Induction heating simplifies metal evaporation for ion plating
Evaporation by induction heating produces significant degree of metal ionization, enhancing degree of penetration of evaporant on substrate.
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Evaporation by induction heating produces significant degree of metal ionization, enhancing degree of penetration of evaporant on substrate.
Development of the Prototype 2 and 3 flash evaporator heat sinks which vaporize an expendable fluid to cool a heat transport fluid loop is reported. The units utilize Freon 21 as the heat transport fluid and water as the expendable fluid to meet the projected performance requirements of the space shuttle for both on-orbit and ascent/reentry operations. The evaporant is pulse-sprayed by on-off control onto heat transfer surfaces containing the transport fluid and exhausted to the vacuum environment through fixed area exhaust ducts.
The heat transfer rate in the meniscus attachment region of a grooved heat pipe evaporator is studied theoretically. The analysis shows that the evaporation takes place mainly in the region where the liquid changes its shape sharply. However, comparisons with available heat transfer data indicate that the heat transfer rate in the meniscus varying region is substantially reduced probably due to groove wall surface roughness.
Measurements were conducted on an evaporating spray in a stagnant environment. The spray was formed using an air-atomizing injector to yield a Sauter mean diameter of the order of 30 microns. The region where evaporation occurred extended approximately 1 m from the injector for the test conditions. Profiles of mean velocity, temperature, composition, and drop size distribution, as well as velocity fluctuations and Reynolds stress, were measured. The results are compared with a locally homogeneous two-phase flow model which implies no velocity difference and thermodynamic equilibrium between the phases. The flow was represented by a k-epsilon-g turbulence model employing a clipped Gaussian probability density function for mixture fraction fluctuations. The model provides a good representation of earlier single-phase jet measurements, but generally overestimates the rate of development of the spray. Using the model predictions to represent conditions along the centerline of the spray, drop life-history calculations were conducted which indicate that these discrepancies are due to slip and loss of thermodynamic equilibrium between the phases.
A description is given of the experimental apparatus and the methods used in the investigation of the degree of fuel (kerosene) evaporation in two types of vaporizing elements in combustion chambers. The results are presented as dependences of the degree of fuel evaporation on the factors which characterize the functioning of the vaporizing elements: the air surplus coefficient, the velocity of flow and temperature of the air at the entrance to the vaporizing element and the temperature of the wall of the vaporizing element.
A model of spray evaporation which employs a second-order turbulence model in conjunction with the locally homogeneous flow approximation, which implies infinitely fast interphase transport rates is presented. Measurements to test the model were completed for single phase constant and variable density jets, as well as an evaporating spray in stagnant air. Profiles of mean velocity, composition, temperature and drop size distribution as well as velocity fluctuations and Reynolds stress, were measured within the spray. Predictions were in agreement with measurements in single phase flows and also with many characteristics of the spray, e.g. flow width, radial profiles of mean and turbulent quantities, and the axial rate of decay of mean velocity and mixture fraction.
Measured reflection efficiencies are presented for flat samples of diamond-turned aluminum, nickel, and evaporated gold surfaces fabricated by techniques suited for EUV telescopes. The aluminum samples were 6.2-cm-diameter disks of 6061-T6, the electroless nickel samples were formed by plating beryllium disks with 7.5-microns of Kanigen. Gold samples were produced by coating the aluminum and nickel samples with 5 strips of evaporated gold. Reflection efficiencies are given for grazing angles in the 5-75 degree range. The results indicate that for wavelengths over about 100 A, the gold-coated nickel samples yield highest efficiencies. For shorter wavelengths, the nickel samples yield better efficiencies. 500 A is found to be the optimal gold thickness.
From the properties of matter the conclusion is derived that the mineral assemblage characteristic of most chondritic meteorites is not at all what is expected to form directly from solar matter. Rather, the major minerals of the ordinary chondrites have chemical compositions indicative of formation from a medium greatly depleted in hydrogen and somewhat deficient in oxygen relative to solar elemental abundance ratios. The re-evaporation of condensed material, after separation from a large fraction of the gaseous components of solar matter, will lead to a medium of the appropriate composition. Such re-evaporation must have occurred at a time prior to the formation of many primitive meteorites.
Films of superconducting Chevrel-phase copper molybdenum sulfide CuxMo6S8 were deposited on sapphire substrates by reactive evaporation using H2S as the reacting gas. Two superconducting temperatures (10.0 K and 5.0 K) of the films were found, corresponding to two different phases with different copper concentrations. All films were superconducting above 4.2 K and contained Chevrel-phase compound as well as free molybdenum. The critical current was measured as a function of applied field. One sample was found to deviate from the scaling law found for co-evaporated or sputtered samples, which possibly indicates a different pinning mechanism or inhomogeneity of the sample.
Thin films of Cr, Mo, and W rapidly evaporated in high vacuum (5 x 10 to the -7th torr) onto room-temperature substrates show anomalously low reflectance (compared to bulk samples). From electron and X-ray diffraction and electron microscopy, the normal bcc crystal structure is found, but with very fine grains. Columnar grains about 100 A in diameter were separated by a less dense grain-boundary network about 10-A wide. The measured optical conductivity agrees with an inhomogeneous-medium model that assumes the normal crystalline conductivity for the grain interiors, with model parameters that correlate to the observed columnar grain size. In contrast, V and Nb films rapidly evaporated onto room-temperature substrates have the reflectance of bulk crystalline material. On liquid-nitrogen temperature substrates, however, V and Nb have normal bcc crystal structure but with small flat-plate grains, and the same model, with appropriate parameters, accounts for the optical conductivity. The difference between these two groups apparently depends on residual gases segregated at the grain boundaries in the Cr-group films.
The dense polydisperse aerosol particles in a quiet chamber may spontaneously go through different microphysical processes including gravitational sedimentation, thermal coagulation, and growth or evaporation. In an earlier paper, we presented the results of a parametric study of the combined and separate effects of thermal coagulation and sedimentation on the time dependence of extinction of four visible and IR laser beams traversing an aerosol medium. As a continuation of this series of studies, the separate and combined effects of growth or evaporation and gravitational sedimentation on the time dependence of extinction of the same four visible and IR laser beams traversing in artificial fogs will be reported in this paper. The method of numerically modeling the change of water droplet size distribution with time due to growth/evaporation and the cutoff of larger aerosols due to gravitational sedimentation is described in detail. Factors governing the relative importance of these two processes are discussed. Results of this study show that the relative humidity or ambient temperature is a crucial parameter in determining the optical depth of the water droplet and aerosol media undergoing microphysical processes.
The effects of growth and evaporation of stratospheric sulfuric acid aerosols on the extinction of solar radiation traversing such an aerosol medium are reported for the case of 1.0-micron solar radiation. Modeling results show that aerosol extinction is not very sensitive to the change of ambient water vapor concentration, but is sensitive to ambient temperature changes, especially at low ambient temperatures and high ambient water vapor concentration. A clarification is given of the effects of initial aerosol size distribution and composition on the change of aerosol extinction due to growth and evaporation processes. It is shown that experiments designed to observe solar radiation extinction of aerosols may also be applied to the determination of observed changes in aerosol optical properties, environmental parameters, or the physical and optical characteristics of sulfate aerosols.
The structure of particle-laden jets and nonevaporating and evaporating sprays was measured in order to evaluate models of these processes. Three models are being evaluated: (1) a locally homogeneous flow model, where slip between the phases is neglected and the flow is assumed to be in local thermodynamic equilibrium; (2) a deterministic separated flow model, where slip and finite interphase transport rates are considered but effects of particle/drop dispersion by turbulence and effects of turbulence on interphase transport rates are ignored; and (3) a stochastic separated flow model, where effects of interphase slip, turbulent dispersion and turbulent fluctuations are considered using random sampling for turbulence properties in conjunction with random-walk computations for particle motion. All three models use a k-e-g turbulence model. All testing and data reduction are completed for the particle laden jets. Mean and fluctuating velocities of the continuous phase and mean mixture fraction were measured in the evaporating sprays.
The recently developed Thermoelectric Integrated Membrane Evaporation Subsystem (TIMES) offers a highly competitive approach to water recovery from waste fluids for future on-orbit stations such as the Space Operations Center. Low power, compactness and gravity insensitive operation are featured in this vacuum distillation subsystem that combines a hollow fiber membrane evaporator with a thermoelectric heat pump. The hollow fiber elements provide positive liquid/gas phase control with no moving parts other than pumps and an accumulator, thus solving problems inherent in other reclamation subsystem designs. In an extensive test program, over 850 hours of operation were accumulated during which time high quality product water was recovered from both urine and wash water at an average steady state production rate of 2.2 pounds per hour.
The results of experimental studies of water storage in a Sitka-spruce canopy are presented and analyzed in terms of model simulations of evaporation. Wet-branch cantilever deflection was measured along with meteorological data on three days in August, 1976, to determine the relationship of canopy evaporation to wind speed and (hence) aerodynamic resistance. Two versions of a simple unilayer model of sensible and latent heat transport from a partially wet canopy were tested in the data analysis: model F1 forbids the exchange of heat between wet and dry foliage surfaces; model F2 assumes that this exchange is highly efficient. Model F1 is found to give results consistent with the rainfall-interception model of Rutter et al. (1971, 1975, 1977), but model F2 gives results which are more plausible and correspond to the multilayer simulations of Sellers and Lockwood (1981) and the experimental findings of Hancock and Crowther (1979). It is inferred that the role of eddy diffusivity for water vapor is enhanced relative to momentum transport, and that the similarity hypothesis used in conventional models may fail in the near vicinity of a forest canopy.
A study is presented of the upward motions of part of the soft X-ray emitting plasma using data for flares collected in 1980 by the Bent Crystal Spectrometer and the Hard X-ray Burst Spectrometer on the Solar Maximum Mission satellite. Results show that upward motions of the soft X-ray plasma are temporally associated with the build up of the thermal phase of flares and with the period of energy deposition as indicated by the hard X-ray emission. In addition, it is found that the hardness of the hard X-ray spectrum, the evaporation velocity, and the rate of increase of the gradual phase are correlated. It is also possible that the total electron energy deposited in the chromosphere, the peak emission measure of the evaporating plasma, and the peak emission measure of the thermal coronal plasma may also be correlated.
The thermal evaporation of a cold spherical cloud embedded in hot gas is analyzed, including the effects of viscous stresses as well as 'saturation' of the conductive heat flux, for the case of equal electron and ion temperatures. The relevant transport properties for an H-He plasma are discussed, including the modification of these transport coefficients when temperature or velocity gradients become large. The fluid-dynamical equations for steady spherical evaporation are given and cast into dimensinless form. Numerical integration of these equations and the results are discussed, emphasizing the novel features of the viscous solutions, astrophysical implications, and uncertainties in the physics.
The vapor pressure and evaporation rate of borides of titanium, zirconium, and chrome; and of strontium and carbides of titanium, zirconium, and chrome, molybdenum silicide; and nitrides of titanium, niobium, and tantalum in a vacuum were studied. It is concluded that all subject compounds evaporate by molecular structures except AlB sub 12' which dissociates, losing the aluminum.