Effects of volatility, viscosity, and non-ideality on particle–particle mixing timescales of secondary organic aerosols
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Schervish, Meredith↗
SEARCH · Engineering Papers
Results for “mixed effects”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Modeling hydrodynamics, magnetic fields, and synthetic radiographs for high-energy-density plasma flows in shock-shear targets
Three-dimensional FLASH radiation-magnetohydrodynamics (radiation-MHD) modeling is carried out to study the hydrodynamics and magnetic fields in the shock-shear derived platform. Here, simulations indicate that fields of tens of Tesla can be generated via the Biermann battery effect due to vortices and mix in the counterpropagating shock-induced shear layer. Synthetic proton radiography simulations using MPRAD and synthetic X-ray image simulations using SPECT3D are carried out to predict the observable features in the diagnostics. Quantifying the effects of magnetic fields in inertial confinement fusion and high-energy-density plasmas represents frontier research that has far-reaching implications in basic and applied sciences.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Atwood effects on nonlocality of the scalar transport closure in Rayleigh-Taylor mixing
The importance of nonlocality is assessed in modeling mean scalar transport for turbulent Rayleigh-Taylor (RT) mixing at different Atwood numbers. Building on the two-dimensional incompressible work of Lavacot et al. [J. Fluid Mech. 985, A47 (2024)], the present work extends the macroscopic forcing method to variable density problems in three-dimensional space to measure moments of the generalized eddy diffusivity kernel in RT mixing for increasing Atwood numbers (𝐴 = 0.05, 0.3, 0.5, 0.8). It is found that as 𝐴 increases, (1) the eddy diffusivity moments become asymmetric and (2) the higher-order eddy diffusivity moments become larger relative to the leading-order diffusivity, indicating that nonlocality becomes more important at higher 𝐴. There is a particularly strong temporal nonlocality at higher 𝐴, suggesting stronger history effects. In conclusion, the implications of these findings for closure modeling for finite-Atwood RT are discussed.
general physics↗
Deployment of Low Temperature Aluminum Dissolution (LTAD) Technology to Retrieve H-Modified (HM) Sludge in SRS Tank 15 – 25672
Tank 15 is a 4,234,000-liter (1,118,500-gallon) Type 2 high-level waste storage tank located in H Tank Farm at the Savannah River Site. It was put into service in 1960 to receive high-activity, H-Modified (HM) waste from H Canyon. Between June 1964 and November 1972, the waste tank was filled six times, and supernate was decanted five times, leaving behind the sludge solids. Tank 15 also received a mixture of high-activity and low-activity HM waste from Tank 16. Tank 15 has more recently undergone several mixing campaigns to remove much of the sludge waste; however, the effectiveness of suspending the sludge heel via mechanical mixing has significantly diminished. Low Temperature Aluminum Dissolution (LTAD) is a process developed for the dissolution of suspended aluminum solids in a large waste storage tank. Originally intended for deployment during the preparation of sludge batches in H Tank Farm for the Defense Waste Processing Facility (DWPF), the process involves maintaining the waste storage tank at a slightly elevated temperature and highly alkaline chemistry to facilitate dissolution of aluminum solids. As mechanical heel removal efforts diminished in effectiveness in Tank 15, LTAD was selected to both reduce the volume of sludge solids remaining in the heel and to modify the sludge rheology to facilitate the suspension of additional solids using the installed mixing devices.
Campbell, Seth G.↗
Sensitivity of Global Ocean Deoxygenation to Vertical and Isopycnal Mixing in an Ocean Biogeochemistry Model
Large-scale loss of oxygen under global warming is termed “ocean deoxygenation” and is caused by the imbalance between physical supply and biological consumption of oxygen in the ocean interior. Significant progress has been made in the theoretical understanding of ocean deoxygenation; however, many questions remain unresolved. The oxygen change in the tropical thermocline is poorly understood, with diverging projections among different models. Physical oxygen supply is controlled by a suite of processes that transport oxygen-rich surface waters into the interior ocean, which is expected to weaken due to increasing stratification under global warming. Using a numerical model and a series of sensitivity experiments, the role of ocean mixing is examined in terms of effects on the mean state and the response to a transient warming. Both vertical and horizontal (isopycnal) mixing coefficients are systematically varied over a wide range, and the resulting oxygen distributions in equilibrated and transient simulations are examined. The spatial patterns of oxygen loss are sensitive to both vertical and isopycnal mixing, and the sign of tropical oxygen trend under climate warming can reverse depending on the choice of mixing parameters. An elevated level of isopycnal mixing disrupts the vertical advective-diffusive balance of the tropical thermocline, increasing the mean state oxygen as well as the magnitude of the transient oxygen decline. These results provide first-order explanations for the diverging behaviors of simulated tropical oxygen with respect to ocean mixing parameters.
58 GEOSCIENCES↗
Operability of a Natural Gas–Air Rotating Detonation Engine
A combustor was developed to operate with natural gas and air as the primary propellants at elevated chamber pressures and air preheat temperatures representative of land-based power generation gas turbine engines. Detonation dynamics were studied to characterize the operability of rotating detonation-based pressure gain combustion systems for this application. Measurements of chamber wave dynamics were performed using high-frequency pressure transducers and high-speed imaging of broadband combustion chemiluminescence. The rotating detonation engine was tested with two injector configurations across a broad range of mass flux (200–500 kg/m 2 /s), equivalence ratio (0.85–1.2), and oxygen mass fraction (23.2–35%) conditions to determine the effect of operating parameters on the propagation of detonation waves in the combustor. Wave propagation speeds of up to 70% of the mixture Chapman–Jouguet detonation velocity and chamber pressure fluctuations greater than 4 times the mean chamber pressure were observed. Supplementing the air with additional oxygen, varying the equivalence ratio, and enriching the fuel with hydrogen revealed that combustor operability is sensitive to the chemical kinetics of the propellant mixture. Comparing the operational trends of the two injector configurations suggests that one design mixes the incoming propellants more effectively. Although most test conditions exhibited counter-rotating detonation waves within the chamber, the injector design with superior mixing characteristics was able to support single-wave propagation.
20 FOSSIL-FUELED POWER PLANTS↗
Experimental measurement of the rapid mixing of fuel and air in a multi-element diffusion (Hencken) burner
Flat flame burners are valuable tools for studying complex combustion phenomena like particle synthesis due to the well-controlled and well-behaved initial and boundary conditions. In this study, the methane/air flame temperature and tracer density profiles of a multi-element diffusion burner equipped with a central tube were characterized using krypton (Kr) x-ray fluorescence at the Advanced Photon Source at Argonne National Laboratory. The experiments were performed using a fuel-to-oxygen equivalence ratio of 0.8 and 3.3% Kr by volume was added to the reactant gases. One- and two-dimensional scans of non-combusting (i.e., cold flow) and combusting conditions, both with and without flow through the central tube were performed. Spatially-resolved Kr number density profiles were obtained at different planar locations and heights above the surface of the burner. The results show rapid mixing occurred near the exit-plane of the burner and increased spatial uniformity was achieved from 0.1 mm to 0.5 mm above the surface of the burner. Further, the data also showed the impact of the central tube flow on the main methane/air flame, including evidence of the central tube flow mixing with the main flow. Flame temperatures were calculated from the fluorescence measurements at various heights above the burner surface and were in good agreement with model predictions for a burner stabilized flame. These high-fidelity measurements provide accurate baseline data that are particularly valuable for understanding the effects of fuel and air mixing on downstream phenomena, such as the formation of condensed-phase products.
42 ENGINEERING↗
Constraints on light dark sector particles from lifetime difference of heavy neutral mesons
Heavy meson decays with missing energy in the final state offer interesting avenues to search for light invisible new physics such as dark matter (DM). In this context, we show that such new physics (NP) interactions also affect lifetime difference in neutral meson-antimeson mixing. We consider general dimension-six effective quark interactions involving a pair of DM particles and calculate their contributions to lifetime difference in beauty and charm meson systems. We use the latest data on mixing observables to constrain the relevant effective operators. We find that lifetime differences provide novel and complementary flavor constraints compared to those obtained from heavy meson decays. Published by the American Physical Society 2024
Astronomy & Astrophysics↗
Using Downwelling Far- and Thermal-Infrared Hyperspectral Radiance for Cloud Phase Classification in the Antarctic
The cloud phase is one of the most important parameters of clouds. In this paper, we propose a method for cloud phase classification that synergistically utilizes the far- and thermal-infrared bands based on the Atmospheric Emitted Radiance Interferometer (AERI) at the Atmospheric Radiation Measurement West Antarctic Radiation Experiment (AWARE) observatory in 2016. The possible features in the far- and thermal-infrared bands are analyzed based on the differences in the simulated cloud brightness temperature (BT) spectra with different cloud phases. Using the support vector machine (SVM) algorithm, four features are determined to identify the cloud phase, which include the BT at 900 cm -1 , the slope of the fitted function of BT in the 900–1000 cm -1 interval, the BT difference (BTD) between 512 cm -1 and 726 cm -1 , and the BTD between 550 cm -1 and 726 cm -1 . Here, the performance of the proposed method is evaluated with Shupe’s and Turner’s method. The monthly average accuracy of the proposed method, the method without the two far-infrared features, and Turner’s method are about 76%, 36%, and 49%, respectively, which infer the good performance of the proposed method and also indicate that the far-infrared band features can effectively enhance cloud phase classification. It is notable that, compared to Shupe’s method, the accuracy for the proposed method is only 61% during the Antarctic summer, which results from the definitions of cloud phase and radiative effect. In addition, the accuracy is only 44% for Turner’s method in seasons with a low frequency of mixed clouds due to the significant effect of water vapor.
54 ENVIRONMENTAL SCIENCES↗
Charge transport in mixed metal halide perovskite semiconductors
Investigation of the inherent field-driven charge transport behaviour of three-dimensional lead halide perovskites has largely remained challenging, owing to undesirable ionic migration effects near room temperature and dipolar disorder instabilities prevalent specifically in methylammonium-and-lead-based high-performing three-dimensional perovskite compositions. Here, in this paper, we address both these challenges and demonstrate that field-effect transistors based on methylammonium-free, mixed metal (Pb/Sn) perovskite compositions do not suffer from ion migration effects as notably as their pure-Pb counterparts and reliably exhibit hysteresis-free p-type transport with a mobility reaching 5.4 cm 2 V –1 s -1 . The reduced ion migration is visualized through photoluminescence microscopy under bias and is manifested as an activated temperature dependence of the field-effect mobility with a low activation energy (~48 meV) consistent with the presence of the shallow defects present in these materials. An understanding of the long-range electronic charge transport in these inherently doped mixed metal halide perovskites will contribute immensely towards high-performance optoelectronic devices.
77 NANOSCIENCE AND NANOTECHNOLOGY↗
Anion Association Strength as a Unifying Descriptor for the Reversibility of Divalent Metal Deposition in Nonaqueous Electrolytes
Developing next-generation battery chemistries that move beyond traditional Li-ion systems is critical to enabling transformative advances in electrified transportation and grid-level energy storage. Here, we provide the first evidence for common descriptors for improved reversibility of metal plating/stripping in nonaqueous electrolytes for multivalent ion batteries. Focusing first on the specific role of chloride (Cl – ) in promoting electrochemical reversibility in multivalent systems, rotating disk (RDE) and ring-disk electrode (RRDE) investigations were performed utilizing a variety of divalent cations (Mg 2+ , Zn 2+ , and Cu 2+ ) and the bis-(trifluoromethane sulfonyl) imide (TFSI – ) anion. By introducing varying concentrations of Cl – , a cooperative effect is observed between TFSI – and Cl – that yields the more reversible behavior of mixed electrolytes relative to electrolytes containing only TFSI – . This effect is shown to be general for Mg, Zn, and Cu electrodeposition, and mechanistic understanding of the role of Cl – in improving reversibility of TFSI-based electrolytes is obtained through the combination of R(R)DE experimental results and density functional theory (DFT) evaluation of the redox activity and thermodynamic stability of various TFSI- and Cl-based solution complexes of metal ions. The cooperative anion effect is further generalized to other mixed-anion systems, where systematic variations in anion association strength predicted from DFT (i.e., Cl – > OTf – ≈ TFSI – > BF 4 – > PF 6 – ) yield corresponding trends in redox potentials and improvements of ≥200 mV in the reversibility of metal deposition/dissolution. These results identify anion association strength as a common descriptor for the reversibility of divalent metal anodes and suggest a set of general design principles for developing new electrolytes with improved activity and stability.
25 ENERGY STORAGE↗
Substitution or Shared Utilization? Intrahousehold Vehicle Use in Mixed-Powertrain Households
While previous research has focused heavily on understanding the factors deriving alternative fuel vehicle adoption rates, there remains a significant gap in understanding how households distribute mileage across different powertrains. This study utilizes data from the 2022 Next Generation National Household Travel Survey to investigate vehicle miles traveled within a sample of 150 plug-in electric vehicle (PEV)-owning households (in which at least one battery electric vehicle is present), characterizing how different powertrains are integrated into daily mobility. Leveraging a Seemingly Unrelated Regression (SUR) framework the study jointly models the utilization of PEVs, hybrid electric vehicles (HEV), and internal combustion engine vehicles (ICEVs) while accounting for household-level substitution effects. The results provide evidence of an asymmetric substitution effect. In households with mixed-powertrain configurations, the ICEV captures a substantially higher share of household miles (compared with the PEV), acting as a utility sponge. Conversely, the model identifies specific socioeconomic and geographic cohorts that prioritize PEV as the primary household workhorse, indicating a systematic sorting effect. Although the sample size limits broader generalizability, these findings suggest that PEVs are used for frequent, specific routine-intensive roles, whereas the ICEV remains a specialized utility vehicle. These insights highlight distinct intrahousehold vehicle use behaviors that are often obscured by aggregate fleetwide statistics.
25 ENERGY STORAGE↗
Shear Assisted Processing and Extrusion (ShAPE) of Plastics: Recycling and Remolding
Polyethylene (PE) and polypropylene (PP) are often disposed as mixed plastic wastes. The challenges in recycling and upcycling these mixed polyolefin wastes lie in the difficulty in separating individual constituents in a cost-effective and scalable manner. Direct recycling the mixed PE and PP wastes in conventional melt-phase extruders typically result in a product with poor properties and low added value, because of immiscibility, phase separation, and lack of crystallinity. Friction extrusion (FE), a solid phase processing technique that has successfully extruded metal matrix composites with desired end products, has never been utilized to address the issue of recycling mixed plastic wastes. In this study, FE was performed on single-stream low-density polyethylene (LDPE), single-stream PP and mixed-stream LDPE+PP. Consolidated filaments of 2.5 mm diameter were extruded from different precursors. The thermal, infrared, and microscopic properties of extruded filaments were measured to evaluate the effects of FE process on the structure of recycled polymers. Meanwhile, the energy efficiency of FE was estimated based on extrusion rates and compared with conventional melt extrusion processes.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
Multi-regime mixing modeling for local extinction and re-ignition in turbulent non-premixed flame by using LES/FDF method
Local extinction and re-ignition occur in turbulent non-premixed combustion when the Damköhler number is not large enough and the combustion is not fully mixing controlled. The occurrence of local extinction introduces locally extinguished flame holes followed by a premixed flame propagation toward the hole center to potentially reignite the flame. The co-existence of the non-premixed and premixed combustion regimes complicates the modeling since traditional combustion models are mostly for a single regime. In this work, we examine the effect of multi-regime mixing modeling in the transported filtered density function (FDF) method on the predictions of local extinction and reignition. Predictions of local extinction and reignition remain a challenge for the FDF method despite the progress made in the past. To account for the multi-regime combustion, two different mixing timescale models for non-premixed and premixed combustion are combined. A flame index based on the gradients of fuel and oxidizer is used to define a weighting factor to blend the two mixing timescale models. A turbulent jet non-premixed flame with substantial local extinction, the Sydney piloted jet flame L, is adopted as a test case to examine the performance of the multi-regime model in large-eddy simulation/FDF modeling. It is found that the traditional non-premixed mixing timescale model when combined with the modified Curl mixing leads to global extinction for the Sydney flame L without the presence of the premixed combustion regime. After accounting for the multi-regime combustion with proper detection of the different combustion regimes, the predictions for the flame statistics and the amount of local extinction are significantly improved. Furthermore, it suggests the need of including multi-regime combustion for the predictions of local extinction and re-ignition in turbulent non-premixed combustion configurations.
42 ENGINEERING↗
The toughest animals of the Earth versus global warming: Effects of long‐term experimental warming on tardigrade community structure of a temperate deciduous forest
Abstract Understanding how different taxa respond to global warming is essential for predicting future changes and elaborating strategies to buffer them. Tardigrades are well known for their ability to survive environmental stressors, such as drying and freezing, by undergoing cryptobiosis and rapidly recovering their metabolic function after stressors cease. Determining the extent to which animals that undergo cryptobiosis are affected by environmental warming will help to understand the real magnitude climate change will have on these organisms. Here, we report on the responses of tardigrades within a five‐year‐long, field‐based artificial warming experiment, which consisted of 12 open‐top chambers heated to simulate the projected effects of global warming (ranging from 0 to 5.5°C above ambient temperature) in a temperate deciduous forest of North Carolina (USA). To elucidate the effects of warming on the tardigrade community inhabiting the soil litter, three community diversity indices (abundance, species richness, and Shannon diversity) and the abundance of the three most abundant species ( Diphascon pingue , Adropion scoticum , and Mesobiotus sp.) were determined. Their relationships with air temperature, soil moisture, and the interaction between air temperature and soil moisture were tested using Bayesian generalized linear mixed models. Despite observed negative effects of warming on other ground invertebrates in previous studies at this site, long‐term warming did not affect the abundance, richness, or diversity of tardigrades in this experiment. These results are in line with previous experimental studies, indicating that tardigrades may not be directly affected by ongoing global warming, possibly due to their thermotolerance and cryptobiotic abilities to avoid negative effects of stressful temperatures, and the buffering effect on temperature of the soil litter substrate.
54 ENVIRONMENTAL SCIENCES↗
Magnetism in metastable and annealed compositionally complex alloys
Compositionally complex materials (CCMs) present a potential paradigm shift in the design of magnetic materials. These alloys exhibit long-range structural order coupled with limited or no chemical order. As a result, extreme local environments exist with a large variations in the magnetic energy terms, which can manifest large changes in the magnetic behavior. In the current work, the magnetic properties of (Cr, Mn, Fe, Ni) alloys are presented. These materials were prepared by room-temperature combinatorial sputtering, resulting in a range of compositions with a single bcc structural phase and no chemical ordering. The combinatorial growth technique allows CCMs to be prepared outside of their thermodynamically stable phase, enabling the exploration of otherwise inaccessible order. The mixed ferromagnetic and antiferromagnetic interactions in these alloys causes frustrated magnetic behavior, which results in an extremely low coercivity (<1mT), which increases rapidly at 50 K. At low temperatures, the coercivity achieves values of nearly 500 mT, which is comparable to some high-anisotropy magnetic materials. Further, commensurate with the divergent coercivity is an atypical drop in the temperature dependent magnetization. These effects are explained by a mixed magnetic phase model, consisting of ferro-, antiferro-, and frustrated magnetic regions, and are rationalized by simulations. A machine-learning algorithm is employed to visualize the parameter space and inform the development of subsequent compositions. Annealing the samples at 600 °C orders the sample, more-than doubling the Curie temperature and increasing the saturation magnetization by as much as 5×. Simultaneously, the large coercivities are suppressed, resulting in magnetic behavior that is largely temperature independent over a range of 350 K. The ability to transform from a hard magnet to a soft magnet over a narrow temperature range makes these materials promising for heat-assisted recording technologies.
36 MATERIALS SCIENCE↗
Pulsed Light Synthesis of High Entropy Nanocatalysts with Enhanced Catalytic Activity and Prolonged Stability for Oxygen Evolution Reaction
The ability to synthesize compositionally complex nanostructures rapidly is a key to high-throughput functional materials discovery. In addition to being time-consuming, a majority of conventional materials synthesis processes closely follow thermodynamics equilibria, which limit the discovery of new classes of metastable phases such as high entropy oxides (HEO). Herein, a photonic flash synthesis of HEO nanoparticles at timescales of milliseconds is demonstrated. By leveraging the abrupt heating and cooling cycles induced by a high-power-density xenon pulsed light, mixed transition metal salt precursors undergo rapid chemical transformations. Hence, nanoparticles form within milliseconds with a strong affinity to bind to the carbon substrate. Oxygen evolution reaction (OER) activity measurements of the synthesized nanoparticles demonstrate two orders of magnitude prolonged stability at high current densities, without noticeable decay in performance, compared to commercial IrO 2 catalyst. This superior catalytic activity originates from the synergistic effect of different alloying elements mixed at a high entropic state. It is found that Cr addition influences surface activity the most by promoting higher oxidation states, favoring optimal interaction with OER intermediates. The proposed high-throughput method opens new pathways toward developing next-generation functional materials for various electronics, sensing, and environmental applications, in addition to renewable energy conversion.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
INL_Intern_Poster_ColeBailey [Poster]
Understanding the thermophysical properties of molten salts is crucial for the advancement of nuclear fuels. This project presents the design of a custom differential thermal analyzer (DTA) that utilizes non-contact ultrasonic mixing to agitate samples and prevent supercooling. The supercooling effect occurs when a liquid is below its freezing point without solidifying. This can be observed when a liquid in a freezer instantly transitions to its solid phase upon disturbance. By avoiding this effect, accurate transition temperatures of molten salts can be gathered for future applications. Initial mixing results were promising, leading to further refinement of the waveguides using ABAQUS to maximize input energy into the fluid. Future work will focus on integrating both mixing and cooling in conjunctions to observe the avoided effect.
46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗