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At least 343 records · Page 19

Current–Induced Ion Concentration Polarization at a Perfect Ion–Exchange Patch in an Infinite Insulating Wall

This research examines theoretically the ion concentration polarization, ion fluxes, and electrostatic fields near an ion exchange patch in the wall of an electrified fluidic channel. These phenomena are important in related microfluidic ion-preconcentration systems. Under an electric field, counterions enter the ion-exchange patch at one side and leave at the other, with salt depletion occurring near the entrance and accumulation near the exit. Furthermore, the high patch conductivity and the concentration profiles lead to local electric field perturbations that may facilitate preconcentration. This study includes analytical expressions of ion concentrations and electrochemical potentials at small to moderate electric fields, as well as numerical simulations. Additionally, a simple matrix of polynomial coefficients (obtained via fitting of numerical data) enables analytical calculation of the 2-dimensional concentration profiles at all electric fields within the range investigated in the numerical simulations. This is possible because a single dimensionless parameter controls this problem.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effect of Many Modes on Self-Polarization and Photochemical Suppression in Cavities

The standard description of cavity-modified molecular reactions typically involves a single (resonant) mode, while in reality the quantum cavity supports a range of photon modes. In this work we demonstrate that as more photon modes are accounted for, physico-chemical phenomena can dramatically change, as illustrated by the cavity-induced suppression of the important and ubiquitous process of proton-coupled electron-transfer. Using a multi-trajectory Ehrenfest treatment for the photonmodes, we find that self-polarization effects become essential, and we introduce the concept of selfpolarization- modified Born-Oppenheimer surfaces as a new construct to analyze dynamics. As the number of cavity photon modes increases, the increasing deviation of these surfaces from the cavityfree Born-Oppenheimer surfaces, together with the interplay between photon emission and absorption inside the widening bands of these surfaces, leads to enhanced suppression. The present findings are general and will have implications for the description and control of cavity-driven physical processes of molecules, nanostructures and solids embedded in cavities.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Tunable ferroelectricity in oxygen-deficient perovskites with Grenier structure

Using first-principles calculations, we predict that tunable ferroelectricity can be realized in oxide perovskites with the Grenier structure and ordered oxygen vacancies. Specifically, we show that R 1/3 A 2/3 FeO 2.67 solids (where R is a rare-earth ion and A an alkaline-earth cation) exhibit polar phases, with a spontaneous polarization tunable by an appropriate choice of R and A. We find that larger cations combined with small R elements lead to a maximum in the polarization and to a minimum in the energy barriers required to switch the sign of the polarization. Ferroelectricity arises from cooperative distortions of octahedral and tetrahedral units, where a combination of rotational and sliding modes controls the emergence of polarization within three-dimensional connected layers. Our results indicate that polar Grenier phases of oxide perovskites are promising materials for microelectronic applications and, in general, for the study of phenomena emerging from breaking inversion symmetry in solids.

Electronic devices↗

Nonlinear dynamics of topological Dirac fermions in 2D spin-orbit coupled materials

Abstract The graphene family materials are two-dimensional staggered monolayers with a gapped energy band structure due to intrinsic spin-orbit coupling. The mass gaps in these materials can be manipulated on-demand via biasing with a static electric field, an off-resonance circularly polarized laser, or an exchange interaction field, allowing the monolayer to be driven through a multitude of topological phase transitions. We investigate the dynamics of spin-orbit coupled graphene family materials to unveil topological phase transition fingerprints embedded in the nonlinear regime and show how these signatures manifest in the nonlinear Kerr effect and in third-harmonic generation processes. We show that the resonant nonlinear spectral response of topological fermions can be traced to specific Dirac cones in these materials, enabling characterization of topological invariants in any phase by detecting the cross-polarized component of the electromagnetic field. By shedding light on the unique processes involved in harmonic generation via topological phenomena our findings open an encouraging path towards the development of novel nonlinear systems based on two-dimensional semiconductors of the graphene family.

36 MATERIALS SCIENCE↗

Corona and solar wind

The Pinhole/Occulter Facility is a powerful tool for studying the physics of the extended corona and origins of the solar wind. Spectroscopic data acquired by the P/OF coronal instruments can greatly expand empirical information about temperatures, densities, flow velocities, magnetic fields, and chemical abundances in the corona out to r or approx. 10 solar radii. Such information is needed to provide tight empirical constraints on critical physical processes involved in the transport and dissipation of energy and momentum, the heating and acceleration of plasma, and the acceleration of energetic particles. Because of its high sensitivity, high spatial and temporal resolutions, and powerful capabilities for plasma diagnostics, P/OF can significantly increase our empirical knowledge about coronal streamers and transients and thereby advance the understanding of the physics of these phenomena. P/OF observations can be used to establish the role in solar wind generation, if any, of small-scale dynamical phenomena, such as spicules, macrospicules and coronal bullets, and the role of the fine-scale structures, such as polar plumes. Finally, simultaneous measurements by the P/OF coronal and hard X-ray instruments can provide critical empirical information concerning nonthermal energy releases and acceleration of energetic particles in the corona.

Withbroe, G. L.↗

Dielectric surface properties of Venus

It has been known for over a decade that certain high-altitude regions on Venus exhibit bizarre radar-scattering and radiothermal-emission behavior. For example, observed values for normal-incidence power reflection coefficients in these areas can exceed 0.5; enhanced back scatter in some mountainous areas in the Magellan SAR images creates a bright surface with the appearance of snow; and reduced thermal emission in the anomalous areas makes the surface there appear hundreds of degrees cooler than the corresponding physical surface temperatures. The inferred radio emissivity in several of these regions falls to 0.3 for horizontal linear polarization at viewing angles in the range 20 deg - 40 deg. Several explanations have been offered for these linked phenomena. One involves single-surface reflection from a sharp discontinuity separating two media that have extremely disparate values of electromagnetic propagation. The mismatch may occur in either or both the real (associated with propagation velocity) or imaginary (associated with absorption) components of the relevant indices of refraction, and the discontinuity must take place over a distance appreciably shorter than a wavelength. An example of such an interaction of Earth would occur at the surface of a body of water. At radio wavelengths, water has an index of refraction of 9 (dielectric permittivity of about 80), and an associated loss factor that varies strongly with the amount of dissolved salts, but is generally significant. Its single-surface radar reflectivity at normal incidence is about 0.65, and the corresponding emissivity (viewed at the same angle) is therefore 0.35. Both these values are similar to the extremes found on Venus, but in the absence of liquid water, the process on Venus requires a different explanation. Two of the present authors (Pettengill and Ford) have suggested that scattering from a single surface possessing a very high effective dielectric permittivity could explain many of the unusual characteristics displayed by the Venus surface. A second explantion relates to the volume scattering that results from successive interactions with one or more interfaces interior to the planetary surface. If the near-surface material has a moderately low index of refraction (to ensure that a substantial fraction of the radiation incident from outside is not reflected, but rather penetrates into the surface), and a very low internal propagation loss, successive internal reflections can eventually redirect much of the energy back through the surface toward the viewer. The necessary conditions for this process to be effective are a low internal propagation loss coupled with efficient internal reflection. At sufficiently low temperatures, fractured water ice displays both the necessary low loss and near-total internal reflection. The possibility that this mechanism might be acting on Venus has recently been put forward.

Pettengill, G. H.↗

International Heliophysical Year

In 1957 a program of international research, inspired by the International Polar Years of 1882-83 and 1932-33, was organized as the International Geophysical Year (IGY) to study global phenomena of the Earth and geospace. The IGY involved about 60,000 scientists from 66 nations, working at thousands of stations, from pole to pole to obtain simultaneous, global observations on Earth and in space. There had never been anything like it before. The fiftieth anniversary of the International Geophysical Year will occur in 2007. We propose to organize an international program of scientific collaboration for this time period called the International Heliophysical Year (IHY). Like it predecessors, the IHY will focus on fundamental global questions of Earth science.

Davila, J. M.↗

The nature and source of solar magnetic phenomena

The heliosphere appears to be powered by coaxial helicity injection from a negative helicity injector in the northern hemisphere and a positive one in the southern hemisphere. The injector magnetic flux for both is the measured solar polar magnetic flux, and the injector voltage is generated by a simple dynamo effect due to the differential rotation of the solar surface with the polar magnetic flux. The dynamo current is estimated from the solar motion that it causes. This current also appears to sustain a thin, shallow global magnetic structure over most of the solar surface that has the form of a 1D minimum energy state. The current channel appears to be destroyed and reformed every 11 years. The currents and magnetic fields reverse in this solar cycle. A brief discussion of surface phenomena observed during this cycle is given. Plasma self-organization is briefly discussed and used in this analysis of solar data. The magnetic phenomena discussed include torsional oscillations, the heat source for the chromosphere and the corona, filaments, meridional flow, the solar cycle, sunspots, CMEs, and flares.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

An Analysis of Closure Mechanisms in the Plasma Wake of the TSS-1R Satellite

Collisionless Plasma Expansion (CPE), also known as "plasma expansion into a vacuum," in its most fundamental form, is the process by which a plasma expands into a void, or region highly depleted of particles. In CPE, the expansion is driven by the highly mobile electron constituent of the plasma as it moves across the density gradient and into the void region. A bi-polar electric field is set up between this rapidly expanding electron front and the massive ions, which have a low thermal speed and lag behind in the region of the plasma-void interface. These ions are quickly accelerated by the expansion electric field and can, theoretically, approach the thermal speed of the electrons. CPE is a fundamental and a very robust process in that it only requires that a sharp density gradient exist in a plasma. It has already been observed to exist in various plasmas ranging over five orders of magnitude in density. The range of phenomena in which CPE has been observed includes the closure of plasma wakes created in simulated space plasmas in the laboratory; it was found to be the process controlling the refilling of the wake created by the Space Shuttle in the ionospheric plasma; and recent in situ data, obtained by the WIND spacecraft as it passed through the wake of the earth's moon last year, have shown CPE to be involved in the closure of the Lunar wake. CPE is also expected to influence the morphology and physics of the solar wind interactions with Mercury and Mars, and has been suggested as a potential factor in such wide ranging phenomena as the acceleration of plasma away from the coma of comets and the energization of ions that underlies the upward expansion of the polar wind into the earth's magnetosphere. The Tethered Satellite System (TSS)-1R data provides an opportunity to test this process in situ under semi-controlled conditions. The available data shows the intensity, drift energy and angle of inclination to the wake of the converging ion streams at a down stream distance of one satellite radius (80 CM).

Stone, N. H.↗

Spacecraft-plasma interaction codes: NASCAP/GEO, NASCAP/LEO, POLAR, DynaPAC, and EPSAT

Development of a computer code to simulate interactions between the surfaces of a geometrically complex spacecraft and the space plasma environment involves: (1) defining the relevant physical phenomena and formulating them in appropriate levels of approximation; (2) defining a representation for the 3-D space external to the spacecraft and a means for defining the spacecraft surface geometry and embedding it in the surrounding space; (3) packaging the code so that it is easy and practical to use, interpret, and present the results; and (4) validating the code by continual comparison with theoretical models, ground test data, and spaceflight experiments. The physical content, geometrical capabilities, and application of five S-CUBED developed spacecraft plasma interaction codes are discussed. The NASA Charging Analyzer Program/geosynchronous earth orbit (NASCAP/GEO) is used to illustrate the role of electrostatic barrier formation in daylight spacecraft charging. NASCAP/low Earth orbit (LEO) applications to the CHARGE-2 and Space Power Experiment Aboard Rockets (SPEAR)-1 rocket payloads are shown. DynaPAC application to the SPEAR-2 rocket payloads is described. Environment Power System Analysis Tool (EPSAT) is illustrated by application to Tethered Satellite System 1 (TSS-1), SPEAR-3, and Sundance. A detailed description and application of the Potentials of Large Objects in the Auroral Region (POLAR) Code are presented.

Mandell, M. J.↗

Progress in Understanding the Pre-Earthquake Associated Events by Analyzing IR Satellite Data

We present latest result in understanding the potential relationship between tectonic stress, electro-chemical and thermodynamic processes in the Earths crust and atmosphere with an increase in IR flux as a potential signature of electromagnetic (EM) phenomena that are related to earthquake activity, either pre-, co- or post seismic. Thermal infra-red (TIR) surveys performed by the polar orbiting (NOAA/AVHRR MODIS) and geosynchronous weather satellites (GOES, METEOSAT) gave an indication of the appearance (from days to weeks before the event) of "anomalous" space-time TIR transients that are associated with the location (epicenter and local tectonic structures) and time of a number of major earthquakes with M>5 and focal depths less than 50km. We analyzed broad category of associated pre-earthquake events, which provided evidence for changes in surface temperature, surface latent heat flux, chlorophyll concentrations, soil moisture, brightness temperature, emissivity of surface, water vapour in the atmosphere prior to the earthquakes occurred in Algeria, India, Iran, Italy, Mexico and Japan. The cause of such anomalies has been mainly related to the change of near-surface thermal properties due to complex lithosphere-hydrosphere-atmospheric interactions. As final results we present examples from the most recent (2000-2004) worldwide strong earthquakes and the techniques used to capture the tracks of EM emission mid-IR anomalies and a methodology for practical future use of such phenomena in the early warning systems.

Ouzounov, Dimitar↗

Species mix & distribution function dependence of energetic-ion driven magnetospheric instabilities on DIII-D (Final Report)

Energetic ions drive a rich variety of instabilities in the complex multi-species plasma of Earth’s magnetosphere. This experiment exploited the highly flexible, high power particle beam injection capability and sophisticated diagnostic suite of the DIII-D tokamak to advance understanding of two particular instabilities of significant interest to the magnetospheric research community that have closely-related counterparts in beam-heated tokamak plasmas: electromagnetic ion cyclotron waves (EMIC) [1], observed at frequencies somewhat below the ion cyclotron frequencies of bulk ion species, and equatorial noise [2], observed at energetic-ion cyclotron harmonics. In the magnetic fusion energy domain, such waves are called ICE (Ion Cyclotron Emission). Recent substantial advances in diagnostic capability in the ion cyclotron range of frequencies in DIII-D, including measurement of wave polarization, spa)al structure and amplitude created an exciting opportunity to challenge and drive advances in theoretical understanding of these phenomena.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

HISCAT: A proposed new scatter facility in Northern Scandinavia

It is proposed that a new versatile ionospheric and atmospheric scatter radar be constructed in northern Scandavia through a multinational collaborative effort. The new facility tentatively named HISCAT (High frequency, High power, High latitude, Heating and Ionospheric Scatter facility), should be used for scientific investigations of: the physics of the neutral (middle) atmosphere; fundamental plasma phenomena, natural or artificially induced in the ionosphere; electrodynamic conditions at high altitudes above the auroral region and in the polar cap ionosphere; plasma waves in the solar atmosphere. The system should thus be able to operate as a mesosphere-stratosphere-troposphere (MST) radar, a so-called ionospheric modification facility, incoherent-scatter radar, coherent-scatter radar, and solar radar. Basically, the new facility should be a device that can operate simultaneously on several frequencies in the frequency range 5 to 50 MHz not covered by other instruments. It should comprise: powerful transmitters, capable of delivering a total average power of several megawatts; an advanced phased antenna array of high gain forming one or two steerable and well collimated beams; and an advanced data collection and analysis system.

Bostrom, R.↗

Evidence for magnetospheric effects on the sodium atmosphere of Mercury

Monochromatic images of Mercury at the sodium D2 emission line showed excess sodium emission in localized regions at high northern and southern latitudes and day-to-day global variations in the distribution of sodium emission. These phenomena support the suggestion that magnetospheric effects could be the cause. Sputtering of surface minerals could produce sodium vapor in polar regions during magnetic substorms, when magnetospheric ions directly impact the surface. Another important process may be the transport of sodium ions along magnetic field lines toward polar regions, where they impact directly on the surface of Mercury and are neutralized to regenerate neutral sodium atoms. Day-to-day variations in planetary sodium distributions could result from changing solar activity, which can change the magnetosphere in time scales of a few hours. Observations of the sodium exosphere may provide a tool for remote monitoring of the magnetosphere of Mercury.

Potter, A. E.↗

Ocean circulation using altimetry

Our group has been very actively involved in promoting satellite altimetry as a unique tool for observing ocean circulation and its variability. TOPEX/POSEIDON is particularly interesting as it is optimized for this purpose. It will probably be the first instrument really capable of observing the seasonal and interannual variability of subtropical and polar gyres and the first to eventually document the corresponding variability of their heat flux transport. The studies of these phenomena require data of the best quality, unbiased extraction of the signal, mixing of these satellite data with in situ measurements, and assimilation of the whole set into a dynamic description of ocean circulation. Our group intends to develop responses to all these requirements. We will concentrate mostly on the circulation of the South Atlantic and Indian Oceans: This will be done in close connection with other groups involved in the study of circulation of the tropical Atlantic Ocean, in the altimetry measurements (in particular, those of the tidal issue), and in the techniques of data assimilation in ocean circulation models.

Minster, Jean-Francois↗

The phase composition of Triton's polar caps

Triton's polar caps are modeled as permanent nitrogen deposits hundreds of meters thick. Complex temperature variations on Triton's surface induce reversible transitions between the cubic and hexagonal phases of solid nitrogen, often with two coexisting propagating transition fronts. Subsurface temperature distributions are calculated using a two-dimensional thermal model with phase changes. The phase changes fracture the upper nitrogen layer, increasing its reflectivity and thus offering an explanation for the surprisingly high southern polar cap albedo (approximately 0.8) seen during the Voyager 2 flyby. The model has other implications for the phase transition phenomena on Triton, such as a plausible mechanism for the origin of geyser-like plume vent areas and a mechanism of energy transport toward them.

Duxbury, N. S.↗

IRTM brightness temperature maps of the Martian south polar region during the polar night: The cold spots don't move

A series of infrared thermal mapper (IRTM) south polar brightness temperature maps obtained by Viking Orbiter 2 during a 35-day period during the southern fall season in 1978 was examined. The maps show a number of phenomena that have been identified in previous studies, including day to day brightness temperature variations in individual low temperature regions and the tendency for IRTM 11-micron channel brightness temperatures to also decrease in regions where low 20-micron channel brightness temperatures are observed. The maps also show new phenomena, the most striking of which is a clear tendency for the low brightness temperature regions to occur at fixed geographic regions. During this season, the coldest low brightness temperatures appear to be concentrated in distinct regions, with spatial scales ranging from 50 to 300 km. There are approximately a dozen of these concentrations, with the largest centered near the location of the south residual polar cap. Other concentrations are located at Cavi Angusti and close to the craters Main, South, Lau, and Dana. Broader, less intense regions appear to be well correlated with the boundaries of the south polar layered deposits and the Mountains of Mitchell. No evidence for horizontal motion of any of these regions has been detected.

Paige, D. A.↗