD&D platform that will enable field trials at biogas and other CO2 sources. A custom 16' long trailer will house a 20L 18-bar bioreactor, 3 - 25 kW proton exchange membrane electrolyzer, and dosing, thermal, and controls systems to support operations with only power, biogas, and water feedstocks required by the field locations. The end-of-project goal is to demonstrate pipeline quality RNG production (> 95% CH4, < 4% H2, <1% CO2, < 0.2% O2 and < 4 parts per million H2 sulfide) using real biogas feedstocks - thereby recycling both greenhouse gases for injection into the natural gas network or to be used onsite.

biogas upgrading↗

DOE OSTI2025

Feasibility and Compatibility of Alternative Fuels in the U.S. Rail Sector: Technoeconomic, Lifecycle, and Supply Chain Analysis

The U.S. rail sector is a cornerstone of the United States’ freight transportation system, responsible for moving approximately 40% of long-distance freight ton-miles each year (AAR, 2025). Freight demand is projected to grow over time (BTS, 2017) thereby necessitating the investigation of alternative fuels that can sustain operational efficiency while reducing emissions and cost impacts. At the same time, it is important to explore alternative fuels as new sources of energy that can increase energy security and resilience for this sector. This report investigates the feasibility and compatibility of seven alternative fuels in the U.S. rail sector, focusing on biofuels and fuels from other renewable energy sources. The study evaluates alternative fuel pathways, considering their technical, economic, and environmental aspects to provide stakeholders with a comprehensive understanding of potential solutions.

09 BIOMASS FUELS↗

DOE OSTI2024

LES and RANS Spray Combustion Analysis of OME 3-5 and n-Dodecane

Clean-burning oxygenated and synthetic fuels derived from renewable power, so-called e-fuels, are a promising pathway to decarbonize compression–ignition engines. Polyoxymethylene dimethyl ethers (PODEs or OMEs) are one candidate of such fuels with good prospects. Their lack of carbon-to-carbon bonds and high concentration of chemically bound oxygen effectively negate the emergence of polycyclic aromatic hydrocarbons (PAHs) and even their precursors like acetylene (C 2 H 2 ), enabling soot-free combustion without the soot-NO x trade-off common for diesel engines. The differences in the spray combustion process for OMEs and diesel-like reference fuels like n-dodecane and their potential implications on engine applications include discrepancies in the observed ignition delay, the stabilized flame lift-off location, and significant deviations in high-temperature flame morphology. For CFD simulations, the accurate modeling and prediction of these differences between OMEs and n-dodecane proved challenging. This study investigates the spray combustion process of an OME 3 − 5 mixture and n-dodecane with advanced optical diagnostics, Reynolds-Averaged Navier–Stokes (RANS), and Large-Eddy Simulations (LESs) within a constant-volume vessel. Cool-flame and high-temperature combustion were measured simultaneously via high-speed (50 kHz) imaging with formaldehyde (CH 2 O) planar laser-induced fluorescence (PLIF) representing the former and line-of-sight OH* chemiluminescence the latter. Both RANS and LES simulations accurately describe the cool-flame development process with the formation of CH 2 O. However, CH 2 O consumption and the onset of high-temperature reactions, signaled by the rise of OH* levels, show significant deviations between RANS, LES, and experiments as well as between n-dodecane and OME. A focus is set on the quality of the simulated results compared to the experimentally observed spatial distribution of OH*, especially in OME fuel-rich regions. The influence of the turbulence modeling is investigated for the two distinct ambient temperatures of 900 K and 1200 K within the Engine Combustion Network Spray A setup. The capabilities and limitations of the RANS simulations are demonstrated with the initial cool-flame propagation and periodic oscillations of CH 2 O formation/consumption during the quasi-steady combustion period captured by the LES.

CFD↗

DOE OSTI2024

Electrification of residential and commercial buildings integrated with hybrid renewable energy systems: A techno-economic analysis

Here, this study assesses the techno-economic viability of city-scale building electrification, comparing a base case scenario with conventional HVAC systems to an electrified scenario with heat pump systems. EnergyPlus simulations reveal a 28% increase in annual electricity consumption in the electrified scenario, shifting the peak consumption from summer to winter with a 49% surge. Hybrid renewable energy systems (HRESs) are then evaluated using HOMER Pro, considering renewable penetration from 0% to 100%. The net present cost (NPC) of the base case and electrified scenarios range from $\$10.34$ to $\$24.38$ billion and $\$8.79$ to $\$50.31$ billion, respectively. Sensitivity analysis explores the impact of carbon tax, fuel price, and renewable subsidies on HRESs in the electrified scenario. Results indicate that applying a carbon tax up to $\$120$/tonne of CO 2 increases the optimum renewable fraction from 5% to 26%, while higher fuel prices and renewable subsidies further enhance the feasibility by shifting the optimum renewable fraction to 60% and 54%, respectively, demonstrating the interplay between economic factors and renewable integration in electrified urban contexts.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2023

Abstract for CRADA between National Energy Technology Laboratory and Mattiq, Inc.

To decarbonize the chemicals and fuels industry, we require new and innovative technologies that can leverage renewable feedstocks including renewable electricity and renewable carbon sources, such as CO 2 . State-of-the-art (SOTA) CO 2 utilization technologies that can produce renewable chemicals and fuels, such as the electrochemical reduction of CO 2 , are still significantly lacking in efficiency, and are therefore not cost-competitive with existing infrastructure. The key bottleneck to cost-competitive chemicals and fuels sourced from CO 2 and renewable electricity is the lack of any efficient catalyst material. The National Energy Technology Laboratory (NETL) and Mattiq will collaborate in the development of an efficient catalyst material that can effectively convert CO 2 into products of interest. Specifically, NETL will utilize high-performance computing to greatly reduce the number of potential materials to be investigated by Mattiq ultrahigh-throughput experimental catalyst discovery framework. This work is poised to rapidly accelerate the development of novel and efficient CO 2 reduction electrocatalysts that can bring CO 2 utilization closer to commercial viability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2021

The zero-emissions cost of energy: a policy concept

The energy sector generates over 70% of global greenhouse gas (GHG) emissions, but existing energy-climate policies do little to reduce GHG emissions to prevent climate change. We present a new carbon tax policy concept in which energy users would be taxed an amount equal to the cost of cleaning up the emissions that they create, wherein the tax revenues would be used to operate negative emissions technologies. The policy is based on applying the zero-emissions cost (ZEC) metric to energy prices, which includes the 'regular' cost of an energy source plus the cost of sequestering its emissions. Using the ZEC, (a) the energy sector would be emissions-neutral, (b) biofuels would be cheaper than petroleum fuels, and (c) renewable electricity would be cheaper than fossil-fuel electricity. We calculate the energy spending as a fraction of gross domestic product for 'regular' and ZEC cost scenarios. Implementing the ZEC carbon-tax policy would enable a monumental shift to a net-zero emissions energy sector, but carries a significant risk of causing an economic recession. The summary point of this commentary is to demonstrate a pathway to achieve net-zero GHG emissions from the US energy sector, and to contemplate the associated economic impacts on our society.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

DOE OSTI2022

Numerical and Experimental Investigations on the Ignition Behavior of OME

On the path towards climate-neutral future mobility, the usage of synthetic fuels derived from renewable power sources, so-called e-fuels, will be necessary. Oxygenated e-fuels, which contain oxygen in their chemical structure, not only have the potential to realize a climate-neutral powertrain, but also to burn more cleanly in terms of soot formation. Polyoxymethylene dimethyl ethers (PODE or OMEs) are a frequently discussed representative of such combustibles. However, to operate compression ignition engines with these fuels achieving maximum efficiency and minimum emissions, the physical-chemical behavior of OMEs needs to be understood and quantified. Especially the detailed characterization of physical and chemical properties of the spray is of utmost importance for the optimization of the injection and the mixture formation process. The presented work aimed to develop a comprehensive CFD model to specify the differences between OMEs and dodecane, which served as a reference diesel-like fuel, with regards to spray atomization, mixing and auto-ignition for single- and multi-injection patterns. The simulation results were validated against experimental data from a high-temperature and high-pressure combustion vessel. The sprays’ liquid and vapor phase penetration were measured with Mie-scattering and schlieren-imaging as well as diffuse back illumination and Rayleigh-scattering for both fuels. To characterize the ignition process and the flame propagation, measurements of the OH* chemiluminescence of the flame were carried out. Significant differences in the ignition behavior between OMEs and dodecane could be identified in both experiments and CFD simulations. Liquid penetration as well as flame lift-off length are shown to be consistently longer for OMEs. Zones of high reaction activity differ substantially for the two fuels: Along the spray center axis for OMEs and at the shear boundary layers of fuel and ambient air for dodecane. Additionally, the transient behavior of high temperature reactions for OME is predicted to be much faster.

33 ADVANCED PROPULSION SYSTEMS↗