SEARCH · Engineering Papers

Results for “generative diffusion”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 343 records · Page 19

All sources NASA NTRS DOE OSTI

NASA NTRS1986

Application of a computational model for vortex generators in subsonic internal flows

A model for the analysis of vortex generators in a fully viscous subsonic internal flow is evaluated. A vorticity source term is used in a modified form of the Parabolized Navier-Stokes equations to model the shed vortex. Computed results are compared with idealized flow vortex paths, and with experimental data for vortex generators embedded in a thick turbulent boundary layer. The analysis is also compared with experimental data for a separated diffusing S-duct and for a diffusing S-duct with vortex generators. Quantitative comparisons are shown for the latter three cases. Emphasis is placed on verifying the ability of the model to predict global distortions in the flow field.

Kunik, W. G.↗

NASA NTRS1986

Application of a computational model for vortex generators in subsonic internal flows

Kunik, W. G.↗

NASA NTRS1985

Sealed bipolar multi-cell battery

A low maintenance battery comprises a sealed casing (102) having a cavity (204) receiving a stack (108) of monopolar and bipolar plates (110, 112) interspersed with mats (122) of fiberglass felt immobilizing electrolyte and forming a gas path for diffusion of oxygen to the negative electrode (112). The casing contains a single, resealable vent (202). During charging, oxygen generated at the positive plate (110) diffuses through the mat (122) and decomposes at the negative plate (112). The negative plate (112) has a larger capacity than the positive plate (110) to prevent evolution of hydrogen. Voltage potential is increased or decreased by placing one or more bipolar plates (120) in series relation between alternating positive and negative monopolar plates that are connected in parallel to respective positive and negative battery terminals (104, 106). The monoplates (110, 112) are connected in parallel to respective positive and negative battery terminals (104, 106) by way of bus plates (114, 116, 130, 132). The resealable vent permits operation by way of the oxygen cycle which prevents loss of electrolyte. The vent prevents invasion of oxygen from the ambient to discharge negative plates.

Rowlette, John J.↗

DOE OSTI2015

Recent Advances in Continuum Modeling of Interfacial and Transport Phenomena in Electric Double Layer Capacitors

Here, whis paper reviews recent advances in physical modeling of interfacial and transport phenomena in electric double layer capacitors (EDLCs) under both equilibrium and dynamic cycling. The models are based on continuum theory and account for (i) the Stern layer at the electrode/electrolyte interface, (ii) finite ion sizes, (iii) steric repulsions, (iv) asymmetric electrolytes featuring ions with different valencies, effective diameters, or diffusion coefficients, (v) electric-field-dependent dielectric permittivity of the electrolyte, and/or (vi) porous three-dimensional morphology of the electrodes. Typical characterization methods such as electrochemical impedance spectroscopy, cyclic voltammetry, and galvanostatic cycling were reproduced numerically to identify the dominant physical phenomena and to gain insight into experimental observations. In addition, recent thermal models derived from first principles for EDLCs under constant-current cycling accounting for irreversible Joule heating and reversible heat generation rates due to ion diffusion, steric effects, and changes in entropy are discussed. Scaling analyses of both equilibrium and dynamic models are also presented as a way to identify self-similar and asymptotic behaviors as well as to develop design rules for electrodes and electrolytes of next generation EDLCs. Throughout the document, special effort has been made to compare model predictions with experimental observations and reported data.

25 ENERGY STORAGE↗

NASA NTRS1972

Dynamic flow angle measurements at the diffuser exit of a Mach 2.5 mixed compression inlet

An exploratory investigation was made to determine the magnitude of the dynamic flow angle at a single point in the diffuser exit of a Mach 2.50 inlet. Results indicate that the maximum flow angle variation was + or - 3 degrees except when vortex generators were installed in the subsonic diffuser. The amplitude of these flow angle fluctuations was directly related to the amplitude of the total pressure fluctuations at the probe survey point. Flow angle fluctuations as high as + or - 11 degrees were recorded when vortex generators were installed near the probe survey point.

Prati, W. M.↗

DOE OSTI2014

Cyanide does more to inhibit heme enzymes, than merely serving as an active-site ligand

Highlights: • Cyanide (CN) is a well-studied toxic principle, known to inhibit heme-enzymes. • Inhibition is supposed to result from CN binding at the active site as a ligand. • Diverse heme enzymes’ CN inhibition profiles challenge prevailing mechanism. • Poor binding efficiency of CN at low enzyme concentrations and ligand pressures. • CN-based diffusible radicals cause ‘non-productive electron transfers’ (inhibition). - Abstract: The toxicity of cyanide is hitherto attributed to its ability to bind to heme proteins’ active site and thereby inhibit their activity. It is shown herein that the long-held interpretation is inadequate to explain several observations in heme-enzyme reaction systems. Generation of cyanide-based diffusible radicals in heme-enzyme reaction milieu could shunt electron transfers (by non-active site processes), and thus be detrimental to the efficiency of oxidative outcomes.

60 APPLIED LIFE SCIENCES↗

DOE OSTI2013

Experimental Studies of Particle Acceleration and Heating During Magnetic Reconnection

Energy conversion from magnetic energy to particle energy during magnetic reconnection is studied in the collisionless plasma of the Magnetic Reconnection Experiment (MRX). The plasma is in the two-fluid regime, where the ion motion is decoupled from that of the electron within the so-called ion diffusion region. For ion heating and acceleration, the role of the in-plane (Hall) electric field is emphasized. The in-plane potential responsible for the Hall electric field is established by electrons that are accelerated near the small electron diffusion region. The in-plane electrostatic potential profile shows a well structure along the direction normal to the reconnection current sheet that becomes deeper and wider downstream as its boundary expands along the separatrices where the in-plane electric field is strongest. Since the Hall electric field is 3--4 times larger than the reconnection electric field, unmagnetized ions obtain energy mostly from the in-plane electric field, especially near the separatrices. The Hall electric field ballistically accelerates ions near the separatrices toward the outflow direction. After ions are accelerated, they are heated as they travel into the high pressure downstream region. This downstream ion heating cannot be explained by classical, unmagnetized transport theory, which suggests that the magnetic field should be important due to an effect called re-magnetization. Electrons are also significantly heated during reconnection. The electron temperature sharply increases across the separatrices and peaks just outside of the electron diffusion region. Unlike ions, electrons acquire energy mostly from the reconnection electric field and the energy gain is localized near the X-point. However, the electron bulk flow energy increase remains negligible. These observations support the assertion that efficient electron heating mechanisms exist around the electron diffusion region and that the generated heat is quickly transported along the magnetic field due to the high parallel thermal conductivity of electrons. Classical Ohmic dissipation based on the perpendicular Spitzer resistivity is too small to compensate the heat flux, indicating the presence of anomalous electron heating. Finally, a total energy inventory is calculated based on analysis of the Poynting, enthalpy, flow energy, and heat flux in the measured diffusion layer. More than half of the incoming magnetic energy is converted to particle energy during collisionless reconnection. Unlike in the Sweet-Parker model, the outgoing Poynting flux is not negligible, which is due to considerable Hall fields, i.e., the quadrupole out-of-plane magnetic field and the in-plane electric field. The total ion energy gain during reconnection is larger than that of electrons, since the energy gain occurs over a broader region. The total ion thermal energy gain is larger than the increase of the ion flow energy. Finally, the electron thermal energy gain is comparable to the ion thermal energy gain, while the electron flow energy remains insignificant.

electron heating↗

DOE OSTI2025

Plasma instabilities dominate radioactive transients magnetic fields: the self-confinement of leptons in Type Ia and core-collapse supernovae, and kilonovae

The light curves of radioactive transients, such as supernovae and kilonovae, are powered by the decay of radioisotopes, which release high-energy leptons through $\beta ^+$ and $\beta ^-$ decays. These leptons deposit energy into the expanding ejecta. As the ejecta density decreases during expansion, the plasma becomes collisionless, with particle motion governed by electromagnetic forces. In such environments, strong or turbulent magnetic fields are thought to confine particles, though the origin of these fields and the confinement mechanism have remained unclear. Using fully kinetic particle-in-cell (PIC) simulations, we demonstrate that plasma instabilities can naturally confine high-energy leptons. These leptons generate magnetic fields through plasma streaming instabilities, even in the absence of pre-existing fields. The self-generated magnetic fields slow lepton diffusion, enabling confinement, and transferring energy to thermal electrons and ions. Our results naturally explain the positron trapping inferred from late-time observations of thermonuclear and core-collapse supernovae. Furthermore, they suggest potential implications for electron dynamics in the ejecta of kilonovae. We also estimate synchrotron radio luminosities from positrons for Type Ia supernovae and find that such emission could only be detectable with next-generation radio observatories from a Galactic or local-group supernova in an environment without any circumstellar material.

instabilities↗

NASA NTRS1991

Monatomic-Oxygen Reactors For Materials Testing And Surface Chemistry

Two kinds of gas-flow reaction chambers expose specimens of materials to spatially even fluxes of monatomic oxygen. Monatomic oxygen diffuses along side-arm tubes attached to flowing-after-glow apparatus. If rate of diffusion high enough, specimens at ends of these tubes receive uniform doses. Monatomic oxygen generated by photolysis in pulsed laser beam diffuses sideways out of laser beam and onto nearby surfaces of specimens.

Koontz, Steve↗

DOE OSTI2025

Plastic from CO 2 , Water, and Electricity: Tandem Electrochemical CO 2 Reduction and Thermochemical Ethylene-CO Copolymerization

Converting CO 2 into industrially useful products is an appealing strategy for utilization of an abundant chemical resource. Electrochemical CO 2 reduction (eCO 2 R) offers a pathway to convert CO 2 into CO and ethylene, using renewable electricity. Here, these products can be efficiently copolymerized by organometallic catalysts to generate polyketones. However, the conditions for these reactions are very different, presenting the challenge of coupling microenvironments typically encountered for the transformation of CO 2 into highly complex but desirable multicarbon products. Herein, we present a system to produce polyketone plastics entirely derived from CO 2 and water, where both the CO and C 2 H 4 intermediates are produced by eCO 2 R. In this system, a combination of Cu and Ag gas diffusion electrodes is used to generate a gas mixture with nearly equal concentrations of CO and C 2 H 4 , and a recirculatory CO 2 reduction loop is used to reach concentrations of above 11% each, leading to a current-to-polymer efficiency of up to 51% and CO 2 utilization of 14%.

carbon storage↗

DOE OSTI2025

Point cloud-based diffusion models for the Electron-Ion Collider

At high-energy collider experiments, generative models can be used for a wide range of tasks, including fast detector simulations, unfolding, searches of physics beyond the Standard Model, and inference tasks. In particular, it has been demonstrated that score-based diffusion models can generate high-fidelity and accurate samples of jets or collider events. This work expands on previous generative models in three distinct ways. First, our model is trained to generate entire collider events, including all particle species with complete kinematic information. We quantify how well the model learns event-wide constraints such as the conservation of momentum and discrete quantum numbers. We focus on the events at the future Electron-Ion Collider, but we expect that our results can be extended to proton-proton and heavy-ion collisions. Second, previous generative models often relied on image-based techniques. The sparsity of the data can negatively affect the fidelity and sampling time of the model. We address these issues using point clouds and a novel architecture combining edge creation with transformer modules called Point Edge Transformers. Third, we adapt the foundation model OmniLearn, to generate full collider events. This approach may indicate a transition toward adapting and fine-tuning foundation models for downstream tasks instead of training new models from scratch.

Araz, Jack Y. [Stony Brook Univ., NY (United State↗

NASA NTRS1980

Thin n-i-p silicon solar cell

A space solar cell concept which combines high cell output with low diffusion length damage coefficients is presented for the purpose of reducing solar cell susceptibility to degradation from the radiation environment. High resistivity n-i-p silicon solar cells ranging from upward of 83 micron-cm were exposed to AM0 ultraviolet illumination. It is shown that high resistivity cells act as extrinsic devices under dark conditions and as intrinsic devices under AM0 illumination. Resistive losses in thin n-i-p cells are found to be comparable to those in low resistivity cells. Present voltage limitations appear to be due to generation and recombination in the diffused regions.

Meulenberg, A., Jr.↗

DOE OSTI2021

Short-range thermal magnon diffusion in magnetic garnet

Here, using the spin Seebeck effect (SSE), we study the propagation distance of thermally induced spin currents inside a magnetic insulator thin film in the short-range regime. We disambiguate spin currents driven by temperature and chemical potential gradients by comparing the SSE signal before and after adding a heat-sinking capping layer on the same device. We report that the measured spin decay behavior near the heat source is well accounted for by a diffusion model where the magnon diffusion length is in submicron range, in other words, two orders of magnitude smaller than previous estimates inferred from the long-range behavior. Our results highlight the caveat in applying a diffusive theory to describe thermally generated magnon transport, where a single decay length may not capture the behavior on all length scales.

36 MATERIALS SCIENCE↗

DOE OSTI2025

Superionic-like diffusion in yttrium dihydride

For the next-generation high temperature microreactors, yttrium dihydride (YH 2 ) is an attractive solid state neutron moderator. Despite a number of recent investigations, the mechanism of hydrogen transport remains poorly understood. Experimental evaluations of diffusivity are inconclusive with large variations in diffusivities and activation energies. In this work, we perform ab initio molecular dynamics (AIMD) simulations on YH 2 for temperatures spanning 300 K to 1200 K. Our main finding is that YH 2 shows a superionic-like behavior with hydrogen atoms hopping from one native site to another above a characteristic temperature of 800 K. This correlated motion results in quasi-one-dimensional string-like displacements that enable the hydrogen atoms to diffuse rapidly. We confirm that the octahedral sites are mostly unoccupied, although channeling through them is the most favored pathway between lattice hops above 800 K. At the highest temperature of 1200 K, the string relaxation time is merely of the order of a few picoseconds, which indicates a liquid-like diffusive behavior. Based on the formation of spontaneous thermal vacancies, an order-disorder crossover temperature T α ~ 800 K is established for YH 2 with an activation energy of 0.83 eV for hydrogen diffusion in the superionic-like state.

Superionic-like Diffusion↗

NASA NTRS1993

Turbulent structure of a wingtip vortex in the near field

The turbulent rollup of a vortex generated by a rectangular wing has been investigated. Extensive mean and turbulence measurements of the flowfield on a wingtip and in the near field have been completed. Velocity fluctuation measurements show that the near-field core is not laminar. A large axial velocity excess was found to exist in the core of the vortex. A momentum balance in the near-field of the wingtip showed that the magnitude of the core Reynolds-stress gradient terms are the same order as the largest terms in the governing equations. Navier-Stokes computations of the identical configuration, including wind tunnel walls and using measured inflow and outflow boundary conditions, reproduced many of the features of the experiment. Inherent limitations of the Baldwin-Barth turbulence model combined with limited grid resolution caused the computed vortex core to be more diffuse than desired. The momentum balance also demonstrated that the level of numerically generated false diffusion in the vortex core is relatively high.

Zilliac, Gregory G.↗

DOE OSTI2019

Entropy-based closure for probabilistic learning on manifolds

In a recent paper, the authors proposed a general methodology for probabilistic learning on manifolds. The method was used to generate numerical samples that are statistically consistent with an existing dataset construed as a realization from a non-Gaussian random vector. The manifold structure is learned using diffusion manifolds and the statistical sample generation is accomplished using a projected Itˆo stochastic differential equation. This probabilistic learning approach has been extended to polynomial chaos representation of databases on manifolds and to probabilistic nonconvex constrained optimization with a fixed budget of function evaluations. The methodology introduces an isotropic-diffusion kernel with hyperparameter ". Currently, " is more or less arbitrarily chosen. In this paper, we propose a selection criterion for identifying an optimal value of ", based on a maximum entropy argument. The result is a comprehensive, closed, probabilistic model for characterizing data sets with hidden constraints. This entropy argument ensures that out of all possible models, this is the one that is the most uncertain beyond any specified constraints, which is selected. Applications are presented for several databases.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2022

Floquet stability analyses of stratified oscillating boundary layers on adiabatic slopes

The presence of a no-slip, impermeable, adiabatic, sloped boundary in an otherwise quiescent, stably stratified, Boussinesq flow generates baroclinic vorticity within a diffusive boundary layer. Such conditions are typical of the oscillating boundary layers on adiabatic abyssal slopes, sloped lake bathymetry and sloped coastal bathymetry in the absence of high-wavenumber internal waves, mean flows, far-field turbulence on larger scales, and resonant tidal–bathymetric interaction. We investigate the linear stability of the oscillating flow within non-dimensional parameter space typical of the $M_2$ tide and hydraulically smooth, middle-latitude abyssal slopes through Floquet linear stability analysis. The flow dynamics depends on three non-dimensional variables: the Reynolds number for Stokes’ second problem, the Prandtl number, and a frequency ratio that accounts for the resonance conditions ($C$, criticality) of the buoyant restoring force and the tidal forcing. The Floquet analysis results suggest that oscillating laminar boundary layers on adiabatic abyssal slopes are increasingly unstable as Reynolds number, criticality parameter and/or spanwise disturbance wavenumber are increased. We also show that the two-dimensional Floquet linear instability necessarily generates three-dimensional baroclinic vorticity, which suggests that the evolution of the gravitational instabilities may be nonlinear as $t→∞$.

42 ENGINEERING↗

DOE OSTI2018

Self-hydrogenated shell promoting photocatalytic H 2 evolution on anatase TiO 2

As one of the most important photocatalysts, TiO 2 has triggered broad interest and intensive studies for decades. Observation of the interfacial reactions between water and TiO 2 at microscopic scale can provide key insight into the mechanisms of photocatalytic processes. Currently, experimental methodologies for characterizing photocatalytic reactions of anatase TiO 2 are mostly confined to water vapor or single molecule chemistry. Here, we investigate the photocatalytic reaction of anatase TiO 2 nanoparticles in water using liquid environmental transmission electron microscopy. A self-hydrogenated shell is observed on the TiO 2 surface before the generation of hydrogen bubbles. First-principles calculations suggest that this shell is formed through subsurface diffusion of photo-reduced water protons generated at the aqueous TiO 2 interface, which promotes photocatalytic hydrogen evolution by reducing the activation barrier for H 2 (H–H bond) formation. Experiments confirm that the self-hydrogenated shell contains reduced titanium ions, and its thickness can increase to several nanometers with increasing UV illuminance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗