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At least 343 records · Page 19

The distribution and significance of evaporitic weathering products on Antarctic meteorites

This paper examines the occurrence of white evaporitic deposits on Antarctic meteorites from the U.S. collection, as a function of meteorite compositional group and weathering category. Evaporites occur with unusual frequency on carbonaceous chondrites. Almost two-thirds of all evaporite-bearing meteorites belong to weathering categories A, A/B, and B. Where chemical data were available, surficial evaporite deposits could be associated with elemental anomalies in meteorite interiors.

Velbel, Michael Anthony↗

Causes of the F region winter anomaly

Measurements made by the Atmosphere Explorer satellites are used to determine the causes of the F-region winter anomaly, i.e., seasonal variations which result in peak electron densities which are larger in winter than in summer. It is found that for the data examined there are three causes of the winter anomaly: (1) seasonal changes in neutral composition; (2) an increase in the vibrational temperature of N2 and hence in the rate coefficient for the reaction O(+)(4S) + N2 yields NO(+) + N; (3) an increase in winter in the production of O(+)(4S) due to enhanced electron quenching of O(+)(2D). The presence of vibrational excitation is inferred from an increase in the rate coefficient for the reaction O(+) + N2 yields NO(+) + N from winter to summer at heights above 260 km. It is demonstrated quantitatively that the initial increase in electron density produced in winter by causes (1) and (2) results in an increase in the quenching of O(+)(4S), thereby enhancing the source of O(+)(4S) ions. It is estimated that causes (1) to (3) account for approximately 55%, 20% and 25% respectively of the seasonal change in O(+)(4S) from summer to winter at solar minimum.

Torr, D. G.↗

Diagnostics Adapted for Heat-Treating Furnace Environment

Diagnostics developed for the in situ monitoring of rocket combustion environments were adapted for use in heat-treating furnaces. Simultaneous, in situ monitoring of the carbon monoxide, carbon dioxide, methane, water, and hydrogen concentrations in the endothermic gas of a heat-treating furnace were demonstrated under a Space Act Agreement between the NASA Lewis Research Center, the Heat Treating Network, and Akron Steel Treating Company. This endothermic gas, or "endogas," is produced in a catalytic process, where natural gas is "cracked" in the presence of air. Variations in the composition of the natural gas supplied lead to variations in the composition of the endothermic gas. These variations could lead to an unacceptable quality of steel products that are hardened through the carborization process that uses this gas. Conventional methods of monitoring the endogas include measuring the dew point of the gas and the oxygen concentration. From these data, the carbon monoxide content of the gas can be calculated. This carbon monoxide concentration creates the carbon potential needed for carburization. Several weak links are present in this approach. The oxygen monitor deteriorates over time, and the measurement might be inaccurate by 50 percent. Also, the chemistry equations, which are based on several assumptions, such as secondary species concentrations, provide only an approximate estimate of the carbon monoxide concentration. To address these weaknesses, we investigated a new method based on ordinary Raman spectroscopy, in which the carbon monoxide concentration is measured directly and in situ. This method measures the laser light scattered from the molecules. Each species interacts with the light and scatters the light at a different frequency. Spectral monitoring of the scattered light intensity at each molecular frequency of interest provides the species concentrations. One advantage over the conventional method is that several species can be monitored simultaneously. A second advantage is that the measurement is direct; there is no need to make assumptions, to filter the gas, or to calibrate the instrument. An instrument was designed consisting of a laser and a detection system within an enclosure, connected to an optical probe by fibers. For determining carbon monoxide concentration, the probe is mounted on the endothermic gas line, close to the generator. Optical fibers with a length of 150 ft have been used to transmit laser light from the instrument to the probe. There, the light is focused into the gas, and the scattered light is collected and transmitted back to the instrument where it is analyzed with a photomultiplier and lock-in amplifier. Laboratory tests have shown that with the current system the concentration of carbon monoxide, water, nitrogen, oxygen, and hydrogen in the air can be monitored with an accuracy of 1 percent. The concentration of carbon dioxide in the air can be monitored with an accuracy of 0.5 percent, and the concentration of methane with an accuracy of 0.2 percent. This instrument was taken to the Akron Steel Treating Plant, where field tests are in progress to verify the system capabilities. Planned developments are improving the accuracy, monitoring multiple locations, and reducing instrument size and cost.

Source record↗

Quantitative Electron Probe Microanalysis: State of the Art

Quantitative electron-probe microanalysis (EPMA) has improved due to better instrument design and X-ray correction methods. Design improvement of the electron column and X-ray spectrometer has resulted in measurement precision that exceeds analytical accuracy. Wavelength-dispersive spectrometer (WDS) have layered-dispersive diffraction crystals with improved light-element sensitivity. Newer energy-dispersive spectrometers (EDS) have Si-drift detector elements, thin window designs, and digital processing electronics with X-ray throughput approaching that of WDS Systems. Using these systems, digital X-ray mapping coupled with spectrum imaging is a powerful compositional mapping tool. Improvements in analytical accuracy are due to better X-ray correction algorithms, mass absorption coefficient data sets,and analysis method for complex geometries. ZAF algorithms have ban superceded by Phi(pz) algorithms that better model the depth distribution of primary X-ray production. Complex thin film and particle geometries are treated using Phi(pz) algorithms, end results agree well with Monte Carlo simulations. For geological materials, X-ray absorption dominates the corretions end depends on the accuracy of mass absorption coefficient (MAC) data sets. However, few MACs have been experimentally measured, and the use of fitted coefficients continues due to general success of the analytical technique. A polynomial formulation of the Bence-Albec alpha-factor technique, calibrated using Phi(pz) algorithms, is used to critically evaluate accuracy issues and can be also be used for high 2% relative and is limited by measurement precision for ideal cases, but for many elements the analytical accuracy is unproven. The EPMA technique has improved to the point where it is frequently used instead of the petrogaphic microscope for reconnaissance work. Examples of stagnant research areas are: WDS detector design characterization of calibration standards, and the need for more complete treatment of the continuum X-ray fluorescence correction.

Carpernter, P. K.↗

Development of improved asbestos reinforced phenolic insulating composites (optimization of physical properties as a function of molding technique and post cure conditions)

Detailed data are presented on phenolic-glass and phenolic-asbestos compounds which compare the effect of compression molding without degas to the effects of four variations of compression molding. These variations were designed to improve elimination of entrapped volatiles and the volatile products of the condensate reaction associated with the cure of phenolic resins. The utilization of conventional methods of degas plus degas by vacuum and directional heat flow methods are involved. Detailed data are also presented on these same compounds, comparing the effect of changes in post-bake time, and post-bake temperature for the five molding techniques.

Hedges, L. M.↗

Environmental Exposure Effects on Composite Materials for Commercial Aircraft

The test program concentrates on three major areas: flight exposure; ground based exposure; and accelerated environmental effects and data correlation. Among the parameters investigated were: geographic location, flight profiles, solar heating effects, ultraviolet degradation, retrieval times, and test temperatures. Data from the tests can be used to effectively plan the cost of production and viable alternatives in materials selection.

Hoffman, D. J.↗

Application of Gr/PMR-15 to commercial aircraft

Following from early experience with polyimides on the SST program and Shuttle aft flap studies the Boeing Company is now working on collaborative programs with its principal nacelle suppliers to pursue the development of Gr/PMR-15 nacelle components. Two programs are currently in effect. The first program is directed specifically towards the flight test and service evaluation at the earliest possible date of a 747 nacelle core cowl structure. The second program seeks to firmly establish the producibility and cost of a 757 thrust reverser C duct in a production environment. The near term objectives of these programs include: (1) the comparison of estimated cost and weight of Gr/PMR-15 versus metal structure, (2) the engine test of representative composite structure, (3) the preliminary design and analysis of the C duct structure, and (4) the preparation of cost data and time schedules for the development and producibility program. In addition to powerplant structure, the propulsion ducting system has shown to be a strong candidate for Gr/PMR-15 application. Currently, the Boeing 747 Organization is evaluating the use of PMR-15 matrix composites to replace nearly 800 lbs of titanium ducting per airplane.

Postlewaite, J.↗

An integrtated approach to the use of Landsat TM data for gold exploration in west central Nevada

This paper represents an integration of several Landsat TM image processing techniques with other data to discriminate the lithologies and associated areas of hydrothermal alteration in the vicinity of the Paradise Peak gold mine in west central Nevada. A microprocessor-based image processing system and an IDIMS system were used to analyze data from a 512 X 512 window of a Landsat-5 TM scene collected on June 30, 1984. Image processing techniques included simple band composites, band ratio composites, principal components composites, and baseline-based composites. These techniques were chosen based on their ability to discriminate the spectral characteristics of the products of hydrothermal alteration as well as of the associated regional lithologies. The simple band composite, ratio composite, two principal components composites, and the baseline-based composites separately can define the principal areas of alteration. Combined, they provide a very powerful exploration tool.

Mouat, D. A.↗

PACE Technical Report Series, Volume 7: Ocean Color Instrument (OCI) Concept Design Studies

Extending OCI hyperspectral radiance measurements in the ultraviolet to 320 nm on the blue spectrograph enables quantitation of atmospheric total column ozone (O3) for use in ocean color atmospheric correction algorithms. The strong absorption by atmospheric ozone below 340 nm enables the quantification of total column ozone. Other applications are possible but were not investigated due to their exploratory nature and lower priority.The first step in the atmospheric correction processing, which converts top-of-the-atmosphere radiances to water-leaving radiances, is removal of the absorbance by atmospheric trace gases such as water vapor, oxygen, ozone and nitrogen dioxide. Details of the atmospheric correction process currently used by the Ocean Biology Processing Group (OBPG) and will be employed for PACE with appropriate modifications, are described by Mobley et al. [2016]. Atmospheric ozone absorbs within the visible to near-infrared spectrum between ~450 nm and 800nm and most appreciably between 530 nm and 650 nm, a spectral region critical for maintaining NASA's chlorophyll-a climate data record and for PACE algorithms planned to characterize phytoplankton community composition and other ocean color products.While satellite-based observations will likely be available during PACE's mission lifetime, the difference in acquisition time with PACE, the coarseness in their spatial resolution, and differences in viewing geometries will introduce significant levels of uncertainties in PACE ocean color data products.

Cetinic, Ivona↗

Aqueous Alteration and Hydrogen Generation on Parent Bodies of Unequilibrated Ordinary Chondrites: Thermodynamic Modeling for the Semarkona Composition

Ordinary chondrites are the most abundant class of meteorites that could represent rocky parts of solar system bodies. However, even the most primitive unequilibrated ordinary chondrites (UOC) reveal signs of mild alteration that affected the matrix and peripheral zones of chondrules. Major chemical changes include oxidation of kamacite, alteration of glass, removal of alkalis, Al, and Si from chondrules, and formation of phases enriched in halogens, alkalis, and hydrogen. Secondary mineralogical changes include formation of magnetite, ferrous olivine, fayalite, pentlandite, awaruite, smectites, phosphates, carbonates, and carbides. Aqueous alteration is consistent with the oxygen isotope data for magnetite. The presence of secondary magnetite, Ni-rich metal alloys, and ferrous silicates in UOC implies that H2O was the oxidizing agent. However, oxidation by H2O means that H2 is produced in each oxidative pathway. In turn, production of H2, and its redistribution and possible escape should have affected total pressure, as well as the oxidation state of gas, aqueous and mineral phases in the parent body. Here we use equilibrium thermodynamic modeling to explore water-rock reactions in UOC. The chemical composition of gas, aqueous, and mineral phases is considered.

Zolotov, M. Y.↗

Geologic Studies of Planetary Surfaces Using Radar Polarimetric Imaging

Radar is a useful remote sensing tool for studying planetary geology because it is sensitive to the composition, structure, and roughness of the surface and can penetrate some materials to reveal buried terrain. The Arecibo Observatory radar system transmits a single sense of circular polarization, and both senses of circular polarization are received, which allows for the construction of the Stokes polarization vector. From the Stokes vector, daughter products such as the circular polarization ratio, the degree of linear polarization, and linear polarization angle are obtained. Recent polarimetric imaging using Arecibo has included Venus and the Moon. These observations can be compared to radar data for terrestrial surfaces to better understand surface physical properties and regional geologic evolution. For example, polarimetric radar studies of volcanic settings on Venus, the Moon and Earth display some similarities, but also illustrate a variety of different emplacement and erosion mechanisms. Polarimetric radar data provides important information about surface properties beyond what can be obtained from single-polarization radar. Future observations using polarimetric synthetic aperture radar will provide information on roughness, composition and stratigraphy that will support a broader interpretation of surface evolution.

Carter, Lynn M.↗

Transforming Satellite Data into Weather Forecasts

A NASA project spans the gap between research and operations, introducing new composites of satellite imagery to weather forecasters to prepare for the next generation of satellites. Satellite imagery has been an immense benefit to weather forecasters. With it, they can assess aviation hazards such as low clouds, monitor thunderstorms, and track the evolution of dust plumes. Satellite sensors are continually evolving to provide ever greater imaging capabilities, and researchers continue to develop advanced techniques to identify hazards in satellite imagery. However, barriers can prevent experimental products from reaching forecasters in the operational environment. A NASA project has developed an interactive process whereby weather forecasters learn to interpret the latest satellite imagery and apply it to their operations. Forecasters then provide feedback to the researchers who are developing algorithms and products to further improve future products. This effort has taken on greater importance with the anticipated launch of a new series of satellites that will provide substantially greater amounts of data than are currently available.

Emily Berndt↗

Iron-absorption band analysis for the discrimination of iron-rich zones

The author has identified the following significant results. Study has concentrated on the two primary aspects of the project, structural analysis through evaluation of lineaments and circular features and spectral analyses through digital computer-processing techniques. Several previously unrecognized lineaments are mapped which may be the surface manifestations of major fault or fracture zones. Two of these, the Walker Lane and the Midas Trench lineament system, transect the predominantly NNE-NNW-trending moutain ranges for more than 500 km. Correlation of major lineaments with productive mining districts implies a genetic relationship, the 50 circular or elliptical features delineated suggest a related role for Tertiary volcanism. Color-ratio composites have been used to identify limonitic zones and to discriminate mafic and felsic rock by combing diazo color transparencies of three different ratios. EROS Data Center scene identification number for color composite in this report is ER 1 CC 500. Refinement of enhancement procedures for the ratio images is progressing. Fieldwork in coordination with both spectral and structural analyses is underway.

Rowan, L. C.↗

Interpretation of Landsat-4 Thematic Mapper and Multispectral Scanner data for forest surveys

Landsat-4 Thematic Mapper (TM) and Multispectral Scanner (MSS) data were evaluated by interpreting film and digital products and statistical data for selected forest cover types in California. Significant results were: (1) TM color image products should contain a spectral band in the visible (bands 1, 2, or 3), near infrared (band 4), and middle infrared (band 5) regions for maximizing the interpretability of vegetation types; (2) TM color composites should contain band 4 in all cases even at the expense of excluding band 5; and (3) MSS color composites were more interpretable than all TM color composites for certain cover types and for all cover types when band 4 was excluded from the TM composite.

Benson, A. S.↗

The 15 years of comet photometry: A comparative analysis of 80 comets

In 1976, a program of narrowband photometry of comets was initiated that has encompassed well over 400 nights of observations. To date, the program has provided detailed information on 80 comets, 11 of which were observed during multiple apparitions. The filters (initially isolating CN, C2, and continuum and later including C3, OH, and NH) as well as the detectors used for the observations were changed over time, and the parameters adopted in the reduction and modeling of the data have likewise evolved. Accordingly, we have re-reduced the entire database and have derived production rates using current values for scalelengths and fluorescence efficiencies. Having completed this task, the results for different comets can now be meaningfully compared. The general characteristics that are discussed include ranges in composition (molecular production rate ratios) and dustiness (gas production compared with Af(rho)). Additionally an analysis of trends on how the production rates vary with heliocentric distance and on pre- and post-perihelion asymmetries in the production rates of individual comets. Possible taxonomic groupings are also described.

Osip, David J.↗

10 000-hr Cyclic Oxidation Behavior of 68 High-Temperature Co-, Fe-, and Ni- Base Alloys Evaluated at 982 deg. C (1800 deg. F)

Power systems with operating temperatures in the range of 815 to 982 C (1500 to 1800 F) frequently require alloys that can operate for long times at these temperatures. A critical requirement is that these alloys have adequate oxidation resistance. The alloys used in these power systems require thousands of hours of operating life with intermittent shutdown to room temperature. Intermittent power plant shutdowns, however, offer the possibility that the protective scale will tend to spall (i.e., crack and flake off) upon cooling, increasing the rate of oxidative attack in subsequent heating cycles. Thus, it is critical that candidate alloys be evaluated for cyclic oxidation behavior. It was determined that exposing test alloys to ten 1000-hr cycles in static air at 982 10 000-hr Cyclic Oxidation Behavior of 68 High-Temperature Co-, Fe-, and Ni-Base Alloys Evaluated at 982 C (1800 F) could give a reasonable simulation of long-time power plant operation. Iron- (Fe-), nickel- (Ni-), and cobalt- (Co-) based high-temperature alloys with sufficient chromium (Cr) and/or aluminum (Al) content can exhibit excellent oxidation resistance. The protective oxides formed by these classes of alloys are typically Cr2O3 and/or Al2O3, and are usually influenced by their Cr, or Cr and Al, content. Sixty-eight Co-, Fe-, and Ni-base high-temperature alloys, typical of those used at this temperature or higher, were used in this study. At the NASA Lewis Research Center, the alloys were tested and compared on the basis of their weight change as a function of time, x-ray diffraction of the protective scale composition, and the physical appearance of the exposed samples. Although final appearance and x-ray diffraction of the final scale products were two factors used to evaluate the oxidation resistance of each alloy, the main criterion was the oxidation kinetics inferred from the specific weight change versus time data. These data indicated a range of oxidation behavior including parabolic (typical of isothermal oxidation), paralinear, linear, and mixed-linear kinetics.

Barrett, Charles A.↗

NASA SPoRT GOES-R Proving Ground Activities

The NASA Short-term Prediction Research and Transition (SPoRT) program is a partner with the GOES-R Proving Ground (PG) helping prepare forecasters understand the unique products to come from the GOES-R instrument suite. SPoRT is working collaboratively with other members of the GOES-R PG team and Algorithm Working Group (AWG) scientists to develop and disseminate a suite of proxy products that address specific forecast problems for the WFOs, Regional and National Support Centers, and other NOAA users. These products draw on SPoRT s expertise with the transition and evaluation of products into operations from the MODIS instrument and the North Alabama Lightning Mapping Array (NALMA). The MODIS instrument serves as an excellent proxy for the Advanced Baseline Imager (ABI) that will be aboard GOES-R. SPoRT has transitioned and evaluated several multi-channel MODIS products. The true and false color products are being used in natural hazard detection by several SPoRT partners to provide better observation of land features, such as fires, smoke plumes, and snow cover. Additionally, many of SPoRT s partners are coastal offices and already benefit from the MODIS sea surface temperature composite. This, along with other surface feature observations will be developed into ABI proxy products for diagnostic use in the forecast process as well as assimilation into forecast models. In addition to the MODIS instrument, the NALMA has proven very valuable to WFOs with access to these total lightning data. These data provide situational awareness and enhanced warning decision making to improve lead times for severe thunderstorm and tornado warnings. One effort by SPoRT scientists includes a lightning threat product to create short-term model forecasts of lightning activity. Additionally, SPoRT is working with the AWG to create GLM proxy data from several of the ground based total lightning networks, such as the NALMA. The evaluation will focus on the vastly improved spatial coverage of the GLM, but with the trade-off of lower resolution compared to the NALMA. In addition to the above tasks, SPoRT will make these data available in the NWS next generation display software, AWIPS II. This has already been successfully completed for the two basic GLM proxies. SPoRT will use these products to train forecasters on the capabilities of GOES-R and foster feedback to develop additional products, visualizations, and requirements beneficial to end users needs. These developments and feedback will be made available to the GOES-R Proving Ground for the upcoming 2010 Spring Program in Norman, Oklahoma.

Stano, Geoffrey T.↗

Comparing Level-2 and Level-3 Satellite Ocean Color Retrieval Validation Methodologies

Many ocean color data applications leverage global spatially composited Level-3(L3) satellite data, because of their regular Earth-grid frame of reference. However, ocean color satellite retrieval performance is routinely evaluated on Level-2 (L2) data at the native satellite swath resolution and geometries. This study assesses how accurately binned and gridded L3 data represent L2 satellite data products via satellite-to-in situ match-up activities.L2 and L3 satellite data retrievals of the photosynthetic pigment chlorophyll-a are compared with a common in situ data set, revealing similar L2 and L3 satellite-to-in situ performance for both MODIS-Aqua and VIIRS-SNPP. This agreement implies that L2 validation results are generally applicable to L3 data. However, uncertainties are introduced during the generation of L3 data from L2 data. L3 data comparisons introduce a wider temporal window between the time of in situ measurement and the time of the satellite observation, which can unintentionally reflect on the quality of the satellite retrieval or algorithm performance. The choice of L3 map projection may introduce additional uncertainty by spatially distorting the true location of the satellite retrievals. Each manipulation of satellite data beyond theinstrument's native spatio temporal reference (L2) reduces the applicability of L2 validation results to higher data processing levels.

Ocean Color↗