Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “grain texture”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 343 records · Page 19

Petrology and thermal history of type IA chondrules in the Semarkona (LL3.0) chondrite

Detailed petrologic studies have been made of 15 type IA, Fe-poor, porphyritic olivine chondrules in Semarkona (LL3.0). Major and minor element concentrations in olivines, pyroxenes, and mesostases, and bulk composition so the chondrules are measured along with zoning profiles in the olivine and pyroxene crystals. The mineral compositions and textures are best interpreted in terms of closed system crystallization in which the olivines and pyroxenes crystallized in situ from a melt corresponding to the bulk composition of the chondrule. Relict olivine grains are not found in the chondrules. Crystallization probably occurred at a cooling rate of the order of 1000 C/hr. Precursor materials of the chondrules were composed of two components, one refractory Ca-, Al-, and Ti-rich, and one less refractory Si-, Fe-, Cr-, and Mn-rich. The evidence is consistent with Semarkona being one of the least metamorphosed ordinary chondrites.

Jones, R. H.↗

Cathodoluminescence observations of in situ aqueous destruction of chondrules in the Murchison CM chondrite

A low-power cathodoluminescence (CL) mosaic of a 1x2 cm section of the Murchison CM chondrite contains chondrules of two types: one contains olivines with red CL and is thought to be the equivalent of group A chondrules of Sears et.; and one without observable CL, which is probably equivalent to their group B chondrules. Both types of chondrule contain dust mantles with a characteristic uniform red CL due to very fine-grained forsterites, but the mantles of group A chondrules have a complex internal structure and are much thicker than the relatively thin rims on the group B chondrules. The variety of internal textures and the progressive integration of the objects with the surrounding matrix suggests to us that these features are large group A chondrules in the process of being destroyed by aqueous alteration. Prior to aqueous alteration, group A chondrules in CM chondrites were larger than group B chondrules, which is contrary to the situation in ordinary chondrites and were apparently destroyed more rapidly than group B chondrules by aqueous alteration.

Sears, Derek W. G.↗

Assessing the Effects of Various Surface Textures and Features on Turbulent Heat Transfer in Hypersonic Flight

Experiments were conducted in the NASA Ames Hypervelocity Free Flight Aerodynamic Facility (ballistic range) to quantify the effects on turbulent convective heat transfer of distributed surface roughness, and of isolated features, representative of thermal protection systems on atmospheric entry vehicles. The surface textures and features were applied on the conic frusta of 45o sphere-cone models having a nose-to-base radius ratio of 0.5, similar to the forebody geometry of the Galileo and Pioneer-Venus entry probes. Test conditions were selected to provide turbulent roughness Reynolds numbers, k+, in the ranges expected for outer planet entry missions. Turbulent flow on the conic frustum was achieved by tripping the flow on the sphere-segment nose cap with distributed surface roughness, created by sand-blasting the nose cap. Surface textures included distributed, acreage, roughness, as well as cavity and groove discrete features. The majority of the data to be presented are results for distributed roughness, which includes both random, sand-grain-like roughness, and regular pattern roughness. The pattern roughness was designed to represent the roughness on woven thermal protection system materials, such as NASA’s 3-D Medium Density Carbon Phenolic (3MDCP), also known as HEEET, developed by the Heatshield for Extreme Entry Environments Technology project. The pattern roughness tested is a 3-D wavy surface, and includes three different roughness element height-to-spacing ratios representative of two configurations of 3MDCP, and spanning ratios measured both before, and after, ablation in an arc jet test facility. The patterns tested in the ballistic range were laser-etched on metal models, and represented an idealized version of the real-world materials in which each roughness element was nearly identical. Additional tests were performed wherein the laser-etched patterns were degraded by sand-blasting with various sized grit media, to produce regular patterns with superimposed irregular roughness, more representative of flight materials. Results of each will be compared. The discrete features tested included cylindrical cavities and rectangular grooves of various width-to-depth ratios. Cavities represent either heatshield damage, such as from micro-meteoroid and orbital debris (MMOD) damage, or from designed penetrations, such as on the Genesis sample return capsule. The grooves were scaled representations of seams between segments of HEEET material in a notional tiled thermal protection system. The tests examined the effects on turbulent heating downstream of the isolated features. The tests were conducted at speeds between 3 km/s and 4 km/s in air between 0.15 atm and 0.25 atm (Mach numbers between 9 and 12). Roughness Reynolds numbers, k+, ranged from 12 to 70 for the sand roughness, and as high as 200 for the pattern roughness. Boundary-layer parameters required for calculating k+ were evaluated using computational fluid dynamics simulations using the DPLR (Data Parallel Line Relaxation) code. Each model included both rough- and smooth-wall segments, and heat transfer augmentation factors were determined as the ratio of the rough-wall to smooth-wall heat flux measured on each test.

hypersonic↗

New Directions in the Quest for Unaltered Ci-Like Material From the Early Solar System

CI meteorites have bulk chemical compositions closely matching the solar photosphere (except volatiles) and thus are considered to represent the starting composition of the Solar System. The return of CI-like samples from asteroid (162173) Ryugu by Hayabusa2 has greatly bolstered studies of CI. However, both CI and the Ryugu samples are CI1, i.e., they were extensively altered by aqueous fluids on their parent bodies so the mineralogy, textures, and oxygen isotope compositions of their CI3 precursors have been obscured. Fortunately, they contain rare remnants of primordial minerals in the form of small anhydrous silicate and Ca-Al-rich grains, and detailed petrologic and isotopic studies of these grains have helped elucidate the nature of their precursors. Here, we continue our work on petrologic and isotopic studies of such phases in Ryugu particle C0137.

C A Goodrich↗

Apollo 14 breccias - General characteristics and classification.

The Apollo 14 breccias are complex and are characterized by a wide range of clast types and textures. The principal fragment types in the breccias are (1) hornfelsed noritic microbreccias; (2) micronorite hornfels; (3) devitrified glass; and (4) ophitic and other kinds of basalt. Based on fragment population, nature of the matrix, grain size and porosity, metamorphic history, and bulk chemical composition, the Apollo 14 breccias can be classified chiefly into regolith microbreccias, Fra Mauro breccias, and spherule-rich microbreccias. Further subdivisions are based principally on the interpretation of metamorphic history. Twenty-six Apollo 14 breccias have been so classified. The complex fragment types contained in Apollo 14 breccias represent multiple episodes of heating and fragmentation. They probably are pre-Imbrian and were not produced by the impact effects of a single event. The variability of their fragment populations is important in the interpretation of pre-Imbrian geologic history.

Chao, E. C. T.↗

Petrological Traverse of the Olivine Cumulate Séítah Formation at Jezero Crater, Mars: A Perspective From SuperCam Onboard Perseverance

Séítah is the stratigraphically lowest formation visited by Perseverance in the Jezero crater floor. We present the data obtained by SuperCam: texture by imagery, chemistry by Laser-Induced Breakdown Spectroscopy, and mineralogy by Supercam Visible and Infrared reflectance and Raman spectroscopy. The Séítah formation consists of igneous, weakly altered rocks dominated by millimeter-sized grains of olivine with the presence of low-Ca and high-Ca pyroxenes, and other primary minerals (e.g., plagioclase, Cr-Fe-Ti oxides, phosphates). Along a ∼140 m long section in Séítah, SuperCam analyses showed evidence of geochemical and mineralogical variations, from the contact with the overlying Máaz formation, going deeper in the formation. Bulk rock and olivine Mg#, grain size, olivine content increase gradually further from the contact. Along the section, olivine Mg# is not in equilibrium with the bulk rock Mg#, indicating local olivine accumulation. These observations are consistent with Séítah being the deep ultramafic member of a cumulate series derived from the fractional crystallization and slow cooling of the parent magma at depth. Possible magmatic processes and exhumation mechanisms of Séítah are discussed. Séítah rocks show some affinity with some rocks at Gusev crater, and with some Martian meteorites suggesting that such rocks are not rare on the surface of Mars. Séítah is part of the Nili Fossae regional olivine-carbonate unit observed from orbit. Future exploration of Perseverance on the rim and outside of the crater will help determine if the observations from the crater floor can be extrapolated to the whole unit or if this unit is composed of distinct sub-units with various origins.

Mars 2020↗

TEM studies of a circumstellar rock

Reported here is the discovery of crystals of titanium carbide in a grain of silicon carbide which formed as a circumstellar dust particle in the atmosphere of a carbon-rich star. Just as in the case of terrestrial rocks, whose assemblage of minerals gives us clues to the composition and conditions of the environment in which they formed, the titanium carbide crystals and their textural relationship to the silicon carbide give us important clues to the nature of the stellar atmosphere in which they formed. From microscopic studies of the relationships between the atomic planes of the silicon carbide and the titanium carbide, we can show that the titanium carbide cannot have existed as already-formed crystals in a gas around which silicon carbide subsequently condensed. An alternative possibility is that both minerals grew quickly and simultaneously from condensing gas in the rapidly cooling and expanding stellar atmosphere. Other microscopic features of the silicon carbide, such as abundant atomic layer disorder and crystal twinning, similarly suggest rapid grain growth. However, another possibility is that the titanium carbide grew inside of the silicon carbide by diffusion of titanium atoms. Our calculations suggest that this scenario is less likely, given the relatively short times (a year or less) for which stellar condensates can be expected to be exposed to temperatures high enough to make diffusion sufficiently rapid.

Bernatowicz, Thomas J.↗

Looking for a Source of Water in Martian Basltic Breccia NWA 7034

The recently described martian meteorite NWA 7034 has high water content compared to other SNC meteorites. Deuterium to hydrogen isotope ratio measurements indicates that there are two distinct delta-D components in NWA 7034, a low temperature (150-500degC) light component around -100per mille and a high temperature (300-1000degC) heavy component around +300per mille. NWA 7034 contains iron-rich phases that are likely secondary aqueous alteration products. They are commonly found as spheroidal objects of various sizes that are often rich in Fe-Ti oxides and possibly iron hydroxides. Iron oxides and oxyhydroxides are very common in weathered rocks and soils on Earth and Mars and they are important components of terrestrial and Martian dust. In NWA 7034 iron-rich phases are found throughout the fine-grained basaltic groundmass of the meteorite. The total amount of martian H2O in NWA 7034 is reported to be 6000 ppm, and in this study we attempt to determine the phase distribution of this H2O by texturally describing and characterizing hydrous phases in NWA 7034, using Fourier transform infrared spectrometry (FTIR) and transmission electron microscopy (TEM).

Muttik, N.↗

The unexpected surface of asteroid (101955) Bennu

NASA’S Origins, Spectral Interpretation, Resource Identification and Security-Regolith Explorer (OSIRIS-REx) spacecraft recently arrived at the near-Earth asteroid (101955) Bennu, a primitive body that represents the objects that may have brought prebiotic molecules and volatiles such as water to Earth1. Bennu is a low-albedo B-type asteroid2 that has been linked to organic-rich hydrated carbonaceous chondrites3. Such meteorites are altered by ejection from their parent body and contaminated by atmospheric entry and terrestrial microbes. Therefore, the primary mission objective is to return a sample of Bennu to Earth that is pristine—that is, not affected by these processes4. The OSIRIS-REx spacecraft carries a sophisticated suite of instruments to characterize Bennu’s global properties, support the selection of a sampling site and document that site at a sub-centimetre scale5,6,7,8,9,10,11. Here we consider early OSIRIS-REx observations of Bennu to understand how the asteroid’s properties compare to pre-encounter expectations and to assess the prospects for sample return. The bulk composition of Bennu appears to be hydrated and volatile-rich, as expected. However, in contrast to pre-encounter modelling of Bennu’s thermal inertia12 and radar polarization ratios13—which indicated a generally smooth surface covered by centimetre-scale particles—resolved imaging reveals an unexpected surficial diversity. The albedo, texture, particle size and roughness are beyond the spacecraft design specifications. On the basis of our pre-encounter knowledge, we developed a sampling strategy to target 50-metre-diameter patches of loose regolith with grain sizes smaller than two centimetres4. We observe only a small number of apparently hazard-free regions, of the order of 5 to 20 metres in extent, the sampling of which poses a substantial challenge to mission success.

D. S. Lauretta↗

Mineralogy of nakhlite Martian meteorites: Implications for their relative burial depths

Nakhlites are Martian cumulate rocks mainly composed of augite with variable amounts of olivine and groundmass (mesostasis). Currently seven samples are known: Nakhla (Nak), Governador Valadares (GV), Lafayette (Laf), NWA817, Y000593 (Y), NWA998 and MIL03346 (MIL). All the nakhlites show a similar unbrecciated cumulate texture, and their identical crystallization and exposure ages suggest that they originated from the same igneous body on Mars and were ejected by the same impact event. It is important to study difference of their mineralogy to reconstruct the igneous body from which nakhlites originated. Augite grains in all nakhlites have a nearly identical core composition (En39Fs22Wo39) and have thin Fe-rich rims. These Fe-rich rims are zoned to Ca-poor pyroxene compositions and the degree of chemical zoning varies from one sample to another. NWA998 has the most Mg-rich edge composition. The edge composition becomes more Fe-rich in the order of Laf, Nak/GV, Y and NWA817. Unlike other samples, the Fe-rich edge of MIL augite is zoned to the hedenbergite composition. Olivine grains in all samples except Laf and NWA998 show extensive chemical zoning whose degree is clearly related to the chemical zoning of pyroxenes. MIL and NWA817 have the widest compositional ranges (Fa54-93). Y has a slightly narrower compositional range of Fa58-85. Nak and GV have even narrower ranges (Fa58-72). In contrast to these samples, olivines in Laf and NWA998 are homogeneous (Fa66-67 and Fa61-62, respectively). Such chemical zoning (Fa and Ca) can be used to quantitatively estimate their cooling rates (burial depths) because it was clearly formed by interaction with the intercumulus melt. The obtained burial depths are 1-2 m for NWA817, 4 m for MIL, 7 m for Y, approx.10 m for Nak and GV, and >30 m for Laf and NWA998. This order is clearly related to the degree of pyroxene chemical zoning. The abundance and mineralogy of nakhlite groundmass are also consistent with this order. In Nak, GV and Laf, the groundmass abundance is about 7-8%. Y and NWA998 have a slightly higher abundance (10%), while NWA817 and MIL have much higher abundance (20-24%). The groundmass texture is also related to its abundance. The groundmass of Nak, GV, Laf and Y is mainly composed of feldspar laths. In contrast, NWA817 and MIL have glassy mesostasis without feldspar crystals. In NWA998, feldspar is a large blocky crystal with clear twinning, suggesting that it is even deeper than Laf.

Mikouchi, T.↗

Surface texture of Vesta from optical polarimetry

Polarimetric, photometric, and reflective spectroscopic properties of asteroid 4 Vesta are simulated in the laboratory by a preparation of eucrite Bereba consisting of a broad mixture of particle sizes (mainly greater than 50-micron) mixed and partially coated with particles of size 10 microns and less. Coarse grains are necessary for producing the same albedo and a very fine dust coating is necessary for producing the same polarization inversion angle as observed for Vesta. There are less small grains and fine dust in this sample than in lunar soils. Photometrically, if coating a sphere, this sample shows a constant brightness on the sunward half of the observed hemisphere, the brightness being given on the other half by the Minnaert reciprocity principle. With such a photometric behavior, the global geometric albedo and the sub-earth point geometric albedo differ by no more than 5%. The microscopic phase coefficient is 0.021 magnitude per degree for the sample; the larger value, 0.025, observed telescopically for Vesta, indicates that large-scale roughness is present on this asteroid.

Le Bertre, T.↗

Textural evidence bearing on the origin of isolated olivine crystals in C2 carbonaceous chondrites

In some cases the mechanical competence of chondrules in carbonaceous chondrites has been reduced by alteration of their mesostasis glass to friable phyllosilicate, providing a mechanism by which euhedral olivines can be separated from chondrules. Morphological features of isolate olivine grains found in carbonaceous chondrites are similar to those of olivine phenocrysts in chondrules. These observations suggest that the isolated olivine grains formed in chondrules, by crystallization from a liquid, rather than by condensation from a vapor.

Richardson, S. M.↗

Microstructural Evolution of the Civet Cat Norite (72255)

The ‘Civet Cat Norite’ is a ~ 2.5 cm clast within the Apollo impact melt breccia sample 72255 collected during Apollo 17 EVA 2 at Boulder 1. The norite is primarily composed of plagioclase and orthopyroxene with fine-scale exsolution lamellae of augite. The plagioclase and orthopyroxene (OPX) coexist with minor quartz and augitic clinopyroxene (CPX), and accessory apatite, baddeleyite, chromite, ilmenite, loveringite, merrillite, rutile and zircon. The major minerals range from 1 to 4 mm in size and show a cataclastic texture indicated by banding of the light and dark phases]. The chemical composition of the orthopyroxene, augitic exsolution lamellae, and exsolved oxides suggest the norite crystallized in the lower crust of the Moon (10 – 70 km depth) and was subsequently excavated by impact(s). Shock pressure estimates for the norite range from 15 – 35 GPa based on maskeleynite formation within the plagioclase, kink banding in pyroxenes, and granular recrystallization in the accessory phosphates. Previous Rb-Sr and 40 Ar/ 39 Ar analyses recalculated with modern decay constants yield relatively young ages of 4.16 ± 0.05 Ga and 3.99 ± 0.03 Ga, respectively. However, recent U-Pb analyses of some zircon grains from within the Civet Cat yield an age of 4.45 ± 0.03 Ga. While this is the oldest age for any rock recovered from the Moon, the full age spread of zircon from the Civet Cat range from ca. 4.46 to 4.02 Ga, indicating variable Pb-loss and complicating interpretation of the primary age. Recent atom probe analyses indicate minimal Pb mobilization within the oldest zircon grain from Civet Cat, supporting the interpretation that these ancient zircon ages reflect the age of the norite, rather than an apparent antiquity caused by reverse discordance. To investigate the potential antiquity and deep crustal origin of the Civet Cat norite, we have undertaken high resolution microstructural analyses of the major, minor, and accessory minerals to characterize the primary igneous textures and secondary overprinting by impact and metamorphism. The employed analytical techniques include scanning electron microscope-based electron backscatter diffraction (EBSD) analyses, electron probe microanalyzer (EPMA) chemical analyses, and transmission electron microscopy (TEM) of pyroxene, plagioclase, quartz, zircon, and phosphates.

T M Erickson↗

Petrology and geochemistry of the high-pressure Nilgiri Granulite Terrane, Southern India

The Nilgiri granulite terrane in Southern India is predominantly composed of late Archaean medium- to coarse-grained enderbitic to charnockitic rocks. The dominant regional foliation strikes N60 to 70E with generally steep dips. Tight minor isoclinal folds have been observed in places. Granoblastic polygonal micro-structures are common and indicate thorough post-kinematic textural and chemical equilibration at conditions of the granulite facies (2.5 Ga ago). Late compressional deformation in connection with the formation of the Moyar and Bhavani shear zones to the north and south of the Nilgiri block, resulted in wide-spread development of weakly to strongly strained fabrics and was accompanied by minor rehydration. Enderbites and charnockites range from tonalitic to granodioritic in composition. A magmatogenic origin of the protoliths is inferred from their chemical characteristics which resemble those of the andesitic to dacitic members of Cordillera-type calc-alkaline igneous suites. A significant lithological feature of the Nilgiri granulite terrane are numerous extended bodies, lenses and pods of gabbroic and pyroxenitic rocks which are aligned conformable to the foliation of the enderbite-charnockite complex and which have also been deformed and metamorphosed at granulite facies conditions.

Srikantappa, C.↗

Recrystallization and superplasticity at 300 C in an aluminum-magnesium alloy

Variations in thermomechanical processing (TMP) which regulate the microstructural characteristics and superplastic response of an Al-10Mg-0.1Zr alloy at 300 C were evaluated. Mechanical property data revealed that the superplastic ductility can be enhanced by simultaneously increasing the total rolling strain, the reduction per pass, and the duration of reheating intervals between passes during isothermal rolling. Texture and microscopy data were consistent with the development of a refined microstructure by recovery-dominated processes, i.e., continuous recrystallization, during the processing. The mechanisms by which a refined substructure can be progressively converted into a fine-grained structure during repeated cycles of deformation and annealing are addressed. A qualitative description of the complex sequence of developments leading to a microstructure better suited to support superplastic response is presented.

Hales, S. J.↗

Planetary Regolith Microstructure: An Unexpected Opposition Effect Result

The Opposition Effect (OE) is the non-linear increase in the intensity of light scattered from a surface as phase angle approaches 0 deg. It is seen in laboratory experiments and in remote sensing observations of planetary surfaces. Understanding the OE is a requirement to fitting photometric models which will produce meaningful results about regolith texture. Our previous laboratory studies are consistent with the hypothesis that the OE in particulate materials is due to two processes, Shadow Hiding (SHOE) and Coherent Backscattering (CBOE). SHOE arises because, as phase angle approaches zero, shadows cast by regolith grains on other grains become invisible to the observer. CBOE results from constructive interference between rays traveling the same path but in opposite directions. In this study we measured the angular scattering properties of 9 mixtures of Aluminum Oxide and Boron Carbide powders of the same particle diameter (25 microns). The reflectance of the materials ranged from 7% (pure B4C) to 91% (pure Al2O3). Along with the reflectance phase curve we measured the circular polarization ratio (CPR) - the ratio of the intensity of the light returned with the same helicity as the incident light to that with the opposite helicity. An increase in CPR with decreasing phase angle indicates increased multiple scattering and is consistent with CBOE (Hapke, 1993). Popular conceptions of CBOE (Belskaya et al, 2003) hold that materials of higher albedo would exhibit increased multiple scattering and that the contribution of CBOE to the OE would increase as albedo increases. Remarkably, we find the highest albedo samples did not have the strongest CBOE opposition peaks. Instead, the maximum CBOE contribution is observed in samples with reflectance between 15 and 40%.

Nelson, R. M.↗

Alkali-granitoids as fragments within the ordinary chondrite Adzhi-Bogdo: Evidence for highly fractionated, alkali-granitic liquids on asteroids

Adzhi-Bogdo is an ordinary chondrite regolith breccia (LL3-6) that fell October 30, 1949 in Gobi Altay, Mongolia. The rock consists of submm- to cm-sized fragments embedded in a fine-grained elastic matrix. The breccia contains various types of clasts, some of which must be of foreign heritage. Based on chemical compositions of olivine some components have to be classified as L-type. Components of the breccia include chondrules, impact melts (some are K-rich, similar to those found in other LL-chondrites, highly recrystalized rock fragments ('granulites'), pyroxene-rich fragments with achondritic textures, and alkali-granitoidal fragments that mainly consist of K-feldspar and quartz or tridymite. Probably, this is the first report on granitoids from asteroids. It can be ruled out that these fragments represent huge rock assemblages of the parent body like granites do on Earth. Therefore, to avoid misunderstandings, these rocks will be designated as granitoids. In one thin section four granitoids were observed. The main phases within these clasts are K-feldspar and SiO2-phases. Minor phases include albite, Cl-apatite, whitlockite, ilmenite, zircon, Ca-poor pyroxene, and an unidentified Na,Ti-bearing silicate. Based on chemical composition and on optical properties quartz appears to be the SiO2-phase in two fragments, whereas tridymite seems to occur in the other two. The calculated formula of the unknown Na,Ti-rich silicate is very close to (Na,Ca)2.7(Fe,Mg)6(Ti)1.3(Si)7(O)24. Quartz and K-feldspar can reach sizes of up to 700 microns. Thus, the fragments can be described as coarse-grained (by chondritic standards). This is especially the case considering that quartz and K-feldspar are very rare minerals in ordinary chondrites. Representative analyses of minerals from some granitoidal clasts are given. Based on the mineral compositions and the modal abundances the bulk compositions were calculated. Besides these granitoidal rocks, pyroxene-rich fragments occur that show exsolution textures that are similar to those found in eucrites.

Bischoff, A.↗

Metal and associated phases in Bishunpur, a highly unequilibrated ordinary chondrite

Bishunpur is one of the most unequilibrated ordinary chondrites, and preserves a relatively unaltered record of solar nebular processes. A survey of three polished thin sections of Bishunpur revealed that metal occurs in three textural domains: (1) in the matrix, (2) within chondrules and (3) in coatings on chondrules. A table provides a textural classification of the various metal types found in Bishunpur and their composition. Electron-microprobe analyses are discussed, and similarities between Bishunpur metal and opaques and those in carbonaceous chondrites are considered. Attention is given to low-Ni kamacite grains in chondrule olivine, Si-bearing chondrule metal, spheroidal metal in chondrules, metal and sulfide-bearing rims, coarse matrix metal, and fine matrix metal formation.

Rambaldi, E. R.↗