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At least 343 records · Page 19

Nickel cadmium cell composite reliability model

Ni-Cd battery reliability has become a critical design parameter with the increasing need for longer life and optimally designed secondary battery power systems in space as well as in more mundane applications. It is the purpose of this paper to present a state-of-the-art Ni-Cd cell reliability model as a function of cumulative cyclic operation, cell temperature and cyclic depth-of-discharge. In addition, a simple and convenient cell failure analysis technique will be presented in which the reliability, the distribution, and the distribution parameters can be determined by visual inspection.

Kirsch, W. W.↗

The redshift and optical structure of the X-ray galaxy cluster A478

Observational results are reported concerning the optical properties of the X-ray cluster of galaxies A478. A cluster redshift of 0.09 is determined, which implies a cluster X-ray luminosity of 10 to the 45th power erg/s over the energy range from 2 to 6 keV. The cluster is classified as type cD, the center of the cluster is found to be consistent with the position of the cD galaxy, and it is shown that the surface distribution of the galaxies in the cluster is well described by a bounded isothermal gas-sphere model. The core radius of the galaxy distribution is estimated to be about 1.5 arcmin, corresponding to approximately 0.20 Mpc for a Hubble constant of 50 km/s per Mpc. It is noted that the observed galaxy distribution is somewhat asymmetric, being elongated along the NE-SW direction.

Bahcall, N. A.↗

New data for the lunar 20 core and a survey of published chemical data

Lunar core samples were analyzed using a spark source mass spectrometer. The analytical results for the four zones of the Lunar 20 core suggest that the core is nonuniform with depth. The higher concentrations of Ce, Sc, Sc, Ba, La, Co, Sr, and Zr in zone 2001 may be connected with the presence in this zone of a basaltic rock type seldom seen in the other zones. That is, about half of the basaltic fragments in the large size fractions in zone 2001 are of a specific porphyritic breccia-like type. Anorthositic fragments containing a notable amount of metallic iron are basically limited to zone 2004 and probably explain the lower concentrations of Ce, Rb, Ba, La, and perhaps Co in this zone. The high concentrations of Ag and Ce found previously are confirmed. Although Ag is at nearly the same concentration in all four zones of the core, Cd in the core is the result of local enrichment. In particular, in zone 2004 the concentration of Cd may be as high as 10 ppm in a sample size of 0.01 mg.

Hubbard, N. J.↗

Development of long life lightweight nickel-cadmium cells and batteries

The paper describes the development of a high-specific energy Ni-Cd cell for a lightweight battery. After preliminary cycling tests on laboratory and commercial cells, a cell was produced that features electrochemically impregnated positive and negative electrodes, a single terminal, and increased amount of electrolyte. This cell weighed an average of 948 g and had a measured specific energy of over 50 Wh/kg at a C/2 discharge to 1.0 V. The epoxy graphite case capable of withstanding internal pressures in excess of 300 psig represents a 35% weight reduction from a lightweight 0.30 mm Ni-Cd case. A pack of these cells was cycled at 70% maximum depth of discharge beyond 10 simulated geosynchronous orbit-eclipse seasons, and high end-of-charge voltages were obtained. A prototype battery consisting of 14 such cells was fabricated and has a measured specific energy of 46 Wh/kg.

Ritterman, P. F.↗

Studies of volatiles in Apollo 17 samples and their implication to vapor transport processes

Flameless atomic absorption (FLAA), X-ray photoemission spectroscopy (XPS) and grain size separation techniques were adopted to analyze Pb, Cd, Zn and S in orange and black droplets from Apollo 17 samples. The FLAA and XPS investigations show volatile trace metal enrichment in smaller grain fractions (broken droplets); thus a part of the volatiles was probably deposited after break-up of the droplets. In addition, redistribution of the volatiles by a cratering event is indicated by continuous decreases in Pb and Cd with core depth. Studies of Zn on individual regolith grains are also reported.

Cirlin, E. H.↗

Advanced methods for preparation and characterization of infrared detector materials

Crystal growth of Hg sub 1-x Cd sub x Te and density measurements of ingot slices are discussed. Radial compositional variations are evaluated from the results of infrared transmission edge mapping. The pseudo-binary HgTe-CdTe phase diagram is examined with reference to differential thermal analysis measurements. The phase equilibria calculations, based on the 'regular association solution' theory (R.A.S.) are explained and, using the obtained R.A.S. parameters, the activities of Hg, Cd, and Te vapors and their partial pressures over the pseudo-binary melt are calculated.

Lehoczy, S. L.↗

WQ 2059-247: An unusual high redshift X-ray cluster

X-ray, optical, and radio observations of a high redshift, Bautz-Morgan type I cluster of galaxies are reported. The cD galaxy contains a powerful, flat spectrum radio source coincident with the possibly stellar nucleus. The cluster is an extremely luminous X-ray source; however, unlike nearby luminous X-ray clusters the X-ray spectrum appears to be rather soft. Two possible interpretations of the soruces are suggested: either the intracluster gas is much cooler in high redshift clusters because they are less relaxed, or the X-ray and radio emissions from WQ 2059-247 are the result of a non thermal QSO/BL Lac type object in the nucleus of the cD.

White, R. A.↗

74001 drive tube - Siderophile elements match II B iron meteorite pattern

Eight siderophile elements, seven volatile elements, and U were determined in three samples from 74001 by radiochemical neutron activation analysis. The siderophile pattern closely corresponds to the addition of approximately 0.1% of II B iron meteorites, and the enrichment of nonsiderophile volatile elements seems to be derived from lunar sources with variation generally following Se content. In addition, in 74001 (predominantly black glass), moderately volatile elements (Ag, Zn) are more abundant than In, Cd, and particularly Bi, while in 74220 (mainly orange glass), Ag, Zn, In, and Cd are almost equally abundant, but Bi is as low as in 74001.

Morgan, J. W.↗

Scanning Auger Microprobe and atomic absorption studies of lunar volcanic volatiles

Results on lunar volatile transport processes have been obtained by studying green and brown glass droplets, orange and black core tube samples and the surface sample 74241 with the Scanning Auger Microprobe (SAM) and by Flameless Atomic Absorption Analysis (FLAA). SAM analyses show that the most dominant volatiles in the top few atomic layers of droplets are Zn and S, confirming that the surface Zn and S are good indicators of pyroclastic origin, and they are not entirely present as ZnS. In addition, FLAA thermal release profiles show that almost all the Zn and Cd are on grain surfaces, indicating that Zn and Cd were completely outgassed from lava fountain products during the volcanic eruption, were recondensed during or after the eruptions, and are thus present as surface coating.

Cirlin, E. H.↗

SAS 3 and related observations of Abell 2029

X-ray and radio observations of the cluster of galaxies show that the central cD galaxy dominates the emissions. Resolution of the X-ray source shows that its extent is significantly greater than that of the profile of surface brightness of the cD galaxy. Dressler's model of most of the cluster mass with very high M/L(v) is similarly extended. The optically dark mass may provide low-energy X-ray emission of the coronae of 5 x 10 to the 16th stars with very high M/L(v), but in the 2-10 keV range the data are consistent with current theoretical predictions for hot intracluster gas.

Johnson, H. M.↗

The structure and evolution of X-ray clusters

Observations of the structure of the X-ray emission from 12 nearby rich clusters of galaxies are presented and interpreted in terms of dynamic cluster evolution. X-ray structures revealed by the Einstein Observatory imaging proportional counter in the range 0.25 to 3.0 keV were analyzed and used to classify the clusters based on their X-ray morphologies. Four categories are observed, consisting of spiral-rich clusters with low X-ray temperatures and velocity dispersions with broad and highly clumped emission, spiral-poor clusters with high X-ray temperatures and velocity dispersions with smoothly varying emission broadly or sharply peaked around a dominant galaxy, and clusters with emission typical of a cD galaxy in a poor cluster or group. The broad, highly clumped cluster emission is interpreted as a result of an early evolutionary stage, while the cD and centrally enhanced emissions represent successive later stages in X-ray galactic cluster evolution.

Jones, C.↗

Effects of heavy metals on the absorbance and reflectance spectra of plants

The spectral responses of plants to various concentrations of heavy metals in their rooting media are investigated in relation to the application of remote sensing methods to the detection of vegetation under stress. Absorption photometry of chloroplasts, measurements of metal and chlorophyll concentrations and reflectance spectrometry were performed on leaves of pea, sunflower and soybean plants grown under greenhouse conditions with the addition of various concentrations of Cd, Cu, Pb and Zn to their rooting media and on leaves of oak trees growing naturally in an area of a copper-arsenic mineralization. Under laboratory conditions, the most general effect observed was growth inhibition and ultimately death, with pea plants also exhibiting changes of chlorophyll a/ chlorophyll b ratios with Cd and Cu and reflectance increases in the visible and decreases in the infrared. Although results for other species indicate that reflectance effects are dependent on species, correlations between reflectance and metal exposure is confirmed by the field investigations. It is concluded that a remote sensing system would be improved by the inclusion of bands around 1.65 and 2.20 microns to detect soil mineralization from plant spectra.

Horler, D. N. H.↗

An accelerated test design for use with synchronous orbit

The Naval Weapons Support Center at Crane, Indiana has conducted a large scale accelerated test of 6.0 Ah Ni-Cd cells. Data from the Crane test have been used to develop an equation for the description of Ni-Cd cell behavior in geosynchronous orbit. This equation relates the anticipated time to failure for a cell in synchronous orbit to temperature and overcharge rate sustained by the cell during the light period. A test design is suggested which uses this equation for setting test parameters for future accelerated testing.

Mcdermott, P. P.↗

Life test of a nickel cadmium battery with a protection/reconditioning circuit

Results are discussed for a Ni-Cd battery test over a period of 8 years, 2 months and 44,213 simulated low Earth orbits. The battery cells were protected against overdischarge and reversal at discharge rates up to 25 amperes (1.25C) by a battery protection and reconditioning circuit. The circuit performed flawlessly during the test, and proved its value, both as a battery reconditioner and a cell protection device. Battery cell failures are also discussed. The test demonstrated the viability of using Ni-Cd batteries at depth-of-discharge up to 25 percent for over 5 years in a low Earth orbit.

Lanier, J. R., Jr.↗

Characterization of the physico-chemical properties of polymeric materials for aerospace flight

Factors contributing to the final failure of Ni-Cd batteries are listed. A differential thermal analyzer was used to study several positive and negative battery electrodes. The negative plates show a very large peak (endotherm) between 245 C and 250C. The second endotherm occurs at 300C indicating the decomposition of Cd(OH)2. In positive plates, a first weak endotherm occurs at 100C, which indicates loss of H2O from Ni(OH)2(H2O)n molecules. A second large endotherm occurs in the range of 290C to 300C, indicating the decomposition of Ni(OH2) to NiO and H2O. Atomic absorption spectroscopy was used to determine nickel, cobalt, cadmium, and potassium content in battery electrolytes and electrodes. Results are presented in tables.

Rock, M.↗

The structure and evolution of X-ray clusters of galaxies

Einstein Observatory observations of the structures of nearby X-ray clusters of galaxies are discussed in relation to dynamic cluster evolution. Examples of Virgo-type clusters, in which cool and hot gas associated with cluster members are presented and variations in surface brightness profile and the location of the cluster center are used to classify the observed clusters. The types of clusters observed are interpreted in terms of dynamic cluster evolution, with Virgo-type clusters with broad, highly clumped emission and low velocity dispersion representing early evolutionary stages, clusters containing a cD galaxy formed as the cluster evolves, and clusters with dominant galaxies and Coma-type clusters representing an equilibrium stage. X-ray emission from poor clusters of galaxies is also considered, and similarities between the presumably collisionally formed cD galaxies in rich and poor clusters are noted. Finally, observations of distant clusters are discussed, and it is noted that their analysis will lead to a better determination of the evolutionary sequence.

Jones, C.↗

SC 2059-247 - An unusual radio/X-ray source in a distant cluster of galaxies

The X-ray, optical and radio properties of a high redshift, Bautz-Morgan type I cluster of galaxies, namely SC 2059-247, are examined. This cluster is optically dominated by a cD galaxy with a powerful flat-spectrum radio source coincident with the possibly stellar nucleus. Two possible interpretations are suggested for the apparently soft X-ray spectrum of the extremely luminous cluster. Either the intracluster gas is much cooler in high-redshift clusters because they are less relaxed, or the X-ray and radio emissions from SC 2059-247 are the result of a nonthermal QSO/BL Lac type object in the nucleus of the cD. If the latter, it would be the first time that an X-ray source similar to a quasar or BL Lac object has been discovered in a previously identified galaxy.

White, R. A.↗

The structure of giant elliptical galaxies in poor clusters of galaxies

Detailed photographic surface photometry is presented of the nine first brightest galaxies in poor clusters suspected of being cD galaxies. The surface photometry is put on an absolute scale, using multiaperture photoelectric photometry. Oemler (1976) and de Vaucouleurs (1948) laws are fitted to the profiles to derive structural parameters, and the structural properties of the galaxies are compared with those of the cD galaxies in rich clusters studied by Oemler (1976) and those of normal ellipticals studied by Kormendy (1977). It is found that (1) the profiles of first brightest galaxies are well fitted by an r to the 1/4 power law over a range of more than nine magnitudes and down to the faintest light levels observed and (2) structural parameters characterizing only the central part of first brightest galaxies in poor and rich clusters, and excluding the envelope component in the case of rich clusters, smoothly extend properties exhibited by normal ellipticals. These observations are consistent with the idea that the central part of first brightest galaxies in both poor and rich clusters is made up by the mergers of smaller galaxies.

Thuan, T. X.↗