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At least 343 records · Page 19

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NASA NTRS2000

A Probabilistic Technique for Improving the Mid-Swath Wind Direction Accuracy of Scanning Pencil Beam Scatterometers

The SeaWinds on QuikSCAT scatterometer is a device developed by NASA JPL to measure the speed and direction of ocean surface winds. Simulations performed in order to determine the expected performance of the instrument prior to its launch have indicated that the accuracy of the retrieved wind vectors varies across the swath. In particular the mid-swath accuracy is worse than that of the rest of the swath. This behavior is a general characteristic of scanning pencil beam scatterometers. For SeaWinds, the accuracy of the rest of the swath, and the size of the swath are such that the instrument meets its science requirements despite mid-swath shortcomings. However, by understanding the problem at mid-swath, we can improve the performance there as well, yielding even better coverage and accuracy than was originally intended. The mid-swath performance degradation is due to suboptimal viewing geometry. In particular mid-swath measurements contains measurements from two azimuths, roughly 180 degrees apart. With the standard wind retrieval technique, mid-swath root mean square (RMS) wind direction errors are approximately 30 degrees for low wind speeds (3 - 5.5 m/s) and 20 degrees for moderate to high wind speeds (5.5 - 30 m/s). We discuss the underlying causes of this phenomenon in detail and propose a modification to the wind retrieval technique in order to improve mid-swath performance. By estimating the range of likely wind directions for each measurement cell, one can optimally apply information from neighboring cells in order to reduce random wind direction errors without significantly degrading the resolution of the resultant wind field. In this manner we are able to achieve mid-swath RMS wind direction errors as low as 15 degrees for low winds and 10 degrees for moderate to high winds, while at the same time preserving high resolution structures such as cyclones and fronts. Since our results are based on simulated data, we also outline a procedure for making use of real data to optimize the technique after launch.

Stiles, Bryan↗

NASA NTRS2000

Hurricane Directional Wave Spectrum Spatial Variation in the Open Ocean and at Landfall

The sea surface directional wave spectrum was measured for the first time in all quadrants of a hurricane in open water using the NASA airborne scanning radar altimeter (SRA) carried aboard one of the NOAA WP-3D hurricane hunter aircraft at 1.5 km height. The SRA measures the energetic portion of the directional wave spectrum by generating a topographic map of the sea surface. At 8 Hz, the SRA sweeps a radar beam of 1' half-power width (two-way) across the aircraft ground track over a swath equal to 0.8 of the aircraft height, simultaneously measuring the backscattered power at its 36 GHz (8.3 mm) operating frequency and the range to the sea surface at 64 positions. These slant ranges are multiplied by the cosine of the off-nadir angles to determine the vertical distances from the aircraft to the sea surface. Subtracting these distances from the aircraft height produces the sea surface elevation map. The sea surface topography is interpolated to a uniform grid, transformed by a two dimensional FFT, and Doppler corrected. The open-ocean data were acquired on 24 August 1998 when hurricane Bonnie was east of the Bahamas and moving toward 330 deg at about 5 m/s. Individual waves up to 18 m height were observed and the spatial variation of the wave field was dramatic. The dominant waves generally propagated at significant angles to the downwind direction. At some positions there were three different wave fields of comparable energy crossing each other. The NOAA aircraft spent over five hours within 180 km of the eye, and made five eye penetrations. On 26 August 1998, the NOAA aircraft flew at 2.2 km height when hurricane Bonnie was making landfall near Wilmington, NC, documenting the directional wave spectrum in the region between Charleston, SC and Cape Hatteras, NC. The aircraft flight lines included segments near and along the shoreline as well as far offshore. Animations of the directional wave spectrum spatial variation along the aircraft tracks on the two flights will be presented using a 100: 1 time compression.

Walsh, Edward J.↗

NASA NTRS2001

Hurricane Directional Wave Spectrum Spatial Variation in the Open Ocean and at Landfall

The sea surface directional wave spectrum was measured for the first time in all quadrants of a hurricane in open water using the NASA scanning radar altimeter (SRA) carried aboard one of the NOAA WP-3D hurricane research aircraft at 1.5 kilometer height. The SRA measures the energetic portion of the directional wave spectrum by generating a topographic map of the sea surface. The data were acquired on 24 August 1998 when Hurricane Bonnie was 400 km east of Abaco Island, Bahamas. Individual waves with heights up to 19 meters were observed and the spatial variation of the wave field was dramatic. The dominant waves generally propagated at significant angles to the downwind direction. At one position, three different wave systems of comparable energy and wavelength crossed each other. The aircraft spent over five hours within 180 kilometers of the Hurricane Bonnie eye and made five eye penetrations. On 26 August 1998, the SRA at 2.2 kilometer height documented the directional wave spectrum in the region between Charleston, SC, and Cape Hatteras, NC, as Hurricane Bonnie was making landfall near Wilmington, NC. The storm was similar in size during the two flights, but the maximum speed in the NOAA Hurricane Research Division surface wind analysis was 15% lower prior to landfall (39 meters per second) than it had been in the open ocean (46 meters per second). This was compensated for by its faster movement prior to landfall (9.5 meters per second) than when it was encountered in the open ocean (5 meters per second), significantly increasing the effective fetch and duration of waves near the peak of the spectrum which propagated in the direction of the storm track. The open ocean wave height variation indicated that Hurricane Bonnie would have produced waves of 11 meters significant wave height on the shore northeast of Wilmington had it not been for the continental shelf. The bathymetry distributed the steepening and breaking process across the shelf so that the wavelength and wave height were reduced gradually as the shore was approached. The wave height 5 kilometers from shore was about 4 meters.

Walsh, E. J.↗

NASA NTRS1945

Flight Measurements of Lateral and Directional Stability and Control Characteristics of the Grumman F8F-1 Airplane

This paper presents the results of flight tests to determine the lateral and directional stability and control characteristics of the Grumman F8F-1 airplane with three vertical-tail configurations. The data presented herein have no bearing on the performance characteristics of the airplane, which were not measured but which were considered to be exceptionally good. The conclusions reached regarding the lateral and directional stability and control characteristics may be summarized as follows: 1. It was found that the directional stability was poor with the production vertical tail. Addition of a 12-inch extension to the vertical fin and rudder produced a desirable improvement in directional stability and control characteristics. However, further enlargement of the vertical tail would be required to make the directional stability satisfactory in all respects. 2. There was a tendency for the rudder control force to overbalance at large angles of right sideslip with the modified vertical tails. There was no such tendency with the production tail configuration which included a dorsal fin. It was concluded that the dorsal fin should have been retained on the modified vertical tails. 3. The aileron control characteristics were better than those of many comparable airplanes which have been tested. However, the ailerons did not satisfy the Navy requirements for satisfactory flying qualities with regard to either control forces or rolling effectiveness. 4. The power of the rudder trimming tab proved to be inadequate and the tab should be enlarged and/or be provided with an increased deflection range.

Crane, H. L.↗

NASA NTRS2007

Direct Coupling From WGM Resonator Disks to Photodetectors

Output coupling of light from a whispering- gallery-mode (WGM) optical resonator directly to a photodetector has recently been demonstrated. By directly is meant that the coupling is effected without use of intervening optical components. Heretofore, coupling of light into and out of WGM resonators has been a complex affair involving the use of such optical components as diamond or glass prisms, optical fibers, coated collimators, and/or fiber tapers. Alignment of these components is time-consuming and expensive. To effect direct coupling, one simply mounts a photodetector in direct mechanical contact with a spacer that is, in turn, in direct mechanical contact with a WGM resonator disk. The spacer must have a specified thickness (typically of the order of a wavelength) and an index of refraction lower, by an adequate margin, than the indices of refraction of the photodetector and the WGM resonator disk. This mechanically simple approach makes it possible to obtain an optimum compromise between maximizing optical coupling and maximizing the resonance quality factor (Q).

Savchenkov, Antoliy↗

NASA NTRS2006

Instruments for Reading Direct-Marked Data-Matrix Symbols

Improved optoelectronic instruments (specially configured digital cameras) for reading direct-marked data-matrix symbols on the surfaces of optically reflective objects (including specularly reflective ones) are undergoing development. Data-matrix symbols are two-dimensional binary patterns that are used, like common bar codes, for automated identification of objects. The first data-matrix symbols were checkerboard-like patterns of black-and-white rectangles, typically existing in the forms of paint, ink, or detachable labels. The major advantage of direct marking (the marks are more durable than are painted or printed symbols or detachable labels) is offset by a major disadvantage (the marks generated by some marking methods do not provide sufficient contrast to be readable by optoelectronic instruments designed to read black-and-white data-matrix symbols). Heretofore, elaborate lighting, lensing, and software schemes have been tried in efforts to solve the contrast problem in direct-mark matrix- symbol readers. In comparison with prior readers based on those schemes, the readers now undergoing development are expected to be more effective while costing less. All of the prior direct-mark matrix-symbol readers are designed to be aimed perpendicularly to marked target surfaces, and they tolerate very little angular offset. However, the reader now undergoing development not only tolerates angular offset but depends on angular offset as a means of obtaining the needed contrast, as described below. The prototype reader (see Figure 1) includes an electronic camera in the form of a charge-coupled-device (CCD) image detector equipped with a telecentric lens. It also includes a source of collimated visible light and a source of collimated infrared light for illuminating a target. The visible and infrared illumination complement each other: the visible illumination is more useful for aiming the reader toward a target, while the infrared illumination is more useful for reading symbols on highly reflective surfaces. By use of beam splitters, the visible and infrared collimated lights are introduced along the optical path of the telecentric lens, so that the target is illuminated and viewed from the same direction.

Schramm, Harry F.↗

NASA NTRS2005

Simulating a Direction-Finder Search for an ELT

A computer program simulates the operation of direction-finding equipment engaged in a search for an emergency locator transmitter (ELT) aboard an aircraft that has crashed. The simulated equipment is patterned after the equipment used by the Civil Air Patrol to search for missing aircraft. The program is designed to be used for training in radio direction-finding and/or searching for missing aircraft without incurring the expense and risk of using real aircraft and ground search resources. The program places a hidden ELT on a map and enables the user to search for the location of the ELT by moving a 14 NASA Tech Briefs, March 2005 small aircraft image around the map while observing signal-strength and direction readings on a simulated direction- finding locator instrument. As the simulated aircraft is turned and moved on the map, the program updates the readings on the direction-finding instrument to reflect the current position and heading of the aircraft relative to the location of the ELT. The software is distributed in a zip file that contains an installation program. The software runs on the Microsoft Windows 9x, NT, and XP operating systems.

Bream, Bruce↗

NASA NTRS2012

Summary of 2011 Direct and Nearby Lightning Strikes to Launch Complex 39B, Kennedy Space Center, Florida

A Lightning Protection System (LPS) was designed and built at Launch Complex 39B (LC39B), at the Kennedy Space Center (KSC), Florida in 2009. This LPS was instrumented with comprehensive meteorological and lightning data acquisition systems that were deployed from late 2010 until mid 2011. The first direct strikes to the LPS were recorded in March of 2011, when a limited number of sensors had been activated. The lightning instrumentation system detected a total of 70 nearby strokes and 19 direct strokes to the LPS, 2 of the 19 direct strokes to the LPS had two simultaneous ground attachment points (in both instances one channel terminated on the LPS and the other on the nearby ground). Additionally, there are more unaccounted nearby strokes seen on video records for which limited data was acquired either due to the distance of the stroke or the settings of the data acquisition system. Instrumentation deployment chronological milestones, a summary of lightning strikes (direct and nearby), high speed video frames, downconductor currents, and dH/dt and dE/dt typical waveforms for direct and nearby strokes are presented.

Mata, C.T.↗

NASA NTRS2016

The Radial Speed-Expansion Speed Relation for Earth-Directed CMEs

Earth-directed coronal mass ejections (CMEs) are the main drivers of major geomagnetic storms. Therefore, a good estimate of the disturbance arrival time at Earth is required for space weather predictions. The STEREO and SOHO spacecraft were viewing the Sun in near quadrature during January 2010 to September 2012, providing a unique opportunity to study the radial speed (V (sub rad)) to expansion speed(V (sub exp)) relationship of Earth-directed CMEs. This relationship is useful in estimating the V (sub rad) of Earth-directed CMEs, when they are observed from Earth view only. We selected 19 Earth-directed CMEs observed by the Large Angle and Spectrometric Coronagraph (LASCO)/C3 coronagraph on SOHO and the Sun Earth Connection Coronal and Heliospheric Investigation (SECCHI)/COR2 coronagraph on STEREO during January 2010 to September 2012. We found that of the three tested geometric CME models the full ice-cream cone model of the CME describes best the V (sub rad) to V (sub exp) relationship, as suggested by earlier investigations. We also tested the prediction accuracy of the empirical shock arrival (ESA) model proposed by Gopalswamy et al.(2005a), while estimating the CME propagation speeds from the CME expansion speeds. If we use STEREO observations to estimate the CME width required to calculate the V (sub rad) from the V (sub exp) measurements, the mean absolute error (MAE) of the shock arrival times of the ESA model is 8.4 hours. If the LASCO measurements are used to estimate the CME width, the MAE still remains below 17 hours. Therefore, by using the simple V (sub rad) to V (sub exp) relationship to estimate the V (sub rad) of the Earth-directed CMEs, the ESA model is able to predict the shock arrival times with accuracy comparable to most other more complex models.

Makela, P.↗

NASA NTRS2017

Examination of the Structural Response of the Orion European Service Module to Reverberant and Direct Field Acoustic Testing

The NASA Orion Multi-Purpose Crew Vehicle (MPCV), comprised of the Service Module, the Crew Module, and the Launch Abort System, is the next generation human spacecraft designed and built for deep space exploration. Orion will launch on NASAs new heavy-lift rocket, the Space Launch System. The European Space Agency (ESA) is responsible for providing the propulsion sub-assembly of the Service Module to NASA, called the European Service Module (ESM). The ESM is being designed and built by Airbus Safran Launchers for ESA. Traditionally, NASA has utilized reverberant acoustic testing for qualification of spaceflight hardware. The ESM Structural Test Article (E-STA) was tested at the NASA Plum Brook Stations (PBS) Reverberant Acoustic Test Facility in April-May 2016. However, Orion is evaluating an alternative acoustic test method, using direct field acoustic excitation, for the MPCVs Service Module and Crew Module. Lockheed Martin is responsible for the Orion proof-of-concept direct field acoustic test program. The E-STA was exposed to direct field acoustic testing at NASA PBS in February 2017. This paper compares the dynamic response of the E-STA structure and its components to both the reverberant and direct field acoustic test excitations. Advantages and disadvantages of direct field acoustic test excitation method are discussed.

Acoustics↗

NASA NTRS2017

Examination of the Structural Response of the Orion European Service Module to Reverberant and Direct Field Acoustic Testing

Acoustics↗

NASA NTRS2016

Automating Microbial Directed Evolution For Bioengineering Applications

From a micro-biology perspective, directed evolution is a technique that uses controlled environmental pressures to select for a desired phenotype. Directed evolution has the distinct advantage over rational design of not needing extensive knowledge of the genome or pathways associated with a microorganism to induce phenotypes. However, there are currently limitations to the applicability of this technique including being time-consuming, error-prone, and dependent on existing assays that may lack selectivity for the given phenotype. The AADEC (Autonomous Adaptive Directed Evolution Chamber) system is a proof-of-concept instrument to automate and improve the technique such that directed evolution can be used more effectively as a general bioengineering tool. A series of tests using the automated system and comparable by-hand survival assay measurements have been carried out using UV-C radiation and Escherichia coli cultures in order to demonstrate the advantages of the AADEC versus traditional implementations of directed evolution such as random mutagenesis. AADEC uses UV-C exposure as both a source of environmental stress and mutagenesis, so in order to evaluate the UV-C tolerance obtained from the cultures, a manual UV-C exposure survival assay was developed alongside the device to compare the survival fractions at a fixed dosage. This survival assay involves exposing E. coli to UV-C radiation using a custom-designed exposure hood to control the flux and dose. Surviving cells are counted then transferred to the next iteration and so on for several iterations to calculate the survival fractions for each exposure iteration.This survival assay primarily serves as a baseline for the AADEC device, allowing quantification of the differences between the AADEC system over the manual approach. The primary data of comparison is survival fractions; this is obtained by optical density and plate counts in the manual assay and by optical density growth curve fits pre- and post-exposure in the automated case. This data can then be compiled to calculate trends over the iterations to characterize increasing UV-C resistance of the E.coli strains. The observed trends are statistically indistinguishable through several iterations from both sources.

Bioengineering↗

NASA NTRS2019

In Situ Observation of Growth Dynamics in DECLIC Directional Solidification Insert Onboard ISS: DSI-R Flight Campaign

The study of solidification microstructure formation is of utmost importance for materials design and processing, as solid-liquid interface patterns largely govern mechanical and physical properties. Pattern selection occurs under dynamic conditions of growth in which the initial morphological instability evolves nonlinearly and undergoes a reorganization process. The dynamic and nonlinear nature of this instability renders in situ observation of the interface an invaluable tool to gain knowledge on the time-evolution of the interface pattern. Transparent organic analogs, which solidify like metallic alloys, allow direct visualization of interface dynamics. Extensive ground-based studies of both metallic and organic bulk samples have established the presence of significant convection during solidification processes that alters the formation of interfacial microstructures. A reduced-gravity environment is therefore mandatory for fluid flow elimination in bulk samples. In the framework of the CNES project MISOL3D (MIcrostrutures de SOLidification 3D) and the NASA projects DSIP (Dynamical Selection of 3D Interface Patterns), SPADES (SPAtiotemporal Evolution of three-dimensional DEndritic array Structures) and CAMUS (ComputAtional Studies of MicrostrUcture Formation During Alloy Solidification in Microgravity), we participated in the development of the Directional Solidification Insert (DSI) of the DEvice for the study of Critical Liquids and Crystallization (DECLIC). The DECLIC-DSI is dedicated to in situ and real-time characterization of solid-liquid interface patterns during directional solidification of transparent alloys in diffusive transport regime. Between April 2010 and March 2011, the first ISS campaign (DSI) explored the entire range of microstructures resulting in unprecedented observations. A second campaign (DSI-R), performed between October 2017 and December 2018, in which the insert contained an alloy of higher solute concentration, allowed to complete the benchmark database. The increase of solute concentration resulted in well-developed dendritic patterns at lower velocities (lower interface curvature and larger tip radius). The microstructure resulting from dendritic growth is dominant in metallurgy so that it is fundamental to understand the mechanisms of its formation. The main aims of this experimental campaign are to understand: the mechanisms of the cell to dendrite transition, the fundamental mechanisms of sidebranching formation, the dependence of dendrite tip shapes on growth conditions, the interaction of primary array and secondary sidebranches, and the influence of subgrain boundaries on the spatiotemporal organization of the array structure. Preparation, analysis and interpretation of the experiments performed onboard ISS are considerably enhanced by experiments performed on ground using thin-samples (Pr. Trivedi’s group) and phase-field simulations of microstructure formation in a diffuse growth regime (Pr. Karma’s group). In this summary, we will present an initial assessment of the results obtained during the DSI-R campaign. Nomenclature Vp: pulling velocity G: thermal gradient L: solidified length rtip: tip curvature radius Acronyms/Abbreviations CADMOS: Centre d'Aide au Développement des activités en Micro-pesanteur et des Opérations Spatiales CNES: Centre National d’Études Spatiales DECLIC: Device for the study of Critical LIquids and Crystallization DSI: Directional Solidification Insert DSI-R: Directional Solidification Insert - Refurbish ISS: International Space Station NASA: National Aeronautics and Space Administration PF: phase-field SCN: Succinonitrile 3D: three-dimensional

Mota, F.L.↗

NASA NTRS2020

“It’s Raining Bits”: Patterns in Directional Precipitation Persistence Across the United States

The spatial and temporal ordering of precipitation occurrence impacts ecosystems, streamflow, and water availability. For example, both large-scale climate patterns and local landscapes drive weather events, and the typical speeds and directions of these events moving across a basin dictate the timing of flows at its outlet. We address the predictability of precipitation occurrence at a given location, based on the knowledge of past precipitation at surrounding locations. We identify ‘‘dominant directions of precipitation influence’’ across the continental United States based on a gridded daily dataset. Specifically, we apply information theory–based measures that characterize dominant directions and strengths of spatial and temporal precipitation dependencies. On a national average, this dominant direction agrees with the prevalent direction of weather movement from west to east across the country, but regional differences reflect topographic divides, precipitation gradients, and different climatic drivers of precipitation. Trends in these information relationships and their correlations with climate indices over the past 70 years also show seasonal and spatial divides. This study expands upon a framework of information-based predictability to answer questions about spatial connectivity in addition to temporal persistence. The methods presented here are generally useful to understand many aspects of weather and climate variability.

North America↗

DOE OSTI2020

Bulk direct gap MoS2 by plasma induced layer decoupling

Bulk direct transition metal dichalcogenide (TMDC) may have an increased interlayer separation of at least 0.5, 1, or 3 angstroms more than its bulk value. The TMDC may be a bulk direct band gap molybdenum disulfide (MoS2) or a bulk direct band gap tungsten diselenide (WSe2). Oxygen may be between the interlayers. A device may include the TMDC, such as an optoelectronic device, such as an LED, solid state laser, a photodetector, a solar cell, a FET, a thermoelectric generator, or a thermoelectric cooler. A method of making bulk direct transition metal dichalcogenide (TMDC) with increased interlayer separation may include exposing bulk direct TMDC to a remote (aka downstream) oxygen plasma. The plasma exposure may cause an increase in the photoluminescence efficiency of the TMDC, more charge neutral doping, or longer photo-excited carrier lifetimes, as compared to the TMDC without the plasma exposure.

36 MATERIALS SCIENCE↗

DOE OSTI2022

Directional infrasound sensing

A method and apparatus for determining a direction of infrasound. Infrasound is received by a directional infrasound sensor comprising a plurality of channels and a plurality of sensor devices. Each channel in the plurality of channels comprises a single opening at a first end of the channel and a closed end opposite the opening. The opening of each channel in the plurality of channels is pointed in a different direction from the opening of each other channel in the plurality of channels. The plurality of sensor devices includes a sensor device at the closed end of each channel in the plurality of channels. Each sensor device in the plurality of sensor devices is configured to generate a sensor signal in response to pressure. The sensor signals generated by the plurality of sensor devices are processed to determine the direction of the infrasound received by the directional infrasound sensor.

Rouse, Jeremy W.↗

DOE OSTI2026

A comparative assessment of the economic viability of nuclear-integrated direct air capture systems

Direct air capture (DAC) systems require heat and electricity to operate, which can be supplied by nuclear power plants (NPPs). In this study, the performance and cost of various conceptual nuclear-DAC systems are assessed, and their performance is compared with several non-nuclear options. Three nuclear-DAC systems are considered: (1) a liquid solvent direct air capture (L-DAC) system with heat supplied from natural gas (NG) and electricity supplied by an NPP, (2) an electrified L-DAC system, fully powered by electricity from an NPP, and (3) a solid sorbent direct air capture (S-DAC) system utilizing both heat and electricity generated by an NPP. Two nuclear technologies are considered: a pressurized water reactor and a high-temperature gas-cooled reactor. Under the medium conservatism scenario, the levelized cost of direct air capture (LCOD) for these systems range from $\$$310/tCO 2 to $\$$525/tCO 2 with the L-DAC system having an NG heat supply at the lower end of the range, and the electrified L-DAC system and the S-DAC system at the higher end of the range. Coupling with nuclear energy led to a 21 % reduction in LCOD for the L-DAC system with NG heat supply and a 29 % reduction for the S-DAC system when compared to fully NG-powered options. When powering the DAC system with grid electricity, the LCOD is highly dependent on the assumed electricity price and carbon intensity. The nuclear option is the cheaper choice when the price of low-carbon grid electricity exceeds $\$$95/MWh and $\$$45/MWh for the L-DAC and S-DAC systems, respectively.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

DOE OSTI2023

Unlocking the Potential of A-Site Ca-Doped LaCo 0.2 Fe 0.8 O 3-δ : A Redox-Stable Cathode Material Enabling High Current Density in Direct CO 2 Electrolysis

Massive carbon dioxide (CO 2 ) emission from recent human industrialization has affected the global ecosystem and raised great concern for environmental sustainability. The solid oxide electrolysis cell (SOEC) is a promising energy conversion device capable of efficiently converting CO 2 into valuable chemicals using renewable energy sources. However, Sr-containing cathode materials face the challenge of Sr carbonation during CO 2 electrolysis, which greatly affects the energy conversion efficiency and long-term stability. Thus, A-site Ca-doped La1– x CaxCo 0.2 Fe 0.8 O 3-δ (0.2 ≤ x ≤ 0.6) oxides are developed for direct CO 2 conversion to carbon monoxide (CO) in an intermediate-temperature SOEC (IT-SOEC). With a polarization resistance as low as 0.18 O cm 2 in pure CO 2 atmosphere, a remarkable current density of 2.24 A cm –2 was achieved at 1.5 V with La 0.6 Ca 0.4 Co 0.2 Fe 0.8 O 3-δ (LCCF64) as the cathode in La 0.8 Sr 0.2 Ga 0.83 Mg 0.17 O 3-δ (LSGM) electrolyte (300 µm) supported electrolysis cells using La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ (LSCF) as the air electrode at 800 °C. Furthermore, symmetrical cells with LCCF64 as the electrodes also show promising electrolysis performance of 1.78 A cm –2 at 1.5 V at 800 °C. In addition, stable cell performance has been achieved on direct CO 2 electrolysis at an applied constant current of 0.5 A cm –2 at 800 °C. The easily removable carbonate intermediate produced during direct CO 2 electrolysis makes LCCF64 a promising regenerable cathode. The outstanding electrocatalytic performance of the LCCF64 cathode is ascribed to the highly active and stable metal/perovskite interfaces that resulted from the in situ exsolved Co/CoFe nanoparticles and the additional oxygen vacancies originated from the Ca 2 Fe 2 O 5 phase synergistically providing active sites for CO 2 adsorption and electrolysis. Here this study offers a novel approach to design catalysts with high performance for direct CO 2 electrolysis.

30 DIRECT ENERGY CONVERSION↗