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At least 343 records · Page 19

Tin–Lead Liquid Metal Alloy Source for Focused Ion Beams

Focused Ion Beam (FIB) systems are increasingly utilized in nanotechnology for nanostructuring, surface modification, doping, and rapid prototyping. Recently, their potential for quantum applications has been explored, leveraging FIB’s direct-write capabilities for in situ single ion implantation, which is crucial for fabricating single photon emitters. Color centers in diamond can function as qubits and are of particular interest due to their capacity to store and transmit quantum information. While Group-IV color centers exhibit high brightness, they require low temperatures to retain coherence. However, lead-vacancy in diamond (PbV) operates at the higher end (4 K) of this temperature spectrum due to larger ground-state splitting, making them particularly interesting. In this context, our study presents results for lead (Pb)-containing alloys with eutectic points below 600 °C and results on using tantalum (Ta) and titanium (Ti) as emitter materials for a Pb liquid metal alloy ion source. We show that a standard FIB system is able to resolve the different Pb isotopes and achieve nanoscale spot sizes, as required for quantum information science applications.

color center↗

Integrating the Design of Desalination Technologies into Produced Water Network Optimization

The oil and gas energy sector uses billions of gallons of water for hydraulic fracturing each year to extract oil and gas. The water injected into the ground for fracturing along with naturally occur-ring formation water from the oil wells surfaces back in the form of produced water. Produced water can contain high concentrations of total dissolved solids and is unfit for reuse outside the oil and gas industry without desalination. In semi-arid shale plays, produced water desalination for beneficial reuse could play a crucial role in alleviating water shortages and addressing extreme drought conditions. In this paper we co-optimize the design and operation of desalination technologies along with operational decisions across produced water networks. A multi-period produced water network model with simplified split-fraction-based desalination nodes is developed. Rigorous steady-state desalination mathematical models based on mechanical vapor recompression are developed and embedded at the desalination sites in the network model. An optimal common design is ensured across all periods using global capacity constraints. The solution approach is demonstrated for multi-period planning problems on networks from the PARETO open-source library. Model formulation and challenges associated with scalability are discussed.

Naik, Sakshi↗

Advanced engine study for mixed-mode orbit-transfer vehicles

Engine design, performance, weight and envelope data were established for three mixed-mode orbit-transfer vehicle engine candidates. Engine concepts evaluated are the tripropellant, dual-expander and plug cluster. Oxygen, RP-1 and hydrogen are the propellants considered for use in these engines. Theoretical performance and propellant properties were established for bipropellant and tripropellant mixes of these propellants. RP-1, hydrogen and oxygen were evaluated as coolants and the maximum attainable chamber pressures were determined for each engine concept within the constraints of the propellant properties and the low cycle thermal fatigue (300 cycles) requirement. The baseline engine design and component operating characteristics are determined at a thrust level of 88,964N (20,000 lbs) and a thrust split of 0.5. The parametric data is generated over ranges of thrust and thrust split of 66.7 to 400kN (15 to 90 klb) and 0.4 to 0.8, respectively.

Mellish, J. A.↗

Long-Wavelength Infrared Detector

Proposed device detects infrared photons of 10- to 100-micrometer wavelength by intersubband absorption in coupled quantum wells. Based on splitting of energy level occuring when two quantum wells placed so close together wave functions of quantized energy levels overlap. Detector absorbs photons, energy which equals difference in energy between two levels resulting from split. Because degree of overlap of wave functions and, therefore, magnitude of split varied by varying width of barrier between two coupled wells, such detector, in principle, designed to operate at any desired wavelength. Restrictions on design parameters of quantum wells of proposed device less severe than single-well devices. Energy levels near tops of wells still necessary so photoexcited carriers tunnel out. Additional flexibility in design obtained by use of wells formed by barriers of different heights.

Vasquez, Richard P.↗

A Method of Monitoring Non-Resonant Raman Lidar Returns During Daylight Hours

A method for using non-resonant Raman lidar during daytime hours is presented. A dual (or quadruple) arrangement of electro-optical channels is set up in the lidar receiver. Each channel contains its own optical spectral response as determined by an appropriate set of interference filters. The incoming signal is split and fed into two channels, filtered (simultaneously) and then inserted into the input terminals of an operational amplifier. The difference signal is selected and amplified whereas the common portion of the signal is highly attenuated (Common Mode Re.jection Ratio = 75-80db). For the present hardware, daylight intensities 10(exp 2)-10(exp 3) times Raman signals are received simultaneously. Mean values of intensities of daylight signals which give rise to a constant differences merely shift the value of the measured variable at the ground. These mean value signals have their common part highly attenuated. The differences of the fluctuation portions of the daylight signal represents a noise signal. Identical (space-time) optical paths for each component of the daylight signal produce the same fluctuational spectra in each channel. Hence noise levels, much less than signal levels, are anticipated. First a N2-H2 ) signal pair is differenced. Then an N2-O2 pair is differenced and used for instrumental normalization purposes. Signal levels to be encountered are quite well known as a result of prior field work. Improved optical design of laser system can reduce mean value of daylight intensities by 10(exp 2). Thus the mean daylight intensity can be set equal to the expected signal levels by more advanced optical design. Performance characteristics of photomultiplier pairs are discussed in this connection.

Cooney, John↗

Modeling Ethanol-Blend Fuel Sprays under Direct-Injection Spark-Ignition Engine Conditions

Computational modeling of fuel-injection and fuel-impingement processes was carried out to provide insight into previous experimental results obtained from a direct-injection spark-ignition research engine operated with various ethanol and aromatic fuel blends. Seven model fuels were evaluated using both single- and split-injection strategies. Model results showed that droplet vaporization enriched the concentrations of aromatic species in the liquid phase, especially those with low vapor pressure, and ethanol-containing fuels altered droplet sizes and led to increased liquid-phase mass in the cylinder. For the spray-modeling conditions studied, most of the injected fuel remained in the liquid phase, which would be expected to result in more fuel impingement on cylinder or piston surfaces. Fuel impinging on lower cylinder-temperature surfaces was found to create wall films that could interact with the piston during the compression stroke. Fuel impinging on hotter piston-temperature surfaces vaporized more readily, but for fuels with high ethanol and aromatic content, wall films remained and were highly concentrated with lower vapor pressure and aromatic compounds. These films could lead to pool fires during combustion and therefore significant particulate matter emissions.

BIOMASS FUELS,INORGANIC, ORGANIC, PHYSICAL, AND AN↗

Design of a Structure for Assembly and Cooling the Magnet of the Next-Generation 45 GHz ECR Ion Source MARS-D

Here, the current Electron Cyclotron Resonance Ion Sources (ECRISs), constructed with Nb-Ti wires and the conventional racetrack-and-solenoid structure, have achieved operating frequencies up to 28 GHz and utilized about 90% of the critical current of the Nb-Ti wire. A Mixed Axial and Radial field System Demonstrator (MARS-D) is being developed at Lawrence Berkeley National Laboratory (LBNL). This system, which consists of an innovative hexagonal Closed-Loop Coil (CLC) and a set of solenoids, can generate higher magnetic fields (up to 150% ) while requiring only about 50% of the superconducting wire, enabling Nb-Ti wires to be used in the next-generation 45 GHz ECRIS. However, the assembly and cooling of such an efficient and compact magnet are particularly challenging due to the small radial gap between the CLC and solenoids, as well as the tight operating temperature margin. To address these challenges, a structure was developed that combines a three-section radially split solenoid mandrel with a series of shrink-fit reinforcement rings and cooling channels. This paper presents the detailed structure, manufacturing method, assembly procedure, impregnation method, mechanical Finite Element Analysis (FEA) comparison, and thermal FEA comparison.

ECR ion sources↗

Fiscal Year 2020 Filtration of Hanford Tank Waste 241-AP-105

Bench-scale filtration testing of 15 liters of 241-AP-105 supernatant was conducted using a Mott inline filter Model 6610 (media grade 5) backpulsed dead-end filter (BDEF) in the hot cells of the Radiochemical Processing Laboratory at Pacific Northwest National Laboratory. The as-received samples were diluted with raw water from the Hanford Site to assess the propensity for solids to form upon dilution and to assess the impact those solids have on filtration performance. The feed was split into two batches. The first batch was settled and decanted as planned in Tank Side Cesium Removal operations. The BDEF was used to filter this AP-105 feed at a targeted flux of 0.065 gpm/ft 2 and exhibited no measurable pressure increase during filtration. The second batch was fed to the BDEF with solids resuspended. This was also operated at the targeted flux of 0.065 gpm/ft 2 . In this case, the target pressure differential of 2 psid (resistance of 6.24 × 10 10 m -1 ) was reached in slightly more than 12 h. A backpulse restored the filter flux; however, the time to the next backpulse was slightly shorter. These tests indicate that after the addition of raw water, settle and decant effectively removed solids from the feed. It is not possible to assess the time required for these solids to settle based on the result from these tests. However, if sufficient time is allowed for the solids to settle, no measurable filter fouling was observed in current testing. In contrast, if insufficient time is allowed for solids to settle, filter fouling will occur relatively quickly and will likely require backpulses more frequently than every 12 hours (1.91 m 3 /m 2 volume filtered). Solids concentrated from backpulse solutions displayed large variability in composition with Al-silicates and mixed chromium-aluminum oxide phases. Amounts of Mg, Fe, and Ca were also found in the presence of Na and O. These solids could be grouped in three categories: (1) soluble Na-salts that formed large block-like particles but were made up of fibrous materials, (2) amorphous Al-phases, and (3) colloidal iron oxides with an average particle diameter of 4.2 µm.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Research in Neutrinoless Double-Beta Decay (Final Report)

The research objective of the supported work was to search for neutrinoless double-beta decay in 76 Ge and investigate and identify backgrounds to a double-beta decay search. Understanding the neutrino mass generation mechanism, the absolute neutrino mass scale, the neutrino mass spectrum, and the possible Majorana nature of neutrinos are some of the future discoveries of the next generation neutrino experiments. The Majorana collaboration operated the Demonstrator experiment comprising 44 kg (30 kg enriched in 76 Ge) of Ge detectors in total split between two modules contained in a low background shield at the Sanford Underground Research Facility in Lead, South Dakota. Observation of 0νββ would have profound implications for the Standard Model of particle physics by demonstrating that neutrinos are Majorana particles, that lepton number is not conserved, and it would provide a measure of the effective Majorana neutrino mass. The decay rate of 0νββ is incredibly small and may only produce a few signature events in a detector per year. Therefore, observation of this rare process demands a careful study and implementation of signal processing, detector design, and new levels of background suppression.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Vibrational spectra and structure of azomethane and azomethane-d6.

The infrared and Raman spectra of azomethane and azomethane-d(6) were examined in detail. Vibrational data provided definitive verification of a trans-structure with C(2h) symmetry. A vibrational assignment is proposed for the 24 fundamental modes based upon the observed contours, isotopic shift ratios, and group frequency correlations. Spectra of the polycrystalline samples indicate that there are at least four molecules per unit cell, since a number of the bands were observed to be split into doublets. The crystal also appeared to have a center of symmetry, since mutual exclusion was clearly operative.

Durig, J. R.↗

STS-83 Day 02

On this second day of the STS-83 mission, the flight crew, Cmdr. James D. Halsell, Jr. Pilot Susan L. Still, Payload Cmdr, Janice E. Voss, Mission Specialists Michael L. Gernhardt and Donald A. Thomas, and Payload Specialists Gregory T. Linteris and Roger K. Crouch can be seen setting up experiments for studying the properties of combustion and the behavior of metals, materials, and fluids in the absence of gravity. The astronauts are split into red and blue teams, each working a 12-hour shift, to allow around-the-clock operations in the pressurized Spacelab science module in Columbia's cargo bay. Thomas is seen activating the Large Isothermal Furnace (LIF) experiment and the Expedite the Processing of Experiments to the International Space Station (EXPRESS) Rack while Linteris continues the activation of Protein Crystal Growth experiments.

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Face Gear Technology for Aerospace Power Transmission Progresses

The use of face gears in an advanced rotorcraft transmission design was first proposed by the McDonnell Douglas Helicopter Company during their contracted effort with the U.S. Army under the Advanced Rotorcraft Transmission (ART) program. Face gears would be used to turn the corner between the horizontal gas turbine engine and the vertical output rotor shaft--a function currently done by spiral bevel gears. This novel gearing arrangement would substantially lower the drive system weight partly because a face gear mesh would be used to split the input power between two output gears. However, the use of face gears and their ability to operate successfully at the speeds and loads required for an aerospace environment was unknown. Therefore a proof-of-concept phase with an existing test stand at the NASA Lewis Research Center was pursued. Hardware was designed that could be tested in Lewis' Spiral Bevel Gear Test Rig. The initial testing indicated that the face gear mesh was a feasible design that could be used at high speeds and load. Surface pitting fatigue was the typical failure mode, and that could lead to tooth fracture. An interim project was conducted to see if slight modifications to the gear tooth geometry or an alternative heat treating process could overcome the surface fatigue problems. From the initial and interim tests, it was apparent that for the surface fatigue problems to be overcome the manufacturing process used for this component would have to be developed to the level used for spiral bevel gears. The current state of the art for face gear manufacturing required using less than optimal gear materials and manufacturing techniques because the surface of the tooth form does not receive final finishing after heat treatment as it does for spiral bevel gears. This resulted in less than desirable surface hardness and manufacturing tolerances. An Advanced Research and Projects Agency (ARPA) Technology Reinvestment Project has been funded to investigate the effects of manufacturing process improvements on the operating characteristics of face gears. The program is being conducted with McDonnell Douglas Helicopter Co., Lucas Western Inc., the University of Illinois at Chicago, and a NASA/U.S. Army team. The goal of the project is develop the grinding process, experimentally verify the improvement in face gear fatigue life, and conduct a full-scale helicopter transmission test. The theory and methodology to grind face gears has been completed, and manufacture of the test hardware is ongoing. Experimental verification on test hardware is scheduled to begin in fiscal 1996.

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Unsteady Velocity Measurements in the NASA Research Low Speed Axial Compressor: Smooth Wall Configuration

The report is a collection of experimental unsteady data acquired in the first stage of the NASA Low Speed Axial Compressor in configuration with smooth (solid) wall treatment over the first rotor. The aim of the report is to present a reliable experimental data base that can be used for analysis of the compressor flow behavior, and hopefully help with further improvements of compressor CFD codes. All data analysis is strictly restricted to verification of reliability of the experimental data reported. The report is divided into six main sections. First two sections cover the low speed axial compressor, the basic instrumentation, and the in-house developed methodology of unsteady velocity measurements using a thermo-anemometric split-fiber probe. The next two sections contain experimental data presented as averaged radial distributions for three compressor operation conditions, including the distribution of the total temperature rise over the first rotor, and ensemble averages of unsteady flow data based on a rotor blade passage period. Ensemble averages based on the rotor revolution period, and spectral analysis of unsteady flow parameters are presented in the last two sections. The report is completed with two appendices where performance and dynamic response of thermo-anemometric probes is discussed.

Lepicovsky, Jan↗

Baseline HSR Inlet and Engine Bay Cowl Seal Requirements

The two dimensinal bifurcated inlet, down selected for the HSR program, and the engine bay cowling consist of many sealing interfaces. The variable geometry characteristics of this inlet and the size of the propulsion system impose new sealing requirements for commercial transport aircraft. Major inlet systems requiring seal development and testing include the ramp system, the bypass/take-off system, and the inlet/engine interface. Engine bay cowling seal interfaces include the inlet/cowling interface, the keel split line, the hinge beam/engine bay cowling, and the nozzle/cowling interface. These seals have to withstand supersonic flight operating temperatures and pressures with typical commercial aircraft reliability and lives. The operating conditions and expected seal lives will be identified for the various interfaces. Boeing's SST seal development program will also be discussed.

Sandquist, David↗

Nuclear Thermal Propulsion (NTP): A Proven, Growth Technology for Fast Transit Human Missions to Mars

The "fast conjunction" long surface stay mission option was selected for NASA's recent Mars Design Reference Architecture (DRA) 5.0 study because it provided adequate time at Mars (approx. 540 days) for the crew to explore the planet's geological diversity while also reducing the "1-way" transit times to and from Mars to approx. 6 months. Short transit times are desirable in order to reduce the debilitating physiological effects on the human body that can result from prolonged exposure to the zero-gravity (0-gE) and radiation environments of space. Recent measurements from the RAD detector attached to the Curiosity rover indicate that astronauts would receive a radiation dose of approx. 0.66 Sv (approx. 66 rem)-the limiting value established by NASA-during their 1-year journey in deep space. Proven nuclear thermal rocket (NTR) technology, with its high thrust and high specific impulse (Isp approx. 900 s), can cut 1-way transit times by as much as 50 percent by increasing the propellant capacity of the Mars transfer vehicle (MTV). No large technology scale-ups in engine size are required for these short transit missions either since the smallest engine tested during the Rover program-the 25 klbf "Pewee" engine is sufficient when used in a clustered arrangement of three to four engines. The "Copernicus" crewed MTV developed for DRA 5.0 is a 0-gE design consisting of three basic components: (1) the NTP stage (NTPS); (2) the crewed payload element; and (3) an integrated "saddle truss" and LH2 propellant drop tank assembly that connects the two elements. With a propellant capacity of approx. 190 t, Copernicus can support 1-way transit times ranging from approx. 150 to 220 days over the 15-year synodic cycle. The paper examines the impact on vehicle design of decreasing transit times for the 2033 mission opportunity. With a fourth "upgraded" SLS/HLV launch, an "in-line" LH2 tank element can be added to Copernicus allowing 1-way transit times of 130 days. To achieve 100 to 120 day transit times, Copernicus' saddle truss/drop tank assembly is replaced by a "star truss" assembly with paired modular drop tanks to further increase the vehicle's propellant capacity. The HLV launch count increases (from approx. 5 to 7) and a fourth engine is needed to reduce total mission burn time and gravity losses. Using a "split mission" approach, the NTPS, in-line tank and the saddle truss/LH2 drop tank elements can be configured as a pre-deployed Earth Return Vehicle/propellant tanker supporting 90-day crewed mission transits. The split mission approach also eliminates the need for on-orbit assembly. Mission scenario descriptions, key features and operational characteristics for five different vehicle configurations are presented.

Borowski, Stanley K.↗

A Flexible Power Method for Solving Infinite Dimensional Tensor Eigenvalue Problems

We propose a flexible power method for computing the leftmost, i.e., algebraically smallest, eigenvalue of an infinite dimensional tensor eigenvalue problem, $H x = \lambda x$, where the infinite dimensional symmetric matrix $H$ exhibits a translational invariant structure. We assume the smallest eigenvalue of $H$ is simple and apply a power iteration of $e^{-H}$ with the eigenvector represented in a compact way as a translational invariant infinite Tensor Ring (iTR). Hence, the infinite dimensional eigenvector can be represented by a finite number of iTR cores of finite rank. In order to implement this power iteration, we use a small parameter $t$ so that the infinite matrix-vector operation $e^{-Ht}x$ can efficiently be approximated by the Lie product formula, also known as Suzuki--Trotter splitting, and we employ a low rank approximation through a truncated singular value decomposition on the iTR cores in order to keep the cost of subsequent power iterations bounded. We also use an efficient way for computing the iTR Rayleigh quotient and introduce a finite size iTR residual which is used to monitor the convergence of the Rayleigh quotient and to modify the timestep $t$. In this paper, we discuss 2 different implementations of the flexible power algorithm and illustrate the automatic timestep adaption approach for several numerical examples.

Beeumen, Roel Van↗

Reactor Network Analysis with Various Reaction Mechanisms to Investigate Hydrogen vs. Methane Fuel at Varying Flame Temperatures with Experimental Data

Emissions data were evaluated for a set of test hardware that adapts Collins Aerospace’s aeroengine liquid fueled injector technology to a ground-based turbine. The hardware was specifically developed to operate on 100% hydrogen; however it has the ability to operate on both pure methane and hydrogen and mixtures in between. 16 injector configurations and seven factors (air split, fuel and air swirl, pressure drop, preheat temperature, fuel composition, and flame temperature) were investigated based on a Box Behnken statistical model. Of the 16, configuration 3 was selected for further discussion being in the middle of the statistical design space. A chemical reactor network was developed based on the experimental data obtained and was assessed with three different mechanisms: GRI Mech 3.0, UCSD, and Galway. All factors were held constant except the fuel composition to directly compare chemical pathways for methane and hydrogen. This study was conducted across different flame temperatures of 1500K, 1675K, and 1850K for both hydrogen and methane. Additional lower flame temperatures of 1100K and 1300K were evaluated for hydrogen. Moreover, results for fully premixed and non-premixed results were compared to obtain information on the implications of mixedness on emissions. These results were compared with the Leonard and Stegmaier plot for methane and a similar plot was constructed for hydrogen.

08 HYDROGEN↗

Computational modelling of Er(3+): Garnet laser materials

The Er(3+) ion has attracted a lot of interest for four reasons: (1) Its (4)I(sub 13/2) yields (4)I(sub 15/2) transition lases in the eyesafe region near 1.5 micron; (2) the (4)I(sub 13/2) transition lases near 2.8 micron, an important wavelength for surgical purposes; (3) it displays surprisingly efficient upconversion with lasing observed at 1.7, 1.2, 0.85, 0.56, 0.55, and 0.47 micron following 1.5 micron pumping; and (4) it has absorption bands at 0.96 and 0.81 micron and thus can be diode pumped. However, properties desirable for upconversion reduce the efficiency of 1.5 and 3 micron laser operation and vice versa. Since all of the processes are influenced by the host via the crystal field induced stark splittings in the Er levels, this project undertook modelling of the host influence on the Er lasinng behavior. While growth and measurement of all ten Er(3+) doped garnets is the surest way of identifying hosts which maximize upconversion (or conversly, 1.5 and 3 micron performance), it is also expensive - costing approximately $10,000/material or approximately $100,000 for the materials computationally investigated here. The calculations were performed using a quantum mechanical point charge model developed by Clyde Morrison at Harry Diamond Laboratories. The programs were used to fit the Er:YAG experimental energy levels so that the crystal field parameters, B(sub nm) could be extracted. From these radial factors, rho (sub n) were determined for Er(3+) in garnets. These, in combination with crystal field components, Anm, available from X-ray data, were used to predict energy levels for Er in the other nine garnet hosts. The levels in Er:YAG were fit with an rms error of 12.2/cm over a 22,000/cm range. Predicted levels for two other garnets for which literature values were available had rms errors of less than 17/cm , showing the calculations to be reliable. Based on resonances between pairs of calculated stark levels, the model predicts GSGG as the best host for 1.5 micron laser operation, GSGG or YSAG as the best host for a 2.8 micron operation, and LuGG as the best host for an upconversion material.

Spangler, Lee H.↗