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All sourcesNASA NTRSDOE OSTI
NASA NTRS2000

TE/TM Simulations of Interferometric Measurements

Interferometric synthetic aperture radar (IFSAR) measurements at X-, C-, L-, and P-band are used to derive ground topography at meter level resolution. Interpretation of the derived topography requires attention due to the complex interaction of the radar signal with ground cover. The presence of penetrable surfaces such as vegetation, and tree canopies poses a challenge since the depth of penetration depends on a number of parameters such as the operating radar frequency, polarization, incident angle, as well as terrain structure. The dependence of the reconstructed topography on polarization may lead to the characterization of the ground cover. Simulation of interferometric measurements is useful for interpretation of the derived topography (B. Houshmand, Proceedings of URSI, 314, 1997). In this talk , time domain simulations for interferometric measurement for TE- and TM- polarization are presented. Time domain simulation includes the effects of the surface material property as well geometry comparable the radar signal wavelength (B. Houshmand, Proceedings of the URSI, 25, 1998). The IFSAR simulation is carried out in two steps. First, the forward scattering data is generated based on full wave analysis. Next, the electromagnetic information is inverted to generate surface topography. This inversion is based on the well known IFSAR processing technique which is composed of signal compression, and formation of an interferogram. The full wave forward scattering data is generated by the scattered-field formulation of the FDTD algorithm. The simulation is carried out by exciting the computational domain by a radar signal. The scattered field is then computed and translated to the receiving interferometric antennas using the time-domain Huygen's principle. The inversion process starts by compressing the time-domain data. The range compressed data from both receivers are then coregistered to form an interferogram. The resulting interferogram is then related to the ground topography using the radar imaging geometry. In this talk, the simulation results are compared with the C-band TM IFSAR derived topography, and the TE/TM SAR images at L-Band.

Houshmand, Bijan↗
DOE OSTI2025

CROCUS Dual Polarization Ceilometer Data at Northeastern Illinois University Rooftop

This dataset is from the Department of Energy Office of Science funded project, CROCUS Urban Integrated Field Laboratory (https://crocus-urban.org/). The dual-polarization ceilometer (Vaisala CL61) is an autonomous lidar system operating at 910 nm wavelength, providing valuable measurements for understanding atmospheric boundary layer evolution, air quality, and cloud-aerosol interactions. The CL61 measures the backscattered signal intensity alternating between parallel- and cross-polarization signals. The unique depolarization measurement capability improves discrimination between different particle types, such as liquid droplets, ice crystals, and aerosols. The depolarization is highly dependent on the scatterer shape and orientation (spherical vs non-spherical particles), with the linear depolarization ratio providing a measure of dominant backscatter signal component from atmospheric particles at various heights, essentially allowing discrimination between liquid and solid particles. With its efficient optical system, CL61’s improved signal-to-noise ratio compared to traditional ceilometers allows studying detailed vertical profiles of aerosols and clouds up to 15 km height.Datasets are stored in a netCDF data format, and we we encourage users to make use of the associated toolkits available from Unidata (https://www.unidata.ucar.edu/software/netcdf/), Project Pythia (https://foundations.projectpythia.org/core/data-formats/netcdf-cf.html), and our “Instrument Cookbooks” (https://crocus-urban.github.io/instrument-cookbooks) for more information on how to process the metadata-rich datasets.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1992

Multi-frequency multi-polarization processing for spaceborne SAR

The Shuttle Imaging Radar-C (SIR-C) is the third in a series of space shuttle based synthetic aperture radars (SAR) sponsored by the National Aeronautics and Space Administration (NASA). The SIR-C ground data processing system is to process the playbacked SAR signal data into a variety of data products for distribution to the science community. An overview of the end-to-end ground data processing system with emphasis on the unique characteristics involved in the system design is presented. Included in the discussion are science requirements, radar system specifications, input data format specifications, system operations design, data products design, processing algorithm design, hardware architecture design, and software design.

Curlander, John C.↗
DOE OSTI2017

Electrochemical Energy Storage with a Reversible Nonaqueous Room-Temperature Aluminum-Sulfur Chemistry

A reversible room-temperature aluminum–sulfur (Al-S) battery is demonstrated with a strategically designed cathode structure and an ionic liquid electrolyte. Discharge–charge mechanism of the Al-S battery is proposed based on a sequence of electrochemical, microscopic, and spectroscopic analyses. The electrochemical process of the Al-S battery involves the formation of a series of polysulfides and sulfide. The high-order polysulfides (S x 2- , x ≥ 6) are soluble in the ionic liquid electrolyte. Electrochemical transitions between S 6 2 - and the insoluble low-order polysulfides or sulfide (S x 2- , 1 ≤ x < 6) are reversible. A single-wall carbon nanotube coating applied to the battery separator helps alleviate the diffusion of the polysulfide species and reduces the polarization behavior of the Al-S batteries.

25 ENERGY STORAGE↗
NASA NTRS1981

Shuttle imaging radar - Research sensor for earth resources observation

The operating characteristics of the Shuttle Imaging Radar (SIR) and intended experimentation to study the effects of the incidence angle, look direction, frequency, and polarization are described. SIR will be flown in 1984-1986, operate in the L- and C-bands, and have a look angle which can be varied through 15-75 deg. Polarizations of HH on the L-band and HH, VV, HV, and VH on the C-band are possible. The SIR will provide 10 and 30 m resolutions in the high and low resolution modes, respectively, with a swatch width between 35-125 km. Real-time to ground and on-board optical recording will be available, together with digital and optical processing. The antennas will be rotated in the Shuttle bay in 5 deg increments, permitting the formation of stereo pictures during several overpasses. Viewing at 1275 MHz is intended for imaging, while the 5300 MHz band can sense soil moisture

Elachi, C.↗
DOE OSTI2024

Special Observing Period (SOP) data for the Year of Polar Prediction site Model Intercomparison Project (YOPPsiteMIP)

The rapid changes occurring in the polar regions require an improved understanding of the processes that are driving these changes. At the same time, increased human activities such as marine navigation, resource exploitation, aviation, commercial fishing, and tourism require reliable and relevant weather information. One of the primary goals of the World Meteorological Organization's Year of Polar Prediction (YOPP) project is to improve the accuracy of numerical weather prediction (NWP) at high latitudes. During YOPP, two Canadian “supersites” were commissioned and equipped with new ground-based instruments for enhanced meteorological and system process observations. Additional pre-existing supersites in Canada, the United States, Norway, Finland, and Russia also provided data from ongoing long-term observing programs. These supersites collected a wealth of observations that are well suited to address YOPP objectives. In order to increase data useability and station interoperability, novel Merged Observatory Data Files (MODFs) were created for the seven supersites over two Special Observing Periods (February to March 2018 and July to September 2018). All observations collected at the supersites were compiled into this standardized NetCDF MODF format, simplifying the process of conducting pan-Arctic NWP verification and process evaluation studies. This paper describes the seven Arctic YOPP supersites, their instrumentation, data collection and processing methods, the novel MODF format, and examples of the observations contained therein. MODFs comprise the observational contribution to the model intercomparison effort, termed YOPP site Model Intercomparison Project (YOPPsiteMIP). All YOPPsiteMIP MODFs are publicly accessible via the YOPP Data Portal (Whitehorse: https://doi.org/10.21343/a33e-j150, Huang et al., 2023a; Iqaluit: https://doi.org/10.21343/yrnf-ck57, Huang et al., 2023b; Sodankylä: https://doi.org/10.21343/m16p-pq17, O'Connor, 2023; Utqiagvik: https://doi.org/10.21343/a2dx-nq55, Akish and Morris, 2023c; Tiksi: https://doi.org/10.21343/5bwn-w881, Akish and Morris, 2023b; Ny-Ålesund: https://doi.org/10.21343/y89m-6393, Holt, 2023; and Eureka: https://doi.org/10.21343/r85j-tc61, Akish and Morris, 2023a), which is hosted by MET Norway, with corresponding output from NWP models.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

THE PHYSICAL ENVIRONMENT OF THE MASSIVE STAR-FORMING REGION W42

We present an analysis of multi-wavelength observations from various data sets and Galactic plane surveys to study the star-formation process in the W42 complex. A bipolar appearance of the W42 complex is evident due to the ionizing feedback from the O5–O6 type star in a medium that is highly inhomogeneous. The Very Large Telescope/NACO adaptive-optics K and L{sup ′} images (resolutions ∼0.″2–0.″1) resolved this ionizing source into multiple point-like sources below ∼5000 AU scale. The position angle ∼15° of the W42 molecular cloud is consistent with the H-band starlight mean polarization angle, which in turn is close to the Galactic magnetic field, suggesting the influence of the Galactic field on the evolution of the W42 molecular cloud. Herschel sub-millimeter data analysis reveals three clumps located along the waist axis of the bipolar nebula, with the peak column densities of ∼(3–5) × 10{sup 22} cm{sup −2} corresponding to visual extinctions of A{sub V} ∼ 32–53.5 mag. The Herschel temperature map traces a temperature gradient in W42, revealing regions of 20 K, 25 K, and 30–36 K. Herschel maps reveal embedded filaments (length ∼1–3 pc) that appear to be radially pointed to the denser clump associated with the O5–O6 star, forming a hub-filament system. A total of 512 candidate young stellar objects (YSOs) are identified in the complex, ∼40% of which are present in clusters distributed mainly within the molecular cloud, including the Herschel filaments. Our data sets suggest that the YSO clusters, including the massive stars, are located at the junction of the filaments, similar to those seen in the Rosette Molecular Cloud.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1987

The role of minerals in the thermal alteration of organic matter. III - Generation of bitumen in laboratory experiments

A series of pyrolysis experiments, utilizing two different immature kerogens (from the Monterey and Green River Formations) mixed with common sedimentary minerals (calcite, illite, or Na-montmorillonite), was conducted to study the impact of the mineral matrix on the bitumen that was generated. Calcite has no significant influence on the thermal evolution of bitumen and also shows virtually no adsorption capacity for any of the pyrolysate. In contrast, montmorillonite (M) and illite, to a lesser extent, alter bitumen during dry pyrolysis. M and illite also display strong adsorption capacities for the polar constituents of bitumen. By this process, hydrocarbons are substantially concentrated within the pyrolysate that is not strongly adsorbed on the clay matrices. The effects of the clay minerals are significantly reduced during hydrous pyrolysis. The strong adsorption capacities of M and illite, as well as their thermocatalytic properties, may in part explain why light oils and gases are generated from certain argillaceous source-rock assemblages, whereas heavy immature oils are often derived from carbonate source rocks.

Huizinga, Bradley J.↗
DOE OSTI2018

Improving Corrosion Resistance of 316L Austenitic Stainless Steel Using ZrO{sub 2} Sol-Gel Coating in Nitric Acid Solution

In this study, thin-film coating of zirconium oxide (ZrO{sub 2}) was prepared by sol-gel method and subsequent heat treatment process. The sol was prepared by controlled hydrolysis of zirconium tetrapropoxide using acetic acid and ethanol/acetylacetone mixture as catalyst and chelating agent, respectively, and finally deposited onto the 316L austenitic stainless steel (316L SS) using dip coating method in order to improve its corrosion resistance in nitric acid medium. The composition, structure, and morphology of the coated surface were investigated by x-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and atomic force microscopy (AFM). The obtained results from XRD and FTIR state the formation of tetragonal and monoclinic ZrO{sub 2} phase. Also, the obtained results from surface morphology investigation by SEM and AFM indicate the formation of smooth, homogeneous and uniform coatings on the steel substrate. Then, the corrosion behavior of stainless steel was investigated in a 1 and 10 M nitric acid solutions using electrochemical impedance spectroscopy and linear polarization test. The obtained results from these tests for ZrO{sub 2}-coated specimens indicated a considerable improvement in the corrosion resistance of 316L stainless steel by an increase in corrosion potential and transpassive potential, and a decrease in passive current density and corrosion current density. The decrease in passive current density in both the concentration of solutions was two orders of magnitude from bare to coated specimens.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Ni{sub 0.36}Al{sub 0.10}Cu{sub 0.30}Fe{sub 0.24} Metallic Inert Anode for the Electrochemical Production of Fe-Ni Alloy in Molten K{sub 2}CO{sub 3}-Na{sub 2}CO{sub 3}

In this paper, a Ni{sub 0.36}Al{sub 0.10}Cu{sub 0.30}Fe{sub 0.24} metallic inert anode was proposed and the electrochemical behaviors were studied in molten K{sub 2}CO{sub 3}-Na{sub 2}CO{sub 3} at 1023 K by polarization curves and Tafel plots. The results indicated that Ni{sub 0.36}Al{sub 0.10}Cu{sub 0.30}Fe{sub 0.24} alloy was stable in carbonate due to the formation of a passivation film on the surface. The film was mainly composed of NiFe{sub 2}O{sub 4} and Al{sub 2}O{sub 3} with a dense structure, which inhibited further corrosion of anode. Moreover, oxygen gas and Fe-Ni alloy have been successfully generated through electrolysis with NiO-Fe{sub 2}O{sub 3} pellet as cathode and Ni{sub 0.36}Al{sub 0.10}Cu{sub 0.30}Fe{sub 0.24} alloy as anode under a potential of 1.9 V for 24 hours. Ni{sub 0.36}Al{sub 0.10}Cu{sub 0.30}Fe{sub 0.24} alloy exhibited bright prospect as a potential candidate of inert anode for green metallurgical process.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Piezoelectric domains in the AlGaN hexagonal microrods: Effect of crystal orientations

Presently, the piezoelectric materials are finding tremendous applications in the micro-mechanical actuators, sensors, and self-powered devices. In this context, the studies pertaining to piezoelectric properties of materials in the different size ranges are very important for the scientific community. The III-nitrides are exceptionally important, not only for optoelectronic but also for their piezoelectric applications. In the present study, we synthesized AlGaN via self-catalytic vapor-solid mechanism by atmospheric pressure chemical vapor deposition technique on AlN base layer over intrinsic Si(100) substrate. The growth process is substantiated using X-ray diffraction and X-ray photoelectron spectroscopy. The Raman and photoluminescence studies reveal the formation of AlGaN microrods in the wurtzite phase and ensure the high optical quality of the crystalline material. The single crystalline, direct wide band gap and hexagonally shaped AlGaN microrods are studied for understanding the behavior of the crystallites under the application of constant external electric field using the piezoresponse force microscopy. The present study is mainly focused on understanding the behavior of induced polarization for the determination of piezoelectric coefficient of AlGaN microrod along the c-axis and imaging of piezoelectric domains in the sample originating because of the angular inclination of AlGaN microrods with respect to its AlN base layers.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

Direct-write laser-assisted patterning of form birefringence in wave plates fabricated by glancing-angle deposition

The development of optics that provide spatial control of birefringence could enable better control of laser beam polarization, but available solutions are limited. Here we demonstrate a method to locally modify the birefringence of wave plates fabricated by glancing-angle deposition. The method employs localized melting of the anisotropic microstructure in a vacuum environment to alter the local birefringence. We demonstrate that this process is only possible under high vacuum to avoid trapping air within the melt zone. The direct-write method presented here can be readily utilized for coatings exhibiting form birefringence of virtually any chemical composition, size, and format.

42 ENGINEERING↗
NASA NTRSDate not supplied

CALIGOLA: A New Spaceborne Lidar Mission

Agenzia Spaziale Italiana (ASI) and NASA are partnering on an exciting new spaceborne lidar mission known as CALIGOLA (i.e., the Cloud and Aerosol Lidar for Global Scale observations of the Ocean-Land-Atmosphere) that seeks to significantly advance our understanding of Earth’s coupled ocean-land-atmosphere systems. By flying an innovative multi-wavelength, polarization-sensitive Raman lidar that will simultaneously acquire elastic backscatter and fluorescence measurements, CALIGOLA will provide new insights into the processes that influence climate, weather, and air quality by vertically profiling microphysical and optical properties of clouds and aerosols. The mission will also probe phytoplankton biomass and zooplankton dynamics and provide observations of surface vegetation, ice, and snow. The mission is planned for launch early next decade and baselined to fly in an orbit that is compatible with NASA’s AOS-Sky mission. This formation flying configuration will enable synergistic retrievals between observations from CALIGOLA and the polarimeter and radar measurements planned for AOS-Sky and thus greatly enhance our ability to explore and characterize the intricate processes that govern the interactions between different components of the Earth system. The presentation will highlight CALIGOLA’s significant science objectives and describe the pioneering instrument that will enable us to achieve these objectives.

Chip Trepte↗
NASA NTRS2008

Proceedings of the 39th Lunar and Planetary Science Conference

Sessions with oral presentations include: A SPECIAL SESSION: MESSENGER at Mercury, Mars: Pingos, Polygons, and Other Puzzles, Solar Wind and Genesis: Measurements and Interpretation, Asteroids, Comets, and Small Bodies, Mars: Ice On the Ground and In the Ground, SPECIAL SESSION: Results from Kaguya (SELENE) Mission to the Moon, Outer Planet Satellites: Not Titan, Not Enceladus, SPECIAL SESSION: Lunar Science: Past, Present, and Future, Mars: North Pole, South Pole - Structure and Evolution, Refractory Inclusions, Impact Events: Modeling, Experiments, and Observations, Mars Sedimentary Processes from Victoria Crater to the Columbia Hills, Formation and Alteration of Carbonaceous Chondrites, New Achondrite GRA 06128/GRA 06129 - Origins Unknown, The Science Behind Lunar Missions, Mars Volcanics and Tectonics, From Dust to Planets (Planetary Formation and Planetesimals):When, Where, and Kaboom! Astrobiology: Biosignatures, Impacts, Habitability, Excavating a Comet, Mars Interior Dynamics to Exterior Impacts, Achondrites, Lunar Remote Sensing, Mars Aeolian Processes and Gully Formation Mechanisms, Solar Nebula Shake and Bake: Mixing and Isotopes, Lunar Geophysics, Meteorites from Mars: Shergottite and Nakhlite Invasion, Mars Fluvial Geomorphology, Chondrules and Chondrule Formation, Lunar Samples: Chronology, Geochemistry, and Petrology, Enceladus, Venus: Resurfacing and Topography (with Pancakes!), Overview of the Lunar Reconnaissance Orbiter Mission, Mars Sulfates, Phyllosilicates, and Their Aqueous Sources, Ordinary and Enstatite Chondrites, Impact Calibration and Effects, Comparative Planetology, Analogs: Environments and Materials, Mars: The Orbital View of Sediments and Aqueous Mineralogy, Planetary Differentiation, Titan, Presolar Grains: Still More Isotopes Out of This World, Poster sessions include: Education and Public Outreach Programs, Early Solar System and Planet Formation, Solar Wind and Genesis, Asteroids, Comets, and Small Bodies, Carbonaceous Chondrites, Chondrules and Chondrule Formation, Chondrites, Refractory Inclusions, Organics in Chondrites, Meteorites: Techniques, Experiments, and Physical Properties, MESSENGER and Mercury, Lunar Science Present: Kaguya (SELENE) Results, Lunar Remote Sensing: Basins and Mapping of Geology and Geochemistry, Lunar Science: Dust and Ice, Lunar Science: Missions and Planning, Mars: Layered, Icy, and Polygonal, Mars Stratigraphy and Sedimentology, Mars (Peri)Glacial, Mars Polar (and Vast), Mars, You are Here: Landing Sites and Imagery, Mars Volcanics and Magmas, Mars Atmosphere, Impact Events: Modeling, Experiments, and Observation, Ice is Nice: Mostly Outer Planet Satellites, Galilean Satellites, The Big Giant Planets, Astrobiology, In Situ Instrumentation, Rocket Scientist's Toolbox: Mission Science and Operations, Spacecraft Missions, Presolar Grains, Micrometeorites, Condensation-Evaporation: Stardust Ties, Comet Dust, Comparative Planetology, Planetary Differentiation, Lunar Meteorites, Nonchondritic Meteorites, Martian Meteorites, Apollo Samples and Lunar Interior, Lunar Geophysics, Lunar Science: Geophysics, Surface Science, and Extralunar Components, Mars, Remotely, Mars Orbital Data - Methods and Interpretation, Mars Tectonics and Dynamics, Mars Craters: Tiny to Humongous, Mars Sedimentary Mineralogy, Martian Gullies and Slope Streaks, Mars Fluvial Geomorphology, Mars Aeolian Processes, Mars Data and Mission,s Venus Mapping, Modeling, and Data Analysis, Titan, Icy Dwarf Satellites, Rocket Scientist's Toolbox: In Situ Analysis, Remote Sensing Approaches, Advances, and Applications, Analogs: Sulfates - Earth and Lab to Mars, Analogs: Remote Sensing and Spectroscopy, Analogs: Methods and Instruments, Analogs: Weird Places!. Print Only Early Solar System, Solar Wind, IDPs, Presolar/Solar Grains, Stardust, Comets, Asteroids, and Phobos, Venus, Mercury, Moon, Meteorites, Mars, Astrobiology, Impacts, Outer Planets, Satellites, and Rings, Support for Mission Operations, Analog Education and Public Outreach.

Source record↗
NASA NTRS1982

Double layer formation

An investigation is conducted of the plasma processes which occur during the formation of a double layer in response to an applied initial electric field, when triggered by a current in the plasma. The important feature of the formation process was the creation of an ion-rich plasma-density cavity. The positive space charge of the cavity was shielded by induction of a negative space charge on the low potential side of the cavity, giving rise to the formation of a fully developed double layer. The shielding was complete only when the electron current from the low potential side exceeded the electron thermal current. It was found that during the formation of double layers counterstreaming electrons are generated. Moreover, transient double layers with reverse polarity also occur during this phase. Thus, the recurring formation of double layers can give rise to flickering double layers.

Singh, N.↗
DOE OSTI2022

Understanding Hydrogenation Chemistry at MgB 2 Reactive Edges from Ab Initio Molecular Dynamics

Solid-state hydrogen storage materials often operate via transient, multistep chemical reactions at complex interfaces that are difficult to capture. Here, we use direct ab initio molecular dynamics simulations at accelerated temperatures and hydrogen pressures to probe the hydrogenation chemistry of the candidate material MgB 2 without a priori assumption of reaction pathways. Focusing on highly reactive ($10\overline{1}0$) edge planes where initial hydrogen attack is likely to occur, we track mechanistic steps toward the formation of hydrogen-saturated BH 4 – units and key chemical intermediates, involving H 2 dissociation, generation of functionalities and molecular complexes containing BH 2 and BH 3 motifs, and B–B bond breaking. Further, the genesis of higher-order boron clustering is also observed. Different charge states and chemical environments at the B-rich and Mg-rich edge planes are found to produce different chemical pathways and preferred speciation, with implications for overall hydrogenation kinetics. The reaction processes rely on B–H bond polarization and fluctuations between ionic and covalent character, which are critically enabled by the presence of Mg 2+ cations in the nearby interphase region. Our results provide guidance for devising kinetic improvement strategies for MgB 2 -based hydrogen storage materials, while also providing a template for exploring chemical pathways in other solid-state energy storage reactions.

08 HYDROGEN↗
NASA NTRS2019

Tropopause Laminar Cirrus and Its Role in the Lower Stratosphere Total Water Budget

Laminar cirrus are thin, extensive, isolated layers of ice clouds frequently observed in the tropical tropopause layer. Widespread laminar cirrus significantly affects tropical tropopause layer total water and thermal budget. In this study, we extract laminar cirrus from the Cloud‐Aerosol Lidar with Orthogonal Polarization Level 1 attenuated total backscatter images for January 2009, in order to characterize statistical properties of laminar cirrus cloud length, base, thickness, optical depth, and layer partial ice water path. These characteristics are used to develop an algorithm identifying laminar cirrus automatically from the Cloud‐Aerosol Lidar with Orthogonal Polarization Level 2 layer product for 2008–2017. The nearly 10‐year records reveal that tropopause laminar cirrus occurrence (30–40% of total cirrus) is strongly anticorrelated with the tropopause temperatures in that colder tropopause in frequent (super)saturation during boreal winter favors in situ formation of clouds. Interannually, anomalously warmer troposphere temperature (ΔT), easterly shear of the quasi‐biennial oscillation, and stronger upwelling branch of the Brewer‐Dobson circulation enhance laminar cirrus formation via cooling of the tropopause. The tropopause laminar cirrus carries ~0.05 mg/m(exp 3) (~0.5 ppmv) of ice water content during boreal winter and <0.01 mg/m(exp 3) during summer, which is anticorrelated with the seasonal variations of water vapor (H2O) observed by the Microwave Lime Sounder, indicating a temperature‐regulated partition between vapor and ice. Interannually, in cirrus‐rich region 1 ppmv decrease in H2O corresponds to 0.2–0.3 ppmv increase in ice water content. Frequently situated in (super)saturated air, tropopause laminar cirrus are likely to survive multiple lifecycles of the sublimation‐deposition processes, and may contribute up to 10% to the total water budget in the lower stratosphere. Satellites constantly observe thin, isolated, extensive layer of cirrus around the tropopause. The so‐called “laminar” cirrus occurrence and their ice amount are strongly regulated by temperature, such that colder temperatures favor more frequent (super)saturation, which results in more frequent laminar cirrus with more ice amount and therefore less water vapor. In this study we analyze laminar cirrus and water vapor from the Cloud‐Aerosol Lidar with Orthogonal Polarization and Microwave Lime Sounder observations, and hypothesize that laminar cirrus could act as an important transient water storage and contribute to the total water budget in the lower stratosphere.

Tao Wang↗
DOE OSTI2017

Capacitive Deionization Using Alternating Polarization: Effect of Surface Charge on Salt Removal

Alternating polarization (AP) at ±1.2/0 V is performed on a capacitive deionization stack assembled with carbon xerogel (CX) electrodes. Long-term testing shows enhanced cycling stability without the formation of inversion peaks. AP also leads to an arch-shaped plot of salt adsorption capacity (SAC) versus cycling time, with the highest SAC of approximately 3 mg (NaCl) g −1 (CX) during this long-term test. Characterization of both the freshly prepared and cycled electrodes depict that AP results in surface charge of all the electrodes being modified from positive to negative character. Here by leveraging balances of electronic, surface, and ionic charges in carbon micropores, it is found that a portion of the electronic charge contributes to the ionic charge for salt adsorption, and another portion is parasitically consumed to balance the surface charge during the charge reconciliation process. When the consumption of electronic charge for charge reconciliation becomes minimal, both the positive and negative surface charges are nearly equivalent on the CX electrode. Under such a condition, the highest SAC values can be achieved for AP testing.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗