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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Metagenomic mapping of cyanobacteria and potential cyanotoxin producing taxa in large rivers of the United States

Abstract Cyanobacteria and cyanotoxin producing cyanobacterial blooms are a trending focus of current research. Many studies focus on bloom events in lentic environments such as lakes or ponds. Comparatively few studies have explored lotic environments and fewer still have examined the cyanobacterial communities and potential cyanotoxin producers during ambient, non-bloom conditions. Here we used a metagenomics-based approach to profile non-bloom microbial communities and cyanobacteria in 12 major U.S. rivers at multiple time points during the summer months of 2019. Our data show that U.S. rivers possess microbial communities that are taxonomically rich, yet largely consistent across geographic location and time. Within these communities, cyanobacteria often comprise significant portions and frequently include multiple species with known cyanotoxin producing strains. We further characterized these potential cyanotoxin producing taxa by deep sequencing amplicons of the microcystin E ( mcyE ) gene. We found that rivers containing the highest levels of potential cyanotoxin producing cyanobacteria consistently possess taxa with the genetic potential for cyanotoxin production and that, among these taxa, the predominant genus of origin for the mcyE gene is Microcystis . Combined, these data provide a unique perspective on cyanobacteria and potential cyanotoxin producing taxa that exist in large rivers across the U.S. and can be used to better understand the ambient conditions that may precede bloom events in lotic freshwater ecosystems.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS2012

Experimental Evaluation of the "Polished Panel Optical Receiver" Concept on the Deep Space Network's 34 Meter Antenna

The potential development of large aperture ground-based "photon bucket" optical receivers for deep space communications has received considerable attention recently. One approach currently under investigation proposes to polish the aluminum reflector panels of 34-meter microwave antennas to high reflectance, and accept the relatively large spotsize generated by even state-of-the-art polished aluminum panels. Here we describe the experimental effort currently underway at the Deep Space Network (DSN) Goldstone Communications Complex in California, to test and verify these concepts in a realistic operational environment. A custom designed aluminum panel has been mounted on the 34 meter research antenna at Deep-Space Station 13 (DSS-13), and a remotely controlled CCD camera with a large CCD sensor in a weather-proof container has been installed next to the subreflector, pointed directly at the custom polished panel. Using the planet Jupiter as the optical point-source, the point-spread function (PSF) generated by the polished panel has been characterized, the array data processed to determine the center of the intensity distribution, and expected communications performance of the proposed polished panel optical receiver has been evaluated.

photon counting detection↗
DOE OSTI2020

Environmental Life Cycle Assessment Spreadsheet tool for Deep Direct-Use Geothermal at the University of Illinois at Urbana-Champaign Campus

A Life Cycle Assessment (LCA) spreadsheet tool was developed to analyze potential environmental benefits of a deep direct-use (DDU) geothermal energy system (GES) at the University of Illinois at Urbana-Champaign (U of IL) campus. The LCA spreadsheet tool is a unique contribution to the feasibility study that provides further insight into the cradle-to-grave environmental impacts associated with the GES over the operating life time, as well as other DDU GES with similar objectives. The tool allows for a more in-depth analysis of the feasibility of DDU GES with respect to the overall environmental impacts. For the U of IL assessment, a doublet (two-well) system is evaluated, which is connected to aboveground mechanical system to supply heating to six agricultural research facilities. The additional of new equipment are assessed for the technical and economic feasibility. The results from this study will also allow geothermal resources from the entirety of the Illinois Basin (ILB) to be assessed and allow the DDU technology to be extended to additional areas of the ILB and other low-temperature sedimentary basins with similar characteristics.

15 GEOTHERMAL ENERGY↗
DOE OSTI2020

Gas Production from Hot Water Circulation through Hydraulic Fractures in Methane Hydrate-Bearing Sediments: THC-Coupled Simulation of Production Mechanisms

Methane hydrates, widely found in permafrost and deep marine sediments, have great potential as a future energy 6 source. Conventional production schemes perform poorly for challenging hydrate reservoirs with low permeability. We propose an 7 efficient production scheme by combining hydraulic fracturing from horizontal wells and hot water circulation through fractures. A 8 fully coupled thermo-hydro-chemical (THC) model is developed to simulate the key physical processes during gas production from 9 a hydrate reservoir representative of typical geological settings in Shenhu, South China Sea. We found that the gas production 10 process has two distinct stages divided by thermal breakthrough: a relatively short prebreakthrough stage and a postbreakthrough 11 stage yielding stable gas production. Heat advection along and near the hydraulic fracture dominates the prebreakthrough stage, 12 whereas conduction-driven thermal recovery in the volume around fractures dominates the postbreakthrough stage. We identified 13 that the steady-state injection temperature has a strong effect on the performance of the proposed scheme while the fluid mass 14 circulation rate has a moderate impact beyond a threshold. The proposed scheme proves to be efficient and robust over a range of 15 reservoir conditions with respect to initial hydrate saturation and intrinsic permeability, including their spatial heterogeneities, 16 thereby offering a promising solution for challenging reservoir conditions.

gas hydrate, fracture flow, gas production, numeri↗
NASA NTRS2010

Reevaluating the Role of Saharan Air Layer in Atlantic Tropical Cyclogenesis and Evolution

The existence of the Saharan air layer (SAL), a layer of warm, dry, dusty air that frequently moves westward off of the Saharan desert of Africa and over the tropical Atlantic Ocean, has long been appreciated. As air moves over the desert, it is strongly heated from below, producing a very hot air mass at low levels. Because there is no moisture source over the Sahara, the rise in temperature causes a sharp drop in relative humidity, thus drying the air. In addition, the warm air produces a very strong jet of easterly flow in the middle troposphere called the African easterly jet that is thought to play a critical role in hurricane formation. In recent years, there has been an increased focus on the impact that the SAL has on the formation and evolution of hurricanes in the Atlantic. However, the nature of its impact remains unclear, with some researchers arguing that the SAL amplifies hurricane development and with others arguing that it inhibits it. The argument for positively influencing hurricane development is based upon the fact that the African easterly jet provides an energy source for the waves that eventually form hurricanes and that it leads to rising motion south of the jet that favors the development of deep thunderstorm clouds. The potential negative impacts of the SAL include 1) low-level vertical wind shear associated with the African easterly jet; 2) warm SAL air aloft, which increases thermodynamic stability and suppresses cloud development; and 3) dry air, which produces cold downdrafts in precipitating regions, thereby removing energy needed for storm development. As part of this recent focus on the SAL and hurricanes (which motivated a 2006 NASA field experiment), there has been little emphasis on the SAL s potential positive influences and almost complete emphasis on its possible negative influences, almost to the point of claims that the SAL is the major suppressing influence on hurricanes in the Atlantic. In this study, multiple NASA satellite data sets (TRMM, MODIS, CALIPSO, and AIRS/AMSU) and National Centers for Environmental Prediction global analyses are used to see if the proposed negative influences deserve all of the attention they have recently received. The results show that storms generally form on the southern side of the African jet, where favorable background rotation is high. The jet often helps to form the northern side of the storms and is typically stronger in storms that intensify than those that weaken, suggesting that jet-induced vertical wind shear is not a negative influence on developing storms. Warm SAL air is confined to regions north of the jet and generally does not impact the tropical cyclone precipitation south of the jet. A comparison of the environments of strongly strengthening storms and of weakening storms shows no differences in SAL structure, indicating that the SAL has little influence on whether storms weaken or intensify. The large-scale flow at upper levels above the SAL was found to be most important, with the environment of strengthening storms having very little vertical wind shear and also favoring more expansive outflow from the storm. The SAL is shown to occur in a large-scale environment that is already characteristically dry as a result of large-scale subsidence (sinking air motions). Strong surface heating and deep dry convective mixing enhance dryness at low levels, but moisten the air at midlevels. Therefore, mid-to-upper-level dryness is not a defining characteristic of the SAL, but is instead a signature of subsidence. As a result, we conclude that the SAL is not the major negative influence on hurricanes that recent studies have emphasized. It is just one of many possible influences and can be both positive and negative.

Braun, Scott A.↗
DOE OSTI2016

A Conceptual World Information Library (WIL) and Land Use Information System (LUIS) - 16181

The Organization for Economic Co-operation and Development Nuclear Energy Agency initiative on the Preservation of Records, Knowledge and Memory is addressing the topic of communicating with future generations on the location, specific contents, and potential risks associated with deep geologic nuclear waste repositories. At the Waste Isolation Pilot Plant (WIPP) in the United States, the U.S. Department of Energy (DOE) has committed, prior to the facility closure, to develop a Passive Institutional Controls (PICs) program designed to last as long as practicable. A portion of this PICs program includes development of records packages, selection of data storage materials and methods, and a determination of records retention/storage locations. The approved plan for record retention at WIPP includes the storage of information including hard copies of data, figures and maps in multiple libraries and archive record centers. With this in mind, it is easy to envision reams of various paper documents in a robust physical archive record center similar to one of the museums in Washington D.C., or DOE's Legacy Management facility in Morgantown, West Virginia. While some portion of records for nuclear waste burial sites should be maintained in this fashion for near-term retrieval purposes, it is widely accepted that this is not an efficient way to communicate with future generations even 1,000 years from now. Transmitting large detailed volumes of information to the future should be captured in an electronic format; maintained on computers, translated by computers, and perhaps updated by artificial intelligence as machine and human languages change over the centuries. In addition to a physical records development and storage process for transmittal to future generations, a web-based electronic database system should be developed. A World Electronic Library (WEL) database could be funded from various nations and perhaps sanctioned by the United Nations and/or the IAEA. This WEL could contain information regarding several different subjects with the intent of being a one-stop-information-shop for future generations. This database would require updates and maintenance for as long as there is a recipient. One subset of the WEL would be a spatial database containing all the information available to any set of GPS coordinates, anywhere within the world. This Land Use Information System (LUIS) database would contain information on past and present land use, natural resources, known geology, hydrology and atmospheric conditions, potential warnings, and other pertinent information. The LUIS database is where specific electronic information, a subset of all the records data gathered for a nuclear waste repository, could reside. For not only would LUIS provide the information on a nuclear waste repository when specific GPS coordinates were entered; but a search from the LUIS on 'Nuclear Waste Repositories' could bring up information, including data on location of repositories, radionuclides, operations, D and D, maps, and regulations, plus many other details for locations throughout the world. This tool could be used by future generations for a number of land use or resource exploration decisions. So what can we do now? We can agree to the types of information that should be captured into an electronic database for nuclear waste repositories. We can agree to the levels of detail, the file names and the formats, for ease of combining information sets in the future. Perhaps we can agree to a central electronic data storage site, or sites, where this information will reside for import into a centralized electronic record system, if one is ever developed. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2016

Two-stage spin transition of iron in FeAl-bearing phase D at lower mantle

Hydrous magnesium silicate phase D plays a key role in the transport of water from the upper to the lower mantle via subducted slabs. Here we report pressure dependence hyperfine and lattice parameters of FeAl-bearing phase D up to megabar pressures using synchrotron nuclear forward scattering and X-ray diffraction in a diamond anvil cell at room temperature. We report FeAl-bearing phase D undergoes a two-stage high-spin to low-spin transition of iron for Fe 2+ at 37–41 GPa and for Fe 3+ at 64–68 GPa. These transitions are accompanied by an increase in density and a significant softening in the bulk modulus and bulk velocity at their respective pressure range. The occurrence of the dense low-spin FeAl-bearing phase D with relatively high velocity anisotropies in deep-subducted slabs can potentially contribute to small-scale seismic heterogeneities in the middle-lower mantle beneath the circum-Pacific area.

58 GEOSCIENCES↗
DOE OSTI2019

Problems of Developing Solid Mineral Deposits on the Sea and Ocean Floor

Brief characteristics of the mineral raw material potential of the deep-sea deposits of ferromanganese nodules in the area of the Clarion-Clipperton Zone leased by Russia in the Pacific Ocean are presented. The creation at the Moscow Mining Institute (MGI) of the USSR’s first Scientific and Technical Problems Laboratory and the results of its work on extraction of minerals from the sea and ocean floor are reviewed. The research works carried out by MGI on underwater mining of ilmenite-rutile-zirconium sands on the Baltic Sea shelf and Iturup Island and tin under conditions of northern seas and the development of the technogenic placer of the East Siberian Sea are analyzed. The concept of using the kinetic energy of coaxially swirled fluid jets in hydrotransport-hoisting devices of vortex slurry preparation, which was tested in the Black Sea and an air-lift mud intake by mechanical and hydraulic loosening for extracting diamond-containing gravel-pebble rocks on the Namibia shelf is given.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Smoothed particle hydrodynamics modeling and analysis of oxide reduction process for uranium oxides

A common kinetic feature for oxide reduction chemical/electrochemical processes is oxygen transport via a porous metallic layer, which has been considered as a rate-determining step for reducing uranium oxides to metallic uranium. Accounting this kinetic behavior must involve the resolution of the moving reactive interface between shrinking oxide and expanding metal phases. This study presents a numerical model using smoothed particles hydrodynamics (SPH) to effectively deal with the evolution of the shrinking core reaction interface and oxygen transport via mass transfer of lithium oxide (Li 2 O) species in multiple mass transfer domains. We successfully validated the proposed model against a theoretical derivation for the oxide reduction process handling a shrinking oxide core with molten salt and metal ash medium on a simple planar geometry. Armed with successful validation results, the model examined a realistic reactant geometry to extend the arguments beyond the one-dimensional analyses, allowing the proposed model to apply to general application scenarios with multi-dimensional geometry. Here, this study demonstrated that the proposed model could simulate and evaluate an arbitrary reaction basket design without iterative experimental trials, which is prohibitive for a scaled high-temperature molten salt study in an inert environment. The construct potentially provides not only deep insights on multiphysics behaviors governing the process dynamics but also a robust framework for evaluating and screening candidate basket designs in the most cost-effective manner.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2023

Acid–Base Chemistry of a Model IrO 2 Catalytic Interface

Iridium oxide (IrO 2 ) is one of the most efficient catalytic materials for the oxygen evolution reaction (OER), yet the atomic scale structure of its aqueous interface is largely unknown. Herein, the hydration structure, proton transfer mechanisms and acid-base properties of the rutile IrO 2 (110)-water interface are investigated using ab-initio based deep neural-network potentials and enhanced sampling simulations. The proton affinities of the different surface sites are characterized by calculating their acid dissociation constants, which yield a point of zero-charge in good agreement with experiments. A large fraction (≈ 80%) of adsorbed water dissociation is observed, together with a short lifetime (≈ 0.5 ns) of the resulting terminal hydroxy groups, due to rapid proton exchanges between adsorbed H 2 O and adjacent OH species. As a result, this rapid surface proton transfer supports the suggestion that the rate-determining step in the OER may not involve proton transfer across the double layer into solution, as indicated by recent experiments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

In Situ Determination of Thermoelastic Properties of Magnesite at High Pressure and Temperature With Implications to Seismic Detectability of Moderately Carbonated Lithologies in the Earth's Mantle

Abstract Subduction of carbonate‐bearing oceanic plates into Earth's interior recycles carbon from the surface to the deep mantle. The subducted carbonates can significantly affect mantle properties and dynamics. Magnesite is recognized as one of the major potential carbon hosts in the deep mantle because of its stability up to deep lower mantle conditions. However, despite many previous studies on the equation of state and elastic properties of magnesite, large discrepancies still exist for its elastic moduli and their pressure and temperature derivatives. Here we report in situ density and elastic wave velocity measurements on a natural magnesite at simultaneous high pressure‐temperature conditions up to ∼8 GPa–1073 K in a multi‐anvil apparatus using ultrasonic and synchrotron X‐ray techniques. Global fitting of the data set to finite strain equations yieldsK S0 = 114.0 ± 1.2 GPa, = 4.9 ± 0.3, = (−0.019 ± 0.002) GPa/K,G 0 = 68.6 ± 0.4 GPa,G′ = 1.6 ± 0.1, and = (−0.018 ± 0.001) GPa/K. Compared to other major upper mantle and transition zone minerals, magnesite has intermediateV P , the lowestV S , and the lowest density. Thus, magnesite possesses higherV P /V S ratio than other mantle minerals in normal mantle regions, whereas this feature is less pronounced in subduction zone environments. Modeling of the velocity profiles of carbonated lithologies along different geotherms suggests that moderately‐enriched magnesite domains are unlikely to be detected seismically in the Earth's mantle.

Geochemistry & Geophysics↗
DOE OSTI2024

Cobalt-free composite-structured cathodes with lithium-stoichiometry control for sustainable lithium-ion batteries

Abstract Lithium-ion batteries play a crucial role in decarbonizing transportation and power grids, but their reliance on high-cost, earth-scarce cobalt in the commonly employed high-energy layered Li(NiMnCo)O 2 cathodes raises supply-chain and sustainability concerns. Despite numerous attempts to address this challenge, eliminating Co from Li(NiMnCo)O 2 remains elusive, as doing so detrimentally affects its layering and cycling stability. Here, we report on the rational stoichiometry control in synthesizing Li-deficient composite-structured LiNi 0.95 Mn 0.05 O 2 , comprising intergrown layered and rocksalt phases, which outperforms traditional layered counterparts. Through multiscale-correlated experimental characterization and computational modeling on the calcination process, we unveil the role of Li-deficiency in suppressing the rocksalt-to-layered phase transformation and crystal growth, leading to small-sized composites with the desired low anisotropic lattice expansion/contraction during charging and discharging. As a consequence, Li-deficient LiNi 0.95 Mn 0.05 O 2 delivers 90% first-cycle Coulombic efficiency, 90% capacity retention, and close-to-zero voltage fade for 100 deep cycles, showing its potential as a Co-free cathode for sustainable Li-ion batteries.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Patterning via optical-saturable transformations: A review and simple simulation model

Most of the nanoscale fabrication in the semiconductor industry is based on patterning with scanning-electron beam lithography (SEBL). Although this approach is very versatile and has very high resolution, it is intrinsically a serial writing process, and therefore, relatively slow. Our group has been investigating alternative nano-fabrication techniques, adapted from ideas of saturating optical transitions such as those used in stimulated emission-depletion microscopy and related methods, and optical interference lithography. Linewidths and resolutions on the scale of a few tens of nanometers and below are highly desirable for various applications in nanotechnology. However, the spatial resolution of optical lithography is restricted by diffraction. In the past, we developed absorbance modulation to overcome this limit. This approach utilizes photochromic molecules that can be optically switched between two thermally stable states, one opaque and the other transparent. However, absorbance modulation is limited to surface (2-D) patterning. Here, we report on an alternative approach that exploits unique combinations of spectrally selective reversible and irreversible photochemical transitions to achieve deep subwavelength resolution with potential extension to 3-dimensions. This approach, which we refer to as patterning via optical-saturable transformations have the potential for massive parallelism, enabling the creation of nanostructures and devices at a speed far surpassing what is possible with SEBL. The aim of our research is to translate the success in circumventing Abbe's diffraction limit in optical microscopy to optical lithography.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

Effect of the tetrahedral groups on the optical properties of LaBRO{sub 5} (R = Si and Ge): A first-principles study

As potential candidates for deep-UV nonlinear optical (NLO) crystals, borosilicates and borogermanates, which contain NLO-active groups such as B-O, Si-O, and Ge-O groups, have fascinated many material scientists' research enthusiasm. In this paper, the electronic structures and optical properties of two isostructural noncentrosymmetric crystals LaBRO{sub 5} (R = Si and Ge) have been studied by the first-principles method. Combined with the analyses of the SHG-density and the localized electron-density difference, contributions of the constituent tetrahedra to the total NLO responses are investigated. Eventually, BO{sub 4} and GeO{sub 4} groups give nearly equal contributions to the SHG effect of LaBGeO{sub 5}, but for LaBSiO{sub 5}, SiO{sub 4} groups express stronger SHG response than that of BO{sub 4}. Such interesting conclusion is consistent with the distortion index analyses and dipole moment.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

CSO and CARMA observations of L1157. I. A deep search for hydroxylamine (NH{sub 2}OH)

A deep search for the potential glycine precursor hydroxylamine (NH{sub 2}OH) using the Caltech Submillimeter Observatory (CSO) at λ = 1.3 mm and the Combined Array for Research in Millimeter-wave Astronomy at λ = 3 mm is presented toward the molecular outflow L1157, targeting the B1 and B2 shocked regions. We report non-detections of NH{sub 2}OH in both sources. We perform a non-LTE analysis of CH{sub 3}OH observed in our CSO spectra to derive the kinetic temperatures and densities in the shocked regions. Using these parameters, we derive upper limit column densities of NH{sub 2}OH of ≤1.4 × 10{sup 13} cm{sup −2} and ≤1.5 × 10{sup 13} cm{sup −2} toward the B1 and B2 shocks, respectively, and upper limit relative abundances of N{sub NH{sub 2OH}}/N{sub H{sub 2}}⩽1.4×10{sup −8} and ≤1.5 × 10{sup −8}, respectively.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

On the dynamics of non-relativistic flavor-mixed particles

Evolution of a system of interacting non-relativistic quantum flavor-mixed particles is considered both theoretically and numerically. It was shown that collisions of mixed particles not only scatter them elastically, but can also change their mass eigenstates thus affecting particles' flavor composition and kinetic energy. The mass eigenstate conversions and elastic scattering are related but different processes, hence the conversion S-matrix elements can be arbitrarily large even when the elastic scattering S-matrix elements vanish. The conversions are efficient when the mass eigenstates are well-separated in space but suppressed if their wave-packets overlap; the suppression is most severe for mass-degenerate eigenstates in flat space-time. The mass eigenstate conversions can lead to an interesting process, called ''quantum evaporation'', in which mixed particles, initially confined deep inside a gravitational potential well and scattering only off each other, can escape from it without extra energy supply leaving nothing behind inside the potential at t → ∞. Implications for the cosmic neutrino background and the two-component dark matter model are discussed and a prediction for the direct detection dark matter experiments is made.

79 ASTRONOMY AND ASTROPHYSICS↗