Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “process cooling”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 343 records · Page 19

Microscale Observation via High-Speed X-ray Diffraction of Alloy 718 During In Situ Laser Melting

The laser melting process is accompanied by rapid evolution in temperature, phase, structure, and strain because of its high heating and cooling rates. In this study, the evolution of grains within a thin solid plate of Ni alloy 718 during laser processing was probed with in situ high-energy x-ray diffraction experiments. The high temporal and spatial resolution available in the measurement allowed us to study the rapid evolution of the melted region beneath the surface of the sample. The characterization of the evolution of secondary phases, i.e., Laves and carbide, was captured despite the weak diffracted peaks caused by small volume fractions. Thermal history was estimated based on changes in the lattice spacing from the thermal contraction upon cooling. In conclusion, the temporal variation in 2θ with azimuthal direction revealed the evolution in anisotropy of lattice spacing and thus of the mechanical state during laser processing.

36 MATERIALS SCIENCE↗

Assessments of advanced reactor heat supply to high temperature industrial unit operations: Heat Engines and Heat Pumps

In this report, the feasibility of employing Advanced Nuclear Reactors to supply the necessary high-quality heat to Industrial Processes is investigated. As a first step, the most relevant industrial applications that could benefit from this coupling were identified. Four industries including petroleum refining (distillation, catalyst regeneration, hydro-steam cracking), chemical polymers, steel manufacturing (metals annealing/soaking) and cement manufacturing (calcination of limestone and dolomite industries) were considered. An overview of the heat duties, i.e., the temperatures and thermal powers required by representative plants of the different processes, was provided. Secondly, the thermodynamic conditions of the steam produced by representative designs of Advanced Reactor concepts (Liquid Metal Fast Breeder Reactors, Molten Salt Reactors, and High Temperature Gas-cooled Reactors) were summarized. The comparison between the requirements of the industrial processes and the capabilities of the candidate nuclear power plants showed that only a few processes could benefit from the coupling. Although Advanced Reactors operate at higher temperatures than Light Water Reactors, the thermodynamic conditions of the generated steam flow rates are generally not suitable for the selected applications. At the same time, data indicate that most of the processes can be suitably supplied if the temperature of steam is elevated to 900 °C. One possible solution to boost the quality of the steam from the nuclear island involves the use of a heat pump. Based on a technology similar to that found in refrigerators and air conditioners, heat pumps extract heat from a source, elevate its temperature and transfer it to where it is needed. A simple numerical example illustrating the viability of this method is described. Specifically, the energy conversion cycle of a conventional Pressurized Water Reactor was extended to incorporate a compressor to raise the heating value of the steam produced by the reactor. Two reference configurations, i.e., one where the industrial process coupled to the nuclear power plant exhausts saturated liquid and the other where it exhausts saturated steam, were considered. The thermal efficiencies achievable by increasing the heating value of the reactor steam in this way are significantly greater than by direct electric heating.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Upper ocean mixing, surface heat fluxes, and heat content variability in the upper 150 m during Hurricane Laura (2020)

Observations (from thermistor sensors and a hurricane glider) and model-based temperature were used to answer questions including the following: 1) What physical and environmental conditions explain the rapid intensification of Hurricane Laura? 2) How did the pre-existing warm mixed layer at Stone mooring (StM) influence the degree of cooling in the mixed layer? 3) How did vertical mixing, surface heat fluxes, and advective processes collectively shape the mixed layer heat evolution at StM? Observations measured by thermistor sensors showed that Hurricane Laura induced a cooling of -1.2oC in the mixed layer when Hurricane Laura’s wind speed increased to 47 m/s on 26 August. This contrasts with the -1.04oC mixed layer temperature change estimated from model-based temperature. At StM, the presence of a 31oC warm mixed layer and elevated heat content (60-80kJ/cm2) effectively preconditioned the upper ocean ahead of Hurricane Laura’s passage. After Hurricane Laura passed, turbulent mixing associated with the storm transported the heat anomalies downward into subsurface layers. In addition, this study shows that a surface heat flux of 5.04 kJ/cm2 supported the intensity of Hurricane Laura as it traversed over the StM. Using a mixed layer heat balance model, this study shows that entrainment flux and surface flux mostly contributed to the observed change in the mixed layer temperature.

Tsai, Senam↗

Design of Novel Hot Gas Component for Gas Turbine Engines Enabled by Materials and Additive Manufacturing Process Development

This CRADA project was the result of a project award under FOA-DOE-0001980. The overarching FOA project team consisted of researchers from Carpenter Technology Corporation (CTC), Solar Turbines Incorporated (Solar), Pennsylvania State University (PSU), University of California-Santa Barbara (UCSB), and Oak Ridge National Laboratory (ORNL). Evaluations were conducted on two high-γ’ superalloys that were designed by CTC and the UCSB. One alloy named GammaPrint-700 (GP-700) is a cobalt-base superalloy. The other alloy named GammaPrint-1100 (GP-1100) is a nickel-base (Ni-base) superalloy. PSU provided expertise and experimental testing of the thermal performance of AM micro-cooling architectures. ORNL provided expertise with the AM superalloy materials characterization and AM processing science. Solar provided turbine component design expertise. The focus of this CRADA report is to document the efforts between ORNL and CTC towards the development of superalloys designed for AM. The project goal was to use an AM processable high-temperature superalloy and design for Additive Manufacturing (DfAM) techniques to design an efficient turbine component (i.e. a turbine tip shoe) with enhanced cooling features that can only be fabricated through additive manufacturing (AM). The efficiencies of existing combined heat and power (CHP) engines are capped by both component design and materials limitations. However, AM of a tip shoe component from a γ’strengthened superalloy offers the design flexibility to increase the efficiency and power of an industrial gas turbine. This project brought about advancements in the DfAM tip shoe design space and in the area of high temperature superalloys processable through laser powder bed fusion (LPBF) AM. State of art computation design tools were utilized to optimize unique cooling features into a tip shoe component design. A two-prong materials development approach was taken to support development of the AM tip shoe geometry. The first approach centered on investigating the processability and the appropriate process science for the industry standard high-γ’ nickel-base (Ni-base) superalloy Mar-M247. This superalloy is typically cast and considered non-weldable by traditional welding standards. In the course of this work, the alloy was not deemed feasible for process scale-up due to significant cracking issues during printing. The second approach focused on the development and evaluation of a novel cobalt-base superalloy, GammaPrint™-700 (GP-700 and a Ni-base superalloy, GammaPrint™-1100 (GP-1100) designed to mitigate the significant AM processing issues with Mar-M247. The processability of these two alloys were investigated through electron beam melting (EBM) binder-jet AM (BJAM), and LPBF as a risk mitigation for manufacturability. To be considered a candidate material for down-selection to proceed to full-scale AM tip shoe engine testing trials, the high temperature creep rupture strength was required to achieve at a minimum, a Larsen Miller Parameter (LMP) increase of 10.9% over the baseline material LPBF AM Hastelloy X.

99 GENERAL AND MISCELLANEOUS↗

Design of Novel Hot Gas Component for Gas Turbine Engines Enabled by Materials and Additive Manufacturing Process Development

This CRADA project was the result of a project award under FOA-DOE-0001980. The overarching FOA project team consisted of researchers from Carpenter Technology Corporation (CTC), Solar Turbines Incorporated (Solar), Pennsylvania State University (PSU), University of California-Santa Barbara (UCSB), and Oak Ridge National Laboratory (ORNL). Evaluations were conducted on two high-γ’ superalloys that were designed by CTC and the UCSB. One alloy named GammaPrint-700 (GP-700) is a cobalt-base superalloy. The other alloy named GammaPrint-1100 (GP-1100) is a nickel-base (Ni-base) superalloy. PSU provided expertise and experimental testing of the thermal performance of AM micro-cooling architectures. ORNL provided expertise with the AM superalloy materials characterization and AM processing science. Solar provided turbine component design expertise. The focus of this CRADA report is to document the efforts between ORNL and CTC towards the development of superalloys designed for AM. The project goal was to use an AM processable high-temperature superalloy and design for Additive Manufacturing (DfAM) techniques to design an efficient turbine component (i.e. a turbine tip shoe) with enhanced cooling features that can only be fabricated through additive manufacturing (AM). The efficiencies of existing combined heat and power (CHP) engines are capped by both component design and materials limitations. However, AM of a tip shoe component from a γ’strengthened superalloy offers the design flexibility to increase the efficiency and power of an industrial gas turbine. This project brought about advancements in the DfAM tip shoe design space and in the area of high temperature superalloys processable through laser powder bed fusion (LPBF) AM. State of art computation design tools were utilized to optimize unique cooling features into a tip shoe component design. A two-prong materials development approach was taken to support development of the AM tip shoe geometry. The first approach centered on investigating the processability and the appropriate process science for the industry standard high-γ’ nickel-base (Ni-base) superalloy Mar-M247. This superalloy is typically cast and considered non-weldable by traditional welding standards. In the course of this work, the alloy was not deemed feasible for process scale-up due to significant cracking issues during printing. The second approach focused on the development and evaluation of a novel cobalt-base superalloy, GammaPrint™-700 (GP-700 and a Ni-base superalloy, GammaPrint™-1100 (GP-1100) designed to mitigate the significant AM processing issues with Mar-M247. The processability of these two alloys were investigated through electron beam melting (EBM) binder-jet AM (BJAM), and LPBF as a risk mitigation for manufacturability. To be considered a candidate material for down-selection to proceed to fullscale AM tip shoe engine testing trials, the high temperature creep rupture strength was required to achieve at a minimum, a Larsen Miller Parameter (LMP) increase of 10.9% over the baseline material LPBF AM Hastelloy X.

36 MATERIALS SCIENCE↗

Ring Formation in Protoplanetary Disks Driven by an Eccentric Instability

We find that, under certain conditions, protoplanetary disks may spontaneously generate multiple, concentric gas rings without an embedded planet through an eccentric cooling instability. Using both linear theory and nonlinear hydrodynamics simulations, we show that a variety of background states may trap a slowly processing, one-armed spiral mode that becomes unstable when a gravitationally stable disk rapidly cools. The angular momentum required to excite this spiral comes at the expense of nonuniform mass transport that generically results in multiple rings. For example, one long-term hydrodynamics simulation exhibits four long-lived, axisymmetric gas rings. We verify the instability evolution and ring-formation mechanism from first principles with our linear theory, which shows remarkable agreement with the simulation results. Dust trapped in these rings may produce observable features consistent with observed disks. Additionally, direct detection of the eccentric gas motions may be possible when the instability saturates, and any residual eccentricity left over in the rings at later times may also provide direct observational evidence of this mechanism.

79 ASTRONOMY AND ASTROPHYSICS↗

Zirconium Sludge Criticality Calculations in Large Process Tanks

The Savannah River Site’s (SRS) H-Canyon recently re-activated its 6.3D electrolytic dissolver to dissolve stainless steel clad research reactor fuels from Japan. A potential new mission was identified to dissolve other long-cooled fuel stored at SRS that is not aluminum clad. In the basic process of dissolution, the spent fuel dissolves into nitric acid (bulk solution). The eight ft. high and four ft. radius 6.3D dissolver is unique in that it has a platinum-coated niobium insert to resist corrosion, and the niobium basket forms an anode and cathode arrangement within the charge chute (Fig 1,2). DC current flows from anode to cathode, at up to 10,000 amps at 45 volts, through the potential gradient in the nitric acid solution, which allows the stainless steel (or other non-aluminum cladding) of the fuel to dissolve.

Wade, Brindley↗

Method for removing a foulant from a gas stream with minimal external refrigeration

A process for removing a foulant from a gas stream. The gas stream is cooled in a series of heat exchangers, causing a portion of the foulant to desublimate and become entrained in a cryogenic liquid. This foulant slurry stream is pressurized, cooled, and separated into a pressurized foulant solid stream and the cryogenic liquid stream. The pressurized foulant solid stream is melted to produce a liquid foulant stream. Heat exchange processes, both internal and external, are provided that close the heat balance of the process. In this manner, the foulant is removed from the gas stream.

Baxter, Larry↗

Study of hydride reorientation and ductility of SRA ZIRLO and PRXA ZIRLO using ring compression testing (RCT)

Before dry storage, spent nuclear fuel is dried at high temperatures, which induces hydride dissolution. Radial hydride particles precipitate when cooled under a stress above a threshold stress. This process can severely degrade the ductility of cladding tubes. Zirconium alloys with different microstructures, such as grain boundary density, were quantified and studied to examine their effect on hydride reorientation. The ring compression loading mode creates a range of stress states depending on the location within the ring with respect to the applied load, producing various hydride morphologies that can be used to study the effects of microstructures on hydride reorientation. Finite element modeling was performed to calculate the hoop stress, which is the dominant stress, during hydride reorientation. These results were coupled with hydride morphology to determine the threshold stress for hydride reorientation, depending on the microstructure. In conclusion, the samples were then mechanically tested using ring compression to evaluate the ductility of zirconium alloys as a function of different hydride morphologies.

Hydride embrittlement↗

Advanced Water-Related Technology Performance Development

This U.S. Department of Energy/National Energy Technology Laboratory techno-economic analysis evaluates those parameters having the greatest performance and cost impact on wet flue gas desulfurization (FGD) effluent wastewater treatment systems, and air cooled condensers for dry cooling systems. Two supercritical pulverized coal power plants are considered: 1) an existing plant (modified for surface water discharge and air emissions consistent with limits for existing plants) retrofitted with wet FGD effluent wastewater treatment and 2) a greenfield plant constructed with an air-cooled condenser (ACC). Sensitivity analyses are completed on various process parameters associated with the wet FGD effluent wastewater treatment system and ACC to determine the impact on the net plant efficiency and levelized cost of electricity (LCOE). Research and development targets are recommended for the parameters shown to have the greatest potential impact on cost or performance.

20 FOSSIL-FUELED POWER PLANTS↗

Multiscale Modeling of Nanoparticle Precipitation in Oxide Dispersion-Strengthened Steels Produced by Laser Powder Bed Fusion

Laser Powder Bed Fusion (LPBF) enables the efficient production of near-net-shape oxide dispersion-strengthened (ODS) alloys, which possess superior mechanical properties due to oxide nanoparticles (e.g., yttrium oxide, Y-O, and yttrium-titanium oxide, Y-Ti-O) embedded in the alloy matrix. To better understand the precipitation mechanisms of the oxide nanoparticles and predict their size distribution under LPBF conditions, we developed an innovative physics-based multiscale modeling strategy that incorporates multiple computational approaches. These include a finite volume method model (Flow3D) to analyze the temperature field and cooling rate of the melt pool during the LPBF process, a density functional theory model to calculate the binding energy of Y-O particles and the temperature-dependent diffusivities of Y and O in molten 316L stainless steel (SS), and a cluster dynamics model to evaluate the kinetic evolution and size distribution of Y-O nanoparticles in as-fabricated 316L SS ODS alloys. The model-predicted particle sizes exhibit good agreement with experimental measurements across various LPBF process parameters, i.e., laser power (110–220 W) and scanning speed (150–900 mm/s), demonstrating the reliability and predictive power of the modeling approach. The multiscale approach can be used to guide the future design of experimental process parameters to control oxide nanoparticle characteristics in LPBF-manufactured ODS alloys. Additionally, our approach introduces a novel strategy for understanding and modeling the thermodynamics and kinetics of precipitation in high-temperature systems, particularly molten alloys.

Wang, Zhengming (ORCID:0000000241627112)↗

Hubble Space Telescope Observations within the Sphere of Influence of the Powerful Supermassive Black Hole in PKS 0745-191

We present Space Telescope Imaging Spectrograph observations from the Hubble Space Telescope of the supermassive black hole (SMBH) at the center of PKS 0745-191, a brightest cluster galaxy (BCG) undergoing powerful radio-mode active galactic nucleus (AGN) feedback (P cav ~ 5 × 10 45 erg s -1 ). These high-resolution data offer the first spatially resolved map of gas dynamics within an SMBH's sphere of influence under such powerful feedback. Our results reveal the presence of highly chaotic, nondrotational ionized gas flows on subkiloparsec scales, in contrast to the more coherent flows observed on larger scales. While radio-mode feedback effectively thermalizes hot gas in galaxy clusters on kiloparsec scales, within the core, the hot gas flow may decouple, leading to a reduction in angular momentum and supplying ionized gas through cooling, which could enhance accretion onto the SMBH. This process could, in turn, lead to a self-regulating feedback loop. Compared to other BCGs with weaker radio-mode feedback, where rotation is more stable, intense feedback may lead to more chaotic flows, indicating a stronger coupling between jet activity and gas dynamics. Additionally, we observe a sharp increase in velocity dispersion near the nucleus, consistent with a very massive M BH ~ 1.5 × 10 10 M ⊙ SMBH. The density profile of the ionized gas is also notably flat, paralleling the profiles observed in X-ray gas around galaxies where the Bondi radius is resolved. These results provide valuable insights into the complex mechanisms driving galaxy evolution, highlighting the intricate relationship between SMBH fueling and AGN feedback within the host galaxy.

79 ASTRONOMY AND ASTROPHYSICS↗

ENVIRONMENTAL DEGRADATION OF HARD AND SOFT MAGNETIC MATERIALS IN GASEOUS AND SUPERCRITICAL CO2 ENVIRONMENTS

It may be beneficial to use hermetic designs for supercritical CO2 (sCO2) cycles machinery as they would eliminate CO2 leakage through shaft end seals. This would reduce CO2 emissions and operating costs for makeup of lost process fluid. Those designs may replace traditional oil-lubricated bearings with actively controlled magnetic bearings operating at high temperatures in the process fluid environment (to reduce the need for active cooling). This paper investigates the material degradation of various types of magnets in CO2. Included are several permanent and soft magnetic materials (Alnico 9C, Alnico 5-7C, and 18-T550 grade SmCo, and Hiperco 50) with or without coatings (nickel plating or C5 coating). The materials were exposed to: (1) flowing gaseous CO2 at 1,022 °F (550 °C) and atmospheric pressure in a furnace and (2) sCO2 at 842 °F (450 °C) and 1,500 psi (103 bar) in an autoclave. The preliminary mass change measured after total exposures of 1,000 hours and 2,000 hours are included.

supercritical CO2, magnetic material↗

Numerical simulations of three-dimensional ion crystal dynamics in a Penning trap using the fast multipole method

We simulate the dynamics, including laser cooling, of three-dimensional (3-D) ion crystals confined in a Penning trap using a newly developed molecular dynamics-like code. The numerical integration of the ions’ equations of motion is accelerated using the fast multipole method to calculate the Coulomb interaction between ions, which allows us to efficiently study large ion crystals with thousands of ions. In particular, we show that the simulation time scales linearly with ion number, rather than with the square of the ion number. By treating the ions’ absorption of photons as a Poisson process, we simulate individual photon scattering events to study laser cooling of 3-D ellipsoidal ion crystals. Initial simulations suggest that these crystals can be efficiently cooled to ultracold temperatures, aided by the mixing of the easily cooled axial motional modes with the low frequency planar modes. In our simulations of a spherical crystal of 1000 ions, the planar kinetic energy is cooled to several millikelvin in a few milliseconds while the axial kinetic energy and total potential energy are cooled even further. This suggests that 3-D ion crystals could be well suited as platforms for future quantum science experiments.

Zaris, John (ORCID:0009000196476323)↗

Combined Heat and Power Technology Fact Sheet Series: Thermal Energy Storage

This fact sheet provides an overview of thermal energy storage (TES) technologies, which heat or cool a storage medium and, when needed, deliver the stored thermal energy to meet heating or cooling needs. TES systems are used in commercial buildings, industrial processes, and district energy installations to deliver stored thermal energy during peak demand periods, thereby reducing peak energy use. TES systems are often integrated with electric or absorption chillers to reduce peak electricity costs and, in the case of new construction, to reduce capital costs by optimizing chiller size. TES technologies can support sites that have either renewable or fossil power generation, including combined heat and power (CHP) installations. With CHP, TES can help optimize equipment size by reducing the required peak CHP thermal capacity and increasing annual CHP usage. TES can also provide turbine inlet cooling for gas turbines used in CHP applications, which increases power production in hot ambient conditions.

Combined Heat and Power, CHP, Thermal Energy, Tech↗

A dimensionless number for high-throughput design of multi-principal element alloys in directed energy deposition

The present study demonstrates the development of a dimensionless number to predict the build height in the additive manufacturing technique of directed energy deposition (DED). The build height can also be used to estimate the dendrite arm spacing and, thus, the cooling rate in the fabrication of samples. A baseline sample, 316L stainless steel, was used to fit the build height to the dimensionless number. A range of process parameters, including laser power, laser feed rate, powder flow rate, layer thickness, and hatch spacing, were varied. Based upon dendrite arm spacing, the estimated cooling rate varied between 102 and 104 K/s. Using the fitted relationship for the stainless steel, high-throughput (HT) processing of multi-principal element alloys (MPEAs) was performed. For this study, HT is the ability to fabricate a batch of 25 bulk samples (∼1 cm3) with different compositions within a 5-h period with ±10 at. % accuracy. A range of compositions using in situ alloying of elemental powders in the Fe–Ni–Cr–Mo system were made. The MPEAs' build height followed the same relationship to the dimensionless number as the 316L alloy. The dimensionless number predicts both macro and meso-scale features in HT processing, thus offering a design tool for choosing process parameters in DED additive manufacturing. Also, the ability to control or increase cooling rates can enhance the ability to promote metastability as well as control meso-scale chemical distributions of alloy samples.

Islam, Zahabul (ORCID:0000000169613209)↗

Half-Heusler alloys as emerging high power density thermoelectric cooling materials

Abstract To achieve optimal thermoelectric performance, it is crucial to manipulate the scattering processes within materials to decouple the transport of phonons and electrons. In half-Heusler (hH) compounds, selective defect reduction can significantly improve performance due to the weak electron-acoustic phonon interaction. This study utilized Sb-pressure controlled annealing process to modulate the microstructure and point defects of Nb 0.55 Ta 0.40 Ti 0.05 FeSb compound, resulting in a 100% increase in carrier mobility and a maximum power factor of 78 µW cm −1 K −2 , approaching the theoretical prediction for NbFeSb single crystal. This approach yielded the highest average zT of ~0.86 among hH in the temperature range of 300-873 K. The use of this material led to a 210% enhancement in cooling power density compared to Bi 2 Te 3 -based devices and a conversion efficiency of 12%. These results demonstrate a promising strategy for optimizing hH materials for near-room-temperature thermoelectric applications.

36 MATERIALS SCIENCE↗

Comptonization by reconnection plasmoids in black hole coronae II: Electron-ion plasma

ABSTRACT We perform 2D particle-in-cell simulations of magnetic reconnection in electron-ion plasmas subject to strong Compton cooling and calculate the X-ray spectra produced by this process. The simulations are performed for trans-relativistic reconnection with magnetization 1 ≤ σ ≤ 3 (defined as the ratio of magnetic tension to plasma rest-mass energy density), which is expected in the coronae of accretion discs around black holes. We find that magnetic dissipation proceeds with inefficient energy exchange between the heated ions and the Compton-cooled electrons. As a result, most electrons are kept at a low temperature in Compton equilibrium with radiation, and so thermal Comptonization cannot reach photon energies $\sim 100\,$ keV observed from accreting black holes. Nevertheless, magnetic reconnection efficiently generates $\sim 100\,$ keV photons because of mildly relativistic bulk motions of the plasmoid chain formed in the reconnection layer. Comptonization by the plasmoid motions dominates the radiative output and controls the peak of the radiation spectrum Epk. We find Epk ∼ 40 keV for σ = 1 and Epk ∼ 100 keV for σ = 3. In addition to the X-ray peak around 100 keV, the simulations show a non-thermal MeV tail emitted by a non-thermal electron population generated near X-points of the reconnection layer. The results are consistent with the typical hard state of accreting black holes. In particular, we find that the spectrum of Cygnus X-1 is well explained by electron-ion reconnection with σ ∼ 3.

Astronomy & Astrophysics↗