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At least 343 records · Page 19

A balloon measurement of the cosmic ray element abundances

The experiment described was flown from Thompson, Canada in August, 1973 to measure the cosmic ray element abundances in the atmosphere. All particles used in the analysis, including approximately 25,000 oxygen and 1600 iron nuclei, had sufficient energy at the top of the atmosphere to trigger the Cerenkov counter. Nuclei between beryllium and nickel were identified, using two plastic scintillators and an acrylic plastic Cerenkov counter. The relative composition and fluxes are determined. Agreement with earlier measurements in the atmosphere is within 5%; however, larger differences appear in composition extrapolated to the top of the atmosphere. In particular, the nitrogen abundance is almost 20% higher and the iron abundance is 20% lower than the generally accepted values.

Ormes, J. F.↗

Evolution of major mineral compositions and trace element abundances during fractional crystallization of a model lunar composition

The evolution of major mineral compositions and trace element abundances during perfect fractional crystallization of a model lunar magma ocean was calculated. The minerals in the model lunar composition were olivine, orthopyroxene, clinopyroxene, and plagioclase. Lunar bulk composition data, major mineral/melt equilibria data, and trace element partition data were taken from published sources. The results show olivine beginning to crystallize at 1380 C. Approximately 50% of the system crystallizes as olivine. From 50 to 60% solidification, orthopyroxene crystallizes alone. During the final 40% solidification, Ca-rich clinopyroxene and plagioclase crystallize together. Various changes in composition of all these minerals are also noted during the process. Concomitant evolution of major element abundances in the melt is followed along with that of trace element abundances. Consequences of the results for constraints on some aspects of the composition of the lunar magma ocean and of the primitive moon are discussed.

Drake, M. J.↗

Abundances of simple oxygen-bearing molecules and ions in interstellar clouds

The abundances of simple oxygen-bearing interstellar molecules in warm (T at least 40 K), diffuse, and moderately thick clouds are calculated on the basis of binary gas-phase reactions. The most important reactions are ion-molecule, charge-exchange, and dissociative-recombination reactions, as suggested mainly by earlier workers. The progenitor of these molecules in diffuse clouds is the cosmic-ray-produced H(+) ion, working through the charge-exchange reaction with O. The ionization of H(+) and He(+) is also discussed. Dissociative charge exchange of He(+) with H2 is an important source of H(+) in regions of large fractional abundance of H2, as well as an important destruction mechanism for He(+) even for small f (at least 0.1). The calculated molecular abundances are consistent with some of the available observational information.

Glassgold, A. E.↗

Detection of O2 dayglow emission from Mars and the Martian ozone abundance

High-resolution spectroscopy of Mars in the vicinity of 1.27 microns has revealed the presence of emission lines of O2 which are interpreted as the result of production of O2(1 delta g) in the ultraviolet photolysis of Martian ozone. In the equatorial region of Mars, the dayglow intensity implies an ozone abundance near 0.2 microatm, which seems consistent with theoretical models which utilize the measured water-vapor abundance. A much larger ozone abundance exists in the atmosphere at high winter latitude, in agreement with direct measurement of ozone absorption performed by the Mariner spacecraft.

Noxon, J. F.↗

Abundance variations in high-velocity interstellar gas

Based on line-of-sight models and profile fitting, abundance variations of Ca, Si, Fe, and Na in high-velocity interstellar clouds toward Mu Columbae, HD 28497, and HD 50896 are discussed. The correlation of larger ratios N(Ca II)/N(Na I) with increasing radial velocity in clouds with absolute values of radial velocity from 20 to 100 km/s, is shown to quite likely be due to abundance variations in Ca rather than an ionization effect. Copernicus UV data show that the ratios N(Fe II)/N(S II) and N(Si II)/N(S II) have the same velocity correlation as Ca II, and the ambiguity concerning the relative abundance of Na I to hydrogen is removed. Theories of grain disruption are discussed as they relate to the observed Ca, Si, and Fe enhancements and their correlation with cloud velocity.

Shull, J. M.↗

The solar boron abundance

Positive evidence for the presence of boron in the sun is reported, and the chemical abundance of boron in the photosphere is derived from photoelectric measurements of the solar spectrum near 2500 A obtained with a rocketborne high-resolution spectrometer. Short sections of the spectrum in the vicinities of the B I lines at 2496.772 and 2497.723 A are plotted. The photospheric boron abundance is determined primarily by analyzing the solar-center spectrum near the first of the two lines in the framework of several single-component photospheric models. The logarithmic boron abundance obtained is 2.6, with an estimated uncertainty of plus or minus 0.3 dex, on the scale where that of hydrogen is 12.0. This value is shown to be in excellent agreement with that predicted for a nucleosynthesis model in which Li, Be, and B are produced by cosmic-ray spallation.

Kohl, J. L.↗

Metal abundance in the Praesepe and Hyades clusters

Calcium K-line photometry is reported for 27 A-type stars in the Praesepe cluster, and the data obtained are compared with previous K-line observations of Hyades stars. It is found that calcium and other metals are generally overabundant in Praesepe relative to field stars and that there is a considerable scatter in metal-abundance indices. Comparison with the Hyades results indicates that the Praesepe stars are as metal-enriched as the Hyades stars. These results are taken as evidence favoring Eggen's (1960) proposal that the Hyades and Praesepe clusters should be regarded as a single group having, on the average, about a factor-of-two higher metal abundance than solar-neighborhood field stars as well as a high internal dispersion in metal-line strengths. The questions of where and how the Praesepe-Hyades stars acquired their high average metal abundances, K-line strengths, and associated dispersions are briefly considered.

Henry, R. C.↗

Heavy element abundances in Ap stars from ultraviolet data. I - The bright reference stars Alpha Lyrae and Alpha Canis Majoris A

Curve-of-growth analysis is used to derive chemical abundances in Alpha Lyr and Alpha CMa, based on ultraviolet spectra obtained with Copernicus. This analysis is part of a program to study the abundances of the heavy elements mercury and platinum and the short-lived element technetium in the atmospheres of Ap and Am stars. Ultraviolet Fe II lines are used to establish the curves of growth for Alpha Lyr and Alpha CMa A; abundances of a variety of elements, along with upper limits on Hg, Pt, and Tc, are derived. In cases where previous studies based on visual spectra have included elements in common with the present analysis, the agreement is good within the known uncertainties. One new element, cadmium, is observed for these two stars. The upper limits on Pt and Hg, as well as Tc, show that these elements are probably not enhanced in Alpha CMa A by more than about one order of magnitude.

Boiarchuk, A. A.↗

A TiO2 abundance map for the northern maria

A map of TiO2 abundance for most of the northern maria is presented. The telescopic data base used is the 0.38/0.56-micron ratio mosaic from Johnson et at. (1977). The titanium content has been estimated using the correlation established by Charette et al. (1974). The combination of observational, processing, and calibration errors indicates that the TiO2 map is accurate to + or - 2% (wt% TiO2) for high TiO2 content (more than 5%) and + or - 1% for low values of TiO2. Analysis of the lunar sample and telescopic data suggests strongly that the spectral parameter mapped is sensitive primarily to TiO2 abundance in the range 3-9% and does not correlate directly with iron content. It is suggested, however, that for the low TiO2 mare regions (less than 2-3% TiO2) there may be a relation between the spectral ratio and iron content and that some of the reddest mare areas in the Imbrium region may have low iron contents as well as low titanium abundances.

Johnson, T. V.↗

Rare-earth abundances in chondritic meteorites

Fifteen chondrites, including eight carbonaceous chondrites, were analyzed for rare earth element abundances by isotope dilution. Examination of REE for a large number of individual chondrites shows that only a small proportion of the analyses have flat unfractionated REE patterns within experimental error. While some of the remaining analyses are consistent with magmatic fractionation, many patterns, in particular those with positive Ce anomalies, can not be explained by known magmatic processes. Elemental abundance anomalies are found in all major chondrite classes. The persistence of anomalies in chondritic materials relatively removed from direct condensational processes implies that anomalous components are resistant to equilibrium or were introduced at a late stage of chondrite formation. Large-scale segregation of gas and condensate is implied, and bulk variations in REE abundances between planetary bodies is possible.

Evensen, N. M.↗

Abundances of molecules in planetary atmospheres from middle infrared spectroscopic observations

The application of middle-infrared spectroscopy to the study of molecular abundances in planetary atmospheres is discussed with particular reference to the Jovian atmosphere. Data on the observed composition of the Jovian atmosphere are examined with speculation as to the sources of the minor components. Solar and Jovian elemental abundances are contrasted, and a dynamical meteorological model of Jupiter's atmosphere is summarized. An observed high-altitude spectrum of Jupiter is compared with synthetic H2O spectra calculated for two abundances (solar and observed). The observed composition of Saturn's atmosphere is reported, and middle-IR studies of terrestrial planets are surveyed.

Larson, H. P.↗

Origin and history of the adcumulate eucrite, Moama as inferred from REE abundances, Sm-Nd and U-Pb systematics

The abundances of Sm-Nd and U-Pb isotopes and of rare earth elements (REE) in Moama cumulate eucrite were investigated. The Sm-Nd data plotted on a Nd-143/Nd-144 vs Sm-147/Nd-144 evolution diagram define a line with a slope corresponding to an age of 4.58 plus or minus 0.05 billion years and an initial Nd-143/Nd-144 ratio of about 0.50684. Moama was found to contain the lowest overall trivalent REE abundances, the most light REE-depleted abundance pattern, and largest positive Eu anomaly of any eucrite yet studied. The REE data indicate that Moama could have been derived by about 1 to 5% fractional crystallization from a liquid with REE contents similar to Juvinas, or about 20 to 30% fractional crystallization from a Sioux County-like liquid. The data are consistent with the hypothesis that the Moama, Serra de Mage, and Moore county cumulate meteorites could have been derived from the same parent liquid. Results of the U-Th-Pb study indicate that the majority of the Pb in Moama is of terrestrial origin, and suggest that the meteorite has undergone a minor thermal event causing re-equilibration of the U-Pb system.

Hamet, J.↗

The determination of electron abundances in interstellar clouds

An independent method is proposed for the determination of electron abundances in dense clouds based upon the abundance ratio of HCO(+) and CO. The method is derived from a simple application of gas phase ion molecule interstellar chemistry. It is noted that unlike the fractionation of deuterated molecules, it applies to warm as well as to cool clouds. The method is illustrated with the results of the recent abundance survey of Wooten et al. (1978). Finally, it is shown that in cases where deuterium enhancement is measured, an upper limit can be obtained for the cosmic ray ionization rate.

Wootten, A.↗

An upper limit to the global SO2 abundance on Io

An upper limit to the global abundance of SO2 gas in the atmosphere of Io has been derived from observations of near-UV reflectivity made from earth orbit. Spectra in the range 2900-3100 A were obtained by the long-wavelength spectrograph of the IUE, and compared with the convolved solar spectrum of Broadfoot (1972). From the apparent solar origin of all the spectral features, an upper limit of 0.008 cm atm was calculated for the abundance of SO2, which was confirmed by ratio spectra of Vesta. Discrepancies between the upper limit obtained and the detection of a column abundance of 0.2 cm atm by the Voyager 1 IRIS experiment have a number of possible explanations, the most likely of which is that the SO2 atmosphere in Io is patchy, being confined to regions over solid deposits and volcanic vents.

Butterworth, P. S.↗

A survey of approximately 1 MeV/nucleon solar flare particle abundances, in the Z ? 1-26 range, during the 1973-1977 solar minimum period

The abundances of the major elements over the range H-Fe in solar flare energetic particles near 1 MeV/nucleon were surveyed for a large number of flares during the period 1973-1977; observations were carried out by the IMP 8 spacecraft in interplanetary space. The survey considered two types of solar flare events: (1) large events from which the average boundaries were deduced, and (2) events which have significant abundance differences from average. In addition, two He-3-rich events with abundance features that are different from previous examples are reported: one case with no enhancements of heavy ions, and a second case in which, compared to O, the heavy-ion enhancements are confined to the charge range Si-Fe rather than the usual case in which all elements Ne-Fe are enriched.

Mason, G. M.↗

Observation of the core of the Perseus cluster with the Einstein solid state spectrometer: Cooling gas and elemental abundances

Solid State Spectrometer observations of the core of the Perseus cluster have resulted in the detection of X-ray emission lines due to Si, S, and Fe. Analysis of the spectrum indicates that the X-ray emission has at least two characteristic temperatures. This is interpreted in the framework of radiative accretion in the core of the cluster. The derived parameters are a cooling time tc less than 2 x 109 yrs for the low temperature gas, a mass accretion rate of approximately 300 Mo/yr and a characteristic size of 10 to 20 Kpc for the cool gas. The Fe abundance in the core, approximately 0.4, is similar to the Fe abundance averaged over the whole cluster indicating that Fe emission is not strongly concentrated about NGC 1275. The Si and S abundances are consistent with solar values.

Mushotzky, R. F.↗

Abundances of energy spectra of individual iron-secondary elements

Relative abundances of individual Iron-secondary elements have been measured using a balloon-borne 6.6 m ster ionization/Cerenkov detector system. The unusually large geometry factor and single-charge resolution yield empirical atmospheric attenuation curves for individual elements which combine with high statistics at float altitude to yield individual element abundances, extrapolated to the top of the atmosphere, with high precision. Results are presented for top-of-the-atmosphere abundances (relative to iron) of individual elements in the Z range 13-30.

Israel, M. H.↗

Models of molecular clouds and the abundances of H2CO and HCO/+/

Observations of HCO(+) and H2CO in a sample of 13 molecular clouds have been analyzed by construction of uniform, spherical cloud models. The total densities and the abundance of HCO(+) and H2CO relative to H2 which result from these models fall into two domains: one group of clouds has a low temperature, moderate density, and high abundances; the other group has higher temperature and density, but lower abundances. The factor distinguishing these groups may be depletion onto grains in the denser sources.

Wootten, A.↗