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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Organic chemistry on Titan

Observations of nonequilibrium phenomena on the Saturn satellite Titan indicate the occurrence of organic chemical evolution. Greenhouse and thermal inversion models of Titan's atmosphere provide environmental constraints within which various pathways for organic chemical synthesis are assessed. Experimental results and theoretical modeling studies suggest that the organic chemistry of the satellite may be dominated by two atmospheric processes: energetic-particle bombardment and photochemistry. Reactions initiated in various levels of the atmosphere by cosmic ray, Saturn wind, and solar wind particle bombardment of a CH4 - N2 atmospheric mixture can account for the C2-hydrocarbons, the UV-visible-absorbing stratospheric haze, and the reddish color of the satellite. Photochemical reactions of CH4 can also account for the presence of C2-hydrocarbons. In the lower Titan atmosphere, photochemical processes will be important if surface temperatures are sufficiently high for gaseous NH3 to exist. Hot H-atom reactions initiated by photo-dissociation of NH3 can couple the chemical reactions of NH3 and CH4 and produce organic matter.

Chang, S.↗
NASA NTRS1979

Study of entry and landing probes for exploration of Titan

Saturn's largest moon, Titan, is a totally unique planetary body which is certain to yield exciting new phenomena. Current information is lacking in detail to distinguish between a thin methane rich atmosphere and a thick nitrogen rich atmosphere. Therefore, both the thin and thick atmospheric models were used for the study of various Titan probe classes described in this report. The technical requirements, conceptual design, science return, schedule, cost and mission implications of three probe classes that could be used for exploration of Titan are defined. The three probe classes were based on a wide range of exploration mission possibilities.

Source record↗
NASA NTRS1980

An entry and landing probe for Titan

Results of a recent study of entry and landing probes for the exploration of Titan are presented. The probes considered were based on a wide range of exploration mission possibilities. They included: an atmospheric science probe; an intermediate, atmospheric and limited surface science probe; and a larger atmospheric and expanded surface science probe. Because of lower gravity on Titan and its atmosphere characteristics, the entry environment is less severe than that of Mars. However, the large uncertainties in the current definition of the atmosphere and uncertainties in Titan's surface characteristics have required trade-offs of various combinations of entry and descent shapes and hard lander configurations. Results show that all probe classes are feasible without major developments.

Murphy, J. P.↗
NASA NTRS1980

Preliminary results of polarimetry and photometry of Titan at large phase angles from Pioneer 11

The imaging photopolarimeter (IPP) aboard the Pioneer 11 spacecraft measured the linear polarization of the integrated disk of Titan in red and blue light at a variety of phase angles from 15 to 97 deg. The large polarization (54%) measured in blue light at 90 deg phase constrains the size of the aerosols near the top of Titan's atmosphere to have radii smaller than about 0.09 microns if they have a refractive index of 2.0. The polarization at 90 deg phase in red light is smaller (41%) and implies that the optical thickness of the layer of small aerosols is about 0.6 above an effectively depolarizing surface. The shape of the polarization versus phase curve in blue light suggests increasing particle size with increasing depth into the atmosphere. The limb darkening of Titan was measured at 28 deg phase by using the imaging mode of the IPP. The limb darkening observed in both colors is reasonably consistent with that given by the scattering models derived from the polarization observations.

Tomasko, M. G.↗
NASA NTRS1981

Titan's hydrogen torus

A model of Titan's hydrogen torus, capable of describing its time evolution under the influence of the gravitational fields of both the satellite and the planet, is presented. Estimated lifetimes for hydrogen atoms near Titan's orbit of the order of 10 to the 7th s, based on recent Pioneer 11 measurements, suggest that the torus completely encircles Saturn and is angularly unsymmetric, having an enhanced gas density near the satellite. New model calculations confirm this and provide an explanation for the torus detected by the Copernicus satellite and the UV instrument of Pioneer 11. Agreement between calculated and observed Lyman alpha intensities suggests a hydrogen escape flux between 1 x 10 to the 9th/sq cm-s and 3 x 10 to the 9th/sq cm-s should be operative at Titan. This produces a torus containing some 10 to the 34th hydrogen atoms.

Smyth, W. H.↗
NASA NTRS1981

The 1-mm brightness temperature of Titan

Titan has been observed with the 5-m Hale telescope at an effective wavelength of 1 mm. Adopting a value of 2700 km for the radius of Titan, a brightness temperature of 86 + or - 12 K is found at 1 mm. By a comparison of the results with previous measurements at longer wavelengths, it is concluded that the satellite surface is the source of the 1-mm radiation. Since the measured brightness temperature is close to the equilibrium temperature of a blackbody at the distance of Saturn, it is believed there is no significant greenhouse effect on Titan.

Roellig, T. L.↗
NASA NTRS1981

Implications of Titan's north-south brightness asymmetry

Voyager 1 images of Titan, when normalized to remove limb darkening, reveal an axially symmetric brightness pattern with significant north-south asymmetry. This interhemispheric contrast seems to be a response to seasonal solar heating variations resulting from Titan's inclined spin axis. The contrast significantly lags the solar forcing, indicating that its production involves the atmosphere well below the unit optical depth level. The contrast has a significant effect on Titan's disk-integrated brightness as seen from earth, and probably accounts for most of the observed long term variation, with solar UV variations accounting for the remainder.

Sromovsky, L. A.↗
NASA NTRS1982

Production and condensation of organic gases in the atmosphere of Titan

The rates and altitudes for the dissociation of atmospheric constituents on Titan are calculated for solar ultraviolet radiation, the solar wind, Saturn magnetospheric particles, the Saturn co-rotating plasma, and cosmic rays. Laboratory experiments show that a variety of simple gas phase organic molecules and more complex organic solids called tholins are produced by such irradiations of simulated Titanian atmospheres. Except for ultraviolet wavelengths longward of the methane photodissociation continuum, most dissociation events occur between about 3100 and 3600 km altitude, corresponding well to the region of EUV opacity detected by Voyager. For a wide variety of simple to moderately complex organic gases in the Titanian atmosphere, condensation occurs below the top of the main cloud deck at about 2825 km. It is proposed that such condensates, beginning with CH4 at about 2615 km, comprise the principal mass of the Titan clouds. There is a distinct tendency for the atmosphere of Titan to act as a fractional distillation device, molecules of greater complexity condensing out at higher altitudes.

Sagan, C.↗
NASA NTRS1982

The induced magnetosphere of Titan

No evidence was found for an intrinsic magnetic field, nor for the development of a bow shock wave, as the corotating Saturnian magnetoplasma convected past Titan during the Voyager 1 close encounter of November 12, 1980. The observation of a well-developed, induced bipolar magnetic tail is evidence, however, of a strong electrodynamic interaction. Three thin, current-carrying regions were crossed which correspond to the inbound and outbound tail magnetopause and an imbedded tail neutral sheet. The interaction is unique among those observed to date in the solar system, in that it is intermediate with respect to sonic and Alfvenic Mach numbers by comparison with Titan in the solar wind and Io in the Jovian magnetosphere. The draping of the Saturnian magnetic field around the ionosphere of Titan is suggested by results of the analysis of magnetic field data.

Ness, N. F.↗
NASA NTRS1982

The plumes of Titan

The plasma density enhancements observed during the Voyager 1 Titan encounter are interpreted in terms of a single plume of plasma wrapped around Saturn by corotation. Consideration is given to the radial motions of the plume driven by fluctuations in solar wind pressure and the dispersal of the plasma by the centrifugal interchange instability, by heating, and by azimuthal acceleration. It is shown that Saturn cannot readily impose corotation directly on the plume and, incidentally, that the total dissipation associated with the Titan-magnetosphere interaction is insufficient to supply the power to produce the observed Titan ultraviolet airglow. A pickup velocity of 8 km/s is inferred on the basis of the observed velocity and a standing wave model. It is found that the Voyager plasma observations are consistent with the predictions of the model.

Eviatar, A.↗
NASA NTRS1982

The spectrum of Titan in the far-infrared and microwave regions

The pressure-induced absorptions of gaseous nitrogen (N2) and methane (CH4) are computed on the basis of the collisional lineshape theory of Birnbaum and Cohen (1976). Laboratory data at 300 and 124 K for N2 and at 296 and 195 K for CH4 are used to determine the collisional time constants and their temperature dependence. The spectrum of Titan from the microwave to the far-infrared region (0.1-600/cm) is then modeled using these opacities and a temperature profile of Titan's atmosphere derived from the Voyager 1 radio occultation experiment. The model atmosphere is composed of N2 and CH4, their relative proportions being determined by the vapor pressure law of CH4. A model with gaseous opacity alone is ruled out by the far-infrared observations. An additional opacity, thought to be associated with a methane cloud, is confirmed. The effective temperature of Titan is estimated at 83.2 plus or minus 1.4 K.

Courtin, R.↗
NASA NTRS1982

The abundance of CH3D in the atmosphere of Titan, derived from 8- to 14-micron thermal emission

The 8.6-micron emission feature of Titan's infrared spectrum was analyzed using the Voyager temperature-pressure profile. Although both C3H8 and CH3D have bands at that wavelength, it is shown that CH3D dominates the observed emission on Titan. A CH3D/CH4 mixing ratio is derived using this band and the strong CH4 band at 7.7 microns. The corresponding D/H ratio is 4.2(+2 -1.5) x 10 to the -4th, neglecting deuterium fractionation with other molecules. The main uncertainty in this value comes from the continuum emission characteristics. The D/H ratio is apparently significantly enhanced on Titan with respect to published values for Saturn.

Kim, S. J.↗
NASA NTRS1983

Internal gravity waves in Titan's atmosphere observed by Voyager radio occultation

The radio scintillations caused by scattering from small-scale irregularities in Titan's neutral atmosphere during a radio occultation of Voyager 1 by Titan are investigated. Intensity and frequency fluctuations occurred on time scales from about 0.1 to 1.0 sec at 3.6 and 13 cm wavelengths whenever the radio path passed within 90 km of the surface, indicating the presence of variations in refractivity on length scales from a few hundred meters to a few kilometers. Above 25 km, the altitude profile of intensity scintillations closely agrees with the predictions of a simple theory based on the characteristics of internal gravity waves propagating with little or no attenuation through the vertical stratification in Titan's atmosphere. These observations support a hypothesis of stratospheric gravity waves, possibly driven by a cloud-free convective region in the lowest few kilometers of the stratosphere.

Hinson, D. P.↗
NASA NTRS1983

Is Titan wet or dry?

Titan's dense and cold nitrogen atmosphere contains a small amount of methane under conditions at least approaching those at which one or both constituents would condense. The possibility of methane and nitrogen rain clouds and global methane oceans has been discussed widely. From specific features of radio occultation and other Voyager results, however, it is concluded that nitrogen does not condense on Titan and that Titan has neither global methane oceans nor a global cloud of liquid methane droplets. Certain results indirectly support the conjecture that methane does not condense at any location. However, other considerations favor a methane ice haze high in the troposphere, and liquid and solid methane might exist on the surface and as low clouds at polar latitudes.

Eshleman, V. R.↗
NASA NTRS1983

Galactic cosmic rays and N2 dissociation on Titan

The electromagnetic and particle cascade resulting from the absorption of galactic cosmic rays in the atmosphere of Titan is shown to be an important mechanism for driving the photochemistry at pressures of 1 to 50 mbar in the atmosphere. In particular, the cosmic ray cascade dissociates N2, a process necessary for the synthesis of nitrogen organics such as HCN. The important interactions of the cosmic ray cascade with the atmosphere are discussed. The N2 excitation and dissociation rates and the ionization rates of the principal atmospheric consituents are computed for a Titan model atmosphere that is consistent with Voyager 1 observations. It is suggested that HCN may be formed efficiently in the lower atmosphere through the photodissociation of methylamine. It is also argued that models of nitrogen and hydrocarbon photochemistry in the lower atmosphere of Titan should include the absorption of galactic cosmic rays as an important energy source.

Capone, L. A.↗
NASA NTRS1984

Photochemistry of the atmosphere of Titan - Comparison between model and observations

Updated chemical schemes and estimates of key rate coefficients are used in the present investigation of the photochemistry of Titan atmosphere C- H- and O-atom containing simple molecules, according to a model incorporating exospheric boundary conditions, vertical transport, and condensation processes at the tropopause. It is suggested that the composition, climatology, and evolution of the Titan atmosphere are controlled by five major processes: CH4 photolysis and photosensitized dissociation, H-to-H2 conversion and hydrogen escape, higher hydrocarbon synthesis, nitrogen and hydrocarbon coupling, and oxygen and hydrocarbon coupling. The model accounts for the minor species concentrations observed by Voyager instruments. Implications of abiotic organic synthesis on Titan for the origin of life on earth are briefly discussed.

Yung, Y. L.↗
NASA NTRS1984

Aerothermodynamic environment and thermal protection for a Titan aerocapture vehicle

This paper presents thermal protection system (TPS) requirements for a potential Titan aerocapture vehicle. Shock-layer solutions are obtained for a nominal trajectory through the current Titan model atmosphere. Fully laminar and fully turbulent solutions are presented along the blunted fore-cone in the windward symmetry plane of a bent-biconic vehicle. Using these solutions to define the aerothermodynamic environment, transient material-response solutions are obtained for a Galileo-type TPS with a carbon-phenolic ablator heat shield. Shock-layer results indicate that turbulent flow is the more realistic flow condition. They also show that the lengthy aerocapture heating pulse is dominated by convective heating. The TPS results show that the required insulation thickness is uniformly about 4 cm along the fore-cone because of the long heat-soak period. The total heat-shield thickness is 6.4 cm at the stagnation point, and 4.7 cm near the end of the fore-cone. These TPS requirements are greater than those presented in a previous Titan aerocapture study.

Green, M. J.↗
NASA NTRS1984

Production and condensation of organic gases in the atmosphere of Titan

The rates and altitudes for the dissociation of atmospheric constituents on Titan are calculated for solar ultraviolet radiation, the solar wind, Saturn magnetospheric particles, the Saturn co-rotating plasma, and cosmic rays. Laboratory experiments show that a variety of simple gas phase organic molecules and more complex organic solids called tholins are produced by such irradiations of simulated Titanian atmospheres. Except for ultraviolet wavelengths longward of the methane photodissociation continuum, most dissociation events occur between about 3100 and 3600 km altitude, corresponding well to the region of EUV opacity detected by Voyager. For a wide variety of simple to moderately complex organic gases in the Titanian atmosphere, condensation occurs below the top of the main cloud deck at about 2825 km. It is proposed that such condensates, begining with CH4 at about 2615 km comprise the principal mass of the Titan clouds. There is a distinct tendency for the atmosphere of Titan to act as a fractional distillation device, molecules of greater complexity condensing out at higher altitudes.

Sagan, C.↗