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NASA NTRS2003

The Organic Component of Interstellar Dust

The distribution, chemical structure, and formation of organic matter in the interstellar medium are important to our understanding of the overall evolution of dust. The exchange of dust between the dense and diffuse interstellar medium, and the effects of processing on dust within dense clouds will affect the inventory of material available for incorporation into newly forming star and planetary systems. Observational ground-based studies have confirmed the widespread distribution of the 3.4 pm absorption band attributed to aliphatic hydrocarbons in the diffuse interstellar medium of our own galaxy, and in the dusty spectra of a few nearby galaxies, while space based observations from IS0 probed the signatures of corresponding mid-infrared features. Laboratory experiments which utilize both thermal processes and energetic processing by high energy photons and cosmic rays, produce candidate materials which offer close matches to the observed diffuse interstellar medium and extragalactic hydrocarbon absorption features. Through an analysis of the 4000 to 1000 cm (2.5 to 10 micrometers) region of the spectrum of diffuse interstellar medium (DISM) dust compared with the spectra of thirteen chemical entities produced in the laboratory which serve as analogs to the interstellar material, significant constraints have been placed on the applicability of proposed candidate materials to explain the interstellar features. The results indicate that the organic refractory material in the diffuse interstellar medium is predominantly hydrocarbon in nature, possessing little nitrogen or oxygen, with the carbon distributed between the aromatic and aliphatic forms. Long alkane chains H3C-(CH2),- with n much greater than 4 or 5 are not major constituents of this material. Comparisons to laboratory analogs indicate the DISM organic material resembles plasma processed pure hydrocarbon residues much more so than energetically processed ice residues. This result is consistent with a birthsite for the carrier of the 3.4 micrometers band in the outflow region of evolved carbon stars. Comparisons of dust from our own galaxy with that of distant galaxies suggests that the organic component of interstellar dust is widespread and may be an important universal reservoir of prebiotic organic carbon.

Pendleton, Yvonne↗

NASA NTRS1999

Probing porous media with gas diffusion NMR

We show that gas diffusion nuclear magnetic resonance (GD-NMR) provides a powerful technique for probing the structure of porous media. In random packs of glass beads, using both laser-polarized and thermally polarized xenon gas, we find that GD-NMR can accurately measure the pore space surface-area-to-volume ratio, S/V rho, and the tortuosity, alpha (the latter quantity being directly related to the system's transport properties). We also show that GD-NMR provides a good measure of the tortuosity of sandstone and complex carbonate rocks.

NASA Discipline Environmental Health↗

NASA NTRS2007

Isotopic Measurements in CAIs with the Nanosims: Implications to the understanding of the Formation process of Ca, Al-Rich Inclusions

Ca, Al-rich Inclusions (CAIs) preserve evidence of thermal events that they experienced during their formation in the early solar system. Most CAIs from CV and CO chondrites are characterized by large variations in O-isotopic compositions of primary minerals, with spinel, hibonite, and pyroxene being more O-16-rich than melilite and anorthite, with delta 17, O-18 = approx. -40%o (DELTA O-17 = delta O-17 - 0.52 x delta O-18 = approx. - 20%o ). These anomalous compositions cannot be accounted for by standard mass dependent fractionation and diffusive process of those minerals. It requires the presence of an anomalous oxygen reservoir of nucleosynthetic origin or mass independent fractionations before the formation of CAIs in the early solar system. The CAMECA NanoSIMS is a new generation ion microprobe that offers high sensitivity isotopic measurements with sub 100 nm spatial resolution. The NanoSIMS has significantly improved abilities in the study of presolar grains in various kind of meteorites and the decay products of extinct nuclides in ancient solar system matter. This instrument promises significant improvements over other conventional ion probes in the precision isotopic characterization of sub-micron scales. We report the results of our first O isotopic measurements of various CAI minerals from EK1-6-3 and 7R19-1(a) utilizing the JSC NanoSIMS 50L ion microprobe. We evaluate the measurement conditions, the instrumental mass fractionation factor (IMF) for O isotopic measurement and the accuracy of the isotopic ratio through the analysis of a San Carlos olivine standard and CAI sample of 7R19-1(a).

Ito, M.↗

NASA NTRS2002

Large Eddy Simulation of Cryogenic Injection Processes at Supercritical Pressure

This paper highlights results from the first of a series of hierarchical simulations aimed at assessing the modeling requirements for application of the large eddy simulation technique to cryogenic injection and combustion processes in liquid rocket engines. The focus is on liquid-oxygen-hydrogen coaxial injectors at a condition where the liquid-oxygen is injected at a subcritical temperature into a supercritical environment. For this situation a diffusion dominated mode of combustion occurs in the presence of exceedingly large thermophysical property gradients. Though continuous, these gradients approach the behavior of a contact discontinuity. Significant real gas effects and transport anomalies coexist locally in colder regions of the flow, with ideal gas and transport characteristics occurring within the flame zone. The current focal point is on the interfacial region between the liquid-oxygen core and the coaxial hydrogen jet where the flame anchors itself.

Oefelein, Joseph C.↗

NASA NTRS2002

Large Eddy Simulation of Cryogenic Injection Processes at Supercritical Pressure

Oefelein, Joseph C.↗

NASA NTRS1994

A study of glow-discharge and permeation techniques for extraterrestrial oxygen beneficiation

Extraction of oxygen from Martian atmosphere and compression of lunar oxygen can utilize stabilized zirconia electrochemical pumps. Silver membranes can be used as electrodes to increase oxygen yield at relatively low temperatures. This study has investigated oxygen permeation through Ag 0.05Zr membranes with glow-discharge assisted disassociation. Data show that the overall process is controlled by bulk diffusion but the slow dissociative adsorption onto the surface limited the overall transport substantially. With glow-discharge assisted dissociation, an order of magnitude increase in oxygen throughput can be produced at relatively low temperatures (450-550C).

Ash, R. L.↗

NASA NTRS1993

Numerical Study of the Transient Vaporization of an Oxygen Droplet at Sub- and Super-Critical Conditions

Unsteady vaporization of a droplet in a high-pressure quiescent environment has been studied. With spherical symmetry and constant pressure, the process is diffusion controlled. At low pressures droplet heating is significant for most of the droplet lifetime, and an unsteady analysis of the gas phase is required. Then, the vaporization of a liquid oxygen droplet in gaseous hydrogen at moderate and high pressures is considered. At super-critical pressures, the surface temperature reaches the computed critical mixture value where a model for super-critical combustion is needed. The details of the diffusion layer of dissolved hydrogen do not significantly affect the results. Various methods are explored to compute the gas-phase density. Under the model's assumptions, homogeneous nucleation is not likely to occur.

Delplanque, J.-P.↗

NASA NTRS1981

Wind induced composition effects at high latitudes

The temperature and compositional structure of the upper atmosphere are discussed in relation to the impacts of wind-induced diffusion processes. Seasonal variations in thermospheric temperature and composition are explained by energy and mass transport from the summer to the winter hemisphere induced by preferential heating, with the winter oxygen bulge participating in a feedback mechanism which acts to dampen wind velocities and increase temperature contrast. Changes in the eddy diffusion coefficient are considered as a complementary mechanism of producing the seasonal anomalies. The role of winds induced by high-latitude heating by particles and Joule dissipation during magnetic storms and substorms in accounting for thermospheric density increases and N2 and Ar enhancements and O and He depletions at high latitudes are discussed, and the rather weak compositional signature of E x B momentum coupling is distinguished from the effects of Joule dissipation.

Mayr, H. G.↗

NASA NTRS1992

Venus lower thermosphere studies

Studies undertaken in this project have sought to understand lower thermospheric structure and dynamics (less than or equal to 145 km), particularly the processes responsible. This is a region just below the reach of in-situ instruments onboard PVO (Pioneer Venus Orbiter) during the first few diurnal cycles. PVO remote airglow observations (nitric oxide, O2, visible, O 1304A) have been coupled with ground-based observations (CO densities, winds, temperatures, O2 IR nightglow) to address the behavior of lower thermospheric winds and chemistry over 95 to 150 km. This interpretation of PVO and related data is accomplished by using the NCAR Venus thermospheric general circulation model (VTGCM) (Bougher et al., 1988; 1990). This model has been modified over the last two years to improve its ability to calculate O, CO, and O2 densities, temperatures, nightglow, and subsolar-to-antisolar and zonal winds over 95 to 150 km (Bougher and Borucki, 1992). Our VTGCM studies show that: (1) O2 visible and IR nightglow distributions can be used to trace lower thermosphere / upper mesosphere winds over 100-130 km. Typically, weak zonal winds (less than or equal to 25 m/sec) and nightglow maximum patches near 0100 LT prevail. Occasionally, strong zonal winds (30-60 m/sec) and airglow patches peaking near 0300 LT characterize the Venus lower thermosphere. (2) It is clear that the dynamics of the Venus 90-130 km region is highly variable on time scales as short as an hour. This is most likely due to the time variable nature of upward propagating gravity waves, which grow in amplitude and eventually break. The resulting turbulence gives rise to local time variable eddy diffusion and momentum drag, both of which strongly impact global density and nightglow distributions. (3) The oxygen chemistry (O, O2, etc.) over 90-120 km is strongly dependent on HO(x) and CLO(x) tracer species that must be properly included in any coupled chemical dynamical model. (4) The density profiles of light species (O, CO, N, He) are strongly affected by large-scale transport by the winds. Strong eddy diffusion is not a suitable model parameterization for approximating these light species, especially for extrapolation into the region below 140 km where PVO in-situ data is lacking. Instead, the fully coupled chemical dynamical VTGCM model should be used to improve estimates of densities within the VTS3 empirical model (Hedin et al., 1983) below 140 km.

Bougher, Stephen W.↗

NASA NTRS1986

Effect of an oxygen plasma on the physical and chemical properties of several fluids for the liquid droplet radiator

The Liquid Droplet Radiator is one of several radiator systems currently under investigation by NASA Lewis Research Center. It involves the direct exposure of the radiator working fluid to the space environment. An area of concern is the potential harmful effects of the low-Earth-orbit atomic oxygen environment on the radiator working fluid. To address this issue, seven candidate fluids were exposed to an oxygen plasma environment in a laboratory plasma asher. The fluids studied included Dow Corning 705 Diffusion Pump Fluid, polymethylphenylsiloxane and polydimethlsiloxane, both of which are experimental fluids made by Dow Corning, Fomblin Z25, made by Montedison, and three fluids from the Krytox family of fluids, Krytox 143AB, 1502, and 16256, which are made by DuPont. The fluids were characterized by noting changes in visual appearance, physical state, mass, and infrared spectra. Of the fluids tested, the Fomblin and the three Krytoxes were the least affected by the oxygen plasma. The only effect noted was a change in mass, which was most likely due to an oxygen-catalyzed deploymerization of the fluid molecule.

Gulino, D. A.↗

NASA NTRS1987

Effect of an oxygen plasma on the physical and chemical properties of several fluids for the Liquid Droplet Radiator

The Liquid Droplet Radiator is one of several radiator systems currently under investigation by NASA Lewis Research Center. It involves the direct exposure of the radiator working fluid to the space environment. An area of concern is the potential harmful effects of the low-Earth-orbit atomic oxygen environment on the radiator working fluid. To address this issue, seven candidate fluids were exposed to an oxygen plasma environment in a laboratory plasma asher. The fluids studied included Dow Corning 705 Diffusion Pump Fluid, polymethylphenylsiloxane and polydimethylsiloxane, both of which are experimental fluids made by Dow Corning, Fomblin Z25, made by Montedison, and three fluids from the Krytox family of fluids, Krytox 143AB, 1502, and 16256, which are made by DuPont. The fluids were characterized by noting changes in visual appearance, physical state, mass, and infrared spectra. Of the fluids tested, the Fomblin and the three Krytoxes were the least affected by the oxygen plasma. The only effect noted was a change in mass, which was most likely due to an oxygen-catalyzed depolymerization of the fluid molecule.

Gulino, Daniel A.↗

NASA NTRS2004

Stressed Oxidation Life Prediction for C/SiC Composites

The residual strength and life of C/SiC is dominated by carbon interface and fiber oxidation if seal coat and matrix cracks are open to allow oxygen ingress. Crack opening is determined by the combination of thermal, mechanical and thermal expansion mismatch induced stresses. When cracks are open, life can be predicted by simple oxidation based models with reaction controlled kinetics at low temperature, and by gas phase diffusion controlled kinetics at high temperatures. Key life governing variables in these models include temperature, stress, initial strength, oxygen partial pressure, and total pressure. These models are described in this paper.

Levine, Stanley R.↗

NASA NTRS1974

The chemistry and diffusion of aircraft exhausts in the lower stratosphere during the first few hours after fly-by

An analysis of the hydrogen-nitrogen-oxygen reaction systems in the lower stratosphere as they are initially perturbed by individual aircraft engine exhaust plumes was conducted in order to determine whether any significant chemical reactions occur, either among exhaust chemical species, or between these species and the environmental ozone, while the exhaust products are confined to intact plume segments at relatively high concentrations. The joint effects of diffusive mixing and chemical kinetics on the reactions were also studied, using the techniques of second-order closure diffusion/chemistry models. The focus of the study was on the larger problem of the potential depletion of ozone by supersonic transport aircraft exhaust materials emitted into the lower stratosphere.

Hilst, G. R.↗

NASA NTRSDate not supplied

Extinction of Solid Diffusion Flame in Microgravity: Details of Quenching and Blowoff Processes

Long duration microgravity experiments aboard the International Space Station determine diffusion flame extinction limits of PMMA spheres. Upon ignition from an electrically-heated coil, the 4-cm-diameter samples are exposed to forced flows ranging from 0.2 to 80 cm/s and an oxygen ranging from 13 to 28% in one atmosphere total pressure. Extinction is reached as oxygen concentration gradually decreases by natural depletion. Five extinction tests are presented at different flow velocities and oxygen concentrations. Quenching at low velocity is observed with the flame tip shrinking upstream and blowoff is observed when a hole forms in the flame at the forward flow stagnation point. However, these processes are not quasistatic. The quenching motion involves periodic flame tip pulsating toward downstream and shrinking upstream with a continually decreasing flame size at the end of each cycle. In blowoff, the flame base pulsates between the flame hole and the downstream location, although with far fewer cycles compared to quenching. The pulsations appear to be the result of a premixed flame front spreading into a combustible mixture. Two specific cases are discussed. In the first, at very low flow velocity (~ 0.4 cm/s) and elevated oxygen, self-sustained flame tip cyclic pulsations are observed for a lengthy period (~15 minutes). In the second case with a higher flow velocity (50 cm/s), the diffusion flame is stabilized at the shoulder of the spherical sample after local stagnation point blowoff. With steady decrease in ambient oxygen due to depletion, spinning flamelets are formed. The long-duration microgravity environment makes it possible to observe. these interesting and detailed extinction processes.

Flame quenching↗

NASA NTRS1978

Artificially created holes in the ionosphere

The artificial creation of ionospheric holes by the release of highly reactive molecules into the F region is investigated. Through ion-atom interchange or charge transfer reactions, H2 or H2O reacts with O(+) to form OH(+) or H2O(+), respectively, which subsequently dissociatively recombines with electrons at a very rapid rate. The diffusion of H2 is also modified by chemical loss to the ambient atomic oxygen atmosphere. The limited spatial and temporal extent of the hole-making process allows several approximations to be made which permit three-dimensional analytic solutions of the continuity equations for the released particles, the O(+) and e(-) densities, and the intermediary molecular ions. A versatile formalism is developed whereby the hole-making capability of virtually any spatial-temporal configuration of released particles can be determined by convolving a set of destruction operators which can be viewed as Green's functions for the problem. As a specific application of the techniques developed, the modification of a winter nighttime ionosphere is described by simulating the release of 1000 kg of water vapor near a height of 300 km.

Mendillo, M.↗

NASA NTRS1983

Interstellar abundances of oxygen and nitrogen

Neutral nitrogen and oxygen column densities or limits are derived for 53 path lengths through the diffuse interstellar medium and compared with column densities of neutral hydrogen. For neither N nor O is a systematic increase of depletion found as reddening increases. The value found for forbidden O/N is 8, and the abundances of N and O are both between 40% and 70% of the solar values. Implications of these results for models of interstellar grains are briefly discussed.

York, D. G.↗

NASA NTRS1984

The plasma wave environment of an auroral arc - Electrostatic ion cyclotron waves in the diffuse aurora

Electric field plasma wave observations were made with a sounding rocket payload in and near a quiet auroral arc. This payload was launched on March 9, 1978 from Poker Flat, Alaska. The payload trajectory was close to the magnetic meridian and passed over a 40 kR auroral arc. The present investigation is concerned with ac electric field observations in the ELF and lower VLF covering a frequency range from 2.5 Hz to 8 kHz. Attention is given to aspects of instrumentation, the general situation, a data analysis, and the obtained results. Waves were observed at low altitude in a region of downward parallel current and diffuse aurora. These waves had properties consistent with those expected for hydrogen and oxygen electrostatic ion cyclotron (EIC) waves.

Bering, E. A.↗

NASA NTRS2007

Increasing Durability of Flame-Sprayed Strain Gauges

Thermally sprayed dielectric ceramic coatings are the primary means of attaching strain and temperature gauges to hot-section rotating parts of turbine engines. As hot-section temperatures increase, lifetimes of installed gauges decrease, and seldom exceed one hour above 2,000 F (approx.1,100 C). Advanced engine components are expected to operate at temperatures approaching 2,200 F (approx.1,200 C), and the required high-temperature lifetime is 10 hours minimum. Typically, to enable a ceramic coating to adhere to the smooth surface of an engine component, a thermally sprayed NiCrAlY or NiCoCrAlY bond coat is applied to the smooth surface, thereby providing a textured surface to which the ceramic coat can adhere. The main failure mechanism of this system is decohesion and/or delamination at the interface between the ceramic top coat and the bond coat, caused by oxidation of the bond coat and stresses from the mismatch between the coefficients of thermal expansion of the ceramic top coat and the metallic bond coat. The approach taken to increase the high-temperature lifetime of a gauge attached to an engine component by the method described above involves (1) selective oxidation of the bond coat by means of a heat treatment in reduced oxygen partial pressure followed by (2) the application of a noble-metal diffusion barrier. In experiments to test this approach, heat treatments of NiCoCrAlY bond coats were carried out in a tube furnace in which, in each case, the temperature was alternately (1) increased at a rate of 3 C per minute and (2) held steady for one hour until the desired temperature was reached. The tube furnace was continuously purged with dry nitrogen gas. A final heat-treatment temperature range of 1,600 to 1,800 F (871 to 982 C) proved most beneficial.

Gregory, Otto J.↗