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AuTl3 crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. Au is bonded to twelve equivalent Tl atoms to form a mixture of edge and face-sharing AuTl12 cuboctahedra. All Au–Tl bond lengths are 3.40 Å. Tl is bonded in a 6-coordinate geometry to four equivalent Au and two equivalent Tl atoms. Both Tl–Tl bond lengths are 3.04 Å.
PtTl3 crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. Pt is bonded to twelve equivalent Tl atoms to form a mixture of edge and face-sharing PtTl12 cuboctahedra. All Pt–Tl bond lengths are 3.30 Å. Tl is bonded in a 6-coordinate geometry to four equivalent Pt and two equivalent Tl atoms. Both Tl–Tl bond lengths are 2.96 Å.
Th2Tl is Khatyrkite structured and crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. Th is bonded in a 4-coordinate geometry to four equivalent Tl atoms. All Th–Tl bond lengths are 3.36 Å. Tl is bonded in a 10-coordinate geometry to eight equivalent Th and two equivalent Tl atoms. Both Tl–Tl bond lengths are 3.03 Å.
Tl3Sn crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Tl is bonded in a 12-coordinate geometry to eight equivalent Tl and four equivalent Sn atoms. There are a spread of Tl–Tl bond distances ranging from 3.44–3.60 Å. There are two shorter (3.46 Å) and two longer (3.52 Å) Tl–Sn bond lengths. Sn is bonded to twelve equivalent Tl atoms to form a mixture of corner and face-sharing SnTl12 cuboctahedra.
Ti2TlC is H-Phase structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Ti is bonded in a 3-coordinate geometry to three equivalent Tl and three equivalent C atoms. All Ti–Tl bond lengths are 3.07 Å. All Ti–C bond lengths are 2.14 Å. Tl is bonded to six equivalent Ti and six equivalent Tl atoms to form TlTi6Tl6 cuboctahedra that share corners with six equivalent TlTi6Tl6 cuboctahedra, corners with six equivalent CTi6 octahedra, edges with six equivalent TlTi6Tl6 cuboctahedra, edges with six equivalent CTi6 octahedra, and faces with six equivalent TlTi6Tl6 cuboctahedra. The corner-sharing octahedral tilt angles are 22°. All Tl–Tl bond lengths are 3.18 Å. C is bonded to six equivalent Ti atoms to form CTi6 octahedra that share corners with six equivalent TlTi6Tl6 cuboctahedra, edges with six equivalent TlTi6Tl6 cuboctahedra, and edges with six equivalent CTi6 octahedra.
CaTlO7Cl5 crystallizes in the monoclinic C2/m space group. The structure is one-dimensional and consists of two CaTlO7Cl5 ribbons oriented in the (0, 0, 1) direction. Ca is bonded in a 6-coordinate geometry to six O atoms. There are a spread of Ca–O bond distances ranging from 2.15–2.80 Å. Tl is bonded in a 6-coordinate geometry to four O and two equivalent Cl atoms. There are two shorter (2.18 Å) and two longer (2.32 Å) Tl–O bond lengths. Both Tl–Cl bond lengths are 3.01 Å. There are five inequivalent O sites. In the first O site, O is bonded in a bent 150 degrees geometry to one Ca and one Cl atom. The O–Cl bond length is 1.59 Å. In the second O site, O is bonded in a linear geometry to one Ca and one Cl atom. The O–Cl bond length is 1.52 Å. In the third O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.49 Å. In the fourth O site, O is bonded in a trigonal planar geometry to one Ca and two equivalent Tl atoms. In the fifth O site, O is bonded in a distorted trigonal planar geometry to one Ca, one Tl, and one Cl atom. The O–Cl bond length is 1.67 Å. There are three inequivalent Cl sites. In the first Cl site, Cl is bonded in a single-bond geometry to one O atom. In the second Cl site, Cl is bonded in a distorted water-like geometry to one Tl and one O atom. In the third Cl site, Cl is bonded in a bent 120 degrees geometry to two O atoms.
CuTl3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Cu is bonded to twelve equivalent Tl atoms to form CuTl12 cuboctahedra that share corners with twelve equivalent CuTl12 cuboctahedra, edges with twenty-four equivalent TlTl8Cu4 cuboctahedra, faces with six equivalent CuTl12 cuboctahedra, and faces with twelve equivalent TlTl8Cu4 cuboctahedra. All Cu–Tl bond lengths are 3.34 Å. Tl is bonded to four equivalent Cu and eight equivalent Tl atoms to form TlTl8Cu4 cuboctahedra that share corners with twelve equivalent TlTl8Cu4 cuboctahedra, edges with eight equivalent CuTl12 cuboctahedra, edges with sixteen equivalent TlTl8Cu4 cuboctahedra, faces with four equivalent CuTl12 cuboctahedra, and faces with fourteen equivalent TlTl8Cu4 cuboctahedra. All Tl–Tl bond lengths are 3.34 Å.
Tl2S is trigonal omega-like structured and crystallizes in the trigonal R3 space group. The structure is two-dimensional and consists of three Tl2S sheets oriented in the (0, 0, 1) direction. there are six inequivalent Tl1+ sites. In the first Tl1+ site, Tl1+ is bonded in a 3-coordinate geometry to three S2- atoms. There are a spread of Tl–S bond distances ranging from 2.92–3.01 Å. In the second Tl1+ site, Tl1+ is bonded in a 3-coordinate geometry to three S2- atoms. There are a spread of Tl–S bond distances ranging from 2.92–3.01 Å. In the third Tl1+ site, Tl1+ is bonded in a 3-coordinate geometry to three S2- atoms. There are a spread of Tl–S bond distances ranging from 2.92–3.01 Å. In the fourth Tl1+ site, Tl1+ is bonded in a 3-coordinate geometry to three S2- atoms. There are two shorter (2.94 Å) and one longer (3.08 Å) Tl–S bond lengths. In the fifth Tl1+ site, Tl1+ is bonded in a 3-coordinate geometry to three S2- atoms. There are two shorter (2.94 Å) and one longer (3.08 Å) Tl–S bond lengths. In the sixth Tl1+ site, Tl1+ is bonded in a 3-coordinate geometry to three S2- atoms. There are a spread of Tl–S bond distances ranging from 2.93–3.08 Å. There are five inequivalent S2- sites. In the first S2- site, S2- is bonded to six Tl1+ atoms to form edge-sharing STl6 octahedra. In the second S2- site, S2- is bonded to six Tl1+ atoms to form edge-sharing STl6 octahedra. In the third S2- site, S2- is bonded to six Tl1+ atoms to form edge-sharing STl6 octahedra. In the fourth S2- site, S2- is bonded to six Tl1+ atoms to form edge-sharing STl6 octahedra. In the fifth S2- site, S2- is bonded to six Tl1+ atoms to form distorted edge-sharing STl6 pentagonal pyramids.
IrTl3 crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. Ir is bonded to twelve equivalent Tl atoms to form a mixture of edge and face-sharing IrTl12 cuboctahedra. All Ir–Tl bond lengths are 3.21 Å. Tl is bonded in a 6-coordinate geometry to four equivalent Ir and two equivalent Tl atoms. Both Tl–Tl bond lengths are 2.87 Å.
HfTl crystallizes in the hexagonal P-6m2 space group. The structure is three-dimensional. Hf is bonded to six equivalent Hf and six equivalent Tl atoms to form HfHf6Tl6 cuboctahedra that share corners with eighteen equivalent HfHf6Tl6 cuboctahedra, edges with six equivalent HfHf6Tl6 cuboctahedra, edges with twelve equivalent TlHf6Tl6 cuboctahedra, faces with eight equivalent HfHf6Tl6 cuboctahedra, and faces with twelve equivalent TlHf6Tl6 cuboctahedra. All Hf–Hf bond lengths are 3.23 Å. All Hf–Tl bond lengths are 3.20 Å. Tl is bonded to six equivalent Hf and six equivalent Tl atoms to form TlHf6Tl6 cuboctahedra that share corners with eighteen equivalent TlHf6Tl6 cuboctahedra, edges with six equivalent TlHf6Tl6 cuboctahedra, edges with twelve equivalent HfHf6Tl6 cuboctahedra, faces with eight equivalent TlHf6Tl6 cuboctahedra, and faces with twelve equivalent HfHf6Tl6 cuboctahedra. All Tl–Tl bond lengths are 3.23 Å.
Tl3Ge is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Tl is bonded to eight equivalent Tl and four equivalent Ge atoms to form distorted TlTl8Ge4 cuboctahedra that share corners with twelve equivalent TlTl8Ge4 cuboctahedra, edges with eight equivalent GeTl12 cuboctahedra, edges with sixteen equivalent TlTl8Ge4 cuboctahedra, faces with four equivalent GeTl12 cuboctahedra, and faces with fourteen equivalent TlTl8Ge4 cuboctahedra. All Tl–Tl bond lengths are 3.41 Å. All Tl–Ge bond lengths are 3.41 Å. Ge is bonded to twelve equivalent Tl atoms to form distorted GeTl12 cuboctahedra that share corners with twelve equivalent GeTl12 cuboctahedra, edges with twenty-four equivalent TlTl8Ge4 cuboctahedra, faces with six equivalent GeTl12 cuboctahedra, and faces with twelve equivalent TlTl8Ge4 cuboctahedra.
Tl3Bi is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Tl is bonded to eight equivalent Tl and four equivalent Bi atoms to form distorted TlTl8Bi4 cuboctahedra that share corners with twelve equivalent TlTl8Bi4 cuboctahedra, edges with eight equivalent BiTl12 cuboctahedra, edges with sixteen equivalent TlTl8Bi4 cuboctahedra, faces with four equivalent BiTl12 cuboctahedra, and faces with fourteen equivalent TlTl8Bi4 cuboctahedra. All Tl–Tl bond lengths are 3.56 Å. All Tl–Bi bond lengths are 3.56 Å. Bi is bonded to twelve equivalent Tl atoms to form BiTl12 cuboctahedra that share corners with twelve equivalent BiTl12 cuboctahedra, edges with twenty-four equivalent TlTl8Bi4 cuboctahedra, faces with six equivalent BiTl12 cuboctahedra, and faces with twelve equivalent TlTl8Bi4 cuboctahedra.
ZnTl3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Zn is bonded to twelve equivalent Tl atoms to form ZnTl12 cuboctahedra that share corners with twelve equivalent ZnTl12 cuboctahedra, edges with twenty-four equivalent TlTl8Zn4 cuboctahedra, faces with six equivalent ZnTl12 cuboctahedra, and faces with twelve equivalent TlTl8Zn4 cuboctahedra. All Zn–Tl bond lengths are 3.39 Å. Tl is bonded to four equivalent Zn and eight equivalent Tl atoms to form TlTl8Zn4 cuboctahedra that share corners with twelve equivalent TlTl8Zn4 cuboctahedra, edges with eight equivalent ZnTl12 cuboctahedra, edges with sixteen equivalent TlTl8Zn4 cuboctahedra, faces with four equivalent ZnTl12 cuboctahedra, and faces with fourteen equivalent TlTl8Zn4 cuboctahedra. All Tl–Tl bond lengths are 3.39 Å.
EuTl3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Eu is bonded to twelve equivalent Tl atoms to form EuTl12 cuboctahedra that share corners with twelve equivalent EuTl12 cuboctahedra, edges with twenty-four equivalent TlEu4Tl8 cuboctahedra, faces with six equivalent EuTl12 cuboctahedra, and faces with twelve equivalent TlEu4Tl8 cuboctahedra. All Eu–Tl bond lengths are 3.50 Å. Tl is bonded to four equivalent Eu and eight equivalent Tl atoms to form distorted TlEu4Tl8 cuboctahedra that share corners with twelve equivalent TlEu4Tl8 cuboctahedra, edges with eight equivalent EuTl12 cuboctahedra, edges with sixteen equivalent TlEu4Tl8 cuboctahedra, faces with four equivalent EuTl12 cuboctahedra, and faces with fourteen equivalent TlEu4Tl8 cuboctahedra. All Tl–Tl bond lengths are 3.50 Å.
ReTl crystallizes in the orthorhombic Imma space group. The structure is three-dimensional. Re is bonded in a 10-coordinate geometry to two equivalent Re and eight equivalent Tl atoms. Both Re–Re bond lengths are 2.48 Å. There are a spread of Re–Tl bond distances ranging from 3.05–3.15 Å. Tl is bonded to eight equivalent Re and four equivalent Tl atoms to form a mixture of distorted edge, face, and corner-sharing TlTl4Re8 cuboctahedra. There are two shorter (3.04 Å) and two longer (3.10 Å) Tl–Tl bond lengths.
VTl3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. V is bonded to twelve equivalent Tl atoms to form VTl12 cuboctahedra that share corners with twelve equivalent VTl12 cuboctahedra, edges with twenty-four equivalent TlTl8V4 cuboctahedra, faces with six equivalent VTl12 cuboctahedra, and faces with twelve equivalent TlTl8V4 cuboctahedra. All V–Tl bond lengths are 3.29 Å. Tl is bonded to four equivalent V and eight equivalent Tl atoms to form TlTl8V4 cuboctahedra that share corners with twelve equivalent TlTl8V4 cuboctahedra, edges with eight equivalent VTl12 cuboctahedra, edges with sixteen equivalent TlTl8V4 cuboctahedra, faces with four equivalent VTl12 cuboctahedra, and faces with fourteen equivalent TlTl8V4 cuboctahedra. All Tl–Tl bond lengths are 3.29 Å.
Pd5TlAs crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. there are two inequivalent Pd sites. In the first Pd site, Pd is bonded in a distorted square co-planar geometry to four equivalent Tl atoms. All Pd–Tl bond lengths are 2.89 Å. In the second Pd site, Pd is bonded in a 4-coordinate geometry to two equivalent Tl and two equivalent As atoms. Both Pd–Tl bond lengths are 2.93 Å. Both Pd–As bond lengths are 2.52 Å. Tl is bonded to twelve Pd atoms to form a mixture of corner and face-sharing TlPd12 cuboctahedra. As is bonded in a body-centered cubic geometry to eight equivalent Pd atoms.
Pr2Tl crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. there are two inequivalent Pr sites. In the first Pr site, Pr is bonded in a 6-coordinate geometry to eight Pr and six equivalent Tl atoms. There are two shorter (3.50 Å) and six longer (3.69 Å) Pr–Pr bond lengths. All Pr–Tl bond lengths are 3.69 Å. In the second Pr site, Pr is bonded to six equivalent Pr and five equivalent Tl atoms to form a mixture of distorted corner and face-sharing PrPr6Tl5 trigonal bipyramids. There are three shorter (3.25 Å) and two longer (3.50 Å) Pr–Tl bond lengths. Tl is bonded in a 11-coordinate geometry to eleven Pr atoms.