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At least 343 records · Page 19

Accurate ab Initio Quartic Force Fields, Vibrational Frequencies, and Heats of Formation for FCN, FNC, ClCN, and ClNC

The XCN and XNC (X = F, Cl) isomers have been investigated using the CCSD(T) method in conjunction with correlation consistent basis sets. Equilibrium geometries, harmonic frequencies, anharmonic constants, fundamental frequencies, and heats of formation have been evaluated. Agreement with experiment for the fundamental frequencies is very good, even for nu(sub 2), for CICN, which is subject to a strong Fermi resonance with 2nu(sub 3). It is also shown that a second-order perturbation theory approach to solving the nuclear Schroedinger equation gives results in excellent agreement with essentially exact variational calculations. This is true even for nu(sub 2) of ClCN, provided that near-singular terms are eliminated from the perturbation theory formulas and the appropriate Fermi interaction energy matrix is then diagonalized. A band at 615/cm, tentatively assigned as the Cl-N stretch in ClNC in matrix isolation experiments, is shown not to be due to ClNC. Accurate atomization energies are determined and are used to evaluate accurate heats of formation (3.1 +/- 1.5, 33.2 +/- 1.5, 72.6 +/- 1.5, and 75.9 +/- 1.5 kcal/mol for FCN, ClCN, FNC, and ClNC, respectively). It is expected that the theoretical heats of formation for FCN, FNC, and ClNC are the most accurate available.

Lee, Timothy J.↗

A Parameterization for the Triggering of Landscape Generated Moist Convection

A set of relatively high resolution three-dimensional (3D) simulations were produced to investigate the triggering of moist convection by landscape generated mesoscale circulations. The local accumulated rainfall varied monotonically (linearly) with the size of individual landscape patches, demonstrating the need to develop a trigger function that is sensitive to the size of individual patches. A new triggering function that includes the effect of landscapes generated mesoscale circulations over patches of different sizes consists of a parcel's perturbation in vertical velocity (nu(sub 0)), temperature (theta(sub 0)), and moisture (q(sub 0)). Each variable in the triggering function was also sensitive to soil moisture gradients, atmospheric initial conditions, and moist processes. The parcel's vertical velocity, temperature, and moisture perturbation were partitioned into mesoscale and turbulent components. Budget equations were derived for theta(sub 0) and q(sub 0). Of the many terms in this set of budget equations, the turbulent, vertical flux of the mesoscale temperature and moisture contributed most to the triggering of moist convection through the impact of these fluxes on the parcel's temperature and moisture profile. These fluxes needed to be parameterized to obtain theta(sub 0) and q(sub 0). The mesoscale vertical velocity also affected the profile of nu(sub 0). We used similarity theory to parameterize these fluxes as well as the parcel's mesoscale vertical velocity.

Lynn, Barry H.↗

Real-Time Optical Flux Limits from Gamma-Ray Bursts Measured by the Gamma-Ray Optical Counterpart Search Experiment

The Gamma-Ray Optical Counterpart Search Experiment presents new experimental upper limits on the optical flux from gamma-ray bursts (GRBs). Our experiment consisted of a fully automated very wide-field opto-electronic detection system that imaged locations of GRBs within a few seconds of receiving trigger signals provided by BATSE's real-time burst coordinate distribution network. The experiment acquired 3800 observing hours, recording 22 gamma-ray burst triggers within approx. 30 s of the start of the burst event. Some of these bursts were imaged while gamma-ray radiation was being detected by BATSE. We identified no optical counterparts associated with gamma-ray bursts among these events at the mV approx. 7.0-8.3 sensitivity level. We find the ratio of the upper limit to the V-band optical flux, F nu, to the gamma-ray fluence, Phi gamma, from these data to be 1 x 10(exp-18) less than F nu Phi gamma less than 2 x 10(exp -16).

Park, H. S.↗

Observation of a Long-Term Spin-up Trend in 4U 1538-52

The high-mass X-ray pulsar 4U 153 8-52 has been continually monitored by the Burst and Transient Source Experiment (BATSE) on Compton Gamma-Ray Observatory. These observations permit the construction of long-term pulse frequency and intensity histories. The frequency history reveals that a reversal of the long-term trend in the accretion torque, from spinning down to spinning up, has occurred, probably in 1988. This is the first time a long-term change is known to have occurred for this source, The magnitude of the average absolute value of (dot-nu / nu) is approximately 10(exp -11)/s over an interval of approximately 5 year is similar during spin-down and spin-up. Shorter term pulse frequency variations of either sign are also observed. The power density spectrum of fluctuations in angular acceleration is consistent with white noise on timescales from 16 to 1600 days. It can be well fit with a power law with a power-law index of 0.10 plus or minus 0.21 and white noise strength of (7.6 +/- 1.6) x 10(exp -21) (Hz/s(exp 2)/Hz). These observations are also used to set 95% confidence level lower and upper limits on the rate of orbital period change, -3.9< dot-P orb /P orb <2. 1, in units of 10(exp -6) yr(exp -1).

Rubin, B. C.↗

Rapid Spin-Up Episodes in the Wind-Fed Accreting Pulsar GX 301-2

The accreting pulsar GX 301-2 (P = 680 s) has been observed continuously by the large-area detectors of the Burst and Transient Source Experiment (BATSE) instrument on the Compton Gamma Ray Observatory since 1991 April 5. Orbital parameters determined from these data are consistent with previous measurements, with improved accuracy in the current orbital epoch. The most striking features in the pulsar frequency history are two steady and rapid spin-up episodes, with a dot-nu approximately equal to (3_5) x 10(exp -12) Hz/s, each lasting for about 30 days. They probably represent the formation of transient accretion disks in this wind-fed pulsar. Except for these spin-up episodes, there are virtually no net changes in the neutron star spin frequency on long timescales. We suggest that the long-term spin-up trend observed since 1984 (dot-nu is approximately equals 2x10(exp -13) Hz/s) may be due entirely to brief (approximately 20 days) spin-up episodes similar to those we have discovered. We assess different accretion models and their ability to explain the orbital phase dependence of the observed flux. In addition to the previously observed preperiastron peak at orbital phase 0.956 +/- 0.022, we also find a smaller peak close to - at orbital phase 0.498 +/- 0.057. We show that if the companion star's effective temperature is less than 22,000 K, then it must have a mass M(sub c) < 70 solar mass and a radius R(sub c) < 85 solar radius so as not to overfill the tidal lobe at periastron. In order not to overflow the Roche lobe at periastron, the corresponding values are M(sub c) < 55 solar mass and R(sub c) < 68 solar radius. These constraints are nearly at odds with the reclassification of the companion as a B1 Ia + hypergiant.

Koh, Danny T.↗

Frequency-Dependent Viscosity of Xenon Near the Critical Point

We used a novel, overdamped oscillator aboard the Space Shuttle to measure the viscosity eta of xenon near its critical density rho(sub c), and temperature T(sub c). In microgravity, useful data were obtained within 0.1 mK of T(sub c), corresponding to a reduced temperature t = (T -T(sub c))/T(sub c) = 3 x 10(exp -7). The data extend two decades closer to T(sub c) than the best ground measurements, and they directly reveal the expected power-law behavior eta proportional to t(sup -(nu)z(sub eta)). Here nu is the correlation length exponent, and our result for the small viscosity exponent is z(sub eta) = 0.0690 +/- 0.0006. (All uncertainties are one standard uncertainty.) Our value for z(sub eta) depends only weakly on the form of the viscosity crossover function, and it agrees with the value 0.067 +/- 0.002 obtained from a recent two-loop perturbation expansion. The measurements spanned the frequency range 2 Hz less than or equal to f less than or equal to 12 Hz and revealed viscoelasticity when t less than or equal to 10(exp -1), further from T(sub c) than predicted. The viscoelasticity scales as Af(tau), where tau is the fluctuation-decay time. The fitted value of the viscoelastic time-scale parameter A is 2.0 +/- 0.3 times the result of a one-loop perturbation calculation. Near T(sub c), the xenon's calculated time constant for thermal diffusion exceeded days. Nevertheless, the viscosity results were independent of the xenon's temperature history, indicating that the density was kept near rho(sub c), by judicious choices of the temperature vs. time program. Deliberately bad choices led to large density inhomogeneities. At t greater than 10(exp -5), the xenon approached equilibrium much faster than expected, suggesting that convection driven by microgravity and by electric fields slowly stirred the sample.

Berg, Robert F.↗

Turbulence and Laminar Structures: Can They Co-Exist?

Schwarzschild first suggested that the laminar structures observed in the high Reynolds number Re = UL/nu approx. = (10(exp 12)) solar photosphere are the result of turbulence rather than a proof of its absence. He reasoned that since turbulence generates large turbulent viscosities nu(sub t) much greater than nu, the "effective" Reynolds number Re = UL/nu(sub t) approx. = O(1). Schwarzschild's argument is, however, incomplete for it assumes that the entire role of the non-linear interactions is to "enhance" viscosity. While this is not true in general, we present a proof of how and why it may occur, thus completing Schwarzschild's argument. We further discuss the fact that the same model non-local turbulence models have been shown to reproduce LES data for a variety of flows pertaining to astrophysics, geophysics and laboratory situations (at a fraction of the time).

Canuto, V. M.↗

Weakly Nonlinear Description of Parametric Instabilities in Vibrating Flows

This project focuses on the effects of weak dissipation on vibrational flows in microgravity and in particular on (a) the generation of mean flows through viscous effects and their reaction on the flows themselves, and (b) the effects of finite group velocity and dispersion on the resulting dynamics in large domains. The basic mechanism responsible for the generation of such flows is nonlinear and was identified by Schlichting [21] and Longuet-Higgins. However, only recently has it become possible to describe such flows self-consistently in terms of amplitude equations for the parametrically excited waves coupled to a mean flow equation. The derivation of these equations is nontrivial because the limit of zero viscosity is singular. This project focuses on various aspects of this singular problem (i.e., the limit C equivalent to (nu)((g)(h(exp 3)))exp -1/2 << 1,where nu is the kinematic viscosity and h is the liquid depth) in the weakly nonlinear regime. A number of distinct cases is identified depending on the values of the Bond number, the size of the nonlinear terms, distance above threshold and the length scales of interest. The theory provides a quantitative explanation of a number of experiments on the vibration modes of liquid bridges and related experiments on parametric excitation of capillary waves in containers of both small and large aspect ratio. The following is a summary of results obtained thus far.

Knobloch, E.↗

The Rapidly Fading Afterglow of GRB 980519

GRB 980519 had the most rapidly fading of the well-documented GRB afterglows, consistent with t(sup -2.05 +/- 0.04) in BVRI as well as in X-rays during the two days in which observations were made. We report VRI observations from the MDM 1.3m and WIYN 3.5m telescopes, and we synthesize an optical spectrum from all of the available photometry. The optical spectrum alone is well fitted by a power law of the form nu(sup - 1.20 +/- 0.25), with some of the uncertainty due to the significant Galactic reddening in this direction. The optical and X-ray spectra together are adequately fitted by a single power law nu(sup 1.05 +/- 0.10). This combination of steep temporal decay and flat broad-band spectrum places a severe strain on the simplest afterglow models involving spherical blast waves in a homogeneous medium. Instead, the rapid observed temporal decay is more consistent with 2 models of expansion into a medium of density n(r) proportional to r(sup -2), or with predictions of the evolution of a jet after it slows down and spreads laterally. The jet model would relax the energy requirements on some of the more extreme GRBs, of which GRB 980519 is likely to be an example because of its large gamma-ray fluence and faint host galaxy.

Halpern, Jules P.↗

The Optical Spectrum of the Geminga Pulsar

We obtained an optical spectrum of the isolated pulsar Geminga at the Keck Observatory. The optical object is at the limit of spectroscopic capability of any telescope, with a continuum flux that is approx. 0.5% of the dark sky on Mauna Kea. With particular attention paid to the dominant systematics of sky subtraction in our observing and analysis methods, we attained approx. 0.1% systematics in heavily binned spectra. The resulting spectrum spanning 3700 - 8000 A has a flat power-law shape f(sub nu) proportional to nu(exp -0.8) and a broad dip over 6300 - 6500 A. Thermal radiation cannot explain the optical spectrum of Geminga. The dominant component can be modeled as either electron synchrotron emission and ion (proton) cyclotron absorption, or ion cyclotron emission, the latter in a 10(exp 11) G magnetic field.

Martin, Christopher↗

Some Thermodynamic Considerations on the Physical and Quantum Nature of Space and Time

It is suggested that the Planck h = m(sub k)c Lambda(sub k) and the Boltzmann k = m(sub k)c nu(sub k)Constants have stochastic foundation. It is further suggested that a body of fluid at equilibrium is composed of a spectrum of molecular clusters (energy levels) the size of which are governed by the Maxwell-Boltzmann distribution function. Brownian motions are attributed to equilibrium between suspensions and molecular clusters. Atomic (molecular) transition between different size atomic- (molecular-) clusters (energy levels) is shown to result in emission/absorption of energy in accordance with Bohr's theory of atomic spectra. Physical space is identified as a tachyonic fluid that is Dirac's stochastic ether or de Broglie's hidden thermostat. Compressibility of physical space, in accordance with Planck's compressible ether, is shown to result in the Lorentz-Fitzgerald contraction, thus providing a causal explanation of relativistic effect in accordance with the perceptions of Poincare and Lorentz. The invariant Schrodinger equation is derived from the invariant Bernoulli equation for incompressible potential flow. Following Heisenberg a temporal uncertainty relation is introduced as Delta(nu(sub Beta)) Delta(Rho(sub Beta)) > = k.

Sohrab, Siavash H.↗

Near-Threshold Rovibrational Excitation of HF by Electron Impact

The pronounced threshold peaks found in cross sections for electron-impact excitation of the vibrational levels of HF have been studied using an R-matrix method, in which electron exchange, correlation effects and polarization are included. Vibration is modelled inside the R-matrix sphere using the energy-modified adiabatic phase matrix method (EMAP). Rotation of the target molecule is treated outside the R-matrix sphere, using the frame transformation method. The external rovibronic close-coupling equations are solved by analytic methods. Analysis of the multichannel threshold structures indicates that the peaks found for rovibrational excitation of nu = 1 can be interpreted as virtual states while those for nu = 2 correspond to nuclear-excited Feshbach resonances. These two different results correspond simply to a change of sign of a small parameter that is determined by the threshold analysis. Whereas the overall shapes of the excitation peaks agree with earlier theoretical results, we have found detailed rotational fine structures for scattering energies on the order of the rotational constant above and below the opening of the vibrational channels. The partial and total cross sections for rovibrational state-to-state transitions in the energy region of the peaks are analysed. Characteristic cusp structures and excitation peaks are found at the rovibrational thresholds for transitions with small angular momentum transfer (Delta)j =0, 1 and 2. Differential cross sections are similar to recent measurements. These experimental data do not show the relatively sharp rise at the vibrational thresholds indicated by theory. Theory and experiment are in good agreement for the shape and magnitude of the angular dependence of cross sections for rovibrational state-to-state transitions, especially at larger energies.

Thummel, Helmar T.↗

Photodissociation of Peroxynitric Acid in the Near-IR

Temperature-dependent near-IR photodissociation spectra were obtained for several vibrational overtone transitions of peroxynitric acid (HNO4) with a tunable OPO photolysis/OH laser-induced-fluorescence system. Band-integrated photodissociation cross-sections (definity integral of sigma(sub diss)), determined relative to that for the 3nu(sub 1), OH stretching overtone, were measured for three dissociative bands. Assuming unit quantum efficiency for photodissociation of 3nu(sub 1), we find 2nu(sub 1) + nu(sub 3)(8242/cm) = (1.21 x 10(exp -20) (independent of temperature), 2nu(sub 1) (6900/cm) = 4.09 x 10(exp 18) * e(sup (-826,5/T)) (295 K greater than T greater than 224 K), and nu(sub 1) + 2nu(sub 3) (6252/cm) = 1.87 x 10(exp -19) * e(sup (- 1410.7/T)) (278 K greater than T greater than 240 K) sq cm/molecule cm. The photodissociation cross-sections are independent of pressure over the range 2 to 40 Torr. Temperature-dependent quantum yields (phi) for these transitions were obtained using integrated absorption cross-sections (definity integral of sigma(sub abs)) of HNO4 overtone vibrations measured with a FTIR spectrometer. In the atmosphere, photodissociation in the infrared is dominated by excitation of the first overtone of the OH stretching vibration (2nu((sub 1)). Inclusion of all dissociative HNO4 overtone and combination transitions yields a daytime IR photolysis rate of approximately 1 x 10(esp -1)/s. This process significantly shortens the estimated lifetime of HNO4 in the upper troposphere and lower stratosphere.

Roehl, Coleen M.↗

Space Telemetry for the Energy Industry

Space telemetry is the process whereby information acquired in orbit is relayed to Earth. In 1981, Bill Sheen, President of Nu-Tech Industries, Inc., saw a need for a better way of monitoring flow, due to high costs of oil and gas, increasing oil field theft and a mounting requirement for more timely information to speed up accounting procedures. Sheen turned to NASA for assistance which was provided by Kerr Industrial Applications Center (KIAC). The system that emerged from two years of research, now in production at Nu-Tech's Fort Worth Texas facility, is known as the Remote Measurement and Control Network.

Source record↗

X-ray QPOs from the Ultra-luminous X-ray Source in M82: Evidence Against Beaming

We report the discovery with the European Photon Imaging Camera (EPIC) CCD cameras onboard XMM-Newton of a 54 mHz quasiperiodic oscillation (QPO) in the greater than 2 keV X-ray flux from the ultra-luminous X-ray source (ULX) X41.4+60 in the starburst galaxy M82. This is the first detection of a QPO in the X-ray flux from an extra-Galactic ULX, and confirms that the source is a compact object. The QPO is detected in the combined PN and MOS data at the approx. 6sigma level, and separately at lower significances in both the PN and MOS instruments. It had a centroid frequency of 54.3 +/- 0.9 mHz, a coherence Q is identical with nu(sub 0)/Delta nu(sub fwhm) is approx. 5, and an amplitude (rms) in the 2 - 10 keV band of 8.5%. Below about 0.2 Hz the power spectrum can be described by a power-law with index approx. 1, and integrated amplitude (rms) of 13.5%. The X-ray spectrum requires a curving continuum, with a disk-blackbody (diskbb) at T = 3.1 keV providing an acceptable, but not unique, fit. A broad Fe line centered at 6.55 keV is required in all fits, but the equivalent width (EW) of the line is sensitive to the choice of continuum model. There is no evidence of a reflection component. The implied bolometric luminosity is approx. 4 - 5 x 10(exp 40) ergs/s. Data from several archival Rossi X-ray Timing Explorer (RXTE) pointings at M82 also show evidence for QPOs in the 50 - 100 mHz frequency range. Several Galactic black hole candidates (BHCs), including GRS 1915+105, GRO J1655-40, and XTE 1550-564, show QPOs in the same frequency range as the 50 - 100 mHz QPOs in X41.4+60, which at first glance suggests a possible connection with such objects. However, strong, narrow QPOs provide solid evidence for disk emission, and thus present enormous theoretical difficulties for models which rely on either geometrically or relativistically beamed emission to account for the high X-ray luminosities. We discuss the implications of our findings for models of the ULX sources.

Strohmayer, Tod E.↗

C-H Hot Bands in the Near-IR Emission Spectra of Leonids

The reported infrared (IR) emission spectra from 1999 Leonid fireballs show a 3.4 micron C-H emission band and unidentified bands at longer wavelengths. Upon atmospheric entry, the Leonid meteorites were flash-heated to temperatures around 2400K, which would destroy any organics on the surface of the meteorite grains. We propose that the nu(sub )CH emission band in the Leonid emission spectra arises from matrix-embedded C(sub n)-H-O entities that are protected from instant pyrolysis. Our model is based on IR absorption nu(sub )CH bands, which we observed in laboratory-grown MgO and natural olivine single crystals, where they arise from C(sub n)-H-O units imbedded in the mineral matrix, indicative of aliphatic -CH2- and -CH3 organics. Instead of being pyrolyzed, the C(sub n)-H-O entities in the Leonid trails become vibrationally excited to higher levels n = 1, 2, 3 etc. During de-excitation they emit at 3.4 microns, due to the (0 => 1) transition, and at longer wavelengths, due to hot bands. As a first step toward verifying this hypothesis we measured the C-H vibrational manifold of hexane (C6H14). The calculated positions of the (2 => l ) , (3 => 2), and possibly (4 => 3) hot bands agree with the Leonid emission bands at 3.5, 3.8 and 4.l microns.

Freund, F. T.↗

Rotational Sweepback of Magnetic Field Lines in Geometrical Models of Pulsar Radio Emission

We study the rotational distortions of the vacuum dipole magnetic field in the context of geometrical models of the radio emission from pulsars. We find that at low altitudes the rotation deflects the local direction of the magnetic field by at most an angle of the order of r(sup 2 sub n), where r(sub n) = r/R(sub lc), r is the radial distance and R(sub lc) is the light cylinder radius. To the lowest (i.e. second) order in r(sub n) this distortion is symmetrical with respect to the plane containing the dipole axis and the rotation axis ((Omega, mu) plane). The lowest order distortion which is asymmetrical with respect to the (Omega, mu) plane is third order in r(sub n). These results confirm the common assumption that the rotational sweepback has negligible effect on the position angle (PA) curve. We show, however, that the influence of the sweep back on the outer boundary of the open field line region (open volume) is a much larger effect, of the order of r(sup 1/2 sub n). The open volume is shifted backwards with respect to the rotation direction by an angle delta(sub o nu) approx. 0.2 sin alpha r(sup 1/2 sub n) where alpha is the dipole inclination with respect to the rotation axis. The associated phase shift of the pulse profile Delta phi(sub o nu) approx. 0.2 r(sup 1/2 sub n) can easily exceed the shift due to combined effects of aberration and propagation time delays (approx. 2r(sub n)). This strongly affects the misalignment of the center of the PA curve and the center of the pulse profile, thereby modifying the delay radius relation. Contrary to intuition, the effect of sweepback dominates over other effects when emission occurs at low altitudes. For r(sub n) < or approx. 3 x 10(exp -3) the shift becomes negative, i.e. the center of the position angle curve precedes the profile center. With the sweepback effect included, the modified delay-radius relation predicts larger emission radii and is in much better agreement with the other methods of determining r(sub n).

Dyks, J.↗

CHANDRA Observations of V407 Vul: Confirmation of the Spin-up

V407 Vu1 (RX J1914.4+2456) is a candidate double-degenerate binary with a putative 1.756 mHz (9.5 min) orbital frequency. In a previous timing study using archival ROSAT and ASCA data we reported evidence for an increase of this frequency at a rate consistent with expectations for gravitational radiation from a detached ultracompact binary system. Here we report the results of new Chandra timing observations which confirm the previous indications of spin-up of the X-ray frequency, and provide much tighter constraints on the frequency derivative, nu (raised dot). We obtained with Chandra a total of 90 ksec of exposure in two epochs separated in time by 11.5 months. The total time span of the archival ROSAT, ASCA and new Chandra data is now approximately equal to 10.5 years. This more than doubles the interval spanned by the ROSAT and ASCA data alone, providing much greater sensitivity to a frequency derivative. With the addition of the Chandra data an increasing frequency is unavoidable, and the mean nu (raised dot) is 7.0 plus or minus 0.8 x l0(exp -18) Hz per second. Although a long-term spin-up trend is confirmed, there is excess variance in the phase timing residuals, perhaps indicative of shorter timescale torque fluctuations or phase instability associated with the source of the X-ray flux. Power spectral searches for periods longward of the 9.5 minute period do not find any significant modulations, however, the sensitivity of searches in this frequency range are somewhat compromised by the dithering of the Chandra attitude. The observed spin-up is of a magnitude consistent with that expected from gravitational radiation decay, however, the factor of approximately equal to 3 variations in flux combined with the timing noise could conceivably result from accretion-induced spin-up of a white dwarf. Continued monitoring to explore correlations of torque with X-ray flux could provide a further test of this hypothesis.

Strohmayer, T.↗